WO2005089071A2 - 無公害防錆顔料組成物 - Google Patents
無公害防錆顔料組成物 Download PDFInfo
- Publication number
- WO2005089071A2 WO2005089071A2 PCT/JP2005/005594 JP2005005594W WO2005089071A2 WO 2005089071 A2 WO2005089071 A2 WO 2005089071A2 JP 2005005594 W JP2005005594 W JP 2005005594W WO 2005089071 A2 WO2005089071 A2 WO 2005089071A2
- Authority
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- WIPO (PCT)
- Prior art keywords
- acid
- calcium
- pigment composition
- pollution
- mackerel
- Prior art date
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- 239000000049 pigment Substances 0.000 title claims abstract description 86
- 239000000203 mixture Substances 0.000 title claims abstract description 72
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 claims abstract description 47
- 239000001506 calcium phosphate Substances 0.000 claims abstract description 46
- 229910000389 calcium phosphate Inorganic materials 0.000 claims abstract description 45
- 235000011010 calcium phosphates Nutrition 0.000 claims abstract description 44
- 239000011575 calcium Substances 0.000 claims abstract description 38
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims abstract description 17
- 229910052791 calcium Inorganic materials 0.000 claims abstract description 17
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000011574 phosphorus Substances 0.000 claims abstract description 14
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 14
- 229910001385 heavy metal Inorganic materials 0.000 claims abstract description 7
- 241000269821 Scombridae Species 0.000 claims description 47
- 235000020640 mackerel Nutrition 0.000 claims description 47
- 229960001714 calcium phosphate Drugs 0.000 claims description 42
- 239000003973 paint Substances 0.000 claims description 34
- 239000002253 acid Substances 0.000 claims description 27
- 150000003839 salts Chemical class 0.000 claims description 18
- 150000001341 alkaline earth metal compounds Chemical class 0.000 claims description 17
- 229960005069 calcium Drugs 0.000 claims description 15
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 14
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 12
- -1 alkaline earth metal salts Chemical class 0.000 claims description 9
- 238000000034 method Methods 0.000 claims description 9
- CWERGRDVMFNCDR-UHFFFAOYSA-N thioglycolic acid Chemical compound OC(=O)CS CWERGRDVMFNCDR-UHFFFAOYSA-N 0.000 claims description 8
- 230000000844 anti-bacterial effect Effects 0.000 claims description 7
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 7
- 229910052751 metal Inorganic materials 0.000 claims description 7
- 239000002184 metal Substances 0.000 claims description 7
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 6
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 6
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 claims description 6
- 230000003373 anti-fouling effect Effects 0.000 claims description 6
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 6
- 150000001875 compounds Chemical class 0.000 claims description 6
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 claims description 6
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 5
- 150000001735 carboxylic acids Chemical class 0.000 claims description 5
- 238000009833 condensation Methods 0.000 claims description 5
- 230000005494 condensation Effects 0.000 claims description 5
- 238000005260 corrosion Methods 0.000 claims description 5
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 claims description 4
- WVMBPWMAQDVZCM-UHFFFAOYSA-N N-methylanthranilic acid Chemical compound CNC1=CC=CC=C1C(O)=O WVMBPWMAQDVZCM-UHFFFAOYSA-N 0.000 claims description 4
- RWZYAGGXGHYGMB-UHFFFAOYSA-N anthranilic acid Chemical compound NC1=CC=CC=C1C(O)=O RWZYAGGXGHYGMB-UHFFFAOYSA-N 0.000 claims description 4
- LMHAGAHDHRQIMB-UHFFFAOYSA-N 1,2-dichloro-1,2,3,3,4,4-hexafluorocyclobutane Chemical compound FC1(F)C(F)(F)C(F)(Cl)C1(F)Cl LMHAGAHDHRQIMB-UHFFFAOYSA-N 0.000 claims description 3
- 229940120146 EDTMP Drugs 0.000 claims description 3
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 3
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims description 3
- 239000000920 calcium hydroxide Substances 0.000 claims description 3
- 229910001861 calcium hydroxide Inorganic materials 0.000 claims description 3
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims description 3
- 239000000292 calcium oxide Substances 0.000 claims description 3
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 3
- NFDRPXJGHKJRLJ-UHFFFAOYSA-N edtmp Chemical compound OP(O)(=O)CN(CP(O)(O)=O)CCN(CP(O)(O)=O)CP(O)(O)=O NFDRPXJGHKJRLJ-UHFFFAOYSA-N 0.000 claims description 3
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 claims description 3
- 229920000137 polyphosphoric acid Polymers 0.000 claims description 3
- 229960004889 salicylic acid Drugs 0.000 claims description 3
