WO2008056755A1 - Matériau composite et procédé servant à produire celui-ci - Google Patents
Matériau composite et procédé servant à produire celui-ci Download PDFInfo
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- WO2008056755A1 WO2008056755A1 PCT/JP2007/071751 JP2007071751W WO2008056755A1 WO 2008056755 A1 WO2008056755 A1 WO 2008056755A1 JP 2007071751 W JP2007071751 W JP 2007071751W WO 2008056755 A1 WO2008056755 A1 WO 2008056755A1
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- resin
- fiber
- composite material
- thermoplastic resin
- fibers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
- C08J5/0405—Reinforcing macromolecular compounds with loose or coherent fibrous material with inorganic fibres
- C08J5/042—Reinforcing macromolecular compounds with loose or coherent fibrous material with inorganic fibres with carbon fibres
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
- C08J5/241—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres
- C08J5/243—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres using carbon fibres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2300/00—Characterised by the use of unspecified polymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2369/00—Characterised by the use of polycarbonates; Derivatives of polycarbonates
Definitions
- the present invention relates to a composite material and a manufacturing method thereof.
- the present invention relates to a method for producing a composite material having excellent strength by impregnating a fiber with a resin by heating with microwaves.
- Fiber-reinforced composite materials that use thermoplastic resin as a matrix are widely known.
- F R T P is a pre-predder in which reinforcing fibers are usually impregnated with resin in the form of dispersed pellets, unidirectional pellets, single strands, unidirectional sheets (UD sheets), woven fabrics or non-woven fabrics.
- the pre-preda is processed into structural members and various parts by injection molding, press molding, in-mold molding or filament winding molding.
- thermoplastic resins generally have high viscosity, the amount of adhesion to the fibers is large and non-uniform, and it is difficult to impregnate each fiber with the thermoplastic resin.
- gas force S generated by heating the thermoplastic resin is difficult to dissipate to the outside, and the adhesion between the fiber and the resin tends to be insufficient.
- Fig. 5 shows an example of a continuous fiber impregnation device using a melting method using external heating (the numerical values in the brackets indicate the symbols in Fig. 5).
- This apparatus has a tank (1 1) in which a molten thermoplastic resin (1 2) is accommodated, and the continuous fiber bundle (1) is immersed in the tank (1 1) to form a continuous fiber bundle (1). It is configured to be impregnated with molten resin (1 2). At that time, the viscosity of the thermoplastic resin is lowered by heating (external heating) with a pinch roller (14) so that the fiber bundle is easily impregnated with the thermoplastic resin.
- Patent Document 1 includes a step of continuously pulling a fiber bundle along a curved surface in a solvent while applying tension, and a step of spreading the fiber bundle, and a step of drying the fiber bundle that has been forced to spread.
- a continuous production method of a prepreg sheet comprising a step of impregnating a dried fiber bundle with a molten resin.
- Such a method not only solves the problem of residual solvent, but also solves the inadequate expansion of the fiber bundle when the dry method is used.
- it is difficult to control the quantity ratio between the resin and the fiber and it is difficult to say that sufficient adhesion can be obtained.
- Patent Document 2 a sheet-like continuous carbon fiber spread in parallel in one direction is impregnated with a solution of a resin that is different from a matrix resin and compatible with a matrix resin, and the solution is dried.
- a method for producing a pre-preda in which a sheet-like resin as a matrix resin is stuck without doing so. Since this method uses a resin solution having compatibility with the matrix resin as a paste, there is a drawback that the remaining solvent deteriorates the performance of the composite material.
- Patent Document 3 proposes a method for producing a pre-preda in which a sheet-like continuous carbon fiber expanded in parallel in one direction is pressed and impregnated into a molten thermoplastic resin film. It is difficult to say that this method still has sufficient adhesion.
- Patent Document 4 proposes a method for continuously producing a fiber reinforced plastic in which a flowable plastic is injected perpendicularly to a fiber material in a number of divided flows and collides with the fiber material.
