WO2005035222A1 - 押出成形機 - Google Patents
押出成形機 Download PDFInfo
- Publication number
- WO2005035222A1 WO2005035222A1 PCT/JP2003/012966 JP0312966W WO2005035222A1 WO 2005035222 A1 WO2005035222 A1 WO 2005035222A1 JP 0312966 W JP0312966 W JP 0312966W WO 2005035222 A1 WO2005035222 A1 WO 2005035222A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- cylinder
- foam
- temperature
- die
- silo
- Prior art date
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/30—Mixing; Kneading continuous, with mechanical mixing or kneading devices
- B29B7/34—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices
- B29B7/38—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary
- B29B7/46—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary with more than one shaft
- B29B7/48—Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary with more than one shaft with intermeshing devices, e.g. screws
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/30—Mixing; Kneading continuous, with mechanical mixing or kneading devices
- B29B7/58—Component parts, details or accessories; Auxiliary operations
- B29B7/60—Component parts, details or accessories; Auxiliary operations for feeding, e.g. end guides for the incoming material
- B29B7/603—Component parts, details or accessories; Auxiliary operations for feeding, e.g. end guides for the incoming material in measured doses, e.g. proportioning of several materials
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/30—Mixing; Kneading continuous, with mechanical mixing or kneading devices
- B29B7/58—Component parts, details or accessories; Auxiliary operations
- B29B7/72—Measuring, controlling or regulating
- B29B7/726—Measuring properties of mixture, e.g. temperature or density
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/30—Mixing; Kneading continuous, with mechanical mixing or kneading devices
- B29B7/58—Component parts, details or accessories; Auxiliary operations
- B29B7/72—Measuring, controlling or regulating
- B29B7/728—Measuring data of the driving system, e.g. torque, speed, power, vibration
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/80—Component parts, details or accessories; Auxiliary operations
- B29B7/82—Heating or cooling
- B29B7/823—Temperature control
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/80—Component parts, details or accessories; Auxiliary operations
- B29B7/82—Heating or cooling
- B29B7/826—Apparatus therefor
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/80—Component parts, details or accessories; Auxiliary operations
- B29B7/88—Adding charges, i.e. additives
- B29B7/94—Liquid charges
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B9/00—Making granules
- B29B9/02—Making granules by dividing preformed material
- B29B9/06—Making granules by dividing preformed material in the form of filamentary material, e.g. combined with extrusion
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B9/00—Making granules
- B29B9/12—Making granules characterised by structure or composition
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C44/00—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
- B29C44/34—Auxiliary operations
- B29C44/36—Feeding the material to be shaped
- B29C44/46—Feeding the material to be shaped into an open space or onto moving surfaces, i.e. to make articles of indefinite length
- B29C44/54—Feeding the material to be shaped into an open space or onto moving surfaces, i.e. to make articles of indefinite length in the form of expandable particles or beads
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/04—Particle-shaped
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/06—Rod-shaped
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/285—Feeding the extrusion material to the extruder
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/285—Feeding the extrusion material to the extruder
- B29C48/286—Raw material dosing
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
- B29C48/50—Details of extruders
- B29C48/76—Venting, drying means; Degassing means
- B29C48/762—Vapour stripping
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/78—Thermal treatment of the extrusion moulding material or of preformed parts or layers, e.g. by heating or cooling
- B29C48/80—Thermal treatment of the extrusion moulding material or of preformed parts or layers, e.g. by heating or cooling at the plasticising zone, e.g. by heating cylinders
- B29C48/83—Heating or cooling the cylinders
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/78—Thermal treatment of the extrusion moulding material or of preformed parts or layers, e.g. by heating or cooling
- B29C48/875—Thermal treatment of the extrusion moulding material or of preformed parts or layers, e.g. by heating or cooling for achieving a non-uniform temperature distribution, e.g. using barrels having both cooling and heating zones
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B29C2793/00—Shaping techniques involving a cutting or machining operation
- B29C2793/009—Shaping techniques involving a cutting or machining operation after shaping
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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- B29C2948/00—Indexing scheme relating to extrusion moulding
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- B29C2948/92095—Angular velocity
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92009—Measured parameter
- B29C2948/92114—Dimensions
- B29C2948/92152—Thickness
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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- B29C2948/00—Indexing scheme relating to extrusion moulding
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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- B29C35/00—Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
- B29C35/02—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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- B29C48/40—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders using two or more parallel screws or at least two parallel non-intermeshing screws, e.g. twin screw extruders
- B29C48/404—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders using two or more parallel screws or at least two parallel non-intermeshing screws, e.g. twin screw extruders the screws having non-intermeshing parts
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2003/00—Use of starch or derivatives as moulding material
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2023/00—Use of polyalkenes or derivatives thereof as moulding material
- B29K2023/10—Polymers of propylene
- B29K2023/12—PP, i.e. polypropylene
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/04—Condition, form or state of moulded material or of the material to be shaped cellular or porous
Definitions
- the present invention relates to an extruder. Background art
- packing cushioning materials housed with these devices have been frequently used.
