WO2008026241A1 - Chromatographe en phase gazeuse - Google Patents
Chromatographe en phase gazeuse Download PDFInfo
- Publication number
- WO2008026241A1 WO2008026241A1 PCT/JP2006/316879 JP2006316879W WO2008026241A1 WO 2008026241 A1 WO2008026241 A1 WO 2008026241A1 JP 2006316879 W JP2006316879 W JP 2006316879W WO 2008026241 A1 WO2008026241 A1 WO 2008026241A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- gas chromatograph
- sample
- silicon
- chromatograph according
- concavo
- Prior art date
Links
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N30/00—Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
- G01N30/02—Column chromatography
- G01N30/04—Preparation or injection of sample to be analysed
- G01N30/06—Preparation
- G01N30/12—Preparation by evaporation
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N30/00—Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
- G01N30/02—Column chromatography
- G01N2030/022—Column chromatography characterised by the kind of separation mechanism
- G01N2030/025—Gas chromatography
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N30/00—Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
- G01N30/02—Column chromatography
- G01N30/04—Preparation or injection of sample to be analysed
- G01N30/06—Preparation
- G01N30/12—Preparation by evaporation
- G01N2030/126—Preparation by evaporation evaporating sample
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N30/00—Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
- G01N30/02—Column chromatography
- G01N30/04—Preparation or injection of sample to be analysed
- G01N30/16—Injection
- G01N30/18—Injection using a septum or microsyringe
- G01N2030/185—Injection using a septum or microsyringe specially adapted to seal the inlet
Definitions
- the present invention relates to a gas chromatograph that separates and detects a liquid sample after it is vaporized in a sample vaporizing section.
- FIG. 7 is a schematic diagram of a conventional gas chromatograph.
- Reference numeral 2 denotes a glass insert at the sample introduction portion, and one end of a first-force ram 6 is connected to the tip of the glass insert. The other end of the first power ram 6 is connected to the detector 8.
- a carrier gas introduction pipe 10 is connected to the base end portion of the sample introduction portion, and the carrier gas whose pressure is adjusted is supplied to the base end portion of the sample introduction portion.
- a septum purge channel that discharges part of the carrier gas is also provided at the base end of the sample introduction unit
- sample introduction part 12 are provided.
- the base end of the sample introduction part is sealed with a septum 14.
- One dollar from the sample injector passes through its septum 14 and the tip is inserted into the glass insert 2 where a gaseous sample is injected.
- the outer peripheral portion of the glass insert 2 is covered with a heating block 51, and a glass wool 53 is fixed inside with a graph eye ferrule 55.
- the liquid sample is injected from the upper part of the glass insert 2 through one dollar, flows downward together with the carrier gas, and comes into contact with the glass wool 53.
- Glass wool 53 is heated to about 250 ° C. by heating block 51. Therefore, the liquid sample flowing through the glass wool is heated and vaporized at the same time as being mixed.
- the vaporized sample is branched into the first power ram 6 and the split flow path 11.
- the sample flowing through the column 6 is separated and then detected by the detector 8.
- Non-Patent Document 1 Anal. Chem. 73, 3639-3645 (2001)
- Non-Patent Literature 2 V. Lehmann, The 10th Annual International Worksnop on Micro Mechanical Systems, 1-6, (1996)
- Non-Patent Document 3 Sensor and Actuators 74, 13-17, (1999)
- Non-Patent Document 4 Basics of Silicon Micromachining (M. Elben Spoke, HV Janssen) Published in 2001 p323-326
- Non-Patent Document 5 Henri Jansen et al., J. Micromech. Microeng. 5, 115 (1995)
- Non-Patent Document 6 Latest Trends in Microfabrication Research 6 pl4-p20 2000 Disclosure of Invention
- Glass wool cannot be washed and needs to be replaced, but the size of glass wool may change before and after replacement. In such a case, even if a ferrule is used, it becomes difficult to fix the glass wool at the same position in the glass insert 2 and this affects the reproducibility of the measurement. In addition, the position of the glass wool in the glass insert changes when the carrier gas pressure changes, affecting the reproducibility of the measurement.
- an object of the present invention is to provide a gas chromatograph provided with a sample vaporizing section that can fix the sample vaporizing section and improve reproducibility.