- a flowable plastic is injected perpendicularly to a fiber material in a number of divided flows and collides with the fiber material.
- Patent Document 5 the sizing agent of the woven fabric is washed and removed with a solvent in a pre-preda using the woven fabric as a reinforcing material and a thermoplastic resin as a matrix, and then dried.
- a method for producing a pre-preda characterized in that a thermoplastic resin film is laminated and pressed in a heated state is disclosed. However, even with this method, the adhesion between the resin and the fabric is still not sufficient.
- Patent Document 6 an additive for improving the dielectric loss coefficient is mixed in a matrix resin when a fiber reinforced pre-predder using polypropylene as a matrix resin is heated and melted to perform stamping molding.
- a lamination molding method in which heating and melting is performed by a microphone mouth wave is disclosed.
- the additive in the matrix resin is heated by the microphone mouth wave, and the fiber and the resin in the vicinity thereof cannot be selectively heated. Therefore, since the entire matrix resin needs to be heated to a high temperature in order to lower the resin close to the fiber to a desired melt viscosity, the entire matrix resin may be thermally deteriorated.
- Patent Document 1 Japanese Patent Application Laid-Open No. 5-7-5 6 2 20
- Patent Document 2 Japanese Patent Application Laid-Open No. Sho 5 8-1 6 2 3 1 7
- Patent Document 3 Japanese Patent Application Laid-Open No. 5 9-1 4 9 2 4
- Patent Document 4 Japanese Patent Application Laid-Open No. Sho 6 1-2 8 6 10 07
- Patent Document 5 Japanese Patent Application Laid-Open No. 6 3-5 4 4 4 1
- Patent Document 6 Japanese Patent Laid-Open No. 6 4-3 4 7 3 3 Disclosure of Invention
- An object of the present invention is to provide a method for producing a composite material in which a thermoplastic resin is used as a matrix and is reinforced with conductive fibers.
- An object of the present invention is to provide a method for producing a composite material having a small porosity and good mechanical properties such as flexural strength and flexural modulus.
- An object of the present invention is to provide a method for producing a composite material having excellent adhesion between a thermoplastic resin and conductive fibers.
- An object of the present invention is to provide a method for producing a composite material in which the molecular weight of the matrix resin is not lowered and the hue is hardly degraded.
- An object of the present invention is to provide a method for producing a composite material with little damage to conductive fibers.
- the present invention provides a method for impregnating a conductive fiber with a microphone when impregnating the conductive fiber with a thermoplastic resin. It is based on the finding that when heated by irradiating with a mouth wave, the viscosity of the thermoplastic resin decreases, the thermoplastic resin satisfactorily impregnates the fiber, and the adhesion is improved.
- the heating by the microwave is limited to the local area in the vicinity of the interface between the conductive fiber and the thermoplastic resin, the deterioration of the resin is suppressed as compared with the external heating method in which the entire thermoplastic resin is heated. Based on finding that.
- non-contact heating by microwaves is based on the finding that there is less damage to the fibers compared to the method in which the conductive fibers are brought into contact with the heater.
- the conductive fiber is irradiated with microwaves and heated before impregnating the conductive fiber with the thermoplastic resin, moisture and impurities attached to the fiber can be efficiently removed, and the thermoplastic resin is removed from the fiber. Based on the finding that it can be impregnated well.
- the present invention includes (1) a step of attaching a thermoplastic resin to conductive fibers (A) and (2) a step of irradiating the fibers with microwaves to generate heat and impregnating the fibers with the resin (B) A method for producing a composite material in which a conductive fiber is impregnated with a thermoplastic resin.
- step (A) it is preferable to attach a molten or powdered thermoplastic resin.
- step (B) it is preferable to impregnate the resin using a heating means in combination. It is preferable to include a step (F-1) of opening the conductive fiber before the step (A). Before the step (A), it is preferable to include a step (F-2) of irradiating the conductive fiber with microwaves and heating the fiber. It is preferable to include step (D) of pressurizing the resin after step (B). After the step (B), it is preferable to include a step (step C) of cooling and solidifying the molten resin.