- a packing cushioning material is obtained by foaming a foam material made of a resin such as polypropylene and molding a foam having small voids formed therein.
- foams are generally produced by an extruder.
- the foaming material is supplied into the cylinder, the foaming fluid such as water and oil is supplied from the tank into the cylinder, and the foaming material and the foaming fluid are kneaded with the screw in the cylinder. While heating the cylinder, it heats up at once. At this time, the foaming fluid kneaded with the foaming material is exposed to high pressure in the cylinder and is in a condensed state or a partially vaporized state. Then, when the foamed material containing the condensed foaming fluid is extruded from a hole formed in the die, the pressurized state is released at a stretch, and explosive vaporization occurs to form a foam.
- the foaming fluid such as water and oil
- a main object of the present invention is to provide an extrusion molding machine capable of preventing backflow of a foaming fluid and improving production efficiency.
- the extrusion molding machine of the present invention includes a silo to which a foaming material constituting a foam is supplied, a cylinder and a screw for kneading and conveying the foaming material supplied to the silo, and is connected to a tip of the cylinder.
- a heater for heating stepwise for heating stepwise.
- the foam material examples include common plastics such as polyethylene (PE), polypropylene (PP), polyamide (6 nylon, 6, 6 nylon, etc .; PA), polyethylene terephthalate (PET), and polylactic acid.
- Biodegradable plastics can be used.
- a material obtained by adding a predetermined additive to these plastics or an extender such as paper or starch can be used.
- an extender such as paper and starch a plant- or wood-derived material such as ground wood flour, activated carbon, and tea husk may be added. In this case, by adding these materials, it is also possible to suppress the adsorption and absorption of undesired substances and the generation of bacteria and viscera.
- Stepwise heating means heating in several stages between the initial temperature and the final temperature.For example, the cylinder is divided into several places, these set temperatures are changed, and stepwise heating is performed. , Etc. to increase the temperature by applying a temperature gradient. If the initial temperature and the final temperature are specified, the set temperature between them is not particularly limited. Therefore, the setting may be such that the temperature is gradually increased, or the temperature may be temporarily reduced on the way.
- a foam is produced as follows.
- the foamed material supplied to the silo is supplied into the cylinder.
- the silo and the screw are fed from the nozzle of the tank connected to the supply path between the silo and the screw.
- the foaming fluid in the tank is supplied to a supply path between the screw and the screw.
- these materials including the foaming fluid supplied into the cylinder are uniformly kneaded by the rotation of the screw while being heated by the heater.
- the foamed material in the cylinder is heated step by step by the heater and becomes a molten state at the final temperature.
- the foaming fluid in the cylinder is heated by the heater to an initial temperature lower than the vaporization temperature at first, and then gradually heated to the final temperature.
- the kneaded material (kneaded material) in which the condensed foaming fluid is uniformly dispersed in the molten foam material is conveyed to the die side by the rotation of the screw.
- the kneaded material conveyed to the die side is further extruded to the outside through a hole formed in the die while being formed into a predetermined shape through the die by rotation of the screw.
- the condensed foaming fluid is released from the pressurized state and evaporates explosively, and the foamed material is rapidly cooled and hardened. A foam having voids is formed.
- the foaming fluid supplied into the cylinder is heated stepwise as the kneading material is conveyed, so that the foaming fluid is heated in comparison with the conventional case where the fluid is heated up to the vaporization temperature or more at once.
- the foaming fluid can be prevented from flowing back to the tank without being affected by sudden changes in expansion.
- the foaming fluid is supplied to the supply path between the screw and the silo, the foaming fluid is not supplied directly to the screw in the cylinder, so it is affected by changes in the foaming fluid in the cylinder. Therefore, the backflow of the foaming fluid to the tank side can be further prevented. In this way, backflow to the tank side can be prevented, so that a foam of stable quality can be efficiently produced.
- the object of the present invention can be achieved.
- the foaming fluid is water
- the heater has an initial temperature of 60 ° C. or more and less than 100 ° C., and a final temperature of 160 ° C.
- the temperature is set at less than 40 ° C., and the foaming material and the foaming fluid are heated in six stages.
- the water supplied into the cylinder is first exposed to a temperature below the boiling point (normally, the boiling point of water is 100 ° C) by the heater, and then heated in six stages, Finally, it is exposed to the environment of more than 160 ° C and less than 240 ° C.