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 claims description 2
- VFFRLRQQWXGEBX-UHFFFAOYSA-N 1-aminonaphthalene-2-carboxylic acid Chemical compound C1=CC=C2C(N)=C(C(O)=O)C=CC2=C1 VFFRLRQQWXGEBX-UHFFFAOYSA-N 0.000 claims description 2
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 claims description 2
- CXOWHCCVISNMIX-UHFFFAOYSA-N 2-aminonaphthalene-1-carboxylic acid Chemical compound C1=CC=CC2=C(C(O)=O)C(N)=CC=C21 CXOWHCCVISNMIX-UHFFFAOYSA-N 0.000 claims description 2
- XFXOLBNQYFRSLQ-UHFFFAOYSA-N 3-amino-2-naphthoic acid Chemical compound C1=CC=C2C=C(C(O)=O)C(N)=CC2=C1 XFXOLBNQYFRSLQ-UHFFFAOYSA-N 0.000 claims description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims description 2
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 claims description 2
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 claims description 2
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 claims description 2
- YYRMJZQKEFZXMX-UHFFFAOYSA-L calcium bis(dihydrogenphosphate) Chemical compound [Ca+2].OP(O)([O-])=O.OP(O)([O-])=O YYRMJZQKEFZXMX-UHFFFAOYSA-L 0.000 claims description 2
- 229940062672 calcium dihydrogen phosphate Drugs 0.000 claims description 2
- JUNWLZAGQLJVLR-UHFFFAOYSA-J calcium diphosphate Chemical compound [Ca+2].[Ca+2].[O-]P([O-])(=O)OP([O-])([O-])=O JUNWLZAGQLJVLR-UHFFFAOYSA-J 0.000 claims description 2
- FUFJGUQYACFECW-UHFFFAOYSA-L calcium hydrogenphosphate Chemical compound [Ca+2].OP([O-])([O-])=O FUFJGUQYACFECW-UHFFFAOYSA-L 0.000 claims description 2
- 229940043256 calcium pyrophosphate Drugs 0.000 claims description 2
- VEJCUEBBRSCJRP-UHFFFAOYSA-L calcium;hydron;phosphonato phosphate Chemical compound [Ca+2].OP(O)(=O)OP([O-])([O-])=O VEJCUEBBRSCJRP-UHFFFAOYSA-L 0.000 claims description 2
- 150000004649 carbonic acid derivatives Chemical class 0.000 claims description 2
- 239000002738 chelating agent Substances 0.000 claims description 2
- 235000015165 citric acid Nutrition 0.000 claims description 2
- 235000019821 dicalcium diphosphate Nutrition 0.000 claims description 2
- 235000019700 dicalcium phosphate Nutrition 0.000 claims description 2
- 150000004679 hydroxides Chemical class 0.000 claims description 2
- 229910052749 magnesium Inorganic materials 0.000 claims description 2
- 239000011777 magnesium Substances 0.000 claims description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 2
- 239000011976 maleic acid Substances 0.000 claims description 2
- 239000001630 malic acid Substances 0.000 claims description 2
- 235000011090 malic acid Nutrition 0.000 claims description 2
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 claims description 2
- 235000019691 monocalcium phosphate Nutrition 0.000 claims description 2
- 235000006408 oxalic acid Nutrition 0.000 claims description 2
- 150000004760 silicates Chemical class 0.000 claims description 2
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 claims description 2
- DLYUQMMRRRQYAE-UHFFFAOYSA-N tetraphosphorus decaoxide Chemical compound O1P(O2)(=O)OP3(=O)OP1(=O)OP2(=O)O3 DLYUQMMRRRQYAE-UHFFFAOYSA-N 0.000 claims description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 2
- 229940078499 tricalcium phosphate Drugs 0.000 claims description 2
- 235000019731 tricalcium phosphate Nutrition 0.000 claims description 2
- 229910000391 tricalcium phosphate Inorganic materials 0.000 claims description 2
- 150000007513 acids Chemical class 0.000 claims 2
- 150000003009 phosphonic acids Chemical class 0.000 claims 2
- MMKNBFSDCOALQO-UHFFFAOYSA-N 1-amino-9,10-dioxoanthracene-2-carboxylic acid Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=CC(C(O)=O)=C2N MMKNBFSDCOALQO-UHFFFAOYSA-N 0.000 claims 1
- WXHLLJAMBQLULT-UHFFFAOYSA-N 2-[[6-[4-(2-hydroxyethyl)piperazin-1-yl]-2-methylpyrimidin-4-yl]amino]-n-(2-methyl-6-sulfanylphenyl)-1,3-thiazole-5-carboxamide;hydrate Chemical compound O.C=1C(N2CCN(CCO)CC2)=NC(C)=NC=1NC(S1)=NC=C1C(=O)NC1=C(C)C=CC=C1S WXHLLJAMBQLULT-UHFFFAOYSA-N 0.000 claims 1
- 150000003863 ammonium salts Chemical class 0.000 claims 1
- 230000001815 facial effect Effects 0.000 claims 1
- IATRAKWUXMZMIY-UHFFFAOYSA-N strontium oxide Chemical class [O-2].[Sr+2] IATRAKWUXMZMIY-UHFFFAOYSA-N 0.000 claims 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract description 11
- 239000011701 zinc Substances 0.000 abstract description 11
- 229910052725 zinc Inorganic materials 0.000 abstract description 11
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 abstract description 5
- 229910052804 chromium Inorganic materials 0.000 abstract description 5
- 239000011651 chromium Substances 0.000 abstract description 5
- 150000002500 ions Chemical class 0.000 abstract description 4
- 231100001261 hazardous Toxicity 0.000 abstract 1
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- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 12