- the conductive fiber is preferably carbon fiber.
- the conductive fiber preferably has a form selected from the group consisting of a strand, a unidirectional (UD) sheet, a woven fabric, and a non-woven fabric.
- the thermoplastic resin is preferably an aromatic polycarbonate resin. It is preferable that the melt volume rate (MVR value) of the aromatic polystrength resin is 70 cm 3 / l 0 min or less.
- the present invention contains conductive fibers and a thermoplastic resin, and has a porosity of 2.6% or less. Includes composite materials. It is preferable that the conductive fiber is substantially unbroken.
- Figure 1 is a schematic diagram of a microwave furnace.
- Fig. 2 shows the relationship between the irradiation time of the microphone mouth wave and the specimen surface temperature when a microwave of 30 to 70 W was induced with the strand fixed using the microwave furnace shown in Fig. 1. It is a graph. In the table, FWD represents the output power of the microwave device, and REW represents the output returned without being absorbed.
- C F carbon fiber
- HTA-12K trade name
- PC polycarbonate resin
- CM 1 00 0 trade name
- Fig. 3 shows the relationship between the microphone mouth wave irradiation time and the sample surface temperature when the microphone mouth wave is guided while the strand is drawn at a speed of 1 to 4 m / min using the apparatus shown in Fig. 1. It is a graph.
- FWD represents the output power of the microwave device
- REW represents the output returned without being absorbed.
- FIG. 4 is a schematic diagram of the steps used in the examples.
- FIG. 5 is a schematic diagram of the process used in the comparative example. Explanation of symbols
- the present invention is a method for producing a composite material in which a conductive fiber is impregnated with a thermoplastic resin. (Conductive fiber)
- Conductive fibers in the present invention are specific resistance 0. 5 QZ cm ⁇ l. 0 X 1 0- 6 QZ cm approximately fibers are preferred. Examples thereof include carbon fiber, metal coated fiber, metal oxide fiber, metal oxide coated fiber, and metal fiber. Of these, carbon fibers are preferred because of their excellent strength and light weight.
- the diameter of the conductive fiber is preferably 6 to 8 m.
- the conductive fiber is preferably a continuous fiber.
- the conductive fiber preferably has a form selected from the group consisting of a strand, a unidirectional (UD) sheet, a woven fabric and a non-woven fabric.
- the strand is preferably a bundle of 11, 2000 to 25, 0,000 fibers having a diameter of 6 to 8 m.
- thermoplastic resin (Thermoplastic resin)
- thermoplastic resin is an aromatic polycarbonate resin, an aromatic polyester resin, an aliphatic polyester resin, a vinyl thermoplastic resin, a methacrylic resin, a polyamide resin, or a polyarylene resin.
- thermoplastic elastomers such as resins, polyolefin resins, and thermoplastic polyurethane elastomers, and thermoplastic polyester elastomers.
- thermoplasticity F is an aromatic polycarbonate resin, an aromatic polyester resin, an aliphatic polyester resin, a vinyl thermoplastic resin, a methacrylic resin, a polyamide resin, or a polyarylene resin.
- thermoplastic elastomers such as resins, polyolefin resins, and thermoplastic polyurethane elastomers, and thermoplastic polyester elastomers.
- Resins can be used alone or in combination of two or more depending on the purpose.
- an aromatic polystrength resin is preferable in that it has good heat resistance, sufficient toughness, strength, and good solubility in a solvent.
- Aromatic polycarbonate resin is usually a variety of aromatic polycarbonate resins with high heat resistance or low water absorption that are polymerized using other divalent phenols in addition to the bisphenol A type poly force—ponate used. There may be.
- the aromatic polycarbonate resin may be produced by any production method, and in the case of interfacial polycondensation, a terminal stopper of monovalent phenols is usually used.
