WO2004080681A1 - Appareils et procedes destines au traitement electrostatique de formulations polymeres - Google Patents

Appareils et procedes destines au traitement electrostatique de formulations polymeres Download PDF

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Publication number
WO2004080681A1
WO2004080681A1 PCT/US2004/006812 US2004006812W WO2004080681A1 WO 2004080681 A1 WO2004080681 A1 WO 2004080681A1 US 2004006812 W US2004006812 W US 2004006812W WO 2004080681 A1 WO2004080681 A1 WO 2004080681A1
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WO
WIPO (PCT)
Prior art keywords
processed material
stage
target
electrostatically processed
electrostatically
Prior art date
Application number
PCT/US2004/006812
Other languages
English (en)
Inventor
Georgios D. Karles
John M. Layman
Diane L. Gee
Robert J. Maher
William R. Sweeney
Original Assignee
Philip Morris Products S.A.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Philip Morris Products S.A. filed Critical Philip Morris Products S.A.
Priority to JP2006509182A priority Critical patent/JP2006524739A/ja
Priority to EP04718491A priority patent/EP1601512A1/fr
Priority to AU2004220079A priority patent/AU2004220079A1/en
Priority to CA002517445A priority patent/CA2517445A1/fr
Publication of WO2004080681A1 publication Critical patent/WO2004080681A1/fr
Priority to NO20054603A priority patent/NO20054603L/no

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B13/00—Conditioning or physical treatment of the material to be shaped
    • B29B13/08—Conditioning or physical treatment of the material to be shaped by using wave energy or particle radiation
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00—Formation of filaments, threads, or the like
    • D01D5/0007—Electro-spinning
    • D01D5/0061—Electro-spinning characterised by the electro-spinning apparatus
    • D01D5/0069—Electro-spinning characterised by the electro-spinning apparatus characterised by the spinning section, e.g. capillary tube, protrusion or pin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B5/00—Electrostatic spraying apparatus; Spraying apparatus with means for charging the spray electrically; Apparatus for spraying liquids or other fluent materials by other electric means
    • B05B5/025—Discharge apparatus, e.g. electrostatic spray guns
    • B05B5/057—Arrangements for discharging liquids or other fluent material without using a gun or nozzle
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D13/00—Complete machines for producing artificial threads
    • D01D13/02—Elements of machines in combination
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/70—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres
    • D04H1/72—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres the fibres being randomly arranged
    • D04H1/728—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres the fibres being randomly arranged by electro-spinning
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H13/00—Other non-woven fabrics
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/02—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of forming fleeces or layers, e.g. reorientation of yarns or filaments
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B5/00—Electrostatic spraying apparatus; Spraying apparatus with means for charging the spray electrically; Apparatus for spraying liquids or other fluent materials by other electric means
    • B05B5/025—Discharge apparatus, e.g. electrostatic spray guns

Definitions

  • Electrostatic processing techniques use electrostatic force to draw a charged polymer formulation from a source to a collector.
  • the electrostatic field acts to accelerate the liquid from the source to the collector, on which the electrostatically processed material is collected.
  • Apparatuses and methods for electrostatically processing polymer formulations are provided.
  • the apparatuses and methods can provide continuous production of electrostatically processed materials.
  • a preferred embodiment of an apparatus for electrostatically processing a polymer formulation comprises a feeding stage operable to continuously eject electrostatically processed material comprising a polymer formulation; a collection stage spaced from the feeding stage; a power supply operable to generate an electric field, which causes the electrostatically processed material ejected from the feeding stage to deposit on the collection stage; and a pick-up stage including a removing device disposed to continuously remove the electrostatically processed material from the collection stage.
  • Polymer formulations that can be electrostatically processed using preferred embodiments of the apparatuses and methods include polymer solutions, dispersions, suspensions, emulsions, mixtures thereof, and polymer melts.
  • the electrostatically processed material can have various forms, including fibers, droplets, beads, films, dry porous films, webs, mats and/or combinations thereof.
  • the electrostatically processed material preferably has at least one micro-scale or nano-scale dimension.
  • Another preferred embodiment of the apparatus comprises a treatment stage, which is operable to treat the electrostatically processed material at the collection stage and/or after being removed from the collection stage.
  • the material can be heated, cured, rolled, cut, stretched, and/or treated to change its surface chemical structure.
  • the treatment stage can also be operated to apply one or more substances to the electrostatically processed material.
  • Another preferred embodiment of the apparatus comprises at least one thickness sensor and/or slack sensor for detecting the thickness of, and/or the amount of slack in, the electrostatically processed material.
  • the apparatus can include a controller, which is operable to receive signals from the sensor(s) and adjust the collection stage and/or pick-up stage, as appropriate, to maintain a desired thickness and/or amount of slack.
  • a preferred embodiment of a method for electrostatically processing a polymer formulation comprises generating an electric field; supplying a polymer formulation to a feeding stage; continuously ejecting electrostatically processed material from the feeding stage through the electric field; collecting the electrostatically processed material at a collection stage; and continuously removing the electrostatically processed material from the collection stage.
  • Figure 1 illustrates a preferred embodiment of an apparatus for electrostatic processing.
  • Figure 2 illustrates a preferred embodiment of a feeding device of the apparatus, which includes multiple nozzles.
  • Figure 3 illustrates another preferred embodiment of the feeding device, which includes dual flow passages and multiple nozzles.
