WO2006062432A1 - Procede de production de semi-coke metallurgique - Google Patents
Procede de production de semi-coke metallurgique Download PDFInfo
- Publication number
- WO2006062432A1 WO2006062432A1 PCT/RU2005/000162 RU2005000162W WO2006062432A1 WO 2006062432 A1 WO2006062432 A1 WO 2006062432A1 RU 2005000162 W RU2005000162 W RU 2005000162W WO 2006062432 A1 WO2006062432 A1 WO 2006062432A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- coal
- semicoke
- layer
- air
- daf
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B49/00—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated
- C10B49/02—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with hot gases or vapours, e.g. hot gases obtained by partial combustion of the charge
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B53/00—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
- C10B53/08—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form in the form of briquettes, lumps and the like
Definitions
- the invention relates to the field of semi-coke production and can be used in metallurgy.
- a known method of producing semicoke by distillation of solid carbon-containing raw materials in a vertical shaft-type autothermal apparatus using air blasting including the stages of heating, drying and carbonation of the raw material, unloading the resulting semicoke from the bottom and the selection of combustible gas, and a product combustible gas having an exit temperature is added to the air blast from the apparatus, in a concentration not exceeding the lower limit of gas ignition, with the addition of about 8-10% of the gas from the volume of the resulting combustible ha to the air blast for, with a carbonization temperature of 920-950 degrees C, and air blast is fed from the opposite side of the coal ignition with a specific flow rate of 100-400 cubic meters / sq.m. (RU 2169166C1, class C10B49 / 04, 20.06.2001) .
- the closest to the claimed method according to the achieved result and technical essence is a method for producing a carbon adsorbent in a vertical shaft-type apparatus with internal heating by burning volatiles and part of the carbon residue in a coal layer blown by an air stream (RF patent JVs 2014883).
- the method involves igniting a layer of coal from the side opposite to the supply of air blast.
- the combustion front is shifted towards the air flow, and behind the front there is a solid residue containing unburned carbon.
- the coal layer successively passes through the stages of heating, drying and carbonization.
- the gas-vapor mixture of carbonization products, as well as part of the solid carbon residue react with oxygen to exhaust it, forming a combustion front with a temperature of 750-900 degrees C.
- a zone of reduction of combustion products (CO 2 and H 2 O) to carbon monoxide forms behind the combustion front and hydrogen.
- Combustible gas DEPARTURED from the apparatus for subsequent processing and use.
- the solid residue has a high internal porosity (over 60%), which provides high sorption activity of the product and its subsequent use as an adsorbent.
- the resulting product despite being close in chemical composition to the metallurgical semi-coke, has a limited scope in metallurgy due to the high content of fine fractions, low density and high ash content. High porosity significantly reduces the strength of the carbon residue.
- the disadvantage is the reduced specific yield of the solid product due to the large burn of the carbon-containing feedstock.
- the invention solves the problem of improving the quality of the resulting solid product that meets the requirements for metallurgical semi-coke.
- the technical result when using the invention is to obtain a solid product having higher strength and density, lower ash content, as well as more large average piece size and in increasing the specific yield of solid product.
- the specified technical result is achieved by the fact that coal of a fraction of 20-70 mm is used as a coal layer, and air is supplied through a coal layer with a specific flow rate of 70-99.5 cubic meters / sq.m., depending on the type of coal.
- a method of producing a metallurgical semi-coke is as follows.
- crushed coal of a fraction of 20-70 mm is loaded to its full height, air blasting with a specific flow rate of 70 to 99.5 cubic meters / sq.m. (depending on the type of coal) is fed and a layer of coal is ignited with side opposite to the supply of blast.
- the formed carbonization front with a constant speed is shifted towards the air flow, and behind the front there is a layer of hot semicoke.
- coal successively passes through the stages of heating, drying, and pyrolysis.
- the combustible components of the pyrolysis products are completely burned up in atmospheric oxygen with the formation of carbon dioxide and water vapor, and then, by reduction on the hot surface of the coke, they turn into combustible components of the gas (carbon monoxide and hydrogen), which does not contain pyrolysis products. After the carbonization front reaches the side of the layer opposite to the ignition side, the process ends. The semicoke layer is cooled and discharged from the bottom of the vertical apparatus.