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- 229910019142 PO4 Inorganic materials 0.000 description 10
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 10
- 239000003795 chemical substances by application Substances 0.000 description 10
- 238000000576 coating method Methods 0.000 description 10
- 239000010452 phosphate Substances 0.000 description 10
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- 229920000180 alkyd Polymers 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
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- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 3
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- RSWGJHLUYNHPMX-ONCXSQPRSA-N abietic acid Chemical compound C([C@@H]12)CC(C(C)C)=CC1=CC[C@@H]1[C@]2(C)CCC[C@@]1(C)C(O)=O RSWGJHLUYNHPMX-ONCXSQPRSA-N 0.000 description 2
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- ROPDWRCJTIRLTR-UHFFFAOYSA-L calcium metaphosphate Chemical compound [Ca+2].[O-]P(=O)=O.[O-]P(=O)=O ROPDWRCJTIRLTR-UHFFFAOYSA-L 0.000 description 2
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- LNTHITQWFMADLM-UHFFFAOYSA-N gallic acid Chemical compound OC(=O)C1=CC(O)=C(O)C(O)=C1 LNTHITQWFMADLM-UHFFFAOYSA-N 0.000 description 2
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- 229910000165 zinc phosphate Inorganic materials 0.000 description 2
- OYHQOLUKZRVURQ-NTGFUMLPSA-N (9Z,12Z)-9,10,12,13-tetratritiooctadeca-9,12-dienoic acid Chemical compound C(CCCCCCC\C(=C(/C\C(=C(/CCCCC)\[3H])\[3H])\[3H])\[3H])(=O)O OYHQOLUKZRVURQ-NTGFUMLPSA-N 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- XZMCDFZZKTWFGF-UHFFFAOYSA-N Cyanamide Chemical compound NC#N XZMCDFZZKTWFGF-UHFFFAOYSA-N 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- OYHQOLUKZRVURQ-HZJYTTRNSA-N Linoleic acid Chemical compound CCCCC\C=C/C\C=C/CCCCCCCC(O)=O OYHQOLUKZRVURQ-HZJYTTRNSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- GOORKRQBHUFLLA-UHFFFAOYSA-N P(O)(O)=O.N(C=C)(C=C)C=C Chemical compound P(O)(O)=O.N(C=C)(C=C)C=C GOORKRQBHUFLLA-UHFFFAOYSA-N 0.000 description 1
- HXNCOGIKSLLIDH-UHFFFAOYSA-N P(O)(O)=O.N(C=CC)(C=CC)C=CC Chemical compound P(O)(O)=O.N(C=CC)(C=CC)C=CC HXNCOGIKSLLIDH-UHFFFAOYSA-N 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- 241000207961 Sesamum Species 0.000 description 1
- 235000003434 Sesamum indicum Nutrition 0.000 description 1
- 239000006087 Silane Coupling Agent Substances 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 229920003180 amino resin Polymers 0.000 description 1
- 230000003064 anti-oxidating effect Effects 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 239000010953 base metal Substances 0.000 description 1
- 210000003323 beak Anatomy 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- FJTUUPVRIANHEX-UHFFFAOYSA-N butan-1-ol;phosphoric acid Chemical compound CCCCO.OP(O)(O)=O FJTUUPVRIANHEX-UHFFFAOYSA-N 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- VSGNNIFQASZAOI-UHFFFAOYSA-L calcium acetate Chemical compound [Ca+2].CC([O-])=O.CC([O-])=O VSGNNIFQASZAOI-UHFFFAOYSA-L 0.000 description 1
- 239000001639 calcium acetate Substances 0.000 description 1
- 235000011092 calcium acetate Nutrition 0.000 description 1
- 229960005147 calcium acetate Drugs 0.000 description 1
- 235000010216 calcium carbonate Nutrition 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- FNAQSUUGMSOBHW-UHFFFAOYSA-H calcium citrate Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O.[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O FNAQSUUGMSOBHW-UHFFFAOYSA-H 0.000 description 1
- 239000001354 calcium citrate Substances 0.000 description 1
- 235000011116 calcium hydroxide Nutrition 0.000 description 1
- 235000012255 calcium oxide Nutrition 0.000 description 1
- 239000008119 colloidal silica Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000007580 dry-mixing Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000010828 elution Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 229940074391 gallic acid Drugs 0.000 description 1
- 235000004515 gallic acid Nutrition 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000001879 gelation Methods 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 235000020778 linoleic acid Nutrition 0.000 description 1
- OYHQOLUKZRVURQ-IXWMQOLASA-N linoleic acid Natural products CCCCC\C=C/C\C=C\CCCCCCCC(O)=O OYHQOLUKZRVURQ-IXWMQOLASA-N 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000008268 mayonnaise Substances 0.000 description 1
- 235000010746 mayonnaise Nutrition 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- MEFBJEMVZONFCJ-UHFFFAOYSA-N molybdate Chemical compound [O-][Mo]([O-])(=O)=O MEFBJEMVZONFCJ-UHFFFAOYSA-N 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 235000021313 oleic acid Nutrition 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000007665 sagging Methods 0.000 description 1
- 235000015067 sauces Nutrition 0.000 description 1
