WO2003086586A1 - Procede de separation de gaz - Google Patents
Procede de separation de gaz Download PDFInfo
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- WO2003086586A1 WO2003086586A1 PCT/JP2003/004655 JP0304655W WO03086586A1 WO 2003086586 A1 WO2003086586 A1 WO 2003086586A1 JP 0304655 W JP0304655 W JP 0304655W WO 03086586 A1 WO03086586 A1 WO 03086586A1
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- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
- B01D53/047—Pressure swing adsorption
- B01D53/053—Pressure swing adsorption with storage or buffer vessel
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- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
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- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
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- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
- B01D53/047—Pressure swing adsorption
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- C01B23/001—Purification or separation processes of noble gases
- C01B23/0036—Physical processing only
- C01B23/0052—Physical processing only by adsorption in solids
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- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
- B01D2253/102—Carbon
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- B01D2253/108—Zeolites
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- B01D2256/10—Nitrogen
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- B01D2259/40011—Methods relating to the process cycle in pressure or temperature swing adsorption
- B01D2259/40028—Depressurization
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- B01D2259/40035—Equalization
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- B01D2259/40011—Methods relating to the process cycle in pressure or temperature swing adsorption
- B01D2259/40043—Purging
- B01D2259/4005—Nature of purge gas
- B01D2259/40052—Recycled product or process gas
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- B01D2259/40011—Methods relating to the process cycle in pressure or temperature swing adsorption
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- B01D2259/40011—Methods relating to the process cycle in pressure or temperature swing adsorption
- B01D2259/40058—Number of sequence steps, including sub-steps, per cycle
- B01D2259/40064—Five
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- B01D2259/40011—Methods relating to the process cycle in pressure or temperature swing adsorption
- B01D2259/40058—Number of sequence steps, including sub-steps, per cycle
- B01D2259/40066—Six
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- B01D2259/40011—Methods relating to the process cycle in pressure or temperature swing adsorption
- B01D2259/40077—Direction of flow
- B01D2259/40081—Counter-current
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- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/40083—Regeneration of adsorbents in processes other than pressure or temperature swing adsorption
- B01D2259/40086—Regeneration of adsorbents in processes other than pressure or temperature swing adsorption by using a purge gas
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- C01B2210/00—Purification or separation of specific gases
- C01B2210/0029—Obtaining noble gases
- C01B2210/0035—Krypton
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- C01B2210/00—Purification or separation of specific gases
- C01B2210/0029—Obtaining noble gases
- C01B2210/0037—Xenon
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- C01B2210/00—Purification or separation of specific gases
- C01B2210/0043—Impurity removed
- C01B2210/0046—Nitrogen
Definitions
- the present invention relates to a method for separating gas components from a mixed gas containing at least two types of gas components, for example, a rare gas and a nitrogen gas, by using a pressure fluctuation type adsorption separation method.
- a method is used in which a rare gas is circulated in a processing chamber in a nitrogen gas atmosphere to generate plasma by high-frequency discharge, and the inside of the chamber is purged with nitrogen gas when an object to be processed is taken out.
- argon gas has been used as a rare gas in this treatment, but in recent years, the use of krypton gas or xenon gas has been studied in order to perform more advanced treatment.
- krypton gas / xenon gas is an extremely expensive gas due to its low abundance in air and the complicated separation process from air. For this reason, if krypton gas or xenon gas is used as a processing atmosphere gas and then discharged (discarded) as it is, there is a problem that the cost required for this atmosphere gas rises.
- the impurity concentration should be at least 100 ppm or less. It is necessary to separate the noble gas from the exhaust gas.
- This pressure fluctuation type adsorption separation method is applicable to the method of recovering a rare gas from the exhaust gas.
- the easily adsorbable components are adsorbed by the adsorbent, and the hardly adsorbable components are adsorbed, albeit slightly.
- the poorly adsorbable components are also present in the gaps between the adsorbents in the adsorption column, a considerable amount of the hardly adsorbable components will be contained in the regenerated exhaust gas discharged in the regeneration step. For this reason, it is difficult to increase the recovery rate of the target gas component (in this example, the hardly adsorbable component).
- Conventional pressure fluctuation type adsorption separation methods include a speed type pressure fluctuation type adsorption separation method using the difference in adsorption speed of the components to be adsorbed and an equilibrium type pressure fluctuation type adsorption separation method using the equilibrium adsorption amount difference. By combining these, the recovery rate can be increased.
- the desorption gas (regenerated exhaust gas) discharged during the regeneration process of the equilibrium pressure fluctuation type adsorption separation method and the velocity type pressure fluctuation type adsorption separation method is stored in a storage tank. Then, this can be mixed with the raw material gas and supplied to the adsorption step again as a circulating raw material gas.
- the equilibrium-type pressure fluctuation-type adsorption separation mechanism and the velocity-type pressure fluctuation-type separation mechanism each require two, that is, four adsorption cylinders in total.
- the gas separation method of alternately supplying a mixed gas to the first and second adsorption cylinders filled with adsorbents (equilibrium type and velocity type) having different adsorption characteristics two adsorption The separation can be performed by the cylinder, so the compactness of the equipment can be enhanced.
- the easily adsorbable component and the hardly adsorbable component to the equilibrium adsorbent are separated by the equilibrium pressure fluctuation type adsorption separation method, and the speed is determined by the speed type pressure fluctuation adsorption separation method in the second adsorption column.