- the velocity of the combustion front was 11.5 cm / h
- the specific yield of semicoke is 42.4 kg / sq.m.
- the yield of semicoke is 48.6%
- the output of combustible gas is 165 cubic meters / sq.m.
- the apparent density of the semicoke is 0.68 g / cu. m
- the structural strength of the semicoke is 74.8%
- the velocity of the combustion front was 9.2 cm / h
- the specific yield of semicoke is 27.7 kg / sq.m.
- the output of combustible gas is 100.2 cubic meters / sq.m.
- the specific heat of combustion of the raw gas is 2.32 MJ / cubic meter
- Ash content of semicoke, A I 5%
- the density of the semicoke is 0.45 g / cu. m
- the proposed method allows to obtain a solid product having higher strength and density, lower ash content, as well as a larger average piece size, and in increasing the specific yield of the solid product (see table).
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Combustion & Propulsion (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Solid Fuels And Fuel-Associated Substances (AREA)
- Carbon And Carbon Compounds (AREA)
- Coke Industry (AREA)
Description
Claims
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
SK5085-2007A SK288409B6 (sk) | 2004-12-03 | 2005-04-01 | Spôsob výroby kusového polokoksu |
DE112005003101T DE112005003101T5 (de) | 2004-12-03 | 2005-04-01 | Verfahren zur Erzeugung von Halbkoks-Stücken |
AU2005312364A AU2005312364B2 (en) | 2004-12-03 | 2005-04-01 | Method for producing lump semicoke |
UAA200707395A UA83961C2 (ru) | 2004-12-03 | 2005-04-01 | Способ получения металлургического полукокса |
US11/792,276 US20080190754A1 (en) | 2004-12-03 | 2005-04-01 | Method for Producing Lump Semicoke |
CA002589727A CA2589727A1 (en) | 2004-12-03 | 2005-04-01 | Method for producing lump semicoke |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
RU2004135326 | 2004-12-03 | ||
RU2004135326/04A RU2275407C1 (ru) | 2004-12-03 | 2004-12-03 | Способ получения металлургического полукокса |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2006062432A1 true WO2006062432A1 (fr) | 2006-06-15 |
Family
ID=36578172
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/RU2005/000162 WO2006062432A1 (fr) | 2004-12-03 | 2005-04-01 | Procede de production de semi-coke metallurgique |
Country Status (9)
Country | Link |
---|---|
US (1) | US20080190754A1 (ru) |
AU (1) | AU2005312364B2 (ru) |
CA (1) | CA2589727A1 (ru) |
CZ (1) | CZ305766B6 (ru) |
DE (1) | DE112005003101T5 (ru) |
RU (1) | RU2275407C1 (ru) |
SK (1) | SK288409B6 (ru) |
UA (1) | UA83961C2 (ru) |
WO (1) | WO2006062432A1 (ru) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
RU2008143627A (ru) * | 2008-11-06 | 2010-05-20 | Закрытое Акционерное Общество "Карбоника-Ф" (Ru) | Способ переработки угля и устройство для его осуществления |
RU2666420C1 (ru) | 2017-11-20 | 2018-09-07 | Общество с ограниченной ответственностью "Объединенная Компания РУСАЛ Инженерно-технологический центр" | Способ получения восстановителя для производства технического кремния |
RU2722557C2 (ru) * | 2018-04-11 | 2020-06-01 | Сергей Григорьевич Степанов | Способ переработки угля |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4883499A (en) * | 1988-05-06 | 1989-11-28 | Beierle Frederick P | Process adapted to produce synthesis gas and activated carbon from organic input material |
RU2014882C1 (ru) * | 1992-11-11 | 1994-06-30 | Исламов Сергей Романович | Способ получения адсорбента |