- the gas chromatograph of the present invention includes a base, a flow path formed in the base, a sample vaporization portion formed by microfabrication in the flow path and having a concavo-convex portion for vaporizing a sample, An energy supply unit that supplies energy for heating the unit, a column that is connected to the sample vaporization unit and separates the sample components sent together with the carrier gas from the sample vaporization unit, and is connected to the elution side of the column. And a detector for detecting the eluted sample components.
- the material of the concavo-convex portion is not particularly limited as long as it can absorb energy.
- silicon, inorganic silicon compound, metal, carbon, ceramic, and composite force consisting of two or more of them are selected. One can be mentioned.
- porous silicon can be mentioned.
- the porous silicon can be formed, for example, by anodizing silicon in hydrofluoric acid.
- a pattern having a rectangular cross section formed on the substrate surface can be given.
- the pattern having the rectangular cross section can be formed, for example, by performing deep ion etching on silicon.
- Still another preferred example of the concavo-convex portion is a needle-like protrusion.
- the needle-like protrusions can be formed, for example, by performing anisotropic dry etching on silicon.
- An example of the needle-like protrusion is black silicon.
- the concavo-convex portion As still another preferable example of the concavo-convex portion, a product produced by molding can be mentioned.
- the shape of the concavo-convex portion includes a rectangular cross section, a needle-like protrusion, a circular cross section, and the like. These shapes can also be formed by using injection molding.
- an electrode connected to the concavo-convex part and a power supply device that supplies current to the concavo-convex part via the electrode may be provided.
- the electrode that connects the concavo-convex part to the power supply can be formed by sputtering or vapor deposition.
- an energy source that gives energy by radiation to the concavo-convex part can be cited.
- induction heating (IH) can be cited as an energy source. In this case, it is possible to irradiate energy with both the uneven portion force and the position force at a distance.
- a lens may be provided between the energy source and the concavo-convex portion in order to efficiently irradiate energy by converging energy from the energy source.
- a lens that can converge energy is preferable.
- a condensing lens can be used!
- the substrate constituting the sample vaporizing section is obtained by bonding and bonding at least two substrates, and the flow path can be formed on at least one of the substrates.
- one of the substrates is a silicon substrate and the other is a glass substrate.
- the gas chromatograph of the present invention includes a base, a flow path formed in the base, a sample vaporization section formed by microfabrication in the flow path and having a concavo-convex portion for vaporizing a sample, An energy supply unit that supplies energy to heat the parts is provided, so that glass wool, glass inserts, and the ferrules for fixing the glass wool are not required, and it is not necessary to replace glass wool, glass inserts, and ferrules. And reproducibility of measurement. In addition, the size of the apparatus can be reduced.
- the temperature of the porous silicon can be increased by energizing the porous silicon, and the sample can be vaporized instantaneously. Become.
- FIG. 1 is a schematic perspective view showing one embodiment of a gas chromatograph.
- FIG. 2 is an exploded perspective view of a sample vaporizing section of the same example.
- FIG. 3 is a schematic perspective view showing another embodiment of the gas chromatograph.
- FIG. 4 shows an example of a process flow for forming porous silicon in the sample vaporization section.
- FIG. 5 shows another embodiment of the process flow for forming porous silicon in the sample vaporization section.
- FIG. 6 is a schematic view of a rugged portion formed by processing a stainless steel plate.
- FIG. 7 is a schematic view of a conventional gas chromatograph.
- FIG. 1 is a schematic perspective view of a gas chromatograph.
- the second is a glass insert of the sample introduction part, and one end of the sample vaporization part 4 is connected to the tip of the glass insert!
- the other end of the sample vaporizing unit 4 is connected to one end of a first-force ram 6 via a glass tube 5, and the other end of the first-force ram 6 is connected to a detector 8.
- the first ram 6 is placed in an oven 7 to maintain a constant temperature.
- a carrier gas introduction pipe 10 is connected to the base end of the sample introduction unit, and the carrier gas is adjusted in pressure by a pressure adjustment mechanism (not shown) for adjusting the pressure, and the base end of the sample introduction unit To be supplied to the department.
- a septum purge channel 12 for releasing a part of the carrier gas is also provided at the base end of the sample introduction unit, and a constant channel resistance is provided in the septum purge channel 12. Yes.