- the aromatic polypone resin can also be a branched polycarbonate resin obtained by polymerizing trifunctional phenols, and can also be an aliphatic dicarboxylic acid, an aromatic dicarboxylic acid, or a divalent aliphatic resin. Alternatively, it may be a copolymer polycarbonate obtained by copolymerizing an alicyclic alcohol.
- the viscosity-average molecular weight of the aromatic polycarbonate resin (M) is preferably 1. 5 X 10 4 ⁇ 4. 0 X 10 4, more preferably 1. 5 X 10 4 ⁇ 3. Ru 8 X 10 4 der.
- the viscosity average molecular weight (M) of the aromatic polycarbonate resin was obtained by inserting the specific viscosity (? 7 SP ) obtained at 20 ° C from a solution of 0.7 g of the polycarbonate resin in 100 ml of methylene chloride into the following equation. Is.
- melt poly U beam rate (MVR value) of the aromatic polycarbonate resin is preferably 70 cmVl 0 minutes or less, more preferably 20 cmVl 0 minutes or less, and most preferably 10 cm 3 / l 0 min or less.
- the above melt volume rate (MVR value) was measured at 300 ° C and 1.2 kg load according to the ISO 1133 standard.
- the present invention is a method for producing a composite material comprising steps (A) and (B). Details of each process will be further described.
- Step (A) is a step of attaching a thermoplastic resin to the conductive fiber.
- the resin is preferably heated to a molten state, or adhered to the fiber surface in the form of a fiber, powder or film that can be easily mixed.
- the step (A) can be performed by immersing the conductive fiber in a tank containing a molten resin.
- Step (B) is a step of irradiating the fiber to which the resin is adhered with microwaves to generate heat and impregnate the fiber with the resin.
- the viscosity of the resin is lowered and the resin is easily impregnated into the fiber.
- the conductive fiber has various irregularities on the surface, but the anchor effect due to the irregularities can be used for the adhesion by contacting with a resin having a fiber strength and a viscosity.
- microwave irradiation the fibers are coated and impregnated with resin more uniformly and strongly.
- the microphone mouth wave is a microphone mouth wave including a millimeter wave having a wavelength of 10 cm or less.
- This microwave can heat conductive fibers typified by carbon fibers and melt the thermoplastic resin at a high temperature. Microwaves are used as a good internal heating means in the present invention.
- the surface temperature of the fiber is preferably in the range of 25 ° C. to 48 ° C., preferably 25 ° C. to 40 ° C., more preferably 3 00 ° C. to 35 ° C. To. If the fiber temperature is within this range, the resin can be impregnated into the fiber.
- the time for heating the fiber by microwave irradiation is preferably in the range of about 0.1 to 100 seconds, more preferably in the range of 0.2 to 60 seconds. If the time is too long, the resin at the interface between the resin and the fiber is thermally deteriorated. If the time is too short, it is difficult to obtain a predetermined adhesion.
- a heating means such as a heat generator or a heat medium.
- the step (B) is preferably performed while pressing the fiber to which the resin is adhered.
- the pressure can be applied while twisting or squeezing. By applying pressure, resin can be supplied between the fibers from the periphery.
- the step (F-1) is a step of opening the conductive fiber.
- the strands of conductive fibers are bundles of 1, 2, 00 to 24, 0, 0 conductive fibers with a diameter of about 7 ⁇ m. If the fibers are not opened widely, the resin will be uniform. Hard to impregnate.
- the bundle of conductive fibers is flattened in a 5 to 10 layer using a roller or air force.
- the step (F-2) is preferably performed before the step (A), and the step (F-2) is preferably performed after the step (F-1).
- Step (F-2) is a step of heating the fibers by irradiating the conductive fibers with microwaves.
- Step (F-2) is a step of removing moisture that causes voids by heating the fibers.