  • Figure 4 illustrates a preferred embodiment of the feeding device including a brush.
  • Figure 5 illustrates another preferred embodiment of the feeding device including a brush construction.
  • Figure 6 illustrates another preferred embodiment of the feeding device, which includes nozzles and nozzle cleaning structure.
  • Figure 7 illustrates a preferred embodiment of the apparatus including a collection stage, a post-collection stage and sensors for monitoring the electrostatically processed material.
  • Figure 8 illustrates a preferred embodiment of the apparatus, which includes a post-collection treatment stage.
  • Figure 9 illustrates another preferred embodiment of the apparatus including a rolling stand.
  • Figure 10 illustrates another preferred embodiment of the apparatus including a release sheet application roll.
  • Figure 11 illustrates a preferred embodiment of the apparatus including the feeding device shown in Figure 5.
  • Figure 12 illustrates a preferred embodiment of the apparatus including the feeding device shown in Figure 6.
  • Figure 13 illustrates another preferred embodiment of the apparatus including a target, which rotates in a liquid.
  • Figure 14 illustrates another preferred embodiment of the apparatus including a funnel-shaped target.
  • Preferred embodiments of apparatuses and methods for electrostatically processing polymer formulations can provide continuous production of electrostatically processed materials.
  • the electrostatically processed materials can be in various forms, including, but not limited to, fibers, droplets, beads, films, dry porous films, webs, mats and/or combinations thereof.
  • the electrostatically processed materials can be micro-scale or nano- scale materials.
  • micro-scale and nano-scale denote materials that have at least one micro-scale dimension, or at least one nano-scale dimension, respectively.
  • the dimension can be, for example, a diameter, maximum transverse dimension, length, width and/or height.
  • the electrostatically processed materials also can have compositions, structures and properties that can be varied by the selection of starting materials and/or processing conditions.
  • electrostatic processing denotes electrostatic spinning (electrospinning) and electrostatic spraying (electrospraying) techniques. Electrospinning produces fibers, and electrospraying produces droplets or clusters of droplets. Such fibers continuously collect on the collection stage, while the droplets or droplet clusters collect in individual droplets on the collection stage.
  • An electrostatically processed material can be formed by electrospinning or electrospraying a polymer formulation by manipulating components of the polymer system and/or changing various process parameters, such as applied voltage, distance from the feeding stage to the collection stage, volumetric flow rate, and the like.
  • process parameters such as applied voltage, distance from the feeding stage to the collection stage, volumetric flow rate, and the like.
  • whether a polymer formulation electrospins or electrosprays can be controlled by changing physical characteristics of the polymer formulation, such as changes in concentration, solvent selection, polymer molecular weight, polymer branching, and the like.
  • FIG. 1 A preferred embodiment of an apparatus 20 for electrostatically processing polymer formulations is depicted in Figure 1.
  • the apparatus 20 comprises a feeding stage 30 and a collection stage 40.
  • the apparatus 20 preferably also includes a pick-up stage, as described below.
  • the apparatus 20 can optionally also include a post-collection treatment stage, as also described below.
  • the feeding stage 30 is operable to continuously eject a polymer formulation 45, which is electrostatically processed.
  • the feeding stage 30 can comprise one feeding device, or alternatively multiple feeding devices.
  • the electrostatically processed material 72 is deposited on, and preferably continuously removed from, the collection stage 40.
  • the polymer formulation can be a polymer solution, dispersion, suspension, emulsion, mixtures thereof, or a polymer melt.
  • the polymer formulation can comprise one-phase or two-phase systems.
  • Exemplary polymer formulations include, but are not limited to, cellulose acetate, poly(ethy!ene- co-vinylacetate), poly(lactic acid), and blends thereof, poly(acrylonitrile), polyaniline-sulfonated styrene, polyaniline, polyester, poly(ethyleneterephthalate), poly(propylene), poly(ethylene) and blends thereof.
  • Exemplary suitable solvents for the polymer formulation include, but are not limited to, water for aqueous solvent-based polymer formulations, and organic solvents, such as acetone and alcohols, for organic solvent- based polymer formulations.
  • Polymer melts can be prepared by techniques known to those skilled in the art and electrostatically processed.
  • Preparation techniques may include premixing and melting the components of the polymer, such as by melt mixing in a heated extrusion apparatus.
  • Electrostatic processing techniques are described, for example, in Larrondo, L. and S. John Manley, J "Electrostatic Fiber Spinning from Polymer Melts, I. Experimental
  • the feeding stage 30 is electrically connected to a power supply 50, which applies a voltage to the feeding stage.
  • the power supply 50 can be either DC or an AC power supply.
  • the collection stage 40 is at ground potential.
  • the feeding stage 30 is operable to introduce the polymer formulation 45 into the electric field.
  • the electric field produces an electrostatic force, which draws the polymer formulation through the space from the feeding stage 30 to the collection stage 40, where the polymer formulation deposits to form fibers, droplets, and/or structures comprising fibers and/or droplets, especially when a transition from electrospraying to electrospinning occurs during processing of a polymer formulation.
  • the electrospraying to electrospinning transition may occur or not occur as the concentration of the polymer in the polymer formulation is increased.
  • a preferred embodiment of the feeding stage 30 is depicted in Figure
  • the feeding stage 30 comprises a feeding device 130 including a flow passage 132 in fluid communication with a manifold 134.