- 239000002453 shampoo Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 239000011973 solid acid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
- NVKTUNLPFJHLCG-UHFFFAOYSA-N strontium chromate Chemical compound [Sr+2].[O-][Cr]([O-])(=O)=O NVKTUNLPFJHLCG-UHFFFAOYSA-N 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 description 1
- 230000000475 sunscreen effect Effects 0.000 description 1
- 239000000516 sunscreening agent Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- 235000013337 tricalcium citrate Nutrition 0.000 description 1
- GQIUQDDJKHLHTB-UHFFFAOYSA-N trichloro(ethenyl)silane Chemical compound Cl[Si](Cl)(Cl)C=C GQIUQDDJKHLHTB-UHFFFAOYSA-N 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000005050 vinyl trichlorosilane Substances 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
- 150000003752 zinc compounds Chemical class 0.000 description 1
- NDKWCCLKSWNDBG-UHFFFAOYSA-N zinc;dioxido(dioxo)chromium Chemical compound [Zn+2].[O-][Cr]([O-])(=O)=O NDKWCCLKSWNDBG-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D17/00—Pigment pastes, e.g. for mixing in paints
- C09D17/004—Pigment pastes, e.g. for mixing in paints containing an inorganic pigment
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D17/00—Pigment pastes, e.g. for mixing in paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
- C09D5/082—Anti-corrosive paints characterised by the anti-corrosive pigment
- C09D5/084—Inorganic compounds
Definitions
- the present invention relates to, for example, a mackerel pigment composition that can be blended with a mackerel paint, and particularly contains no heavy metals such as lead, chromium, and zinc, and is applicable to various waterproof paints and oils.
- the present invention relates to a non-polluting shampoo pigment composition which is possible, versatile, and excellent in a saba prevention effect. Background technology
- lead-based pigments such as lead red, cyanamide, and lead suboxide
- chromate-based pigments such as zinc chromate and strontium chromate have been widely used as sesame pigments.
- phosphate-based, molybdate-based, organic phosphonate-based, and borate-based pigments have been proposed as non-pollution-type anti-pigment pigments.
- Non-polluting antifouling paints generally use solid acids that are easily eluted as the main component, so that excessive acid elution is suppressed and solid base is used as an auxiliary component to keep the coating neutral. It contains. For this reason, many pollution-free sunscreen pigments that have been conventionally marketed contain zinc oxide as a solid base.
- non-polluting anti-reflective pigments containing no zinc oxide have also been developed (for example, Japanese Patent Application Laid-Open Nos. 8-2833619, 11-049797, and Japanese Patent Application Laid-Open No. 2003-111132).
- Japanese Unexamined Patent Publication No. 2003-113482 discloses a saba prevention pigment composition from a precipitate obtained by reacting sodium tripolyphosphate and a water-soluble alkaline earth metal compound in a wet manner. proposes a method of obtaining, in the explosion ⁇ sweetener composition thus obtained, the water-soluble ions, e.g., N a + N 0 3 - , since such C l _ many mixed, the long-term Cross protection cannot be obtained. Disclosure of the invention
- the present invention relates to a pollution-free antifouling cosmetic composition free of heavy metals, characterized by containing a condensed calcium phosphate obtained by firing the mixture at 180 to 350 ° C. The invention's effect
- the pollution-free antifouling composition of the present invention does not contain harmful heavy metal elements such as lead, chromium or the like and zinc, is pollution-free, and exhibits an excellent antibacterial effect.
- This anti-saba pigment composition can be blended with various types of resin-based paints, and is extremely useful as a face for anti-metallic paints of various metals.
- the mackerel pigment can be used in the same manner as various uses of the mackerel pigment, for example, as a method for using it as another material for mackerel, for example, adding it to mackerel oil or using it all at once.
- BEST MODE FOR CARRYING OUT THE INVENTION for example, as a method for using it as another material for mackerel, for example, adding it to mackerel oil or using it all at once.
- the condensed calcium phosphate in the mackerel pigment composition of the present invention is slightly dissolved in water under a corrosive atmosphere and has a very strong chelating power on metals. However, it is considered that a passive film is formed on the iron surface to prevent the occurrence of mackerel.
- the condensed calcium phosphate used in the present invention has the following formula (1):
- the condensed calcium phosphate of the formula (1) includes a compound having an arbitrary number of waters of crystallization.