- a method for separating easily adsorbed components and poorly adsorbed components from the adsorbent will be described. ⁇
- the mixed gas of the raw materials is introduced into the adsorption column under pressure to adsorb easily adsorbable components for each adsorbent, and recover the hardly adsorbable components as product gas.
- the pressure in the adsorption column is reduced to desorb the easily adsorbed components adsorbed by the adsorbent, thereby regenerating the adsorbent.
- the recycled exhaust gas is mixed with the mixed gas of the raw materials and supplied to the adsorption column in the adsorption process as circulating raw material gas.
- one adsorption column can be used for each pressure fluctuation type adsorption separation method.
- the product recovery rate is the ratio of the product gas derived flow rate to the circulating raw material gas supply flow rate defined below.
- the present invention has been made in view of the above circumstances, and when separating these gas components from a mixed gas containing a plurality of gas components by using a pressure fluctuation type adsorption separation method, these gas components are separated.
- An object of the present invention is to provide a gas separation method capable of efficiently recovering and reducing cost.
- the gas separation method of the present invention comprises: a first adsorption column provided with a first adsorbent that is hardly adsorbed to the first gas component and easily adsorbable to the second gas component; A second adsorption column provided with a second adsorbent which is easily adsorbable to one gas component and hard to adsorb to the second gas component,
- an adsorbing step of supplying the mixed gas under pressure, adsorbing the second gas component, and separating the first gas component as the first product gas is performed.
- Step 2 a regeneration step of desorbing the first gas component by decompression is performed (Step 2)
- a gas in the first adsorption column is introduced into the second adsorption column, and the pressure in the first adsorption column is reduced by equalizing the pressure in these adsorption columns.
- a regeneration step of desorbing the second gas component by depressurization is performed, and in the second adsorption column, the mixed gas is supplied under pressure, the first gas component is adsorbed, and the second gas component is converted into the second gas component.
- An equalizing pressure reducing step is performed, and in the first adsorption column, the first gas component and the second gas component are subjected to a pressure equalizing step of pressurizing the first adsorption column by introducing gas from the second adsorption column. It is characterized by being separated.
- the first and second product gas are stored in the first and second product gas storage tanks for storing the first and second product gas in the regeneration step in the first and second adsorption columns.
- Each product gas in the gas storage tank is introduced into the first and second adsorption columns, respectively.
- each product gas in the first and second product gas storage tanks is introduced.
- the first and second purge gas storage tanks storing the gas in the first and second adsorption cylinders as a purge gas are used, and the pressure equalization step in the first and second adsorption cylinders is performed. Then, the gas in the first and second adsorption cylinders is stored as a purge gas in the first and second purge gas storage tanks, respectively, in the regeneration process in the first and second adsorption cylinders. It is preferable to introduce the purge gas from the purge gas storage tank into the first and second adsorption columns, respectively.
- one of the first and second gas components can be krypton gas or xenon gas, and the other can be nitrogen gas.
- one of the first and second adsorbents can be an equilibrium separation type adsorbent, and the other can be a velocity separation type adsorbent.
- one of the first and second adsorbents can be activated carbon and the other can be zeolite.
- FIG. 1 is a schematic configuration diagram showing a gas separation device capable of performing a first embodiment of the gas separation method of the present invention.
- FIGS 2A to 2D are process diagrams of the first embodiment of the gas separation method of the present invention.
- FIG. 3 is a schematic configuration diagram showing a gas separation device capable of performing the second embodiment of the gas separation method of the present invention.
- 4A to 4D are process diagrams of a second embodiment of the gas separation method of the present invention.
- Figure 5 is a graph showing the test results.
- FIG. 1 shows a gas separation apparatus capable of performing a first embodiment of the gas separation method of the present invention.
- the gas separation device includes a raw material storage tank 1 into which a raw material gas that is a mixed gas containing at least two types of gas components is introduced, a compressor 2 that compresses the circulating raw material gas from the raw material storage tank 1, A first separation unit 3 for separating the first gas component in the circulating raw material gas from the compressor 2 as a first product gas, and a second separation unit for separating the second gas component in the circulating raw material gas as a second product gas It has four.
- the first separation unit 3 includes a first adsorption column 11 for separating a first gas component in the circulating raw material gas as a first product gas, and a first product gas storage tank 12 for storing the first product gas. I have.
- Reference symbol L3 is an introduction line for introducing the circulating raw material gas from the compressor 2 to the first adsorption column 11.
- the introduction line L3 is connected to a lower portion of the first adsorption column 11.
- the symbol L 4 has a function of introducing the first product gas from the first adsorption column 11 into the first product gas storage tank 12 and a function of returning the first product gas from the storage tank 12 to the adsorption column 11. It is a pipeline having The pipeline L4 is connected to an upper part of the first adsorption column 11.
- the symbol L5 is an outlet pipe for extracting the first product gas from the storage tank 12.
- Reference numeral L 9 denotes a return line for returning the regenerated exhaust gas from the first adsorption column 11 to the raw material storage tank 1.
- Reference symbol L I 1 is an introduction pipe for introducing the first product gas in the first product gas storage tank 12 into the first adsorption column 11 as a purge gas.
- the first adsorption column 11 uses a first adsorbent that is hardly adsorbable to the first gas component and easy to adsorb to the second gas component.
- the second separation unit 4 uses the second gas component in the circulating feed gas as the second product gas.