  • the manifold 134 can include a single nozzle, or preferably a plurality of nozzles 136, as shown.
  • the nozzles 136 can be arranged parallel to each other as depicted, or alternatively can have other desired orientations.
  • the nozzles 136 can be positioned in a horizontal plane as depicted, or alternatively can be positioned at different angles relative to the horizontal to change the direction of impingement of the electrostatically processed material on the collection stage 40.
  • the number of nozzles 136 in the manifold 134 can be chosen based on different factors, such as the desired throughput of fibers from the feeding device 130, or the size of the collection surface(s) of the collection stage on which the polymer is deposited.
  • the number of nozzles 136 in the manifold 134 and/or the number of manifolds 134 including nozzles 136 can be increased in the apparatus to increase throughput of electrostatically processed material.
  • the size of the nozzle 136 openings of the manifold 134 can be the same as each other, or two or more nozzles can have different sized openings.
  • the nozzles 136 can have a suitable nozzle opening size and length to produce a jet or spray of the polymer formulation with desired characteristics.
  • the polymer formulation is supplied to the flow passage 132 of the feeding device 130 from a source 138 in fluid communication with the flow passage 132.
  • the source 138 preferably has a sufficiently large capacity of the polymer formulation to allow for the continuous production of a desired amount of electrostatically processed material by operation of the apparatus.
  • the feeding stage 30 preferably comprises at least one pump 137 between the source 138 and flow passage 132.
  • the pump 137 is operable to supply the polymer formulation to the manifold 134, preferably at a controlled rate, to thereby control the ejection rate of the polymer formulation from the nozzle(s) 136.
  • the pump 137 can be used to supply a single manifold, or alternatively two or more manifolds.
  • the polymer formulation can be fed through the one or more nozzles 136 of the manifold 134 using various alternative feeding techniques including, for example, gravity, compressed air, piston motion, or the like.
  • FIG. 3 depicts a feeding device 230 according to another preferred embodiment.
  • the feeding device 230 includes a first flow path 233 in fluid communication with a first source 238 of a polymer formulation, a solvent, at least one optional active component, or a mixture of a solvent and at least one optional active component, and a second flow path 235 in fluid communication with a second source 239 of a polymer formulation, a solvent, at least one optional active component, or a mixture of a solvent and at least one optional active component.
  • the first and second polymer formulations can be the same or different formulations.
  • the active component can be, for example, at least one cross-linking agent, photoinitiator, thermal initiator, or the like.
  • the first flow path 233 and second flow path 235 are in fluid communication with the flow passage 232.
  • the feeding device 230 is operable to produce electrostatically processed materials from a single polymer formulation or from two-component polymer formulations. Particularly, the same or different polymer formulation can be introduced via the first flow path 233 and second flow path 235 into the flow passage 232, where the polymer formulations are combined together to form a mixed polymer formulation, which is ejected from the nozzles 236.
  • a polymer formulation can be supplied from the first source 238 or second source 239, and a solvent or active component supplied from the other of the first source 238 or second source 239, to change the polymer formulation composition to affect the composition and/or processing characteristics of the polymer formulation.
  • the feeding device 230 preferably comprises a first pump 237 and a first valve 241 between the first source 238 and the flow passage 232, and a second pump 240 and a second valve 243 between the second source 239 and the flow passage 232, to supply the contents of the first source 238 and second source 239 to the manifold 234, preferably at controlled flow rates, to thereby control the ejection rate of the polymer formulation from the one or more nozzles 236 of the feeding device 230.
  • the solvent alone can be flowed to the manifold 234 from the first source 238 or second source 239 to clean the nozzles, as desired.
  • an in-line mixer 244 can be provided along the flow passage 232 to promote mixing of the polymer formulation prior to being ejected from the nozzles 236.
  • FIG 4 depicts a feeding device 330 according to another preferred embodiment.
  • the feeding device 330 includes an open container 332, which contains a polymer formulation, and a brush 340.
  • the feeding device 330 also includes a polymer formulation supply system 344, such as shown in Figure 3, to replenish the polymer formulation in the container 332 as it is consumed during electrostatic processing.
  • the brush 340 includes a plurality of bristles 342 made of an electrically conductive material, such as a metal or metal alloy.
  • the brush 340 can be connected to a suitable drive source 345, such as a variable speed motor, which is operable to rotate the brush 340 at a desired speed as indicated by arrow A.
  • a power supply 346 can be electrically connected to the brush 340, such as to the axis 347.
  • the power supply 346 can be either a DC or an AC power supply.
  • FIG. 5 illustrates a feeding device 430 according to another preferred embodiment.
  • the feeding device 430 includes an alternative brush 440, and a container 432 containing the polymer formulation 45.
  • the brush 440 includes a body 442 and bristle-like extensions 444 extending outward from the body 442.
  • the brush 440 is made of an electrically conductive metal or metal alloy.
  • the extensions 444 contact, and are wetted by, the polymer formulation 45 in the container 432, causing the polymer formulation 45 to be ejected into the electric field and drawn toward the collection stage.
  • a feeding device 530 according to another preferred embodiment is depicted in Figure 6.
  • the feeding device 530 includes a polymer formulation flow passage 560, a cleaning liquid flow passage 570, and a plurality of nozzles 581-588 extending outwardly from the surface 552.