- Equation (1) Examples of the condensed calcium phosphate represented by, CaH 2 P 2 0 7 and, Ca 2 P 2 0 7, Ca 3 H 2 (P 2 O v) 2, Ca 4 H 2 (P 3 O 10) 2 such ⁇ Ca 4 P 6 0 19 is one representative, it is desirable that these single or a mixture thereof.
- Such a condensed calcium phosphate represented by the formula (1) can be identified mainly by using an X-ray diffraction method and by a beak obtained by an X-ray diffractometer (XRD).
- the condensed calcium phosphate used in the present invention may be in a single crystalline state or in a mixture of various crystalline states (including amorphous).
- the condensed calcium phosphate which is a constituent component of the mackerel-proof pigment composition of the present invention may be a mixture of the above-mentioned potassium and phosphorus components in the range of 180 to 350. Bake at C temperature, preferred Preferably, firing at a temperature of 200 to 290 ° C. is desirable. If the firing temperature is lower than 180 ° C, phosphoric acid does not condense and condensed calcium phosphate cannot be obtained. Also, the firing temperature is higher than 3 5 0 ° C, because many of the generated condensation calcium phosphate resulting in turn to main evening calcium phosphate ((C a (P_ ⁇ 3) 2), condensed phosphoric acid having an anti ⁇ Calcium is not available.
- the firing time of the mixture of the calcium component and the phosphorus component is not particularly limited, but is preferably, for example, 1 to 30 hours. Further, the condensed calcium phosphate after calcination may be subjected to operations such as pulverization and classification depending on the use and the like.
- the phosphorus component include orthophosphoric acid, polyphosphoric acid, phosphorous acid, diphosphorus pentoxide, and the like.
- the calcium component include calcium alone, calcium oxide, calcium hydroxide, calcium carbonate, calcium hydrogen phosphate, calcium dihydrogen phosphate, tricalcium phosphate, calcium pyrophosphate, and calcium dihydrogen pyrophosphate. And the like. It should be noted that calcium nitrate, calcium acetate, and calcium chloride have a tendency that water-soluble ions remain in the baked product and the basin-proofing properties of the pigment decrease.
- the present inventor conducted a search for a solid base to be combined with condensed calcium phosphate in order to produce a pollution-free antibacterial pigment free of zinc.
- the alkaline earth metal compound was successfully protected. It has been found that it has an effect of improving the ⁇ property.
- the alkaline earth metal compound include oxides such as calcium, magnesium, and strontium, hydroxides, silicates, and carbonates. It is desirable to use the compound of .
- the amount of the alkaline earth metal compound is from 0 to 90% by mass, more preferably from 0.1 to 60% by mass, based on the whole non-polluting mackerel pigment composition. Therefore, in this case, the amount of the condensed calcium phosphate is 10 to 100% by mass, more preferably 40 to 99.9% by mass, based on the total amount of the pollution-free mackerel pigment composition.
- the alkaline earth metal compound is contained in an amount of 0.5 to 20% by mass based on the total pollution-free pigment composition. It is desirable that there be. Further, one or more of these alkaline earth metal compounds may be used.
- the mixing ratio of the condensed calcium phosphate is smaller than the above range, the amount of condensed phosphate ions, which is a factor for exerting the effect of preventing mackerel, decreases, and the effect of preventing mackerel is not sufficient.
- the amount increases, the solid acidity of the condensed calcium phosphate cannot be neutralized due to the decrease in the amount of the alkaline earth metal compound, so that the protective effect based on the condensed calcium phosphate tends to decrease.
- the alkaline earth metal compound can be used by mixing with the condensed calcium phosphate or by baking the mixture.
- a silicon compound may be further added to the above-mentioned condensed calcium phosphate and a mixture thereof with the alkaline earth metal compound.
- Mixing a silicon compound is preferable because corrosion products of the base metal can be fixed and the protection effect can be improved.
- the silicon compound include, but are not particularly limited to, colloidal silica, silicic acid synthesized by a wet method or a gas phase method, and natural minerals containing silicic acid in the form of silicon dioxide.
- the amount of the silicon compound to be used is generally from 0 to 80% by mass, preferably from 0.5 to 50% by mass, based on the whole non-polluting mackerel pigment composition.
- the pollution-free mackerel pigment composition of the present invention exhibits sufficient mackerel-preventing effect when the above-mentioned condensed calcium phosphate is used alone or in combination with an alkaline earth metal compound.
- an acid or a carboxylic acid and / or a neutral salt thereof (chelating compound) is contained, a synergistic effect is exhibited, and the basin preventing effect is further improved.
- Organic phosphones having chelating ability for use in the pollution-free mackerel pigment composition of the present invention examples include aminotrialkylenephosphonic acid, such as nitrilotrismethylene phosphonic acid, nitrilotriethylene phosphonic acid, nitrilotrispropylene phosphonic acid, and nitritritritriethylmethylene phosphonic acid, ethylenediaminetetramethylenephosphonic acid, and ethylenediaminetetrane.