- a second adsorption column 21 for separation and a second product gas storage tank 22 for storing a second product gas are provided.
- Reference numeral L 6 denotes an introduction line for introducing the circulating raw material gas from the compressor 2 into the second adsorption column 21.
- the introduction line L6 is connected to a lower part of the second adsorption column 21.
- the symbol L7 has a function of introducing the second product gas from the second adsorption cylinder 21 into the second product gas storage tank 22 and a function of returning the second product gas from the storage tank 22 to the adsorption cylinder 21. It is a pipeline having The pipeline L7 is connected to the upper part of the second adsorption column 21.
- the symbol L8 is an outlet pipe for extracting the second product gas from the storage tank 22.
- Reference symbol L 10 denotes a return pipe for returning the regenerated exhaust gas from the second adsorption column 21 to the raw material storage tank 1.
- Reference numeral L12 denotes an introduction pipe for introducing the second product gas in the second product gas storage tank 22 into the second adsorption column 21 as a purge gas.
- the second adsorption column 21 uses a second adsorbent that is hardly adsorbable to the second gas component and is easily adsorbed “I” to the first gas component.
- activated carbon which is an equilibrium separation type adsorbent.
- Activated carbon has the properties of a large amount of krypton gas adsorbed (easily adsorbable) and a small amount of nitrogen gas adsorbed (poor adsorbent) as equilibrium adsorption. .
- zeolite 4A Na-A type zeolite which is a speed separation type adsorbent.
- Zeolite 4A is less likely to adsorb krypton gas with a relatively large molecular diameter (poor adsorbability), has a smaller molecular diameter than krypton gas, and has the property of adsorbing nitrogen gas (easy adsorbability). .
- This characteristic is a separation property generally called a velocity separation type. If an appropriate adsorption time is selected, nitrogen gas can be selectively adsorbed, and krypton gas can be adsorbed without adsorption. Can be derived from
- the above-mentioned mixed gas is introduced into the raw material storage tank 1 through the pipe L1 as the raw material gas.
- the first adsorber 11 has a cliff.
- An adsorption step is performed to adsorb ton gas and separate nitrogen gas as the first product gas.
- the circulating raw material gas from the raw material storage tank 1 is compressed by the compressor 2 and supplied to the first adsorption column 11 through the line L3.
- the nitrogen gas in the first product gas storage tank 12 is led out of the system as a first product gas through the pipe L5.
- the circulating raw material gas is supplied to the adsorption cylinder 11 and the valve V 2 is closed until the pressure of the adsorption cylinder 11 becomes higher than the storage tank 12. It is preferable to open the valve V2 when the pressure becomes higher than 12, and to introduce the gas in the adsorption column 11 into the storage tank 12 through the line L4.
- a pipe (not shown) connecting the adsorption cylinder 11 and the storage tank 12 was provided, and a check valve was provided in this pipe so that the pressure of the adsorption cylinder 11 became higher than that of the storage tank 12. At this point, the gas in the adsorption column 11 may be introduced into the storage tank 12 through this conduit.
- a regeneration step of desorbing nitrogen gas by decompression is performed.
- the valve V8 is opened to desorb the nitrogen gas adsorbed in the adsorption step prior to step 1, and is returned to the raw material storage tank 1 as regeneration exhaust gas through the line L10.
- the second adsorbent is regenerated.
- the krypton gas in the second product gas storage tank 22 is introduced into the second adsorption column 21 through the pipe L 12, and the krypton gas is passed through the second adsorption column 21, and the second adsorbent Promotes the desorption of nitrogen gas adsorbed on the surface.
- step 1 the gas (regenerated exhaust gas, etc.) returned from the adsorption column 21 (the adsorption column 11 in step 3) and the raw material gas introduced from line L1 Charge storage tank 1
- the circulating raw material gas which is a mixture of the return gas from the adsorption column 21 (the adsorption column 11 in the step 3) and the source gas, is supplied to the first adsorption column 11 (the step 3 in the step 3). 2 It is supplied to the adsorption column 21).
- the gas in the adsorption column 11 is introduced into the second adsorption column 21 to equalize the pressure in the adsorption columns 11
- An equalizing pressure reducing step for reducing the pressure of the adsorption column 11 is performed.
- valves VI and V4 are opened to connect the first adsorption column 11 and the second adsorption column 21 by the pipes L3 and L6.
- the first adsorption column 11 is in a high pressure state by step 1 (adsorption process), and the second adsorption column 21 is in a low pressure state by step 1 (regeneration process).
- the gas in the cylinder 11 is introduced into the second adsorption cylinder 21 through the pipes L3 and L6, and the first adsorption cylinder 11 is depressurized, so that the adsorption cylinders 11 and 21 are equalized.
- step 2 the first adsorption column 11 is depressurized, and the krypton gas adsorbed on the first adsorbent is desorbed and introduced into the second adsorption column 21 to pressurize the second adsorption column 21 An equalizing pressure step is performed.
- the gas from the first adsorption column 1.1 is introduced into the second adsorption column 21 by the pressure equalizing and depressurizing step, and krypton gas is supplied from the second product gas storage tank 22. It is introduced into the second adsorption column 21 through the path L7. Thereby, the second adsorption cylinder 21 is pressurized.
- step 2 (equalizing pressure reducing step in the first adsorption column 11 and equalizing pressure increasing step in the second adsorption column 21), the supply of the circulating raw material gas is continued without stopping the driving of the compressor 2. .