  • the number of nozzles of the feeding device 530 can be varied to produce a desired ejection pattern and throughput of the polymer formulation.
  • a polymer formulation is supplied to the polymer formulation flow passage 560 from a source of the polymer formulation.
  • a cleaning liquid is supplied to the cleaning liquid flow passage 570 from a source of the cleaning liquid.
  • the feeding device 530 is rotatable as represented by arrow C, such that the nozzles 581-588 in succession come into fluid communication with the polymer formulation flow passage 560 containing the polymer formulation. As shown, when the feeding device 530 is at a particular angular orientation, a nozzle, such as nozzle 581 , is in fluid communication with the polymer formulation flow passage 560, such that the polymer formulation can be ejected from this nozzle.
  • the feeding device 530 includes a stationary mask 590 having an opening 591.
  • the mask 590 is provided to cover the inlet end of the nozzles 581-588 as they rotate over the mask 590.
  • the mask 590 covers the inlets of the nozzles 582-588, preventing the flow of the cleaning liquid into these nozzles.
  • the opening 591 supplies cleaning liquid to a nozzle as it rotates over the location of the opening 591.
  • the cleaning liquid can flow into nozzle 585 in communication with the opening 591 in the mask 590 in the illustrated position of the feeding device 530.
  • cleaning liquid can be sequentially supplied to the nozzles 581-588 as they rotate in this order over the mask 590.
  • the cleaning liquid can be any suitable liquid that is effective to remove polymer material that may deposit in the flow passages of the nozzles 581-588 during operation of the feeding device 530.
  • the cleaning liquid can be water for water-based polymer formulations, or acetones, alcohols, or other organic solvents for solvent-based polymer formulations.
  • the cleaning liquid is preferably flowed through the nozzles 581-588 at a high pressure to enhance removal of deposited polymer material from the flow passages of the nozzles. Accordingly, the nozzles 581-588 can be cleaned during operation of the feeding device 530 to achieve more consistent and uniform ejection of the polymer formulation from the nozzles.
  • the feeding stage 30 can include one or more feeding devices, such as the feeding devices 130, 230, 330, 430 and 530 described above, to enable the production of electrostatically processed material structures, such as mats or webs, composed of different polymeric materials, or to produce structures having different compositional and/or density characteristics.
  • the relative spatial locations of the different feeding devices of the feeding stage 30 can be chosen relative to each other and to the collection stage 40 to produce fibrous structures having different densities, morphologies, or other characteristics.
  • the polymer formulation feeding device can include an electrically conductive portion electrically connected to a pole of a power supply.
  • the electrically conductive portion can be, for example, the manifolds 134 ( Figure 2) and 234 ( Figure 3) of the feeding devices 130 and 230, respectively, or the brushes 340 ( Figure 4) and 440 ( Figure 5) of the feeding devices 330 and 430, respectively.
  • the polymer formulation can be charged by placing an electrode in the polymer formulation flow passage 560 of the feeding device 530.
  • the collection stage 40 can alternatively be charged, with the feeding stage 30 being grounded, in order to generate the electric field between the feeding stage and the collection stage.
  • the apparatus 100 includes a feeding device, such as the feeding device 230 described above, a collection stage 40, and a post-collection stage 60 downstream from the collection stage 40.
  • a feeding device such as the feeding device 230 described above
  • a collection stage 40 and a post-collection stage 60 downstream from the collection stage 40.
  • the polymer formulation 45 is ejected from the feeding device 230 onto a target 70 of the collection stage 40
  • electrostatically processed material 72 is formed on the outer surface 74 of the target 70
  • the electrostatically processed material is collected at the pick-up stage 60.
  • the target 70 includes a body 76, which can have various shapes and sizes. As depicted, the body 76 can be cylindrical roll having a cylindrical outer surface 74. Alternatively, the outer surface 74 of the body 76 can have other shapes, such as oval or the like. The outer surface 74 can include one or more flat portions and/or contoured portions (e.g., including protuberances, as well as depressions, grooves, channels, or the like). The shape and/or surface configuration of the outer surface 74 can be selected based on factors, such as the desired shape of the deposited polymer material. The body 76 of the target 70 can be solid, or alternatively can be hollow to reduce the weight of the target 70.
  • the body 76 can comprise a suitable electrically conductive material, such as aluminum, aluminum alloys, or like metals.
  • the target 70 can be made entirely of the electrically conductive material, or alternatively can include an outer portion, such as an electrically conductive coating, formed over the body 76 and including the outer surface 74.
  • the target 70 can be made of a non- conductive material.
  • the target 70 is positioned sufficiently close to a member made of a conductive material and connected to a pole of a power supply, which can be either a DC or an AC power supply, or alternatively grounded with voltage applied to the feeding stage, in order to generate the electric field.
  • the polymer formulation is ejected from the feeding stage 30, drawn toward the conductive member and deposited on the target 70.
  • the apparatus 100 can include one feeding stage and one target 70, or alternatively can include one or more feeding stages and two or more targets. By incorporating more than one target, the apparatus 100 can produce different electrostatically processed material structures, having the same or different polymeric compositions and/or structures, on the different targets. The different structures can be produced in any desired order on the different targets, such as simultaneously or sequentially.
  • the target 70 is preferably selectively rotatable (as represented by arrow D), and/or translatable in x, y and/or z directions, to change the location of the target at which the polymer formulation impacts during operation of the apparatus 100.