- aminotrialkylenephosphonic acid such as nitrilotrismethylene phosphonic acid, nitrilotriethylene phosphonic acid, nitrilotrispropylene phosphonic acid, and nitritritriethylmethylene phosphonic acid, ethylenediaminetetramethylenephosphonic acid, and ethylenediaminetetrane.
- Ethylenediaminetetraalkylenephosphonic acid such as ethylenephosphonic acid, ethylenediaminetetrapropylenephosphonic acid, methane-1-hydroxy-1-, 1-diphosphonic acid, benzene-1-hydroxy-1-, 1,1-diphosphonic acid, propane Examples thereof include alkylmethane 1-1-hydroxy-1,1-diphosphonic acid such as 1-hydroxy-1,1-diphosphonic acid and 2-hydroxyphosphonoacetic acid.
- carboxylic acids having chelating ability include, for example, citric acid, malic acid, oxalic acid, malonic acid, succinic acid, itaconic acid, maleic acid, glycolic acid, mercaptoacetic acid, thioglycolic acid, salicylic acid, and sulfo acid.
- Examples of the neutralized salts of these carboxylic acids include alkali metals, alkaline earth metals, aluminum, and ammonium ions of the above compounds (primary, secondary, tertiary or quaternary ammonium substituted with a nitrogen atom). , Etc.), etc.).
- the amount of the organic phosphonic acid or carboxylic acid having chelating ability and / or the neutralized salt thereof is not particularly limited, but is preferably 0 to 20% by mass relative to the whole non-polluting mackerel pigment composition. %, Preferably 2 to 15% by mass.
- the non-polluting anti-fouling pigment composition of the present invention is required to have a dispersibility of mackerel pigment particles containing condensed calcium phosphate as a main component in consideration of the miscibility with a vehicle when applied to a anti-fouling paint.
- a surface treatment may be applied accordingly.
- the surface treatment method a conventional method performed to achieve the above object can be used. For example, a higher fatty acid or a derivative thereof, an acidic phosphate ester or a derivative thereof, a rosin acid or a derivative thereof, or silane coupling is used. It may be a surface-treated one or two or more selected from agents.
- Examples of the higher fatty acid or a derivative thereof include acid phosphoric acid ester such as acetic acid, lauric acid, myristic acid, palmitic acid, stearic acid, oleic acid, linoleic acid, linoleic acid or a metal salt or amide thereof.
- acid phosphoric acid ester such as acetic acid, lauric acid, myristic acid, palmitic acid, stearic acid, oleic acid, linoleic acid, linoleic acid or a metal salt or amide thereof.
- the paint When using the non-polluting mackerel pigment composition of the present invention in combination with mackerel paint, the paint is used not only for conventional solvent-based paints but also for recent environmental issues. It can be applied to water-based paints (water-soluble resin-based, dispersion-based, emulsion-based, etc.) and powder paints that are attracting attention. Also use paint Various binders can be used as the binder for the resin without particular limitation.
- the pollution-free mackerel pigment composition of the present invention contains condensed calcium phosphate, an alkaline earth metal compound, an organic phosphonic acid or a carboxylic acid, and / or a neutralized salt thereof. Even if they are separately added to the above-mentioned resin for paint without kneading them beforehand and kneaded in the paint, it is possible to produce a fireproof paint excellent in fireproof effect.
- non-polluting antibacterial pigment composition of the present invention When using the non-polluting antibacterial pigment composition of the present invention in a non-polluting antibacterial paint, it is desirable to use the non-polluting antibacterial pigment composition of the present invention alone. Good.
- the non-polluting anti-dust pigment composition of the present invention may be used for other purposes such as addition to anti-reflection oil, kneading to a plastic product used in combination with metal, etc.
- it can be applied to the use of P Mackerel pigment, and the use is not limited to a specific use.
- the condensation calcium phosphate A is a mixture of such CaH 2 P 2 0 7 and Ca 4 H 2 (P 3 O 10) 2.
- the condensation calcium phosphate B is a CaH 2 and P 2 0 7, Ca 3 H 2 (P 2 O v) 2, Ca 4 H 2 (P 3 O 10) a mixture of such 2.
- the condensed calcium phosphates A to C prepared as described above, and an alkaline earth metal compound, or an organic phosphonic acid or a carboxylic acid and / or a neutralized salt thereof are prepared in the following table. Dry-blending each at the compounding ratio shown in 1, Examples 1 to 1 o.
- Comparative Example 1 calcium metaphosphate (not condensed calcium phosphate) and magnesium oxide were used.
- Comparative Example 2 aluminum tripolyphosphate (“K-FRESH” manufactured by Tiki Co., Ltd.) In 1), z is 3) and calcium metasilicate were dry-mixed at the compounding ratio shown in Table 1 to obtain a mackerel-resistant pigment.
