WO2005100832A1 - Metal vent - Google Patents
Metal vent Download PDFInfo
- Publication number
- WO2005100832A1 WO2005100832A1 PCT/US2005/012294 US2005012294W WO2005100832A1 WO 2005100832 A1 WO2005100832 A1 WO 2005100832A1 US 2005012294 W US2005012294 W US 2005012294W WO 2005100832 A1 WO2005100832 A1 WO 2005100832A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- membrane
- vent
- aperture
- bearing surface
- shell
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16K—VALVES; TAPS; COCKS; ACTUATING-FLOATS; DEVICES FOR VENTING OR AERATING
- F16K24/00—Devices, e.g. valves, for venting or aerating enclosures
- F16K24/04—Devices, e.g. valves, for venting or aerating enclosures for venting only
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03B—APPARATUS OR ARRANGEMENTS FOR TAKING PHOTOGRAPHS OR FOR PROJECTING OR VIEWING THEM; APPARATUS OR ARRANGEMENTS EMPLOYING ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ACCESSORIES THEREFOR
- G03B17/00—Details of cameras or camera bodies; Accessories therefor
- G03B17/02—Bodies
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K5/00—Casings, cabinets or drawers for electric apparatus
- H05K5/02—Details
- H05K5/0213—Venting apertures; Constructional details thereof
- H05K5/0216—Venting plugs comprising semi-permeable membranes
Definitions
- Vents find use in many applications.
- electrical component housings, gear housings, brake housings and even vehicle bodies use vents to equalize pressure between the housing or body interior and the surrounding environment.
- the function of the vent is not bulk flow for pressure equalization, but diffusion for the purpose of transporting select components across the media, such as the diffusion of water across a media for moisture control.
- the driving force is not pressure, but temperature, osmotic pressure, electrostatic attraction or repulsion, or some other driving force.
- Vents are also used in many other applications, such as electrical and mechanical equipment housings or chemical containers. Such housings, enclosures or containers are collectively referred to herein as a "housing.”
- vents must not only be gas permeable to allow for pressure equalization, but also be liquid impermeable to seal the interior of a housing from moisture, liquids or contaminants, which can damage internal equipment or components and corrode the housing.
- Press fitted vents containing a molded polymer or plastic body and a porous membrane formed from polytetrafluoroethylene (PTFE), polypropylene or polyethylene are known.
- PTFE polytetrafluoroethylene
- Known polymer vents are used as air vent devices in, for example, a breather valve, a filter, a diaphragm device, etc.
- Press fitted vents typically include a membrane with circumferentially located holes that are positioned between rigid resin portions bound together through the circumferentially located holes. This rigid member is encompassed by a soft resin to form the press fitted article.
- Many other configurations of molded polymer or plastic vents are known, however, all suffer significant shortcomings.
- Metal vents are known to provide improved durability in some applications.
- known metal vents rely on some form of sealant, adhesive or gasket to seal the membrane to the vent. These sealants and gaskets are also subject to degradation, and may not be useful at high temperatures.
- the invention provides a vent consisting essentially of a metal body comprising an aperture for the passage of a fluid, a first membrane bearing surface surrounding the aperture and a second membrane bearing surface surrounding the aperture and a membrane having a first side in contact with the first membrane bearing surface and a second side in contact with the second membrane bearing surface, wherein an interfering relation between the membrane, the first membrane bearing surface and the second membrane bearing surface forms a seal surrounding the aperture.
- the invention provides a vent consisting essentially of a metal body having an aperture for the passage of a fluid and a membrane bearing surface surrounding the aperture; a membrane covering the aperture and having a first side in contact with the first membrane bearing surface and a second side opposite the first side; a metal shell having a second membrane bearing surface, the second membrane bearing surface in contact with the second side of the membrane and the shell attached to the body by an interference fit to form a seal surrounding the aperture.
- the invention provides a device comprising: a housing; a port in the housing; and a vent disposed over the port, the vent consisting essentially of: a metal body having an aperture for passage of a gas; a membrane spanning the aperture; and a metal shell having a perforation therein for the passage of a gas, the shell attached to the body by an interference fit to form a seal between the membrane and the body, the seal surrounding the aperture.