- the heated water is once vaporized, then pressurized and condensed by the foamed material conveyed in and after the space surrounded by the cylinder and the die, discharged from the die to the outside, and pressurized. When the state is released, it evaporates at a stretch, so that a foam is formed. Even when water that is easily available as described above is used as a raw material, backflow of water can be prevented by heating in stages, and therefore, a foam having stable quality can be efficiently produced at low cost.
- the foaming material is formed in a granular form, and that the foaming material includes a vibration mechanism that intermittently vibrates a side portion of the siphon.
- the powdery foam material a powdery material, a granular material, a pellet-like material, a pulverized material, and the like can be used. '
- the vibration mechanism for example, a mechanism that uses a motor to rotate the cam to strike the side of the silo to vibrate, a mechanism that vibrates by electromagnetic vibration using a leaf spring, an electromagnet, or the like is used. it can.
- the vibration mechanism intermittently vibrates the side portions of the silo, thereby eliminating the adhesion between the foamed materials.
- the foamed powder material can be smoothly supplied into the cylinder.
- the vibration mechanism includes a motor and a cam connected to the motor, and the cam strikes a side surface of the silo in response to driving of the motor. It is preferable to vibrate the rhinoceros.
- the vibration mechanism can be constructed relatively simply by attaching the cam to the motor and arranging the tip of the cam rotated by the motor to strike the side surface of the silo.
- a plurality of extrusion holes are formed in the die, and the plurality of holes have a triangular shape defined by three adjacent holes. It is preferable that they are distributed so as to be equal.
- the quality of the shape and the like may be unstable due to the occurrence of unfoamed parts, the occurrence of blisters due to excessive foaming, and the clogging of the foamed material in the die, that is, the non-fused portion of the foam.
- the distance between the plurality of holes formed in the die is approximately equal, so that the shape of the foam discharged from the die and foamed Quality can be easily stabilized.
- each of the plurality of holes is formed in a circular shape, and the diameter of the circular hole is 1.8 mn! Preferably it is ⁇ 2.2 mm.
- a temperature control device for adjusting the temperature of the die to a temperature between 160 ° C and 220 ° C.
- the temperature of the die is set to be lower than 160 ° C by heating by the temperature control device, there is a possibility that an insufficiently foamed portion may be generated. If the temperature is higher than ° C, there is a risk that excessive heat will cause kogation in the foamed material due to thermal degradation. Therefore, by controlling the temperature of the die in the above-described range, a foam having sufficient foaming and high quality can be obtained more reliably.
- the extruder may be provided with a cutter which is arranged on the cylinder side instead of the die and cuts the foam extruded from the cylinder by rotating at a constant speed. ,.
- a base portion which is attached to a cylinder and discharges the kneaded material extruded from the cylinder, and a cutter body which cuts a foam formed by foaming the kneaded material discharged from the die portion.
- a cutter body which cuts a foam formed by foaming the kneaded material discharged from the die portion.
- the foam of any length can be easily manufactured.
- FIG. 1 is a diagram schematically showing an extruder according to a first embodiment of the present invention.
- FIG. 2 is an exploded perspective view showing a part of a cylinder and a die according to the first embodiment.
- FIG. 3 is a front view showing the die.
- FIG. 4 is a view showing a plate-like foam according to the first embodiment.
- FIG. 5 is a diagram schematically showing an extruder according to a second embodiment of the present invention.
- FIG. 6 is a perspective view showing a cutter according to the second embodiment.
- FIG. 7 is a view showing a cylindrical foam according to the second embodiment.
- FIG. 1 is a diagram schematically showing an extruder 11 according to the present invention.
- an extruder 11 heats and melts a foamed material 1 containing a thermoplastic resin such as polypropylene, extrudes it into a predetermined shape, and molds the foamed material having voids therein.
- the foamed material 1 includes a base 2 as a main component and an additive 3 for adjusting the base 2 so that uniform voids are formed.
- Base 2 contains 40% by weight of polypropylene 2A as a resin component powder, It contains 60% by weight of powdered corn starch 2B as a non-resin component.
- the melting point of polypropylene 2A is 160 ° C.
- the polypropylene 2A other shapes such as pellets other than powder may be used.
- the additive 3 is talc 3A added at a predetermined weight ratio to the base 2.
- the resin component cannot be disposed of as general waste.
- Non-resin components are components other than metals, paper, glass, and plastic that are not subject to recycling, and are not subject to recycling under the Containers and Waste Recycling Law and can be disposed of as general waste. .
- the additive is a foaming regulator added to adjust the degree of foaming when the foamed material is foamed.
