Classifications

• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
  • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
  • C08J5/005—Reinforced macromolecular compounds with nanosized materials, e.g. nanoparticles, nanofibres, nanotubes, nanowires, nanorods or nanolayered materials
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B82—NANOTECHNOLOGY
  • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
  • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
  • C08J3/00—Processes of treating or compounding macromolecular substances
  • C08J3/20—Compounding polymers with additives, e.g. colouring
  • C08J3/203—Solid polymers with solid and/or liquid additives
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
  • C08K3/00—Use of inorganic substances as compounding ingredients
  • C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
  • C08J2377/00—Characterised by the use of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Derivatives of such polymers
  • C08J2377/04—Polyamides derived from alpha-amino carboxylic acids

Definitions

• Nanocomposites are composite materials that contain particles in the size range of 1-
• These materials bring into play the submicron structural properties of molecules.
• These particles such as clay and carbon nanotubes (CNT) generally have excellent properties, a high aspect ratio, and a layered structure that maximizes bonding between the polymer and particles.
• Adding a small quantity of these additives (0.5-5%) can increase many of the properties of polymer materials, including higher strength, greater rigidity, high heat resistance, higher UV resistance, lower water absorption rate, lower gas permeation rate, and other improved properties (T. D. Fornes, D. L. Hunter, and D. R. Paul, "Nylon-6 nanocomposites from Alkylammonium-modified clay: The role of Alkyl tails on exfoliation," Macromolecules 37, pp. 1793-1798 (2004)).
• Fig. 1 illustrates a schematic diagram of a ball milling apparatus
• Fig. 2 illustrates a flow diagram of manufacturing nylon 11/clay/SEBS/composite resins
• Fig. 3 illustrates a photograph of neat nylon 6 pellets on the left, which are transparent in contrast with nylon 6/CNT pellets on the right.
• Improved mechanical properties of both clay and carbon nanotube (CNT)-reinforced polymer matrix nanocomposites are obtained by pre-treating nanoparticles and polymer pellets prior to a melt compounding process.
• the nanoparticles are coated onto the surface of the polymer pellets by a ball-milling process.
• the nanoparticles thin film is formed onto the surface of the polymer pellets after the mixture is ground for a certain time.
• the ball-milling process 1. Allows nanoparticles to attach onto the surface of the polymer pellets;
• fillers such as graphite particles, carbon fibers, fullerence, carbon nanotubes, and ceramic particles may also be used.
• Nylon 11 pellets were obtained from Arkema Co., Japan (product name: RILSAN).
• Clay was provided by Southern Clay Products, US (product name: Cloisite ® series 93A). It is a natural montmorillonite modified with a ternary ammonium salt.
• both clay and nylon 11 pellets were dried in vacuum oven at 8O 0 C for at least 16 hours to fully eliminate the moisture. Then they were put in a glass container to go through the ball milling process in step 202.
• Fig. 1 is a schematic diagram of a typical ball milling apparatus. The speed of this machine is about 50-60 revolutions per minute. In this method, 5 wt. % and 10 wt. % of the clay powders were chosen for the experiment. The mixture was ground at least half an hour to allow all the clay particles to be attached onto the surface of the nylon 11 pellets. Solvents such as IPA, water, or acetone may be added into the mixture. For comparison, a direct mixing method was also used. The clay and nylon 11 were put in a plastic bag and hand shaken for at least half an hour.
• HAAKE Rheomex CTW 100 twin screw extruder Germany was used to blend nylon 6/clay/SEBS nanocomposites in step 203. Following are the parameters used in this process:
• a quantity of the nylon 11 pellets and clay for each operation is 1 pound because the twin screw needs to be cleaned using the mixture before collecting the composite resin.