- Comparative Example 3 zinc phosphate-containing aluminum tripolyphosphate (“K-WHITE AZP 500” manufactured by Tika Co., Ltd.), and as Comparative Example 4 calcium-modified aluminum tripolyphosphate (“K-WHITE Ca650” manufactured by Tika Co., Ltd.) ), Zinc oxide-modified aluminum tripolyphosphate (“K-WHI TE # 105” manufactured by Tika Co., Ltd.) as Comparative Example 5, and zinc phosphate (“ZPF” manufactured by Sakai Chemical Industry Co., Ltd.) as Comparative Example 6. Each was used as an anti-pigment pigment. Comparative Examples 3 to 6 are commercially available mackerel pigments.
- Test 1 Evaluation of the use of the non-polluting mackerel pigment composition in an air-dry type epoxy resin-based paint Example 1 to L0 and Comparative Example 1 to 6 And the effect of the P method was confirmed.
- epoxy resin solution manufactured by Mitsui Petrochemical Co., Ltd., xylene 75%) 26 parts, titanium oxide 5 parts, talc 15 parts, calcium carbonate 25 parts, sauce 2 parts of a stopping agent, 2 parts of an antisettling agent, 1 part of an antifoaming agent, 12 parts of xylene, and 8 parts of isopropyl alcohol were dispersed and mixed to prepare respective base agents. Also cured
- a hardening agent was prepared by adding 32 parts of xylene to 68 parts of a polyamide resin and sufficiently mixing and dissolving. 80 parts of each prepared base agent and 20 parts of the curing agent were mixed well to prepare each paint.
- Each paint obtained was coated on a cold-rolled steel sheet J IS G3141 SPCC—SB (150 x 70 x 1. Omm, manufactured by Nippon Yukto Co., Ltd.) using a brush to make the film thickness after drying 40 / m. It was painted to become. Then, it was dried at room temperature for 2 weeks.
- test plate thus prepared was subjected to a cross-cut using a katsuyuichi knife to reach the substrate, and allowed to stand in a salt spray tester maintained at 35 ° C.
- the coating was sprayed on the coating at an amount of lkg / cm 2 per hour for 500 hours, and the width of the corrosion from the center line of the mackerel and blister on the flat surface of the coating and the center line of the cross cut portion were observed. Evaluation method and evaluation criteria
- the basin effect was evaluated from the area of ⁇ and swelling after the test.For a cross cut part, the length of ⁇ and swelling from the center line of the cut part was measured as the corrosion width, and the basin effect was measured. Was evaluated. As shown in Table 2, the evaluation criteria of each mackerel effect were expressed as a score of 0 to 5 as shown in Table 2.
- the non-polluting mackerel pigment composition of the present invention (Examples 1 to 10) had better protection than Comparative Examples 1 and 2 and the commercially available water-resistant pigment (Comparative Examples 3 to 6). ⁇ Effective.
- Test 2 Evaluation when the Mackerel pigment composition was used for an air-drying medium-oil alkyd resin paint For the waterproof pigments of Examples 1 to 10 and Comparative Examples 1 to 6 obtained as described above, Formulated in an alkyd resin paint to confirm the anti-basket effect and storage stability It was.
- Each of the obtained paints was applied twice to a cold-rolled steel plate JIS G3141 SPCC-SB (150 x 70 x 1.0 mm, manufactured by Nippon Yuct Co., Ltd.) using a brush, and the film thickness after drying was 70%. ⁇ M. Then, it was dried at room temperature for 2 weeks. Salt spray test and its evaluation method
- the salt spray test was conducted in the same manner as in Test 1 above, and the salt spray test was performed on both the flat part and the cross-cut part of each test plate using the evaluation methods and evaluation criteria shown in Table 2 as in Test 1. Was evaluated for its mackerel prevention effect.
- Each of the paints prepared as described above was placed in a 250 ml mayonnaise bottle, sealed and kept in a constant temperature room kept at 50 ° C. for 30 days to perform a storage stability test of the paints.
- the viscosity of the paint was measured by a B-type viscometer, and the particle size of the paint after the test and before the test was measured by a grind gauge.
- the evaluation was “ ⁇ ” if the change in viscosity before and after the test was less than 10% and there was no change in particle size, and “ ⁇ ” if the change in viscosity (thickening) or the increase in particle size was 10% or more.
- the non-polluting mackerel pigment composition of the present invention (Examples 1 to 10) is superior to Comparative Examples 1 and 2 and commercially available mackerel pigments (Comparative Examples 3 to 6). It had a protective effect.
- Comparative Examples 3 and 5 containing zinc were used.
- the anti-reflective pigments of Examples 4 and 6 were particularly bad because of the occurrence of shielding, but the zinc-free antibacterial pigments of Examples 1 to 10 of Examples 1 to 10 were good.
- ADVANTAGE OF THE INVENTION does not contain harmful heavy metal elements, such as lead and chromium, zinc, etc., is pollution-free, and can provide the mackerel-proof pigment composition which exhibits the excellent mackerel-proof effect.
- This mackerel-proof pigment composition can be used for various paints, and is extremely useful as a protective material for various metals.