- This circulating raw material gas is supplied to the second adsorption cylinder 21 through the pipe L6 together with the gas introduced from the adsorption cylinder 11 to the adsorption cylinder 21.
- step 2 When shifting from step 1 to step 2, the introduction destination of the circulating feed gas changes from the first adsorption cylinder 11 to the second adsorption cylinder 21.In step 2, the first adsorption cylinder 1 1 Since the second adsorption column 21 is pressurized by the introduction of gas from the compressor, the load applied to the compressor 2 does not significantly decrease. 3)
- a regeneration step of desorbing krypton gas by decompression is performed.
- the krypton gas adsorbed in step 1 is desorbed by opening the valve V7, and is returned to the raw material storage tank 1 as regeneration exhaust gas through the line L9.
- the first adsorbent is regenerated.
- the nitrogen gas in the first product gas storage tank 12 is introduced into the first adsorption cylinder 11 through the pipe LI 1, and this nitrogen gas is passed through the first adsorption cylinder 11, and the first adsorbent It promotes the desorption of krypton gas adsorbed on the ground.
- an adsorption step of adsorbing nitrogen gas and separating krypton gas as a second product gas is performed.
- the circulating raw material gas from the raw material storage tank 1 is compressed by the compressor 2 and supplied to the second adsorption column 21 through the line L6.
- the krypton gas in the second product gas storage tank 22 is led out of the system as a second product gas through the line L8.
- adsorption pressure the highest ultimate pressure in the adsorption step in the adsorption step in a range of 300 to 500 kPa (gauge pressure).
- adsorption pressure is set to more than 500 kPa (gauge pressure), it is necessary to increase the flow rate of the circulating raw material gas supplied to the adsorption column 21. growing.
- the impurity concentration in the product gas will increase, resulting in an increase in the amount of adsorbent charged or a decrease in the product recovery rate.
- the equipment cost and operating cost can be kept low without lowering the product recovery rate. .
- the circulating raw material gas is supplied to the adsorption cylinder 21 and the valve V 5 is closed until the pressure of the adsorption cylinder 21 becomes higher than the storage tank 22. It is preferable to open the valve V5 when the pressure becomes higher than 22 and to introduce the gas in the adsorption cylinder 21 into the shell tank 22 through the line L7.
- a pipe (not shown) connecting the adsorption cylinder 21 and the storage tank 22 was provided, and a check valve was provided in this pipe so that the pressure of the adsorption cylinder 21 became higher than that of the storage tank 22. At this point, the gas in the adsorption column 21 may be introduced into the storage tank 22 through this conduit.
- the gas in the second adsorption column 21 is introduced into the first adsorption column 11 to equalize the adsorption columns 11 and 21 to form the second adsorption column 21.
- valves VI and V4 are opened to connect the first adsorption column 11 and the second adsorption column 21 by the pipes L3 and L6.
- the pressure of the first adsorption column 11 is low due to step 3 (regeneration process), and the pressure of the second adsorption column 21 is high due to step 3 (adsorption process).
- the gas in the cylinder 21 is introduced into the first adsorption cylinder 11 through the lines L6 and L3, and the second adsorption cylinder 21 is depressurized. I will be hit.
- step 4 the second adsorption column 21 is depressurized, the nitrogen gas adsorbed on the second adsorbent is desorbed, and introduced into the first adsorption column 11 to pressurize the first adsorption column 11 A pressure equalizing and pressurizing step is performed.
- the gas from the second adsorption column 21 is While being introduced into the first adsorption column 11, the nitrogen gas in the storage tank 12 is introduced into the first adsorption column 11 from the first product gas storage tank 12 through the line L 4. Thereby, the inside of the first adsorption column 11 is pressurized.
- step 4 (equalizing pressure reducing step in the second adsorption column 21 and equalizing pressure increasing step in the first adsorption column 11), the supply of the circulating raw material gas is continued without stopping the driving of the compressor 2. .
- the circulating raw material gas is supplied to the first adsorption column 11 through the pipe L3 together with the gas introduced from the adsorption column 21 to the adsorption column 11.
- step 4 When shifting from step 3 to step 4, the introduction destination of the circulating feed gas changes from the second adsorption cylinder 21 to the first adsorption cylinder 11, but in step 4, the second adsorption cylinder 2 1 Since the first adsorption column 11 is pressurized by the introduction of gas from the compressor, the load applied to the compressor 2 does not significantly decrease.
- the cycle time (time required for a series of processes, the time required for steps 1 to 4 in the above embodiment) in the pressure fluctuation type adsorption separation method is an important factor that has a large effect on product recovery and adsorbent loading. Parameter.
- the cycle time should be set so that the amount of adsorbent and compressor capacity can be set low according to the type of adsorbent and the component concentration of the circulating feed gas without reducing the product recovery.
- a connecting line L14 connecting the line L13 on the outlet side of the compressor 2 and the raw material storage tank 1 is provided, and the circulating raw material gas from the compressor 2 is provided. A part of the waste gas can be returned to the raw material storage tank 1 through the connecting line L14.
- Steps 2 and 4 the adsorbing cylinder 11 and the adsorbing cylinder 21 are communicated with each other by the pipelines L3 and L6, and the adsorbing cylinder 11 and the adsorbing cylinder 21 are equalized.