- the raw material tank 20 includes a first tank 21 to which polypropylene 2A is supplied, and a second tank 22 to which corn starch 2B and talc 3A are supplied and uniformly mixed. Prepare.
- the silo 30 temporarily stores the raw materials 2 A, 2 B, and 3 A supplied from the raw material tank 20, and stores a predetermined amount of each of the raw materials 2 A, 2 B, and 3 A in the cylinder 5. It is automatically supplied into 0.
- the silo 30 includes a first silo 31 connected to the first tank 21 via a pipe 3OA, and a second silo 3 2 connected to a second tank 22 via a pipe 30B.
- the first silo 31 temporarily stores the polypropylene 2A and supplies the polypropylene 2A into the cylinder 50.
- the silo mouth body 33 having a mortar-shaped taper and A vibration mechanism 34 for intermittently beating and vibrating the side surface 33 A of the silo body 33 is provided. Since polypropylene 2A has relatively high fluidity, a configuration without the vibration mechanism 34 is also possible.
- the vibration mechanism 3 4 includes a motor 3 4 1 and a cam 3 4 2 attached to the motor 3 4 1.
- the cam 3 4 2 rotates according to the driving of the motor 3 4 1, and the cam 3 4
- the tip 3 4 2 A of 2 beats the side 3 3 A of the silo body 33 periodically.
- the side portion 3 3 A of the silo body 33 vibrates, so that even if the polypropylenes 2 A adhere to each other in the silo body 33, these adhesions are released.
- the polypropylene 2A falls along the mortar-shaped taper and moves to the cylinder 50 side.
- the second silo 32 temporarily accommodates corn starch 2B and talc 3A, and supplies these raw materials 2B and 3A into the cylinder 50.
- the same silo body 33 as described above is used.
- a vibration mechanism 34 is used.
- the fluid tank 40 stores water 41 which is a foaming fluid, and supplies the water 41 into the cylinder 50 through a pipe 40 connected to a path between the silo 30 and the screw 70. .
- the cylinder 50 has a hollow box shape that stores the foamed material 1 supplied from the silo 30 and the water 41 supplied from the fluid tank 40.
- FIG. 2 is an exploded perspective view showing a part of the cylinder 50 and the die 80.
- the cylinder body 51 has an elliptical opening 51A for discharging a kneaded material A (FIG. 1), which is a kneaded material of the raw materials 1 and 41, and upper and lower sides of the opening 51A.
- a total of four bolt holes 51B are formed.
- the discharge portion 52 has an opening 51A and four bolt holes 51B, and is formed with a fitting hole 52A for fitting a part of the die 80.
- the heaters 60 independently heat the six locations 50 A to 50 F of the cylinder 50, and the six heaters 60 attached to the respective locations 50 A to 50 F of the cylinder 50 A heater body 61 (61A to 61F) and a control unit 62 for controlling the temperatures of these six heater bodies 61 (61A to 61F) are provided.
- the temperatures of the six locations 50A to 50F of the cylinder 50 are set in six stages as follows in order from the right side in FIG. The temperature setting varies depending on the raw materials used, the water content in the raw materials, weather conditions, and the like.
- the heater body 61 displays the set temperatures of the respective portions 50 A to 50 F and the actually measured temperatures.
- the screw 70 kneads the foaming material 1 and the water 41 supplied into the cylinder 50, conveys the kneaded material A, and discharges the kneaded material A to the outside via the discharge portion 52 of the cylinder 50. It has two screw bodies 71, 72 and a drive unit 73 for rotating these two screw bodies 71, 72, and has a two-axis structure.
- the two screw bodies 71 and 72 are arranged adjacent to each other in the cylinder 50 so as to be substantially parallel to each other. Threads 71 A and 72 A are formed on the two screw bodies 71 and 72, respectively. These threads 71 A and 72 A are oriented in the same direction.
- the driving unit 73 rotates the two screw bodies 71 and 72 in directions approaching each other.
- the die 80 has a function of forming a void in the kneading material A discharged from the discharge portion 52 of the cylinder 50 to form a foam B, and a molding of the foam B.
- a first block 81 composed of four members, and a second block 83 attached to the discharge side of the first block 81.
- the first block 81 includes a fitting projection 811 fitted into the fitting hole 52A of the discharge portion 52 of the cylinder 50, and a first block main body 812 having a rectangular parallelepiped shape.
- each eyelet 82A is 2.0 mm.
- FIG. 3 shows the first block main body 8 12 opposite to the fitting projection 8 11 It is a front view showing a side surface.
- the rectangular portion 8 12 A As shown in FIG. 3, when the plurality of small holes 8 2 A define a rectangular portion 8 12 A formed to be wide in the horizontal direction, which is a direction orthogonal to the extrusion direction, the rectangular portion 8 2 A
- the rectangular portion 812A has a shape corresponding to the extruded shape.