- the conventional method of heating conductive fibers in contact with a hot plate has the disadvantage of damaging the fibers, whereas heating by microwave irradiation in the process (F-2) is non-contact and there is no risk of damaging the fibers. .
- the microwave heating is preferably performed higher than the resin temperature.
- the surface temperature of the conductive fiber is 330 to 3800C.
- step (D) may be performed.
- Step (D) is a step of pressurizing the resin.
- Step (D) is a step of further impregnating the fibers by applying pressure to the low-viscosity resin using the residual heat of microwave heating in step (B).
- the fiber may be squeezed with a roller or shaken. By pulling continuously while twisting, pressure is applied to the fiber and the resin, and the resin is supplied to the bubbles generated by the shrinkage of the void resin.
- step (C) is preferably performed.
- Step (C) is a step of cooling and solidifying the molten resin.
- step (B) a composite material in which the resin is cooled and solidified is obtained. The cooling may be performed at room temperature or forcibly using a medium.
- Process (F-1) to process (C) may be a continuous process using continuous fibers, or may be a batch process. More preferably, it is a continuous process.
- the temperature in the furnace can be controlled, it is possible to carry out steps (F-2) to (D) in one furnace instead of using multiple microwave furnaces.
- the ratio of the thermoplastic resin can be increased by repeating such steps. Steps (F-1) to (C) can be put in the same chamber and performed under reduced pressure.
- the composite material of the present invention contains conductive fibers and a thermoplastic resin, and has a porosity of 2.6% or less.
- the conductive fibers in the composite material are preferably substantially unbroken.
- the conductive fiber and the thermoplastic resin are as described above.
- the amount of conductive fibers in the composite material is preferably 3 to 90% by weight, more preferably 5 to 70% by weight, and more preferably 10 to 60% by weight in 100% by weight of the composite material.
- the bending strength (MPa) was measured according to ISO I78.
- the flexural modulus (MPa) was measured according to ISO I78.
- a polystrength Ponate resin was collected by the following method. That is, the composite material is dissolved in methylene chloride and filtered to separate the conductive fibers and the polyponate resin, and then the polycarbonate methylene chloride solution is dried to form a film. The resin was collected. Next, the viscosity average molecular weight was measured by the method described in the text. The value obtained by subtracting the molecular weight from the molecular weight of the raw material polycarbonate resin powder was evaluated as ⁇ .
- a polycarbonate resin was collected from the composite material produced in each example in the same manner as the measurement of the decrease in molecular weight.
- a solution prepared by dissolving 10 g of the collected polycarbonate resin with 90 g of methylenlide was placed in a glass container with an inner thickness of 1 Omm, a width of 36 mm, and a depth of 42 mm.
- the b value was measured by the transmitted light method using a color analyzer TC-1 80 OMK-II.
- the value obtained by subtracting the b value of the raw material polycarbonate resin measured by the same method was evaluated as the Ab value.
- a microphone mouth-wave furnace was designed to induce irradiation of 5 GHz microwaves. Using this microwave furnace, we improved the temperature distribution so that it could be observed with a thermotracer, examined the angle between the microwave in the furnace and the direction of fiber bundle travel, and leaked the microwave mouth waves at the entrance and exit of the fiber bundle.
- the microwave irradiation device shown in Fig. 1 was fabricated by examining the number and dimensions of the internal step rings of the pipe at the entrance and exit for prevention.
- the fiber bundle receives the micro waveform only once, so the reflected wave in the furnace was used again.
- the reflection adjustment plate (10) was moved to determine the stable heating tuning position where the reflected wave in the furnace could be irradiated again.
- the microwave output (FWD) was changed, the power of the reflected wave (REV) returned was measured, and the energy absorbed by the specimen and the temperature of the specimen were recorded.
- the conductive fiber can be efficiently heated by microphone mouth wave irradiation as shown in Figs. Microwave mouth heating was performed under the same conditions using a preheated 20 ° C to 320 ° C aromatic polystrength Ponate resin, but there was no heat generation and the temperature gradually decreased.