- the invention provides a method of making a vent, comprising the steps of: providing a metal housing including an aperture therethrough for the passage of a gas, covering the aperture with a membrane such that the membrane contacts the housing, attaching a cover having a perforation therein to the housing by an interference fit such that the cover contacts the membrane, whereby a seal is formed between the membrane and the housing.
- Fig. 1 is a cross sectional view of a vent in accordance with the present invention.
- Fig. 2 is a detailed perspective view of a vent in accordance with the present invention shown in partial cut-away.
- Fig. 3 shows another aspect of a vent in accordance with the present invention.
- Figs. 4-6 show another embodiment of a vent in accordance with the present invention in which an insert is placed in a housing and the vent is pressed into the insert.
- Figs. 7-8 show another embodiment of a vent in accordance with the present invention in which the vent is adapted to be secured to a housing using a locking ring.
- Fig. 9 shows another embodiment of a vent in accordance with the present invention in which the vent comprises only a membrane sealed between two metal parts.
- Fig. 10 shows another embodiment of a vent in accordance with the present invention in which the vent body comprises a single metal part.
- the vent provides pressure equalization for a housing, such as an equipment enclosure for mechanical or electrical equipment, or a chemical enclosure.
- the vent comprises an all metal body with a metal shell or cap.
- the vent body includes an aperture providing fluid communication between the enclosure and the atmosphere.
- a vapor permeable, liquid impermeable membrane spans the aperture, allowing gaseous communication between the enclosure and the atmosphere, but preventing ingress of liquids or other contaminants.
- the metal shell may be adapted to protect the membrane and include perforations to provide fluid communication between the atmosphere and the membrane.
- the shell and vent body are uniquely assembled using only an interference fit.
- the membrane is compressed between an upper membrane bearing surface on the shell and a lower membrane bearing surface on the vent body. Compression of the membrane seals the membrane over the aperture.
- This novel construction provides an extremely rugged and durable vent that avoids the use of sealants, adhesives or gaskets and the like, which may degrade over time and when subjected to harsh environments.
- Metal construction also advantageously permits the use of vents in accordance with the present invention in high temperature applications, such as in lighting enclosures. It is advantageous that lighting equipment, particularly emergency lighting equipment, be listed by Underwriters Laboratories ("UL"). Molded plastic and other non metallic vents typically cannot meet UL standards for fire protection lighting. Furthermore, metal construction can be more cost effective for limited commercial production than polymer construction because of the cost and complexity of plastic injection and extrusion molding.
- UL Underwriters Laboratories
- the metal vent body includes an elongated root for insertion into the housing and a flared head for holding the membrane.
- An aperture extends through the vent body from root to head, providing fluid communication between the housing and the atmosphere.
- the root of the vent body may be of any shape, but typically is cylindrical to match vent holes drilled or formed into a housing.
- the root may be tapered at its end to facilitate insertion or to permit the vent to be driven into the housing.
- threads may be cut or rolled into the outside of the root which cooperate with a tapped hole in the housing.
- a variety of other securing mechanisms may also be incorporated into the root to retain the vent.
- a groove may be incorporated in the root to receive a snap ring to retain the vent.
- a locking ring could be pressed onto the root after insertion into the housing.
- the root is threaded to match a tapped hole in the housing.
- the head of the vent body includes a lower membrane bearing surface.
- the membrane bearing surface is typically round to match a cylindrical aperture, but may be of any shape and size to suit the application.
- the membrane bearing surface surrounds the aperture.
- the shape of the head of the vent body is not critical; it may be cylindrical or of any other shape depending on the application.
- the head may include a hexagonal part, so that a wrench can be used to drive a threaded vent into a tapped housing.
- the aperture may be machined or formed into the vent body and may be straight, tapered or of any other configuration.
- the aperture may be a tapered hole, which is narrow at the root and gradually increases in diameter in the direction of the top. Alternatively, the hole diameter may increase incrementally, with the diameter at the shaft typically being narrower than at the top. The larger area near the head permits a larger membrane to be used, which may improve venting in some applications.