- the septum purge flow path 12 is also provided with a pressure sensor 20 for detecting the pressure at the proximal end of the sample introduction part.
- the pressure adjusting mechanism of the carrier gas inlet 10 takes in the detection output of the pressure sensor 20 and adjusts the flow rate of the carrier gas.
- sample injector 16 syringe
- the needle 18 passes through the septum 14 and the tip is inserted into the glass insert 2 where a liquid sample is injected.
- the syringe that injects the sample through the needle 18 is controlled by the sample injector 16 to automatically inject the sample!
- the sample vaporizing section 4 is, for example, a chip, and is formed from a base 22, a channel 24 formed in the base 22, and an uneven portion 26 that is formed in the channel 24 by microfabrication and vaporizes the sample. Become. When the uneven portion 26 is electrically heated, an electrode for connecting the uneven portion 26 and the power supply device 27 is disposed.
- a through hole 28 is provided on the sample introduction part side of the flow path 24, and a through hole 29 is provided on the sample output side of the flow path 24.
- the through hole 29 is connected to the glass tube 5, and the glass tube 5 is provided with a carrier gas introduction tube 11 and a split flow path 13 for discharging a part of the carrier gas.
- the material of the concavo-convex portion 26 can be selected from at least one group force composed of silicon, inorganic silicon compound, metal, carbon, and ceramic, or a composite thereof, but each material was used. The processing method in this case and the shape of the concavo-convex portion 26 will be described later.
- FIG. 2 is an exploded perspective view of the sample vaporizing unit of the same embodiment.
- the glass substrate 21 is a glass substrate and 23 is a silicon substrate. On one side of the silicon substrate 23, a flow path 24 and a through hole 29 to be a sample discharge port of the flow path 24 are formed.
- the glass substrate 21 has a flow path 2
- a through hole 28 to be a sample introduction part 4 is formed.
- a position corresponding to the through hole 28 in the flow path 24 is an uneven portion 26.
- An electrode made of gold or platinum is formed by a sputtering method or the like at a position where the upper surface of the uneven portion 26 and the uneven portion 26 are connected to the external power supply device 27.
- the substrates 21 and 23 are faced and bonded so that the surface on which the flow path 24 is formed is on the inside.
- the upper and lower surfaces of the joined sample vaporizing section 4 are connected to the jig 34, through gaskets 30, 32, respectively.
- the size of the sample vaporization section 4 is not particularly limited, but the length of the substrates 21, 23 is 20 mm X 50mm, the width of the flow path 24 is 2mm, the depth is 0.5mm, the flow path 24 The length is preferably about 30 mm. Further, the diameter of the uneven portion 26 is preferably about 3 mm.
- the oven 7 is set to 150 ° C in order to control the first ram 6 at a constant temperature.
- the uneven portion 26 is energized by the power supply 27 and heated to 250 ° C.
- the carrier gas is supplied so as to be adjusted to a constant pressure, and in that state, about 1 ⁇ L of a liquid sample is injected into the glass insert 2 through the sample injector 16 and the needle 18. It is.
- the liquid sample is instantly vaporized by the heat generated by the concavo-convex portion 26, and is transported through the channel 24 to the sample discharge side by the carrier gas, and branches into the split channel 13 and the capillary column 6 at a split ratio of 200: 1.
- the sample that enters the column 6 that is controlled to a constant temperature by the oven 7 is separated in the column 6 and detected by the detector 8.
- force from the sample injector 16 to inject the liquid sample through the dollar 18 About 1 ⁇ L of the sample is dropped from the sample injection port onto the surface of the concavo-convex portion 26 by an auto sampler, auto injector, micro syringe, etc. You may do it.
- the apparatus configuration of the gas chromatograph is the same as that of the embodiment of FIG. 1, and one end of the sample vaporizing unit 4 is connected to the tip end of the glass insert 2, and the other end of the sample vaporizing unit 4 is connected to the capillary column via the glass tube 5. It is connected to one end of 6 and the other end of the first force ram 6 is led to the detector 8.
- the glass tube 5 is provided with a carrier gas introduction tube 11 and a split flow path 13 for discharging a part of the carrier gas.