- thermoplastic resin a polystrength Ponate resin powder (manufactured by Teijin Chemicals Ltd., Panlite L-1225WP, viscosity average molecular weight: about 22,500, M "R value: 11 cm 0 min) was used.
- Carbon fiber filament as conductive fiber manufactured by Toho Tenax, HTA-12K (trade name), number of filaments: 12,000, filament diameter: 7 m, fineness: 800 g / l, 000m, tensile strength: 3.92 GPa ) It was used.
- a composite material was manufactured by the following process using the apparatus shown in FIG.
- the numbers in Katsuko indicate the symbols in the figure.
- the carbon fiber filaments were opened through a guide port (2).
- the distance between the guide ports was 600 mm, and the carbon fiber travel speed was about 2 Omm / sec.
- Microwave irradiation: Process (F-2) The opened carbon fiber was passed through a microwave induction furnace (13) for microwave irradiation. The microwave was irradiated for about 0.3 seconds. By this microwave irradiation, the power of the microphone mouth wave and the reflection in the furnace were adjusted up and down by the plunger so that the surface temperature of the carbon fiber in the furnace (measured with an infrared thermotracer) was 330 ° C.
- the carbon fiber was immersed in a polycarbonate molten resin (12) having a temperature of 300 C stored in the tank (11). After soaking, the carbon fiber was squeezed with a pinch roller (14) and then squeezed at the die exit.
- the carbon fiber is removed from the tank (11) by the filament twister.
- Microwave was irradiated through a microwave induction furnace (13) installed in the space up to (15). Heating was performed by adjusting the output and plunger so that the surface temperature was 300 ° C as measured by an infrared thermotracer. Surface temperature is a thermo tracer
- the obtained composite material contained about 15% by weight of carbon fiber in 100% by weight.
- the obtained composite material was cut into 7 cm, dried at 120 ° C for 6 hours, and placed in parallel, and 10 pieces were placed in parallel and hot-pressed under conditions of 300 ° C and 5 kgZ cm 2 for 5 minutes.
- a test piece having an Ommx length of 7 Ommx and a thickness of 4 mm was formed.
- the mechanical strength was measured using the test piece. The results are shown in Table 1.
- a composite material was prepared in the same manner as in Example 1 except that it did not pass through the microwave induction furnace (1 3) installed in the space from the guide roller (2) to the pinch roller (14). A similar evaluation was performed. The results are shown in Table 1.
- a composite material was prepared in the same manner as in Example 2 except that it did not pass through the microwave induction furnace (1 3) installed in the space from the guide roller (2) to the pinch roller (14). A similar evaluation was performed. The results are shown in Table 1.
- Example 1 a composite material was prepared in the same way as in Example 1 except that heating with a pinch roller (14) (external heating) was performed (Fig. 5), and the same evaluation as in Example 3 was performed. Carried out. The results are shown in Table 1.
- Example 5 a composite material was prepared in the same manner as in Example 2 except that heating with a pinch roller (14) (external heating) was performed (Fig. 5), and evaluation similar to that in Example 4 was performed. Carried out. The results are shown in Table 1.
- Table 1 shows that microwave heating is lower than external heating. It can be seen that the porosity is high. Examples 5-8
- a composite material was prepared in the same manner as in Comparative Examples 1 and 2 except that the temperature setting was reduced by 50 ° C., and the same evaluation as in Comparative Examples 1 and 2 was performed. The results are shown in Table 2.
- the production method of the present invention it is possible to produce a composite material having a small residual strain, a low porosity, and good mechanical properties such as bending strength and bending elastic modulus.
- a composite material having excellent adhesion between the matrix resin and the conductive fibers can be produced.
- the conductive fiber can be maintained at a high temperature for a long time with low energy.
- the resin temperature around the conductive fibers rises, it becomes easier to absorb microwaves, and the viscosity of the resin is further lowered and impregnation may be carried out.