- two rectangular ports 812A are provided at upper and lower sides of the rectangular section 812A at positions corresponding to the four port holes 51B of the cylinder body 51, for a total of four port holes. Holes 812B are formed.
- the second block 83 is for forming a void in the kneading material A to form a foam B having a predetermined cross section.
- the second block 8 3 a box having a plate-shaped base portion 8 3 1 attached to the first block 81, a hollow formed in the base portion 8 3 1, and a certain length in the direction of extrusion And a shaped part 8 32.
- a position corresponding to the plurality of small holes 82A of the first block 81 that is, a rectangular opening 831A corresponding to the rectangular portion 812A is formed.
- four bolts at the upper and lower sides of the opening 831A corresponding to the four bolt holes 812B of the first block 81 are provided with four bolts.
- Notch 8 3 B is formed.
- a supply-side opening 832A is formed at a position corresponding to the opening 831A on the surface on the opening 831A side.
- an emission-side opening 832B having the same shape as the supply-side opening 832A is formed on the surface opposite to the surface on the opening 831A side.
- the molded portion 832 has a box-shaped upper surface 832Z which is configured to be attached and detached by itself. By removing the upper surface 832Z, the inside is exposed and can be easily cleaned.
- the blocks 81 and 82 correspond to each other.
- Four bolts 86 are inserted into the notches 83B, the bolt holes 81B, and the bolt holes 5IB, and are fixed to the cylinder 50.
- the belt conveyor 90 conveys the foam B discharged from the injection side opening 832 B of the second block 83 constituting the die 80, and also coarsens the foam B. It cuts.
- the transport path of the belt conveyor 90 is provided with a press roller for adjusting the thickness of the product and a rough cutter.
- the rough cutting cutter adjusts the width of the product according to the conveyor speed of the belt conveyor 90, and is provided with a cooling fan for cooling the foam B and a cutting device for cutting the foam B.
- the foam B is stored in a predetermined box after being configured as a final product.
- the final product stored in this box is appropriately enclosed in a bag or the like and shipped as a product. Next, the procedure for producing the foam B will be described.
- a predetermined amount of polypropylene 2A from the first silo 31 and the second Predetermined amounts of raw materials 2 B and 3 A are supplied into the cylinder 50 from the silo 32.
- a predetermined amount of water 41 is supplied from the fluid tank 40 to a raw material supply path between the screw 70 and the silo 30.
- the polypropylene 2A is completely melted when heated by the heater 60 and reaches a melting point of 160 ° C. or higher, that is, when transported to the third location 50 C or higher.
- Other raw materials 2B and 3A are uniformly dispersed in the molten polypropylene 2A.
- the water 41 is heated by the heater 60, but since the first point 5OA of the cylinder 50 is set at 80 ° C, the water 41 is completely heated at the first point 5OA. It is not vaporized and remains mostly liquid. After that, the second place 50 B or higher In this case, it is heated to a temperature higher than the vaporization temperature and vaporized to vapor, but it is condensed due to the pressurized atmosphere between the cylinder 50, the raw material to be transported later, and the die 80. . As a result, water in a state in which steam and a liquid are mixed is included in the kneading material A.
- the elongate kneading material A that has passed through the small holes 82A is rapidly decompressed and foams explosively, resulting in a plurality of elongated foams B corresponding to the plurality of small holes 82A. Since the plurality of small holes 82A are evenly arranged as described above, these elongated foams B are tightly integrated with each other without any gap.
- the volume of water 41 which is a foaming fluid, becomes 1200 times when it is vaporized.
- Water 41 in kneading material A is required in a large excess to dissolve the hydrophilic component of the additive added to generate uniform foaming and to generate sufficient steam explosion (foaming). You.
- the addition of excess water 41 in this manner removes latent heat when it is extruded from the die 80 and evaporates.Therefore, some of the water vapor inside the foamed tissue returns to water in a liquid state.
- the volume of the foam B may be reduced by the water 41, and the tissue may shrink, and a sufficient foam may not be obtained.
- the energy deprived at this time is 2.26 MJ / kg (converted to 539 kca1 / kg). Accordingly, in order to secure the deprived energy, the die 80 is continuously heated by the temperature control device 100 to promote the vaporization of the water 41 and suppress the shrinkage of the foam B. ⁇
- the integrated foam B is supplied into the forming portion 832 of the second block 83 via the opening 831A of the base 831 and the supply side opening 832A of the forming portion 832. .
- the foam B supplied into the molding portion 832 is formed in a plate shape having a rectangular cross section while being transported to the injection side opening 832 B, and the injection side opening 83 2 It is extruded to the outside through B and molded.