- a pipe (not shown) connecting the adsorption cylinder 11 and the adsorption cylinder 21 is provided separately from the pipes L3 and L6.
- the cylinder 21 may be connected.
- Step 2 the gas in the first adsorption column 11 is introduced into the second adsorption column 21 to equalize the adsorption column 11 and the adsorption column 21. Perform the depressurizing step and the equalizing pressurizing step.
- Step 2 since the pressure of the first adsorption column 11 is reduced, the gas containing a large amount of krypton gas adsorbed by the first adsorption column 11 is introduced into the second adsorption column 21 together with the circulating raw material gas. .
- the krypton concentration in the gas introduced into the second adsorption column 21 in step 2 becomes higher than the krypton gas concentration in the circulating feed gas.
- step 4 the gas in the second adsorption column 21 is introduced into the first adsorption column 11 to equalize the pressure in the adsorption column 11 and the adsorption column 21. I do.
- step 4 since the pressure in the second adsorption column 21 is reduced, the gas containing a large amount of nitrogen gas adsorbed in the second adsorption column 21 is introduced into the first adsorption column 11 together with the circulating raw material gas. Is done.
- the nitrogen concentration in the gas introduced into the first adsorption column 11 in Step 4 becomes higher than the nitrogen concentration in the circulating feed gas.
- the gas having a high concentration of the target gas (krypton gas or nitrogen gas) to be separated as the product gas is adsorbed to the adsorption columns 11 and 2. Can be supplied to one.
- the target gas krypton gas or nitrogen gas
- Steps 1 and 3 the efficiency of talipton adsorption in the adsorption column 11 and the efficiency of nitrogen adsorption in the adsorption column 21 can be improved. Recovery rate can be increased.
- the capacity of the compressor 2 can be reduced. For example, compared to the conventional method, The capacity can be reduced by 5 to 20%.
- the compressor 2 can be reduced in size and space can be saved, and the equipment cost can be reduced. '
- steps 2 and 4 the adsorption cylinders 11 and 21 to which the circulating raw material gas is introduced are pressurized by the equalizing pressure reducing step and the pressure pressurizing step.
- the load on the compressor 2 can be reduced.
- the capacity of the compressor 2 can be set small, and the equipment cost can be kept low.
- FIG. 3 shows a gas separation device capable of performing the second embodiment of the gas separation method of the present invention.
- the gas separation device shown here is not provided with pipelines L 1 and 1 2 for introducing nitrogen gas or krypton gas from the product gas storage tanks 12 and 22 to the adsorption cylinders 11 and 21.
- the gas separation apparatus shown in FIG. 1 is different from the gas separation apparatus shown in FIG. 1 in that first and second purge gas storage tanks 13 and 23 for storing gases derived from the adsorption tubes 11 and 12 as purge gas are provided. .
- the first purge gas storage tank 13 is connected to the pipe L4 via the pipe L15, and the gas in the storage tank 13 is used as the purge gas through the pipes L15 and L4 as the first adsorption column.
- the second purge gas storage tank 23 is connected to the pipe L7 via the pipe L16, and the gas in the storage tank 23 is used as a purge gas through the pipes L16 and L7 as the second adsorption column. 2 can be supplied to one.
- the mixed gas is introduced as raw material gas into raw material storage tank 1 through line L1.
- the first adsorption column 11 includes an adsorption step of adsorbing the taliptone gas in the circulating raw material gas and leading the nitrogen gas out of the system as a first product gas through the storage tank 12. Do.
- a regeneration step of desorbing nitrogen gas by depressurization is performed in the second adsorption column 21. In this regeneration step, the nitrogen gas adsorbed in the adsorption step prior to step 1 is desorbed, and the pipe L 10 Through to the raw material storage tank 1.
- the purge gas in the second purge gas storage tank 23 is introduced into the second adsorption column 21 through the pipes L16 and L7, and this gas is circulated through the second adsorption column 21.
- the gas in the first adsorption column 11 is introduced into the second adsorption column 21 through lines L3 and L6 to equalize the pressure of the adsorption columns 11 and 21.
- the pressure equalizing pressure reducing step of reducing the pressure of the first adsorption column 11 is performed.
- a part of the gas in the adsorption column 11 (for example, the gas in the space above the adsorption column 11) is introduced into the first purge gas storage tank 13 as purge gas through the pipes L4 and L15. I do.
- a pressure equalizing step of pressurizing the second adsorption column 21 by equalizing the pressure of the adsorption columns 11 and 21 is performed.
- the gas from the first adsorption column 11 is introduced into the second adsorption column 21 by the pressure equalizing and depressurizing step, and the krypton gas is supplied from the storage tank 22 to the second adsorption column 2. Introduced in 1. Thereby, the second adsorption cylinder 21 is pressurized.
- a regeneration step of desorbing krypton gas by decompression is performed in the first adsorption column 11.
- the krypton gas adsorbed in step 1 is desorbed and returned to the raw material storage tank 1 as regeneration exhaust gas through line L9.
- the purge gas in the first purge gas storage tank 13 is introduced into the first adsorption column 11 through the pipes L15 and L4, and this gas is passed through the first adsorption column 11 1Promote desorption of krypton gas adsorbed on the adsorbent.
- an adsorption step of adsorbing nitrogen gas in the circulating raw material gas and leading the krypton gas out of the system as a second product gas through the storage tank 22 is performed.