- the composite material of the present invention uses a thermoplastic resin as a matrix, it can be subjected to processing such as thermal bending by heating by microwave irradiation, and can also be used for welding processing. Therefore, a plate-like composite material of the present invention can be produced, and various bending processes and cutting processes can be performed according to the purpose, and the processed molded body can be molded in a mold.
- the aggregate of long fibers obtained by cutting a composite material containing continuous fibers can be used for injection molding, injection compression molding, extrusion compression molding, and thermoforming.
- the composite material of the present invention is useful as a molding material and can be used in general industrial fields such as aerospace and automobiles.
Description
Claims
Priority Applications (3)
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JP2008543132A JP5371437B2 (ja) | 2006-11-09 | 2007-11-02 | 複合材料およびその製造方法 |
US12/312,425 US8043669B2 (en) | 2006-11-09 | 2007-11-02 | Composite material and process for the production thereof |
EP07831482.0A EP2080781A4 (en) | 2006-11-09 | 2007-11-02 | COMPOSITE MATERIAL AND PROCESS FOR PRODUCING THE SAME |
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JP2006-303661 | 2006-11-09 | ||
JP2006303661 | 2006-11-09 |
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WO2008056755A1 true WO2008056755A1 (fr) | 2008-05-15 |
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PCT/JP2007/071751 WO2008056755A1 (fr) | 2006-11-09 | 2007-11-02 | Matériau composite et procédé servant à produire celui-ci |
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US (1) | US8043669B2 (ja) |
EP (1) | EP2080781A4 (ja) |
JP (1) | JP5371437B2 (ja) |
CN (1) | CN101511919A (ja) |
WO (1) | WO2008056755A1 (ja) |
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JP2012062428A (ja) * | 2010-09-17 | 2012-03-29 | Nissin Kogyo Co Ltd | 炭素繊維複合材料の製造方法及び炭素繊維複合材料 |
JP2012184286A (ja) * | 2011-03-03 | 2012-09-27 | Teijin Techno Products Ltd | 繊維強化プラスチック及びその製造方法 |
JP2012526885A (ja) * | 2009-05-12 | 2012-11-01 | アルケマ フランス | 繊維基材と、この繊維基材の製造方法と、その使用 |
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JP2016049646A (ja) * | 2014-08-28 | 2016-04-11 | 国立大学法人岐阜大学 | 炭素繊維強化複合材料成形体およびその製造方法、並びに炭素繊維強化複合材料成形体の修復方法 |
JP2016124887A (ja) * | 2014-12-26 | 2016-07-11 | 三菱エンジニアリングプラスチックス株式会社 | 炭素長繊維/ポリカーボネート樹脂複合材料及び炭素長繊維/ポリカーボネート樹脂複合ペレットの製造方法 |
CN113818103A (zh) * | 2015-03-31 | 2021-12-21 | 帝人株式会社 | 碳纤维及碳纤维的制造方法 |
CN113818103B (zh) * | 2015-03-31 | 2024-02-13 | 帝人株式会社 | 碳纤维及碳纤维的制造方法 |
JP2019137863A (ja) * | 2018-02-13 | 2019-08-22 | 日信工業株式会社 | 熱可塑性樹脂組成物の製造方法及び熱可塑性樹脂組成物 |
WO2023054465A1 (ja) * | 2021-09-30 | 2023-04-06 | 三菱瓦斯化学株式会社 | 連続繊維強化熱可塑性樹脂シートの製造方法 |
Also Published As
Publication number | Publication date |
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JP5371437B2 (ja) | 2013-12-18 |
US8043669B2 (en) | 2011-10-25 |
JPWO2008056755A1 (ja) | 2010-02-25 |
CN101511919A (zh) | 2009-08-19 |
EP2080781A4 (en) | 2014-06-11 |
US20100059719A1 (en) | 2010-03-11 |
EP2080781A1 (en) | 2009-07-22 |
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