- the plate-shaped continuous foam B discharged from the injection-side opening 832B is conveyed by the belt conveyor 90.
- the conveyed foam B is appropriately cut into a predetermined shape.
- the foam B is manufactured by the above procedure. According to the above-described embodiment, the following effects can be obtained.
- the water 41 supplied into the cylinder 50 is heated step by step by the heater 60 as the screw 70 is transported.
- the backflow of the water 41 to the tank 40 can be prevented without being affected by a sudden change in the expansion of the water 41.
- the water 41 is supplied to the supply path between the screw 70 and the silo 30, the water 41 is not directly supplied to the screw 70 in the cylinder 50, so Since the water 41 is not affected by the change in the water 41, the backflow of the water 41 to the tank 40 can be further prevented. As described above, since the backflow to the tank 40 side can be prevented, the foam B having stable quality can be efficiently produced.
- the side wall 33A of the silos 31 and 32 is beaten by the vibration mechanism 34 to intermittently vibrate the side wall 33A.
- the adhesion of the raw materials 2A, 2B, and 3A is eliminated, and the powdery raw materials 2A, 2B, and 3A can be smoothly supplied into the cylinder 50.
- the cam 34 is attached to the motor 341, so that the tip of the cam 34 rotating by driving the motor 34 strikes the side portion 33A of the silos 31 and 32.
- the vibration mechanism 34 can be easily configured simply by arranging it.
- the heater 60 can easily adjust the heating temperature of the six locations 50A to 50F of the cylinder 50 with one control unit 62, so that the temperature adjustment is easy.
- the cylinder 50 can be temperature-controlled in six steps, so that a higher quality foam B can be manufactured by appropriately changing the temperature and the environment at the time of manufacture.
- a plurality of small holes 82A are formed so that the triangular arrangement pattern defined by the three small holes 82A adjacent to each other is the same. Quality can be easily stabilized. At this time, since the diameter of the small hole 82A is set to 2.0 mm, foaming can be performed more favorably and a stable shape can be formed.
- the temperature of the die 80 is adjusted to a temperature between 160 ° C and 220 ° C by the temperature control device 100, so that unnecessary shrinkage can be suppressed and foaming can be surely made. A foam B having a good shape can be produced.
- the first block 81 since the fitting projection 811 that fits into the fitting hole 52A of the discharge portion 52 of the cylinder 50 is provided, the first block 81 It can be prevented from coming off from or slipping out of 2. In addition, there is an advantage that the escape of steam due to high pressure can be prevented.
- the foam B in the molding portion 832 can be sufficiently molded.
- the upper surface 8332Z is detachable, so that the inside can be easily cleaned after manufacturing.
- foam B Since the main component is a non-resin component that can be disposed of as general waste, foam B is not a component to be recycled under the Containers and Recycling Law. For this reason, since the foam B can be treated as general waste, it can be easily disposed of at a reduced cost. At this time, the content of the resin component is smaller than that of a general foam, so that when incinerated, the calorific value is small and black smoke is not generated, so that the environment can be protected. It should be noted that even with such a composition, a foam B that can be sufficiently used as an actual product can be manufactured.
- foam B Since such a foam B has flexibility due to voids formed therein, it can be suitably used as a cushioning material for sensitive equipment such as precision equipment and fruits. Further, since the foam B has a relatively high specific heat, it can be suitably used as a heat insulating material.
- Polypropylene 2A is used as the resin component, but foam 2B can be easily manufactured because polypropylene 2A is more excellent in workability and mechanical suitability than other resin components.
- the foam B Since the foam B is finally made into a plate shape, it can secure a certain degree of rigidity in addition to flexibility.For example, it can be used as a partition plate for separating fruits and vegetables individually or as a heat insulating material. It can be suitably used. In addition, since the foam B has sufficient restorability and poor water solubility, it can be sufficiently used as a cushioning material for packing.
- the extruder 12 according to the second embodiment of the present invention is different from the extruder 11 according to the first embodiment in a portion corresponding to a die 80, and other configurations are completely the same. It is. For this reason, only the cutter 200, which is a part arranged in place of the die 80, will be described.
- FIG. 5 is a diagram schematically showing an extruder 12 according to the present invention.
- FIG. 6 is an enlarged view of the cutter 200.
- the cutter 200 foams the kneading material A extruded from the cylinder 50 to form a foam B, and cuts the foam B.
- the cutter 200 includes a mounting portion 210 attached to the discharge portion 52 of the cylinder 50, and a cutter main body 220.