- the gas in the second adsorption column 21 is introduced into the first adsorption column 11 through the lines L6 and L3, and the pressure in the adsorption column 11 and the adsorption column 21 is equalized.
- an equalizing pressure reducing step of reducing the pressure of the second adsorption column 21 is performed.
- a part of the gas in the adsorption cylinder 21 (for example, the gas in the gap above the adsorption cylinder 21) is introduced into the second purge gas storage tank 23 as a purge gas through the pipes L7 and L16. I do. '
- a pressure equalizing step of pressurizing the first adsorption column 11 by equalizing the pressure of the adsorption column 11 and the adsorption column 21 is performed.
- the gas from the second adsorption column 21 is introduced into the first adsorption column 11 by the pressure equalizing and depressurizing step, and the nitrogen gas in the storage tank 12 is passed through the line L4. And is introduced into the first adsorption column 11. Thereby, the first adsorption column 11 is pressurized.
- the gas in the first adsorption column 11 is introduced into the second adsorption column 21 to equalize the pressure in the adsorption column 11 and the adsorption column 21.
- the adsorption cylinder 11 This improves krypton adsorption and nitrogen adsorption in the adsorption column 21.
- the compressor 2 can be reduced in size and space can be saved, and the equipment cost can be kept low. .
- the purge gas from the purge gas storage tank 23 (or the purge gas storage tank 13) is supplied to the adsorption cylinder 21 (or the adsorption cylinder 1). 1), the product gas in storage tank 22 (or storage tank 1 2) does not need to be used as purge gas.
- purge gas storage tank 13 (or storage neon soda 23)
- purge gas storage tank 13 It is also possible to provide a line connecting the adsorption tube 11 and the adsorption tube 21 (or the adsorption tube 21) in addition to the line L15 (or the line L16), and to use separate lines when introducing and discharging the purge gas. (Not shown).
- the mixed gas containing nitrogen and krypton was set as the separation target, but the gas component to be separated is not limited to this.
- xenon may be set as the separation target instead of krypton.
- the mixed gas was separated as follows.
- the specifications of the gas separator used are shown below.
- the cylindrical adsorption column having an inner diameter of 70.3 mm and a length of 54 Omm was filled with 1.42 kg of zeolite 4A (second adsorbent).
- the above gas separator was operated with steps 1 to 4 as one cycle and one cycle operation time of 400 seconds.
- the time of each step was as shown in Table 2.
- step 1 As shown in FIGS. 1 and 2A, valves VI, V3, V6, V8, and V10 were opened, and the other valves were closed.
- the mixed gas is introduced into the raw material storage tank 1 at a flow rate of 0.44 L in, and the circulating raw material gas from the raw material storage tank 1 is passed through the pipeline L 3 at 4.7 LZ min using the compressor 2. And supplied to the first adsorption column 11. The concentration of the circulating feed gas was adjusted so that it was almost the same as the feed gas composition.
- the valve V2 After supplying the circulating raw material gas until the pressure of the adsorption cylinder 11 becomes higher than the pressure of the storage tank 12, the valve V2 is opened, and the gas (nitrogen gas) in the adsorption cylinder 11 is supplied to the line L4. And collected in the first product gas storage tank 12. At this time, the pressure of the first adsorption column 11 was set to 180 to 435 kPa (gauge pressure) (adsorption step).
- the gas in the adsorption column .21 was returned to the raw material storage tank 1 through line L10 as regenerated exhaust gas.
- the pressure of the second adsorption column 21 was reduced, and the nitrogen gas adsorbed by the second adsorbent was desorbed.
- the pressure in the second adsorption column 21 was set to 0 to: 10 kPa (gauge pressure).
- the krypton gas in the second product gas storage tank 22 was introduced into the second adsorption column 21 through the line L12, and the adsorption column 21 was purged (regeneration step).
- valves V2, V8, and VI0 were closed, and valves V1, V4, and V5 were opened.
- the first adsorption column 11 and the second adsorption column 21 are communicated with each other via the lines L3 and L6, and the gas in the first adsorption column 11 is passed through the lines L3 and L6. It was introduced into the second adsorption column 21.
- krypton gas was introduced into the second adsorption column 21 from the second product gas storage tank 22 through the line L7.
- the pressure of the first adsorption column 11 was reduced to 290 kPa (gauge pressure), and the pressure of the second adsorption column 21 was raised to 260 kPa (gauge pressure). Pressure step).
- the gas in the first adsorption column 11 was returned to the raw material storage tank 1 as regeneration exhaust gas through the line L9.
- the pressure of the first adsorption column 11 was set to 0 to 10 kPa (gauge pressure). .
- the nitrogen gas in the first product gas storage tank 12 was introduced into the first adsorption cylinder 11 through the pipe L11, and the adsorption cylinder 11 was purged (regeneration step).
- the circulating raw material gas was supplied to the second adsorption column 21 through the line L 6.
- valve V5 After supplying the circulating raw material gas until the pressure in the adsorption cylinder 21 becomes higher than the pressure in the storage tank 22, the valve V5 is opened, and the gas (krypton gas) in the adsorption cylinder 21 is passed through the line L7. Collected in the second product gas storage tank 22. At this time, the pressure of the second adsorption column 21 was set to 260 to 420 kPa (gauge pressure) (adsorption step). As shown in FIGS. 1 and 2D, valves V7, V9, and V5 were closed, and valves V1, V2, and V4 were opened.