- the sample vaporizing section 4 includes a base 22, a channel 24 formed in the base 22, and an uneven portion 26 that is formed in the channel 24 by microfabrication and vaporizes the sample.
- a through hole 28 is provided on the sample introduction side of the flow path 24, and a through hole 29 is provided on the sample discharge side.
- an energy source 31 and a condensing lens 30 that emits light emitted from the energy source 31 are provided in the vicinity of the sample vaporizing part 4.
- the liquid sample is injected from the sample injector 16 into the glass insert 2 via $ 18. Then, it is introduced into the sample vaporizing section 4 together with the carrier gas introduced from the carrier gas introduction pipe 10. Since the uneven portion 26 in the sample vaporizing section 4 is heated to 250 ° C. by the radiant heat from the energy source 31, the liquid sample is vaporized by the heat generated by the uneven portion 26.
- the vaporized sample is transported through the channel 24 to the sample discharge side by the carrier gas, and is branched into the split channel 13 and the first power ram 6 at a split ratio of 200: 1.
- the sample that enters the column 6 controlled to a constant temperature (150 ° C) by the oven 7 is separated in the column and detected by the detector 8.
- the energy emitted from the energy source 31 is N laser or the like.
- Non-Patent Document 1 can be used (see Non-Patent Document 1).
- a YAG laser or an N laser was used.
- electromagnetic induction heating can also be performed using a metallic uneven portion.
- the condensing lens 30 that condenses the energy emitted from the energy source 31 and the energy source 31 magnetic lines of force may be used as the energy source.
- iron, stainless steel, or an alloy thereof it is preferable to use iron, stainless steel, or an alloy thereof as the material of the concave and convex portions.
- Figure 4 shows the process flow for forming porous silicon in the sample vaporization section.
- a silicon substrate 23 is prepared.
- the upper surface of the silicon substrate 23 is thermally oxidized to form a silicon oxide film 41 on the surface of the silicon substrate 23.
- a mask is formed on portions other than the portion corresponding to the flow path 24 on the silicon oxide film 41, and the oxide film pattern 41a is formed on the silicon substrate 23 by photolithography and etching techniques. .
- (H) Ultrasonic processing is performed at a position corresponding to the sample outlet of the flow path 24 to form a through hole 29.
- a sand blast method may be used as another example of the method for forming the through hole.
- through holes 28 are formed at positions corresponding to the concavo-convex portions 26 by a processing method such as a sand blast method.
- bonding may be performed with hydrofluoric acid in a state where a silicon oxide film is formed on the silicon substrate 23.
- FIG. 5 shows another process flow for forming porous silicon on a chip as a sample vaporizing section, showing a cross-sectional view on the left side and a top view on the right side.
- a silicon oxide film 41 is formed on the surface of the silicon substrate 23 by thermally oxidizing the upper surface of the silicon substrate 23.
- a resist (not shown) is applied on the silicon oxide film 41, and a resist pattern is formed by photolithography using the mask 42 shown in (C2).
- the mask 42 has a pattern for forming a sample vaporization portion on the substrate 23.
- the black portion is a portion where a Cr film is present, and the white portion is a light transmission portion.
- the silicon oxide film 41 is etched to form a silicon oxide film pattern 44 on the silicon substrate 23.
- the flow path 24 is formed on the silicon substrate 23 by subjecting the uneven portion 26 side force to photolithography and ion etching.
- a Ti film and a Pt film are formed on the surface of the concavo-convex portion 26 and the silicon substrate 23 by sputtering through a mask, and a thickness of 30 nm is formed by forming a Ti film as a lower layer and a Pt film as an upper layer. Electrode 45 is formed.
- a through hole 29 is formed on the sample discharge side of the flow path 24 by a sandblast method.
- the upper surface of the silicon substrate 23 is bonded to the glass substrate 21 in which the through hole 28 is formed on the sample introduction side of the flow path 24.
- a silicon oxide film is formed on the upper surface of the silicon substrate 23 by sputtering, and bonded to the glass substrate 21 by hydrofluoric acid.
- the uneven portion 26 can also be formed by anisotropic dry etching. For example, if a black surface method (see Non-Patent Document 4) is used, needle-shaped protrusions (Black Silicon (see Non-Patent Document 5) are used on a silicon substrate. ;))) can be formed.