- the mounting portion 210 is mounted on the discharge portion 52 of the cylinder 50 to foam the kneading material A extruded from the cylinder 50 and to function as a die. It has a hollow box-shaped base member 211 and a plate-shaped auxiliary member 221 formed on a surface of the base member 211 on the extrusion side.
- the trapping member 2 12 has a small hole 2 12 A penetrating therethrough.
- a not-shown fitting portion that fits into the fitting hole 52A of the discharge portion 52 of the cylinder 50 is formed on the surface of the cylinder 50 side.
- a rectangular opening is formed.
- a hole (not shown) larger than the small hole 2 12 A is formed at a position corresponding to the small hole 2 12 A on a surface 2 IX of the auxiliary member 2 12 which is a surface on the extrusion side. Therefore, the kneading material A extruded from the cylinder 50 passes through the inside of the base material 211. It is pushed out from the small hole 2 12 A of the auxiliary member 2 12. When extruded, the kneaded material A is decompressed and foams to form a foam B.
- the power cutter main body 220 supports the mounting portion 210 and cuts the foam B extruded from the mounting portion 210 into a predetermined length. And a support member 225 for supporting the shaft member 221.
- the shaft member 222 cuts the extruded foam B, and includes a shaft body 222 and a blade 222 attached to a tip of the shaft body 222.
- the shaft body 222 is configured to be rotatable at a constant speed by a drive mechanism such as a motor (not shown).
- the rotation speed can be adjusted by controlling the driving mechanism.
- the blade 223 includes two blades 223A and 223B in a direction perpendicular to the shaft main body and parallel to each other. These two blades 2 2 3 A and 2 2 3 B have their respective cutting edges 2 24 oriented in the direction of rotation indicated by arrow C in the figure. Thus, for example, while the blade 2 23 A makes one rotation in the direction of arrow C, the blade tip 2 24 passes over the small hole 2 12 A twice.
- the support member 225 is a member that supports the shaft main body 222 and the mounting portion 210.
- the kneaded material A extruded from the cylinder 50 passes through the inside of the base material 211, and is extruded from the small hole 2 12 A of the catching member 21 2. Is done.
- the kneading material A is decompressed and foams to form a foam B.
- the foam B extruded from the small hole 21A is cut into a predetermined length by the two blades 22A and 22B that rotate with the rotation of the shaft body 222. In this way, as shown in FIG. 7, a cylindrical foam B having a predetermined length of, for example, about 10 cm is formed.
- the foam B is formed into a relatively small cylindrical shape, even when used as a cushioning material for precision equipment, it can be arranged without gaps, and the internal precision equipment can be reliably protected.
- polypropylene 2A is used as the foam material, but is not limited thereto, and other thermoplastic resins may be used.
- corn starch 2B, talc 3A, and the like were added, but these may not be added, or other materials may be added.
- a material obtained by mixing materials such as wood flour, activated carbon, and tea husk at a fixed ratio may be employed. At this time, it is preferable to mix these materials to such an extent that they can exhibit an adsorption function and a function of suppressing the generation of bacteria and mold by adding these materials.
- the composition of the foam material 1 is not particularly limited.
- the foaming fluid is water 41.
- the present invention is not limited to this.
- other fluids such as oils and fats may be used.
- the initial temperature is set at 80 ° C., but is not limited thereto, and may be set at, for example, 50 ° C. Further, the initial temperature may be set to a temperature equal to or higher than the vaporization temperature depending on the raw material.
- the final temperature was 230 ° C., but is not limited to this, and may be, for example, 150 ° C., that is, the temperature at which the foaming fluid is completely vaporized.
- the temperature may be any temperature at which the foam material melts.
- the heater 60 is set in six steps. However, the present invention is not limited to this.
- the heater 60 may be set in three steps.
- the raw materials 2 and 3 are in the form of powder and granules, but may be in a state of being coarsely pulverized.
- the vibration mechanism 34 is constituted by the motor 341 and the cam 3442.
- the present invention is not limited to this.
- other mechanisms such as a mechanism for electromagnetically vibrating may be used. May be adopted.
- the embodiment has an advantage that the raw material can be supplied more efficiently.
- the vibration mechanism 34 is provided in both of the two silos.
- the vibration mechanism may be configured in only one of the silos, and the raw material may be supplied with sufficient efficiency. If it does not need to be provided.
- the screw 70 has two axes.
- the present invention is not limited to this, and the screw 70 may have one axis.
- the number of the blades 223 is two, but may be one, and the number is not particularly limited.
- the diameter of the small hole 82 A was as follows. Table 2 shows the diameter of the small holes 82A in each example and the state (properties) of the foam.
- the diameter of the small hole 82 A in the first embodiment is set as follows: Was the same as in Examples 1 to 3.
- Table 2 shows the diameter of the small hole 82 A and the state (properties) of the foam in each comparative example.