- the first adsorption column 11 and the second adsorption column 21 are communicated with each other through the lines L3 and L6, and the gas in the second adsorption column 21 is passed through the lines L3 and L6. 1 Introduced into adsorption column 11.
- the pressure of the first adsorption column 11 was increased to 180 kPa (gauge pressure), and the pressure of the second adsorption column 21 was reduced to 240 kPa (gauge pressure). And equalizing pressure step).
- the first product gas with a nitrogen concentration of 99.5% is recovered in the first product gas storage tank 12, and the krypton gas concentration in the second product gas storage tank 99. 995% of the second product gas was recovered.
- Table 3 shows the product gas flow rates and product recovery rates.
- First and second adsorption cylinders, and a compressor for supplying a mixed gas to these adsorption cylinders The mixed gas was separated by using a gas separation device.
- test conditions were the same as in Example 1 except that the supply rate of the circulating raw material gas from the compressor was 5.3 L / min.
- the adsorption process and the regeneration process are performed alternately, and when one adsorption column is in the adsorption process, the regeneration process is performed in the other adsorption column.
- Table 3 also shows the product gas flow rates and product recovery rates under the same conditions as in Example 1 with the same product nitrogen gas concentration and product krypton gas concentration.
- Table 3 shows that the gas separation method of Example 1 was able to increase the product recovery rate as compared with Comparative Example 1.
- Separation of the mixed gas was performed using the same gas separation device as that used in Example 1. c This gas separation device was operated with an operation time of one cycle of 600 seconds. The adsorption step and the regeneration step were each performed for 29 seconds, and the equalizing pressure reducing step and the equalizing pressure step were each performed for 5 seconds.
- Example 1 As the mixed gas, the same gas used in Example 1 was used.
- the flow rates of the product nitrogen gas and the product krypton gas were both 0.15 L Zmin.
- the supply flow rate of the circulating raw material gas was changed in the range of 2.8 to 4.0 L / min, and the fluctuations of the product nitrogen gas concentration and the product krypton gas concentration due to the flow rate change were measured.
- the pressure in the adsorption process of the first adsorption column 11 and the second adsorption column 21 changed according to the flow rate of the circulating raw material gas.
- Figure 1 shows the change in the adsorption pressure of the first adsorption column 1 and the concentration of krypton gas in the first product gas. See Figure 5.
- FIG. 6 shows changes in the adsorption pressure of the second adsorption column 21 and the nitrogen gas concentration in the second product gas.
- the adsorption pressure exceeds 500 kPa (gauge pressure)
- the nitrogen concentration will increase, leading to an increase in the amount of adsorbent charged and a decrease in the product recovery rate.
- the adsorption pressure is preferably in the range of 300 to 500 kPa (gauge pressure).
- the adsorption pressure is adjusted to an optimal range by the pressure-fluctuation-type adsorption separation method, which separates talibton gas from a mixed gas consisting of nitrogen and talipton using a rate separation adsorbent such as Zeolite 4A. You need to do that.
- INDUSTRIAL APPLICABILITY In the gas separation method of the present invention, in steps 2 and 4, an equalizing pressure reducing step and an equalizing pressure increasing step of equalizing the first and second adsorption columns are performed.
- a gas having a high concentration of the target gas to be separated as a product gas can be supplied to the adsorption column. Therefore, in the adsorption process of the steps subsequent to Steps 2 and 4 (Steps 3 and 1), the adsorption efficiency of gas components can be increased, and the product recovery rate can be increased. Also, since the adsorption efficiency can be improved, the capacity of the compressor can be reduced.
- the compressor can be reduced in size and space can be saved, and the equipment cost can be kept low.
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Description
Claims
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
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EP03723107A EP1495793A4 (en) | 2002-04-15 | 2003-04-11 | GUEST RACE PROCEDURE |
AU2003236218A AU2003236218A1 (en) | 2002-04-15 | 2003-04-11 | Gas separating method |
KR1020047016342A KR100984796B1 (ko) | 2002-04-15 | 2003-04-11 | 가스 분리 방법 |
US10/510,745 US7300497B2 (en) | 2002-04-15 | 2003-04-11 | Gas separating method |
IL16445604A IL164456A0 (en) | 2002-04-15 | 2004-10-10 | Gas separation method |