  • the target 70 can be mounted on a shaft 78, which is operatively connected to a motor 80 (preferably a variable speed motor) operative to rotate the target 70 in one direction, or in oscillating rotation, during set-up and/or operation of the apparatus 100 to control the formation of electrostatically processed material on the target.
  • the target 70 is preferably selectively rotatable by complete and/or partial reverse rotations.
  • the target 70 can be mounted on a translatable target support, which can be translated in x, y and/or z directions.
  • the target 70 preferably is rotatable and/or translatable at different speeds during electrostatic processing to control the thickness of the electrostatically processed material deposited on the target.
  • the pick-up stage 60 of the apparatus 100 is operative to remove the electrostatically processed material 72 from the target 70.
  • the pick-up stage 60 preferably is operative to continuously remove the electrostatically processed material 72 from the target 70, to enable continuous production by operation of the apparatus 100.
  • the pick-up stage 60 preferably also collects the removed electrostatically processed material 72.
  • the collected electrostatically processed material 72 can be subjected to one or more post-processing treatments to alter its structure and/or properties.
  • the pick-up stage 60 includes a suitable device for removing the electrostatically processed material 72 from the target.
  • the pick-up stage 60 can include one or more doctor blades 62 positioned relative to the target 70 to operatively interact with the target 70 to remove the electrostatically processed material 72 from the target surface 74.
  • the pick-up stage can include mechanical, vacuum, or gas assist devices to transfer the removed electrostatically processed material 72 from the target 70 to a desired location.
  • the pick-up stage 60 can comprise one roll, such as roll 64, or alternatively two or more rolls.
  • the roll 64 is rotated as represented by arrow E to wind the electrostatically processed material 72 removed from the target 70 onto the roll.
  • the roll 64 is preferably operatively connected to a motor 68 operative to rotate the roll 64 during operation of the apparatus 100 to control coiling of electrostatically processed material 72 onto the roll.
  • the roll 64 is preferably rotatable at different speeds depending on the rotation rate of the target 70.
  • the rolls can be vertically stacked, for example, to provide for uninterrupted changeover during processing.
  • the roll 64 preferably is also translatable to follow translational movements of the target 70.
  • the target 70 and roll can be mounted on a common translatable support.
  • the rate of pick-up of the removed electrostatically processed material 72 on the roll 64 can be the same or different from the rate at which the electrostatically processed material 72 is deposited on the target 70.
  • the rolls preferably can be operated at different speeds from each other to process the removed electrostatically processed material 72 to change its characteristics, such as its density and/or morphology.
  • the apparatus 100 preferably includes at least one thickness sensor 110 positioned to detect the thickness of the electrostatically processed material 72 on the target 70.
  • the thickness sensor 110 can be, for example, a reflective laser sensor, which emits light onto the material. Such thickness sensor 110 determines the thickness of the electrostatically processed material 72 on the target 70 based on the amount of time required for the light 112 to impinge on the electrostatically processed material 72 and reflect back to the thickness sensor 110.
  • Other types of sensors, such as light sensors or the like, can alternatively be used in the apparatus 100 to determine the thickness of the electrostatically processed material 72 on the target 70.
  • the apparatus 100 preferably also includes a controller 115, which is operable to receive signals from the thickness sensor 110 and determine the electrostatically processed material 72 thickness. If the controller determines that the electrostatically processed material 72 thickness is either above or below a desired thickness, the controller 115 can send a signal to the motor 80, causing adjustment of the rotational and/or translational speed of the target 70, so as to increase or decrease the residence time of the deposition surface(s) of the target 70 in the deposition zone. Accordingly, the apparatus 100 can control the thickness of the deposited electrostatically processed material 72 on the target 70. The rotational and/or translational speed of the target 70 can thus be adjusted to control the rate of production of electrostatically processed material by the apparatus.
  • the apparatus 100 preferably also includes at least one slack sensor
  • the slack sensor 120 positioned to detect the amount of slack in the electrostatically processed material 72 at one or more selected locations between the target 70 and the roll 64.
  • the slack sensor 120 can also be a reflective laser sensor, such as described above, which determines the amount of slack of the electrostatically processed material based on the amount of time required for the light 122 to impinge on the electrostatically processed material 72 and reflect back to the slack sensor 120.
  • the slack sensor 120 is also electrically connected to the controller 115.
  • the slack sensor 10 sends signals to the controller 115, which then determines the amount of slack in the electrostatically processed material 72. If the amount of slack differs from a desired value, the controller 115 sends a signal to the motor 68, causing adjustment of the rotational and/or translational speed of the roll 64, depending on the rotational and/or translational speed of the target 70, in order to maintain a desired level of slack in the electrostatically processed material 72.
  • the electrostatically processed material 72 removed from the target 70 can be transferred to the pick-up stage 60 either through the air, or alternatively through another fluid medium.
  • the removed electrostatically processed material can be transferred through one or more liquids to treat the polymer material.
  • the liquid can be an adhesive formulation (e.g., PVA glue, polyacrylate glue, or the like), or a solvent effective to form interfiber bonds in the electrostatically processed material 72.
  • an apparatus 200 includes a post-collection treatment stage 125 located between the collection stage 40 and the pick-up stage 60.
  • the treatment stage 125 is operable to impart desired physical, chemical and/or electrical properties to the polymer material.
  • the electrostatically processed material can be heated, cured, or subjected to corona treatment.