- the Shell is of all metal construction and is adapted to be secured to the vent body by an interference fit.
- the shell is cylindrical to match a similarly-shaped a vent body head.
- the shell is adapted to protect the membrane from physical damage and liquid exposure and is perforated to allow a gas to pass through it.
- the shell includes an upper membrane bearing surface.
- the upper membrane bearing surface cooperates with the lower membrane bearing surface on the vent body to compress the membrane. Compression of the membrane seals the aperture to prevent ingress of liquid and contaminants.
- the upper and lower membrane bearing surfaces are adapted to maximize compression of the membrane.
- the bearing surfaces may be configured to minimize contact area.
- a ridge or other protrusion may be incorporated into the membrane bearing surface of the shell or the vent body to minimize membrane contact area and increase compressive force per unit area.
- the choice of metallic materials for the vent body and shell are not critical and those of skill in the art will understand that material selection will vary with the application.
- the vent is constructed of a stainless steel.
- the stainless steel may be an alloy comprising nickel, chromium, vanadium, molybdenum or manganese and combinations thereof.
- the membrane is porous.
- the membrane is formed from expanded polytetrafluoroethylene (ePTFE).
- ePTFE expanded polytetrafluoroethylene
- Exemplary ePTFE materials may be prepared in accordance with the methods described in U.S. Patent Nos.
- Porous ePTFE membranes may also be prepared by other methods.
- Porous ePTFE comprises a porous network of polymeric nodes and interconnecting fibrils and is commercially available in a wide variety of forms from W.L. Gore & Associates, Inc., Newark, DE.
- ePTFE ePTFE
- fibril structure As the term “ePTFE” is used herein, it is intended to include any PTFE material having a node and fibril structure, including in the range from a slightly expanded structure having fibrils extending from relatively large nodes of polymeric material, to an extremely expanded structure having fibrils that merely intersect with one another at nodal points.
- the fibrillar character of the structure is identified by microscopy. While the nodes may easily be identified for some structures, many extremely expanded structures consist almost exclusively of fibrils with nodes appearing only as the intersection point of fibrils. The resulting micropores or voids allow for good gas or air flow while providing water resistance.
- the membrane may optionally include one or more fillers or coatings, also referred to as additives.
- additives may be included in the matrix of the ePTFE itself.
- the membrane may be imbibed with an additive/solvent mixture allowing good penetration of the additive into the porosity of the film. Imbibing is accomplished by first preparing an additive/solvent solution, and second, combining this solution with a porous film like expanded PTFE.
- the additive may also be coated onto one or more sides of the membrane. Desirable additives may include absorbents, adsorbents, surface energy modifiers; colorants, pigments, anti-microbials, antibacterial agents, antifungals; and mixtures thereof.
- the membrane may include a support layer, such as a woven or non woven fabric or a fiber scrim.
- the support layer may be laminated, bonded or only positioned adjacent to the membrane.
- the thickness of the membrane is not critical, however, the membrane must be sufficiently thick to maintain a seal by an interference fit of the shell and vent body. Thin membranes require more precise machining and fitting of parts. Thicker membranes can be used, provided they are sufficiently permeable for effective venting. Preferably, the membrane is at least about 3 mils, or at least about 5 mils, 10 mils or 13 mils.
- the shell is preferably secured to the vent body by an interference fit.
- an "interference fit” is intended to encompass all manner of fitting parts in which the assembly is maintained by the aggregation of internal forces within the parts and friction between parts, without the use of adherents, such as adhesives, or welding, brazing and the like or caulking materials, compression gaskets, springs and the like.
- Methods of securing the shell to the vent body by an interference fit may include, for example, the use of snap rings, press fitting, friction fitting or others.
- the shell may include tabs which project inward to cooperate with a groove or recess in the vent body. The tabs snap into place in the recess to lock the shell in place.
- the present invention provides a one-piece, metal vent body.
- an aperture is provided through the one-piece vent body from the root to the head.