- the anti-pigment pigment can be used in the same manner as various uses of the anti-pigment pigment, such as the method of using it as another mackerel material, for example, adding it to mackerel oil, or using it all at once.
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
Description
Claims
Priority Applications (8)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP05721521A EP1731580B1 (en) | 2004-03-18 | 2005-03-18 | Pollution-free rustproof pigment composition |
DE602005018463T DE602005018463D1 (de) | 2004-03-18 | 2005-03-18 | Umweltbelastungsfreie rostfeste pigmentzusammensetzung |
CA2559947A CA2559947C (en) | 2004-03-18 | 2005-03-18 | Environmentally pollution-free anti-corrosion pigment composition |
AT05721521T ATE452950T1 (de) | 2004-03-18 | 2005-03-18 | Umweltbelastungsfreie rostfeste pigmentzusammensetzung |
CN2005800086834A CN1934204B (zh) | 2004-03-18 | 2005-03-18 | 无公害防锈颜料组合物 |
JP2006511330A JP4154439B2 (ja) | 2004-03-18 | 2005-03-18 | 無公害防錆顔料組成物 |
US11/531,786 US20070012220A1 (en) | 2004-03-18 | 2006-09-14 | Environmentally Pollution-Free Anti-Corrosion Pigment Composition |
US12/257,115 US7828884B2 (en) | 2004-03-18 | 2008-10-23 | Environmentally pollution-free anti-corrosion pigment composition |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2004-078019 | 2004-03-18 | ||
JP2004078019 | 2004-03-18 |
Publications (3)
Publication Number | Publication Date |
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WO2005089071A2 true WO2005089071A2 (ja) | 2005-09-29 |
WO2005089071A1 WO2005089071A1 (ja) | 2005-09-29 |
WO2005089071A3 WO2005089071A3 (ja) | 2005-11-17 |
Family
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2007126565A (ja) * | 2005-11-04 | 2007-05-24 | Dainippon Toryo Co Ltd | 亜鉛めっき鋼板又は亜鉛合金めっき鋼板用塗料組成物及びその塗装鋼板 |
JP2010031297A (ja) * | 2009-11-16 | 2010-02-12 | Kansai Paint Co Ltd | 耐食性に優れた塗料組成物 |
JP2012051979A (ja) * | 2010-08-31 | 2012-03-15 | Dainippon Toryo Co Ltd | 防錆顔料組成物及び防錆塗料組成物 |
KR101695865B1 (ko) | 2016-04-19 | 2017-01-13 | 한재진 | 수용성 녹 비활성화제 조성물 및 이를 포함하는 수용성 녹 비활성화제 |
JP2017523275A (ja) * | 2014-07-07 | 2017-08-17 | ユニバーシティ・カレッジ・ダブリン,ナショナル・ユニバーシティ・オブ・アイルランド,ダブリン | 熱制御コーティング |
Non-Patent Citations (1)
Title |
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See references of EP1731580A4 * |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2007126565A (ja) * | 2005-11-04 | 2007-05-24 | Dainippon Toryo Co Ltd | 亜鉛めっき鋼板又は亜鉛合金めっき鋼板用塗料組成物及びその塗装鋼板 |
JP2010031297A (ja) * | 2009-11-16 | 2010-02-12 | Kansai Paint Co Ltd | 耐食性に優れた塗料組成物 |
JP2012051979A (ja) * | 2010-08-31 | 2012-03-15 | Dainippon Toryo Co Ltd | 防錆顔料組成物及び防錆塗料組成物 |
JP2017523275A (ja) * | 2014-07-07 | 2017-08-17 | ユニバーシティ・カレッジ・ダブリン,ナショナル・ユニバーシティ・オブ・アイルランド,ダブリン | 熱制御コーティング |
KR101695865B1 (ko) | 2016-04-19 | 2017-01-13 | 한재진 | 수용성 녹 비활성화제 조성물 및 이를 포함하는 수용성 녹 비활성화제 |
Also Published As
Publication number | Publication date |
---|---|
KR100866699B1 (ko) | 2008-11-03 |
DE602005018463D1 (de) | 2010-02-04 |
CA2559947C (en) | 2012-05-22 |
CN1934204B (zh) | 2010-08-18 |
CN1934204A (zh) | 2007-03-21 |
KR20080075233A (ko) | 2008-08-14 |
JP4154439B2 (ja) | 2008-09-24 |
US20090078158A1 (en) | 2009-03-26 |
US7828884B2 (en) | 2010-11-09 |
JPWO2005089071A1 (ja) | 2008-01-31 |
KR100871207B1 (ko) | 2008-12-01 |
CA2559947A1 (en) | 2005-09-29 |
US20070012220A1 (en) | 2007-01-18 |
ATE452950T1 (de) | 2010-01-15 |
EP1731580A4 (en) | 2007-04-04 |
WO2005089071A3 (ja) | 2005-11-17 |
EP1731580A2 (en) | 2006-12-13 |
KR20070009616A (ko) | 2007-01-18 |
EP1731580B1 (en) | 2009-12-23 |
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