  • the treatment stage 125 can include a radiation emitting device operable to heat the material to a desired temperature.
  • the radiation emitting device can be, for example, a heater, such as a conventional heater or an infrared heater, or a furnace.
  • the heater can heat the material to a suitably high temperature to, for example, dry or cure the electrostatically processed material 72. Drying can be performed if the electrostatically processed material 72 has already been transferred through a liquid, as described above.
  • the treatment stage 125 can include an ultraviolet (UV) light or electron beam source, which can be used to cure some polymer formulations.
  • UV ultraviolet
  • the treatment stage 125 can include a corona treatment device operable to subject the electrostatically processed material to a corona treatment to create surface functional groups.
  • the treatment stage 125 can also, or alternatively, be operable to deposit one or more desired substances on the electrostatically processed material.
  • the treatment stage 125 can include a source of one or more dopants and/or catalysts, which can be applied to the electrostatically processed material.
  • the treatment stage 125 can include a source of one or more drugs or active ingredients, which can be applied to the material.
  • the treatment stage can apply one or more coating layers on the removed polymer material.
  • a coating having desired chemical and/or physical properties can be deposited on the removed electrostatically processed material.
  • the one or more substances, or coatings can be applied to the electrostatically processed material at the treatment stage 125 by a suitable application process, such as spraying, dipping, rolling, brushing, deposition processes, or the like, using a suitable applicator device.
  • a suitable application process such as spraying, dipping, rolling, brushing, deposition processes, or the like, using a suitable applicator device.
  • FIG. 9 depicts an apparatus 300 according to another preferred embodiment.
  • the apparatus 300 includes a rolling stand including rolls 65, through which the electrostatically processed material 72 is transferred.
  • the rolls 64 can reduce the thickness of the electrostatically processed material 72 to a desired thickness.
  • the electrostatically processed material can be stretched to impart directional stress in the material.
  • FIG. 10 depicts an apparatus 400 according to another preferred embodiment.
  • the apparatus 400 includes an applicator, such as a roll 67 of a release sheet 69, which applies the release sheet to the electrostatically processed material 72 at the collection stage to prevent blocking and allow easier separation of the coiled material.
  • an applicator such as a roll 67 of a release sheet 69
  • the electrostatically processed material 72 can be cut after it is removed from the target 70.
  • a cutting stage can be disposed to cut the removed electrostatically processed material 72 into mats of a desired length as an alternative to coiling a continuous length of the electrostatically processed material 72 onto the roll 64.
  • Figure 11 illustrates an apparatus 500 according to another preferred embodiment.
  • the apparatus 500 includes the feeding device 430 shown in Figure 5.
  • the apparatus 500 can include a treatment stage 225 disposed to treat the electrostatically processed material 72 while on the target 70.
  • one or more substances can be applied to the electrostatically processed material 72 at the target 70, as opposed to, or in addition to, at the treatment stage 125, as described above.
  • Figure 12 illustrates an apparatus 600 according to another preferred embodiment, which includes the feeding device 530 shown in Figure 6.
  • Figure 13 illustrates an apparatus 700 according to other preferred embodiment.
  • the apparatus 700 includes a feeding stage 30 and a collection stage 40.
  • the feeding stage 30 can include a multiple-nozzle feeding device, such as depicted.
  • the feeding stage 30 alternatively can include, for example, the feeding device 330, 430 or 530, as described above.
  • the collection stage 40 includes a target 70, and a container 90 of a liquid 92. As the target 70 is rotated, a portion of the target 70 comes into contact with and is wetted by, the liquid 92. A source 91 of the liquid 92 is in fluid communication with the container 90 to replenish the liquid consumed during processing.
  • the apparatus 700 can include a cascade liquid source to apply the liquid to electrostatically processed material deposited on the target 70.
  • the liquid 92 preferably has a composition effective to impart desired properties, characteristics and/or morphologies to the electrostatically processed material, or to promote bonding of the electrostatically processed material, such as inter-fiber bonding.
  • the liquid 92 can be a phase separation-producing solution that causes phase separation of the electrostatically processed material, resulting in different fiber morphologies, or liquid absorption.
  • the liquid 92 can alternatively be an active agent that is adsorbed within the electrostatically processed material, such as a cross-linking agent, catalyst, or the like.
  • the liquid 92 can be a binder effective to produce bonded structures, such as webs or mats, from electrostatically processed material deposited on the target 70.
  • FIG 14 illustrates an apparatus 800 according to another preferred embodiment.
  • the apparatus 800 includes a feeding stage 30 and a collection stage 40.
  • the feeding stage 30 can include a multi-orifice feeding device, such as depicted.
  • the feeding stage 30 can include, for example, a feeding device 330, 430 or 530, as described above.
  • the collection stage 40 includes a funnel-shaped target 95, which may be stationary or movable.
  • the target 95 includes a conical portion 96 and a passage 97 extending through the target.
  • the polymer formulation 45 is ejected from the feeding device 30 and electrostatically processed material 72 is collected on the inner surface of the conical portion 96 of the target 95.
  • the collected electrostatically processed material 72 can be removed from the conical portion 96 using a suitable gas emitting device 98, such as a gas gun or the like.
  • a vacuum is created in the passage 97 by the vacuum system to draw the fibers as a continuous thread 99 through the passage.
  • the thread 99 may be collected on a spool, or the like.