- the head includes a lower membrane bearing surface surrounding the aperture.
- the head also includes an upper membrane bearing surface surrounding the aperture.
- a membrane is disposed between the upper and lower membrane bearing surfaces and held in place by compression between membrane bearing surfaces.
- the membrane may be placed between membrane bearing surfaces and the upper membrane bearing surface may be part of a lip or edge which is rolled or pressed to deform the vent body such that the membrane is held between the upper and lower membrane bearing surfaces.
- the vent body 10 includes a root 12 having threads 14 and a head 16, which includes a hexagonal shaped portion 18.
- the hexagonal shaped portion permits using a wrench to drive the vent into a tapped housing.
- Threads may be National Pipe Thread (NPT) or straight threads. Where straight threads are used, a gasket 20 may be used to seal the vent to the housing.
- Groove 22 is cut into the head above the hexagonal portion.
- An aperture 24 extends through the vent body from root to head.
- a shell 30 is secured to the vent body by an interference fit.
- a snap ring 38 on the shell cooperates with the groove 22 to secure the shell to the vent body.
- the shell also includes a baffle 32 extending toward the cap.
- the cap 40 fits over the shell 30 and is held in place by cooperation of dimples 42 bearing on the shell.
- the cap includes perforations 44 at its outer perimeter.
- the perforations are positioned outside the baffle 32 such that liquids entering the perforations are prevented from contacting the membrane 50 by the baffle. Gaps between dimples provide a drainage path, labeled A-A, between the cap and the shell for liquid entering the perforations by 44.
- Dimples 46 in the top shell contact the upper edge of the baffle, maintaining a gap between the top shell and baffle to permit gas flow.
- the membrane 50 is compressed at its perimeter between the upper membrane bearing surface 48 of the shell and the lower membrane bearing surface 34 of the vent body.
- Figs. 4-6 show another embodiment.
- the housing to be vented includes a wall 2 that has an opening or port 4 that receives an insert 60 having threads 62.
- the insert 60 has a hexagonal recess 64 adapted to receive an alien wrench type driver for installing the insert in the housing.
- Formed or machined into the insert is a passageway 66 for passing a fluid.
- a web 68 extends from the interior sides of the passageway.
- Surrounding the passageway is a groove 61 for receiving a gasket 63.
- the vent includes a shell 70 and a vent body 80.
- the vent body includes an elongated root 82 having a raised snap ring 84 formed therein.
- the shell includes perforations 72 which permit the flow of gas through the top shell.
- vent body 10 has a cylindrical root 12 for insertion into a housing.
- FIG. 9 shows a two piece construction. A top shell is pressed over a vent body having an aperture to seal the membrane over the aperture.
- Fig. 10 shows a one-piece vent body construction. The metal vent body includes both the upper membrane bearing surface and the lower membrane bearing surface. Test Methods
- Water Resistance - Suter Method Membranes suitable for use in the present invention may be tested for water-resistance using a modified Suter test apparatus, which is a low water entry pressure challenge. Water is forced against the underside of a by two circular rubber gaskets in a leak-proof clamped arrangement. In deformable samples, the sample may be overlaid by a reinforcing scrim (e.g. an open non- woven fabric) clamped over the sample. The upper side of the sample is open to the atmosphere and visible to the operator. The water pressure on the underside of the sample is increased to 2 psi by a pump connected to a water reservoir, as indicated by a pressure gauge and regulated by an in-line valve.
- a reinforcing scrim e.g. an open non- woven fabric
- the upper side of the sample is visually observed for a period of three minutes for the appearance of any water which might be forced through the sample in the event of lack of water-resistance. Liquid water seen on the surface is interpreted as a deficiency in the water-resistance of the sample (i.e., a leak). The sample has passed the test if no liquid water is visible on the upper side of the sample within the three minute test period.