- the set temperature of the die 80 by the temperature control device 100 is as follows.
- Table 3 shows the set temperature and the shape of the foam in each example.
- the procedure was the same as in Examples 4 to 7, except that the set temperature of the die 80 by the temperature control device 100 was as follows.
- Table 3 shows the set temperature of the temperature control device 100 and the shape of the foam in each comparative example.
- Set temperature of temperature control device 100 room temperature, 240 ° C
- the present invention can be used as an extrusion molding machine for molding a foam having small voids formed therein, and protects precision instruments such as electronic devices and electronic components and perishable items such as fruits from external impact. Can be used for the production of cushioning material for packaging.
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- Engineering & Computer Science (AREA)
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- Thermal Sciences (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
- Molding Of Porous Articles (AREA)
Abstract
Description
Claims
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
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CNB2003801104690A CN100513133C (zh) | 2003-10-09 | 2003-10-09 | 挤压成形方法 |
EP03751419A EP1671778A4 (en) | 2003-10-09 | 2003-10-09 | EXTRUSION MOLDING MACHINE |
AU2003271148A AU2003271148A1 (en) | 2003-10-09 | 2003-10-09 | Extrusion molding machine |
PCT/JP2003/012966 WO2005035222A1 (ja) | 2003-10-09 | 2003-10-09 | 押出成形機 |
US10/575,105 US20070122515A1 (en) | 2003-10-09 | 2003-10-09 | Extrusion molding machine |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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PCT/JP2003/012966 WO2005035222A1 (ja) | 2003-10-09 | 2003-10-09 | 押出成形機 |
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WO2005035222A1 true WO2005035222A1 (ja) | 2005-04-21 |
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PCT/JP2003/012966 WO2005035222A1 (ja) | 2003-10-09 | 2003-10-09 | 押出成形機 |
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US (1) | US20070122515A1 (ja) |
EP (1) | EP1671778A4 (ja) |
CN (1) | CN100513133C (ja) |
AU (1) | AU2003271148A1 (ja) |
WO (1) | WO2005035222A1 (ja) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN103101166A (zh) * | 2012-12-14 | 2013-05-15 | 刘福华 | 一种pp原料板材生产工艺及装置 |
CN103101167A (zh) * | 2012-12-20 | 2013-05-15 | 刘福华 | 一种pp原料棒材挤出生产工艺 |
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CN102601916B (zh) * | 2012-03-15 | 2016-05-04 | 大连吉润高新技术机械有限公司 | 一种智能大容量挤注成型机组 |
JP6277446B2 (ja) * | 2013-03-21 | 2018-02-14 | 日本碍子株式会社 | 連続押出成形装置 |
CN103465459A (zh) * | 2013-09-27 | 2013-12-25 | 昆山凯诺尔金属制品有限公司 | 一种节能塑料挤出机 |
US9943987B2 (en) * | 2013-12-26 | 2018-04-17 | Mold-Masters (2007) Limited | Extruder feed path vibrator |
EP3922610A4 (en) * | 2019-03-04 | 2022-03-02 | BKT Co., Ltd. | ECOLOGICAL FOAMING BODY AND METHOD FOR MANUFACTURING THEREOF |
CN114407269A (zh) * | 2021-12-21 | 2022-04-29 | 中广核博繁新材料(南通)有限公司 | 一种聚丙烯发泡粒子混炼挤出设备及使用方法 |
CN118372503B (zh) * | 2024-06-21 | 2024-10-01 | 四川省现代生物技术有限公司 | 一种蒲公英金银花根茎叶花提取设备及其提取方法 |
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- 2003-10-09 WO PCT/JP2003/012966 patent/WO2005035222A1/ja active Application Filing
- 2003-10-09 EP EP03751419A patent/EP1671778A4/en not_active Withdrawn
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CN103101166A (zh) * | 2012-12-14 | 2013-05-15 | 刘福华 | 一种pp原料板材生产工艺及装置 |
CN103101167A (zh) * | 2012-12-20 | 2013-05-15 | 刘福华 | 一种pp原料棒材挤出生产工艺 |
CN103101167B (zh) * | 2012-12-20 | 2016-04-20 | 深圳市恩欣龙特种工程塑料有限公司 | 一种pp原料棒材挤出生产工艺 |
Also Published As
Publication number | Publication date |
---|---|
AU2003271148A1 (en) | 2005-04-27 |
US20070122515A1 (en) | 2007-05-31 |
CN100513133C (zh) | 2009-07-15 |
CN1839027A (zh) | 2006-09-27 |
EP1671778A1 (en) | 2006-06-21 |
EP1671778A4 (en) | 2008-02-20 |
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