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)
  • Electrostatic Spraying Apparatus (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Nonwoven Fabrics (AREA)
  • Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Treatments Of Macromolecular Shaped Articles (AREA)

Abstract

L'invention concerne des appareils et des procédés destinés au traitement électrostatique en continu de formulations polymères. Les appareils comprennent un étage d'alimentation fonctionnant de manière à éjecter en continu le matériau traité par procédé électrostatique et un étage de collecte qui sert à la collecte de matériaux éjectés. Les appareils comprennent également un dispositif destiné à évacuer en continu le matériau traité par procédé électrostatique de l'étage de collecte, et éventuellement pour rembobiner le matériau traité par procédé électrostatique. Un étage de traitement peut aussi servir à appliquer des substances au matériau traité par procédé électrostatique afin de modifier les caractéristiques du matériau et/ou pour traiter physiquement le matériau, par exemple, par laminage ou par réchauffement. Les matériaux traités par procédé électrostatique peuvent être à l'échelle micro ou nano.
PCT/US2004/006812 2003-03-07 2004-03-08 Appareils et procedes destines au traitement electrostatique de formulations polymeres WO2004080681A1 (fr)

Priority Applications (5)

Application Number Priority Date Filing Date Title
JP2006509182A JP2006524739A (ja) 2003-03-07 2004-03-08 ポリマー配合物を静電加工する装置及び方法
EP04718491A EP1601512A1 (fr) 2003-03-07 2004-03-08 Appareils et procedes destines au traitement electrostatique de formulations polymeres
AU2004220079A AU2004220079A1 (en) 2003-03-07 2004-03-08 Apparatuses and methods for electrostatically processing polymer formulations
CA002517445A CA2517445A1 (fr) 2003-03-07 2004-03-08 Appareils et procedes destines au traitement electrostatique de formulations polymeres
NO20054603A NO20054603L (no) 2003-03-07 2005-10-06 Apparat og metode for elektrostatisk prosessering av polymere formuleringer

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US45254303P 2003-03-07 2003-03-07
US60/452,543 2003-03-07

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AU (1) AU2004220079A1 (fr)
CA (1) CA2517445A1 (fr)
NO (1) NO20054603L (fr)
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DE102005008926A1 (de) * 2005-02-24 2006-11-16 Philipps-Universität Marburg Verfahren zur Herstellung von Nano- und Mesofasern durch Elektrospinning von kolloidalen Dispersionen
JP2007092212A (ja) * 2005-09-28 2007-04-12 Teijin Ltd 静電紡糸法により繊維構造体を製造する装置および方法
JP2007092237A (ja) * 2005-09-29 2007-04-12 Teijin Ltd 静電紡糸法による繊維構造体の製造方法
JP2007303015A (ja) * 2006-05-10 2007-11-22 Univ Of Shiga Prefecture 静電紡糸装置
WO2008010307A1 (fr) * 2006-07-21 2008-01-24 Hirose Seishi Kabushiki Kaisha Procédé de production d'un ensemble de microfibres
JP2008038312A (ja) * 2006-08-10 2008-02-21 Japan Vilene Co Ltd ポリマー溶液供給部材、静電紡糸装置及び静電紡糸不織布の製造方法
JP2008050719A (ja) * 2006-08-25 2008-03-06 Japan Vilene Co Ltd ポリマー溶液供給部材、静電紡糸装置及び静電紡糸不織布の製造方法
JP2008540858A (ja) * 2005-05-03 2008-11-20 ザ ユニバーシティ オブ アクロン 電界紡糸繊維の製造方法および製造装置ならびにそれらによって製造された繊維
JP2010502855A (ja) * 2006-09-06 2010-01-28 コーニング インコーポレイテッド ナノファイバー、ナノフィルムおよびそれらの製造／使用方法
JP2012122152A (ja) * 2010-12-06 2012-06-28 Toptec Co Ltd ナノ繊維製造装置
US8298471B2 (en) 2007-12-11 2012-10-30 Basf Se Process for producing nano- and mesofibers by electrospinning colloidal dispersions comprising at least one essentially water-insoluble polymer
WO2013165975A1 (fr) * 2012-04-30 2013-11-07 The Johns Hopkins University Microfibres étirées électromécaniquement et procédés d'utilisation de ces dernières
US8770959B2 (en) 2005-05-03 2014-07-08 University Of Akron Device for producing electrospun fibers
US8834775B2 (en) 2009-09-09 2014-09-16 Panasonic Corporation Method of manufacturing nanofibers
US8916086B2 (en) 2007-04-17 2014-12-23 Stellenbosch University Process for the production of fibers
EP2780150A4 (fr) * 2011-11-17 2015-10-28 Harvard College Systèmes, dispositifs et procédés destinés à la fabrication de fibres polymères
DE102014013354A1 (de) 2014-09-08 2016-03-10 Rainer Busch Die Erfindung betrifft eine Vorrichtung und Verfahren zur Herstellung von mikroverkapselten Paraffinpartikel durch ein elektrostatisches Rotationsdüsen-Absprühverfahren sowie die Verwendung dieses Verfahren. Die so verkapselten Paraffinpartikel können für