- Example 1 A vent body was machined from hexagonal stainless steel bar stock. The stock was cut to length and threads were cut into one end of the bar stock. A hole was drilled through the length of the bar stock to create an aperture. Starting from the end opposite from the thread, the hexagonal bar stock was rounded to create cylinder above a hexagonal driving portion. Next, a groove was cut in the cylinder near the top. Finally, the membrane bearing surface was prepared on the top of the cylinder section of the bolt by sanding with 600 grit sand paper to remove any burs and to provide some grip to the membrane bearing surface.
- the shell was formed using a deep draw metal forming process to first form a cylindrical shell.
- inward projecting dimples were placed in four evenly spaced locations around the outer wall. The dimples are located near the bottom edge.
- the shell was perforated by drilling a series of holes near the perimeter.
- the components were assembled using a pneumatic press applying a force of 565 pounds. Pressure was maintained for 3 seconds after the components were snapped together. As the shell and vent body are brought together, the dimples in the top shell snap into the groove cut into the cylindrical section of the vent body.
- Example Two A shell was formed of 304 stainless steel using a deep draw metal forming process. As described above, an "S" shaped bend was created in the shell to form the upper membrane bearing surface. Dimples were placed in four evenly spaced locations around the outer wall of the shell near the bottom edge. Perforations were provided above the "S" shaped bend. The vent body was also formed using a deep draw metal forming process and 304 stainless steel. A tube was flared to form a flange on one end. An inverted “U” shape having a bend radius of 0.010" was formed such that the "U" shape was on outside edge of the flange. The inverted "U” shape provides the lower membrane bearing surface.
- the components were assembled with a press applying a force of 565 pounds. This pressure is maintained for 3 seconds after the components are snapped together. As the shell and vent body are brought together, the dimples in the shell snap over the outside edge of the "U" shape on the vent body. The upper membrane bearing surface in the shell is compressed against the lower membrane bearing surface on the vent body. The microporous membrane disk of Example 1 is compressed between bearing surfaces to form a seal surrounding the aperture.
- a silicone O-ring is placed on to the root of the vent body.
- a hole is drilled into the housing slightly larger than the outside diameter of the shaft on the vent body.
- the root on the vent body is inserted into the hole on the housing.
- a self-locking ring such as a "Rotor Clip TY-37” may be pushed onto the shaft so that the O-ring is compressed between the housing and the vent body.
- Example Three A 304 stainless steel shell was formed in the shape of an inverted cup using a deep draw metal process. A hole was cut from the center of the shell. A vent body was formed of the same material in the shape of an inverted cup. A lower membrane bearing surface was formed by an outwardly projecting rib in the top surface of the bottom cup near the outer perimeter of the vent body. A hole is cut in the bottom of the cup to form an aperture. The components were assembled using a hydraulic press applying a force of 70 pounds. A microporous membrane disc of Example 1 was placed inside the top cup. Friction between the inner wall of the top shell and the outer wall of the vent body provides an interference fit. Compression of the microporous membrane disc between the top shell and the rib in the vent body creates a seal surrounding the aperture.