- a black surface method see Non-Patent Document 4
- needle-shaped protrusions Black Silicon (see Non-Patent Document 5) are used on a silicon substrate. ;))
- the applied power is set to 50 W
- the etching pressure is set to 2.7 Pa
- the SF gas flow rate is set to 20 sccm
- the O gas flow rate is set to 15 ccm.
- the concavo-convex part is produced by a metal powder injection molding method.
- metal powder for example, metal powder
- Non-Patent Document 6. Stainless steel, ceramic, iron, titanium, titanium alloy, iron-nickel alloy, tungsten alloy or a mixture thereof) and plastic noder, and after injection molding, degrease and sinter to complete the metal irregularities ( See Non-Patent Document 6.) 0
- the material of the concavo-convex portion 26 is not limited to silicon, but may be any material that absorbs the wavelength of the laser used.
- Si is formed on the concavo-convex part 26 and inorganic key
- the sample vaporizing section 4 can be easily formed by bonding the silicon substrate 23 and the glass substrate 21, but a substrate made of other materials such as a stainless steel substrate can also be used. As an example, a structure (for example, porous silicon) that becomes an uneven portion is placed on a stainless steel plate in which a channel is formed in advance.
- FIG. 6 is a schematic view in which a rugged portion is formed by processing a stainless steel plate.
- a stainless steel jig 34 in which the through hole 35 is formed and a stainless steel jig 36 in which the through hole 37 and the flow path 24 are formed are joined so as to sandwich the flow path 24.
- a part of the flow path 24 is an uneven portion 26 and is connected to a power supply device 27.
- the microstructure 26, the flow path 24, and the through holes 35, 37 can be made by electrical discharge machining, and the jigs 34, 36 should be fixed by welding, crimping, brazing, or adhesive. I can do it.
- the concave and convex portions 26 and the flow paths 24 are formed by covering the stainless steel substrate itself.
- the present invention can be used in a gas chromatograph that separates and detects a liquid sample after it is vaporized in a sample vaporizing section.
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- Life Sciences & Earth Sciences (AREA)
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- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Sampling And Sample Adjustment (AREA)
- Other Investigation Or Analysis Of Materials By Electrical Means (AREA)
- Micromachines (AREA)
Description
Claims
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US12/439,159 US8196450B2 (en) | 2006-08-28 | 2006-08-28 | Gas chromatograph |
JP2008531901A JP4849127B2 (ja) | 2006-08-28 | 2006-08-28 | ガスクロマトグラフ |
PCT/JP2006/316879 WO2008026241A1 (fr) | 2006-08-28 | 2006-08-28 | Chromatographe en phase gazeuse |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/JP2006/316879 WO2008026241A1 (fr) | 2006-08-28 | 2006-08-28 | Chromatographe en phase gazeuse |
Publications (1)
Publication Number | Publication Date |
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WO2008026241A1 true WO2008026241A1 (fr) | 2008-03-06 |
Family
ID=39135533
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2006/316879 WO2008026241A1 (fr) | 2006-08-28 | 2006-08-28 | Chromatographe en phase gazeuse |
Country Status (3)
Country | Link |
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US (1) | US8196450B2 (ja) |
JP (1) | JP4849127B2 (ja) |