US10060851B2 (en) 2013-03-05 2018-08-28 Plexense, Inc. Surface plasmon detection apparatuses and methods
US10359362B2 (en) 2013-04-15 2019-07-23 Plexense, Inc. Method for manufacturing nanoparticle array, surface plasmon resonance-based sensor and method for analyzing using same
US10519569B2 (en) 2013-02-13 2019-12-31 President And Fellows Of Harvard College Immersed rotary jet spinning devices (IRJS) and uses thereof
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JP2008531860A (ja) * 2005-02-24 2008-08-14 ビーエーエスエフ ソシエタス・ヨーロピア コロイド状分散液のエレクトロスピニングによるナノ繊維およびメソ繊維の製造方法
DE102005008926A1 (de) * 2005-02-24 2006-11-16 Philipps-Universität Marburg Verfahren zur Herstellung von Nano- und Mesofasern durch Elektrospinning von kolloidalen Dispersionen
JP4805957B2 (ja) * 2005-02-24 2011-11-02 ビーエーエスエフ ソシエタス・ヨーロピア コロイド状分散液のエレクトロスピニングによるナノ繊維およびメソ繊維の製造方法
JP2008540858A (ja) * 2005-05-03 2008-11-20 ザ ユニバーシティ オブ アクロン 電界紡糸繊維の製造方法および製造装置ならびにそれらによって製造された繊維
JP4908498B2 (ja) * 2005-05-03 2012-04-04 ザ ユニバーシティ オブ アクロン 紡糸用電界紡糸装置、および紡糸方法
US8770959B2 (en) 2005-05-03 2014-07-08 University Of Akron Device for producing electrospun fibers
JP2007092212A (ja) * 2005-09-28 2007-04-12 Teijin Ltd 静電紡糸法により繊維構造体を製造する装置および方法
JP2007092237A (ja) * 2005-09-29 2007-04-12 Teijin Ltd 静電紡糸法による繊維構造体の製造方法
JP2007303015A (ja) * 2006-05-10 2007-11-22 Univ Of Shiga Prefecture 静電紡糸装置
WO2008010307A1 (fr) * 2006-07-21 2008-01-24 Hirose Seishi Kabushiki Kaisha Procédé de production d'un ensemble de microfibres
JP2008038312A (ja) * 2006-08-10 2008-02-21 Japan Vilene Co Ltd ポリマー溶液供給部材、静電紡糸装置及び静電紡糸不織布の製造方法
JP2008050719A (ja) * 2006-08-25 2008-03-06 Japan Vilene Co Ltd ポリマー溶液供給部材、静電紡糸装置及び静電紡糸不織布の製造方法
JP2010502855A (ja) * 2006-09-06 2010-01-28 コーニング インコーポレイテッド ナノファイバー、ナノフィルムおよびそれらの製造／使用方法
US8916086B2 (en) 2007-04-17 2014-12-23 Stellenbosch University Process for the production of fibers
US8298471B2 (en) 2007-12-11 2012-10-30 Basf Se Process for producing nano- and mesofibers by electrospinning colloidal dispersions comprising at least one essentially water-insoluble polymer
US8834775B2 (en) 2009-09-09 2014-09-16 Panasonic Corporation Method of manufacturing nanofibers
JP2012122152A (ja) * 2010-12-06 2012-06-28 Toptec Co Ltd ナノ繊維製造装置
EP2780150A4 (fr) * 2011-11-17 2015-10-28 Harvard College Systèmes, dispositifs et procédés destinés à la fabrication de fibres polymères
US9738046B2 (en) 2011-11-17 2017-08-22 President And Fellows Of Harvard College Methods for the fabrication of polymeric fibers
WO2013165975A1 (fr) * 2012-04-30 2013-11-07 The Johns Hopkins University Microfibres étirées électromécaniquement et procédés d'utilisation de ces dernières
US10119202B2 (en) 2012-04-30 2018-11-06 The Johns Hopkins University Method for preparing electro-mechanically stretched hydrogel micro fibers
US11779682B2 (en) 2012-04-30 2023-10-10 The Johns Hopkins University Electro-mechanically stretched micro fibers and methods of use thereof
US10519569B2 (en) 2013-02-13 2019-12-31 President And Fellows Of Harvard College Immersed rotary jet spinning devices (IRJS) and uses thereof
US11174571B2 (en) 2013-02-13 2021-11-16 President And Fellows Of Harvard College Immersed rotary jet spinning (iRJS) devices and uses thereof
US10060851B2 (en) 2013-03-05 2018-08-28 Plexense, Inc. Surface plasmon detection apparatuses and methods
US10359362B2 (en) 2013-04-15 2019-07-23 Plexense, Inc. Method for manufacturing nanoparticle array, surface plasmon resonance-based sensor and method for analyzing using same
DE102014013354A1 (de) 2014-09-08 2016-03-10 Rainer Busch Die Erfindung betrifft eine Vorrichtung und Verfahren zur Herstellung von mikroverkapselten Paraffinpartikel durch ein elektrostatisches Rotationsdüsen-Absprühverfahren sowie die Verwendung dieses Verfahren. Die so verkapselten Paraffinpartikel können für

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NO20054603L (no) 2005-12-05
JP2006524739A (ja) 2006-11-02
AU2004220079A1 (en) 2004-09-23
EP1601512A1 (fr) 2005-12-07
CN1774321A (zh) 2006-05-17
RU2005131013A (ru) 2006-03-20
KR20050113637A (ko) 2005-12-02
NO20054603D0 (no) 2005-10-06
CA2517445A1 (fr) 2004-09-23

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