• the synthesized resin may make 20 bars by the following injection molding process.
• step 204 the nanocomposite fiber was quenched in water and palletized using a Haake PPl Palletizer POSTEX after extrusion process.
• step 205 the nanocomposite pellets were dried at 7O 0 C prior to the injection molding process to make specimens.
• a Mini-Jector Model 55, Mini- Jector Machinery Corp. Newbury, Ohio, USA laboratory-scale injection molding machine was used in step 206 to make impact bars for physical testing in step 207. Samples were added with specific dimensions using ASTM-specified molds (ASTM D256 for impact strength testing, ASTM D790 for flexural modulus testing). Following are the parameters used:
• the specimens were dried in a desiccator for at least 40 hours' conditioning before the testing process. Flexural modulus and impact of the samples were characterized using Standard 3 -point bending method.
• Table 1 shows the mechanical properties (flexural modulus and impact strength) of the nylon 11/clay/SEBS composites with different weight ratios.
• nylon 11 /clay nanocomposites pre-treated by ball milling process are better than those by the direct mixing process at the same loading of clay .
• Nylon 6 pellets were obtained from UBE Co., Japan (product name: SFl 018A). Clay was provided by Southern Clay Products, US (product name: Cloisite ® series 93A). The carbon nanotubes used in this case were double wall CNTs (DWNTs). DWNTs were obtained from Nanocyl, Inc., Belgium.
• Fig. 3 shows a picture of neat nylon 6 pellets (left) and nylon 6/CNT right. Neat nylon 6 is transparent, while it was black after the ball milling process with CNTs because CNTs have a black color. It means that CNTs were evenly coating onto the surface of the nylon 6 pellets.
• a quantity of the nylon 6 pellets and CNTs for each operation was 1 pound because the twin screw needed to be cleaned using the mixture before collecting the composite resin.
• the synthesized resin made 20 bars by following injection molding process.
• the nanocomposite fiber was quenched in water and palletized using a Haake PPl Palletizer POSTEX after the extrusion process.
• the nanocomposite pellets were dried at 7O 0 C prior to the injection molding process to make specimens.
• a Mini-Jector Model 55, Mini-Jector Machinery Corp. Newbury, Ohio, USA laboratory-scale injection molding machine was used to make impact bars for physical testing. Samples were molded with specific dimensions using ASTM-specified molds (ASTM D638 for tensile strength testing, ASTM D790 for flexural modulus testing). Following are the parameters used:
• nylon 6/CNT nanocomposites pre-treated by the ball milling process were better than those of neat nylon 6.
• Nylon 6/CNT nanocomposites synthesized by melt compounding process hold worse mechanical properties than neat nylon 6 (Dhanote, “Nanocomposites with functionalized carbon nanotubes", Mat. Res. Soc. Symp. Proc. Vol. 788, Ll 1.17.1-L11.17.6).

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• Chemical & Material Sciences (AREA)
• Engineering & Computer Science (AREA)
• Materials Engineering (AREA)
• Chemical Kinetics & Catalysis (AREA)
• Medicinal Chemistry (AREA)
• Polymers & Plastics (AREA)
• Organic Chemistry (AREA)
• Nanotechnology (AREA)
• Health & Medical Sciences (AREA)
• Composite Materials (AREA)
• General Physics & Mathematics (AREA)
• Condensed Matter Physics & Semiconductors (AREA)
• Crystallography & Structural Chemistry (AREA)
• Physics & Mathematics (AREA)
• Manufacturing & Machinery (AREA)
• Compositions Of Macromolecular Compounds (AREA)
• Carbon And Carbon Compounds (AREA)
• Processes Of Treating Macromolecular Substances (AREA)
• Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)

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• 2007
  • 2007-04-03 US US11/695,877 patent/US20070276077A1/en not_active Abandoned
  • 2007-04-04 TW TW096112076A patent/TW200806718A/zh unknown
  • 2007-04-04 WO PCT/US2007/065923 patent/WO2008057623A2/en not_active Ceased
  • 2007-04-04 JP JP2009504437A patent/JP5048053B2/ja not_active Expired - Fee Related

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