WO (1) | WO2008026241A1 (ja) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2009118825A1 (ja) * | 2008-03-25 | 2009-10-01 | 株式会社島津製作所 | ガスクロマトグラフ |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102007052500A1 (de) * | 2007-11-02 | 2009-06-04 | Helmholtz Zentrum München Deutsches Forschungszentrum Für Gesundheit Und Umwelt (Gmbh) | Verfahren und Vorrichtung für den Nachweis von mindestens einer Zielsubstanz |
TW201231968A (en) * | 2011-01-28 | 2012-08-01 | Univ Nat Taiwan Normal | Analysis and detection device |
WO2013021067A1 (en) * | 2011-08-11 | 2013-02-14 | Dsm Ip Assets B.V. | Multi-mode gas chromatography injector |
CN104483423B (zh) * | 2014-12-31 | 2016-03-09 | 同方威视技术股份有限公司 | 样品采集和热解析进样装置和方法以及痕量检测设备 |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5240195U (ja) * | 1975-09-13 | 1977-03-22 | ||
JPS58182156U (ja) * | 1982-05-31 | 1983-12-05 | 株式会社島津製作所 | ガスクロマトグラフの試料気化室 |
JPS59120956A (ja) * | 1982-12-28 | 1984-07-12 | Shimadzu Corp | ガスクロマトグラフ |
JPH0694691A (ja) * | 1991-11-29 | 1994-04-08 | Shimadzu Corp | スプリットインジェクタ |
JPH0943215A (ja) * | 1995-07-28 | 1997-02-14 | Shimadzu Corp | ガスクロマトグラフ装置 |
JPH1151920A (ja) * | 1997-08-05 | 1999-02-26 | Shimadzu Corp | ガスクロマトグラフ装置 |
JP2001235458A (ja) * | 2000-02-23 | 2001-08-31 | Shimadzu Corp | ガスクロマトグラフ装置 |
Family Cites Families (5)
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JPS5240195A (en) * | 1975-09-25 | 1977-03-28 | Hitachi Ltd | Gas chromatography |
JPS58182156A (ja) * | 1982-04-16 | 1983-10-25 | Sanyo Electric Co Ltd | デイスク再生装置 |
US5313832A (en) * | 1991-12-23 | 1994-05-24 | Ford Motor Company | Composite mass air flow sensor |
GB9203463D0 (en) * | 1992-02-19 | 1992-04-08 | Applied Res Lab | Method and apparatus for analytical sample preparation |
WO2006033348A1 (ja) * | 2004-09-22 | 2006-03-30 | National University Corporation Tokyo University Of Agriculuture And Technology | 標識酵素 |
-
2006
- 2006-08-28 US US12/439,159 patent/US8196450B2/en not_active Expired - Fee Related
- 2006-08-28 WO PCT/JP2006/316879 patent/WO2008026241A1/ja active Application Filing
- 2006-08-28 JP JP2008531901A patent/JP4849127B2/ja active Active
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
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JPS5240195U (ja) * | 1975-09-13 | 1977-03-22 | ||
JPS58182156U (ja) * | 1982-05-31 | 1983-12-05 | 株式会社島津製作所 | ガスクロマトグラフの試料気化室 |
JPS59120956A (ja) * | 1982-12-28 | 1984-07-12 | Shimadzu Corp | ガスクロマトグラフ |
JPH0694691A (ja) * | 1991-11-29 | 1994-04-08 | Shimadzu Corp | スプリットインジェクタ |
JPH0943215A (ja) * | 1995-07-28 | 1997-02-14 | Shimadzu Corp | ガスクロマトグラフ装置 |
JPH1151920A (ja) * | 1997-08-05 | 1999-02-26 | Shimadzu Corp | ガスクロマトグラフ装置 |
JP2001235458A (ja) * | 2000-02-23 | 2001-08-31 | Shimadzu Corp | ガスクロマトグラフ装置 |
Non-Patent Citations (2)
Title |
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HYNES A.M. ET AL: "Resent advances in silicon etching for MEMS using the ASE process", SENSORS AND ACTUATORS A, vol. 74, 1999, pages 13 - 17, XP004167996 * |
LEHMANN V.: "Porous Silicon - A New Material for Mems", IEEE THE 9TH ANNUAL INTERNATIONAL WORKSHOP ON MICRO ELECTRO MECHANICAL SYSTEMS, 24 May 1996 (1996-05-24), pages 1 - 6, XP000689241 * |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2009118825A1 (ja) * | 2008-03-25 | 2009-10-01 | 株式会社島津製作所 | ガスクロマトグラフ |
JPWO2009118825A1 (ja) * | 2008-03-25 | 2011-07-21 | 株式会社島津製作所 | ガスクロマトグラフ |
JP4840532B2 (ja) * | 2008-03-25 | 2011-12-21 | 株式会社島津製作所 | ガスクロマトグラフ |
Also Published As
Publication number | Publication date |
---|---|
US8196450B2 (en) | 2012-06-12 |
US20090255322A1 (en) | 2009-10-15 |
JPWO2008026241A1 (ja) | 2010-01-14 |
JP4849127B2 (ja) | 2012-01-11 |
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