Landscapes
- Engineering & Computer Science (AREA)
- General Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Self-Closing Valves And Venting Or Aerating Valves (AREA)
- Closures For Containers (AREA)
- Control And Other Processes For Unpacking Of Materials (AREA)
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA2562598A CA2562598C (en) | 2004-04-12 | 2005-04-11 | Metal vent |
| EP05735508A EP1740861B1 (en) | 2004-04-12 | 2005-04-11 | Metal vent |
| JP2007508452A JP4718540B2 (ja) | 2004-04-12 | 2005-04-11 | 金属製通気口 |
| DE602005011268T DE602005011268D1 (de) | 2004-04-12 | 2005-04-11 | Metallischer abzug |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/823,066 | 2004-04-12 | ||
| US10/823,066 US7357709B2 (en) | 2004-04-12 | 2004-04-12 | Metal vent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2005100832A1 true WO2005100832A1 (en) | 2005-10-27 |
Family
ID=34965797
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/US2005/012294 Ceased WO2005100832A1 (en) | 2004-04-12 | 2005-04-11 | Metal vent |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US7357709B2 (https=) |
| EP (1) | EP1740861B1 (https=) |
| JP (1) | JP4718540B2 (https=) |
| AT (1) | ATE415583T1 (https=) |
| CA (1) | CA2562598C (https=) |
| DE (1) | DE602005011268D1 (https=) |
| WO (1) | WO2005100832A1 (https=) |
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| EP2007500A4 (en) * | 2006-04-17 | 2009-05-13 | Gore Enterprise Holdings Inc | AERATION SYSTEM FOR AXLE |
| EP2121366A4 (en) * | 2007-02-27 | 2013-02-13 | Scania Cv Ab | FUEL TANK VENTILATION ASSEMBLY FOR A VEHICLE FUEL TANK AND FUEL TANK THEREFORE EQUIPPED |
| CN105546169A (zh) * | 2016-01-11 | 2016-05-04 | 唐凯 | 防水透气阀 |
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| FR3164870A1 (fr) * | 2024-07-17 | 2026-01-23 | Ampere Sas | Dispositif de mise à l’air d’un carter pour compatibilité électromagnétique |
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| EP2007500A4 (en) * | 2006-04-17 | 2009-05-13 | Gore Enterprise Holdings Inc | AERATION SYSTEM FOR AXLE |
| JP2009533633A (ja) * | 2006-04-17 | 2009-09-17 | ゴア エンタープライズ ホールディングス,インコーポレイティド | 車軸ベント |
| AU2007241008B2 (en) * | 2006-04-17 | 2010-11-25 | W. L. Gore & Associates, Inc. | Axle vent |
| EP2121366A4 (en) * | 2007-02-27 | 2013-02-13 | Scania Cv Ab | FUEL TANK VENTILATION ASSEMBLY FOR A VEHICLE FUEL TANK AND FUEL TANK THEREFORE EQUIPPED |
| US10639579B2 (en) | 2014-10-01 | 2020-05-05 | Donaldson Company, Inc. | Pleated tank vent |
| EP3045969A1 (en) * | 2015-01-15 | 2016-07-20 | LG Innotek Co., Ltd. | Camera module for vehicle comprising a vent hole closed by a membrane |
| US9749508B2 (en) | 2015-01-15 | 2017-08-29 | Lg Innotek Co., Ltd. | Camera module for vehicle |
| US10717031B2 (en) | 2015-01-28 | 2020-07-21 | Donaldson Company, Inc. | Barrier vent assembly |
| US11395985B2 (en) | 2015-01-28 | 2022-07-26 | Donaldson Company, Inc. | Barrier vent assembly |
| US12194402B2 (en) | 2015-01-28 | 2025-01-14 | Donaldson Company, Inc. | Barrier vent assembly |
| CN105546169B (zh) * | 2016-01-11 | 2017-12-01 | 唐凯 | 防水透气阀 |
| CN105546169A (zh) * | 2016-01-11 | 2016-05-04 | 唐凯 | 防水透气阀 |
| CN108397581A (zh) * | 2018-05-28 | 2018-08-14 | 南京若吉电子有限公司 | 一种大尺寸加固显示器透气防潮结构 |
| DE102019215742A1 (de) * | 2019-10-14 | 2021-04-15 | Elringklinger Ag | Druckausgleichsvorrichtung und Verfahren zur Herstellung einer Druckausgleichsvorrichtung |
| US12414246B2 (en) | 2023-08-03 | 2025-09-09 | Nokia Solutions And Networks Oy | Filtering apparatuses and systems for electronic enclosures |
Also Published As
| Publication number | Publication date |
|---|---|
| CA2562598C (en) | 2010-02-09 |
| US20050227610A1 (en) | 2005-10-13 |
| ATE415583T1 (de) | 2008-12-15 |
| EP1740861B1 (en) | 2008-11-26 |
| CA2562598A1 (en) | 2005-10-27 |
| US7357709B2 (en) | 2008-04-15 |
| DE602005011268D1 (de) | 2009-01-08 |
| JP4718540B2 (ja) | 2011-07-06 |
| JP2007532842A (ja) | 2007-11-15 |
| EP1740861A1 (en) | 2007-01-10 |
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