RU2169166C1 (ru) * | 2000-07-06 | 2001-06-20 | ЗАО "Карбоника-Ф" | Способ получения полукокса |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB369394A (en) * | 1931-03-20 | 1932-03-24 | Hugh Edward Powell | Improvements in or relating to processes for the production of smokeless fuel |
US2996437A (en) * | 1957-01-30 | 1961-08-15 | Otto & Co Gmbh Dr C | Process and device for coking of fuels |
US3272721A (en) * | 1963-11-21 | 1966-09-13 | Harvey Aluminum Inc | Process for desulfurizing and coking high sulfur content coal |
US3355363A (en) * | 1964-02-14 | 1967-11-28 | Stanley J Gasior | Method of producing a nonagglomerating char from a strongly caking coal |
US3525674A (en) * | 1966-05-23 | 1970-08-25 | Barnebey Cheney Co | Submerged combustion carbonization |
DE1921710A1 (de) * | 1969-04-29 | 1971-01-28 | Rheinische Braunkohlenw Ag | Verfahren und Vorrichtung zur Verkokung von Braunkohle,insbesondere von Rohbraunkohle |
US4201655A (en) * | 1976-12-17 | 1980-05-06 | Continental Oil Company | Process for making metallurgical coke |
FI60402C (fi) * | 1978-11-28 | 1982-01-11 | Outokumpu Oy | Foerfarande och anordning foer framstaellning av koks eller aktivt kol fraon fuktig organisk substans |
CS215714B1 (cs) * | 1980-01-25 | 1982-09-15 | Petr Buryan | Způsob výroby smolného koksu |
DE3614757A1 (de) * | 1985-05-06 | 1987-11-05 | Didier Eng | Verfahren, gefaess und anlage zur erzeugung von koks |
RU2014883C1 (ru) * | 1993-08-16 | 1994-06-30 | Исламов Сергей Романович | Способ получения углеродного адсорбента |
CZ287437B6 (cs) * | 1995-02-20 | 2000-11-15 | Miloslav Ing. Vítek | Způsob kontinuální výroby černouhelného polokoksu |
AU757941C (en) * | 1998-07-29 | 2004-02-12 | Kawasaki Steel Corporation | Method for producing metallurgical coke |
JP4608752B2 (ja) * | 1999-10-20 | 2011-01-12 | Jfeスチール株式会社 | 高炉用高反応性高強度コークスおよびその製造方法 |
-
2004
- 2004-12-03 RU RU2004135326/04A patent/RU2275407C1/ru active
-
2005
- 2005-04-01 AU AU2005312364A patent/AU2005312364B2/en not_active Ceased
- 2005-04-01 UA UAA200707395A patent/UA83961C2/ru unknown
- 2005-04-01 US US11/792,276 patent/US20080190754A1/en not_active Abandoned
- 2005-04-01 CA CA002589727A patent/CA2589727A1/en not_active Abandoned
- 2005-04-01 CZ CZ2007-437A patent/CZ305766B6/cs not_active IP Right Cessation
- 2005-04-01 SK SK5085-2007A patent/SK288409B6/sk not_active IP Right Cessation
- 2005-04-01 DE DE112005003101T patent/DE112005003101T5/de not_active Ceased
- 2005-04-01 WO PCT/RU2005/000162 patent/WO2006062432A1/ru active Application Filing
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4883499A (en) * | 1988-05-06 | 1989-11-28 | Beierle Frederick P | Process adapted to produce synthesis gas and activated carbon from organic input material |
RU2014882C1 (ru) * | 1992-11-11 | 1994-06-30 | Исламов Сергей Романович | Способ получения адсорбента |
RU2169166C1 (ru) * | 2000-07-06 | 2001-06-20 | ЗАО "Карбоника-Ф" | Способ получения полукокса |
Also Published As
Publication number | Publication date |
---|---|
US20080190754A1 (en) | 2008-08-14 |
CZ2007437A3 (cs) | 2007-09-26 |
AU2005312364B2 (en) | 2010-08-05 |
UA83961C2 (ru) | 2008-08-26 |
CA2589727A1 (en) | 2006-06-15 |
CZ305766B6 (cs) | 2016-03-09 |
RU2275407C1 (ru) | 2006-04-27 |
AU2005312364A1 (en) | 2006-06-15 |
SK50852007A3 (sk) | 2008-01-07 |
SK288409B6 (sk) | 2016-10-03 |
DE112005003101T5 (de) | 2007-10-31 |
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