Applications Claiming Priority (2)
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JP2002-112145 | 2002-04-15 | ||
JP2002112145A JP3899282B2 (ja) | 2002-04-15 | 2002-04-15 | ガス分離方法 |
Publications (1)
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WO2003086586A1 true WO2003086586A1 (fr) | 2003-10-23 |
Family
ID=29243305
Family Applications (1)
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PCT/JP2003/004655 WO2003086586A1 (fr) | 2002-04-15 | 2003-04-11 | Procede de separation de gaz |
Country Status (9)
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US (1) | US7300497B2 (ja) |
EP (1) | EP1495793A4 (ja) |
JP (1) | JP3899282B2 (ja) |
KR (1) | KR100984796B1 (ja) |
CN (1) | CN1299800C (ja) |
AU (1) | AU2003236218A1 (ja) |
IL (1) | IL164456A0 (ja) |
TW (1) | TW589222B (ja) |
WO (1) | WO2003086586A1 (ja) |
Cited By (3)
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WO2012136913A1 (fr) | 2011-04-08 | 2012-10-11 | L'air Liquide,Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Mélange d'un adsorbant et d'un matériau à changement de phase à densité adaptée |
US8574346B2 (en) | 2006-09-25 | 2013-11-05 | L'air Liquide Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | PSA method using a composite adsorption bed comprising an adsorbent and PCM agglomerates |
JP7429563B2 (ja) | 2020-02-28 | 2024-02-08 | 株式会社アドバン理研 | ガス発生装置およびガス製造方法 |
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US8795411B2 (en) | 2011-02-07 | 2014-08-05 | Air Products And Chemicals, Inc. | Method for recovering high-value components from waste gas streams |
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JP6235794B2 (ja) * | 2013-05-28 | 2017-11-22 | 住友精化株式会社 | アルゴン精製方法およびアルゴン精製装置 |
US11557462B2 (en) | 2019-03-13 | 2023-01-17 | Kla Corporation | Collecting and recycling rare gases in semiconductor processing equipment |
JP7289909B1 (ja) | 2021-12-28 | 2023-06-12 | 大陽日酸株式会社 | 圧力変動吸着式ガス分離装置 |
IL313880A (en) * | 2021-12-28 | 2024-08-01 | Taiyo Nippon Sanso Corp | System for gas separation in pressure swing adsorption |
JP7381554B2 (ja) * | 2021-12-28 | 2023-11-15 | 大陽日酸株式会社 | 圧力変動吸着式ガス分離装置 |
JP7289908B1 (ja) | 2021-12-28 | 2023-06-12 | 大陽日酸株式会社 | 圧力変動吸着式ガス分離装置 |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3788036A (en) * | 1972-07-26 | 1974-01-29 | D Stahl | Pressure equalization and purging system for heatless adsorption systems |
US4661125A (en) * | 1984-05-22 | 1987-04-28 | Seitetsu Kagaku Co., Ltd. | Process for producing high concentration oxygen by a pressure-swing-adsorption method |
JPH01184016A (ja) | 1988-01-20 | 1989-07-21 | Tokico Ltd | 気体分離装置 |
EP0334495A2 (en) * | 1988-03-17 | 1989-09-27 | Sumitomo Seika Chemicals Co., Ltd. | Process for recovering oxygen enriched gas |
JP2000241590A (ja) * | 1999-02-23 | 2000-09-08 | Japan Atom Power Co Ltd:The | 希ガス濃縮方法及び希ガス濃縮装置 |
JP2002306918A (ja) * | 2001-04-16 | 2002-10-22 | Nippon Sanso Corp | ガス分離方法とその装置 |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4190424A (en) * | 1975-07-17 | 1980-02-26 | Boc Limited | Gas separation |
JP3076912B2 (ja) * | 1989-11-08 | 2000-08-14 | 株式会社日立製作所 | 混合ガスの分離方法及び装置 |
JP3628439B2 (ja) * | 1996-05-20 | 2005-03-09 | 財団法人産業創造研究所 | 酸素−窒素混合ガス中のクリプトンの濃縮法 |
JP2001116836A (ja) | 1999-10-22 | 2001-04-27 | Osaka Gas Co Ltd | 隠蔽物探査方法及び探査装置 |
JP3891773B2 (ja) * | 2000-10-20 | 2007-03-14 | 大陽日酸株式会社 | ガスの分離精製方法及びその装置 |
US6896330B1 (en) * | 2003-11-19 | 2005-05-24 | Ming-Ming Yu | 360-degree swivel cushion |
-
2002
- 2002-04-15 JP JP2002112145A patent/JP3899282B2/ja not_active Expired - Lifetime
-
2003
- 2003-04-10 TW TW092108197A patent/TW589222B/zh not_active IP Right Cessation
- 2003-04-11 CN CNB038080729A patent/CN1299800C/zh not_active Expired - Fee Related
- 2003-04-11 WO PCT/JP2003/004655 patent/WO2003086586A1/ja active Application Filing
- 2003-04-11 US US10/510,745 patent/US7300497B2/en not_active Expired - Fee Related
- 2003-04-11 EP EP03723107A patent/EP1495793A4/en not_active Withdrawn
- 2003-04-11 KR KR1020047016342A patent/KR100984796B1/ko not_active IP Right Cessation
- 2003-04-11 AU AU2003236218A patent/AU2003236218A1/en not_active Abandoned
-
2004
- 2004-10-10 IL IL16445604A patent/IL164456A0/xx not_active IP Right Cessation
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3788036A (en) * | 1972-07-26 | 1974-01-29 | D Stahl | Pressure equalization and purging system for heatless adsorption systems |
US4661125A (en) * | 1984-05-22 | 1987-04-28 | Seitetsu Kagaku Co., Ltd. | Process for producing high concentration oxygen by a pressure-swing-adsorption method |
JPH01184016A (ja) | 1988-01-20 | 1989-07-21 | Tokico Ltd | 気体分離装置 |
EP0334495A2 (en) * | 1988-03-17 | 1989-09-27 | Sumitomo Seika Chemicals Co., Ltd. | Process for recovering oxygen enriched gas |
JP2000241590A (ja) * | 1999-02-23 | 2000-09-08 | Japan Atom Power Co Ltd:The | 希ガス濃縮方法及び希ガス濃縮装置 |
JP2002306918A (ja) * | 2001-04-16 | 2002-10-22 | Nippon Sanso Corp | ガス分離方法とその装置 |
Non-Patent Citations (1)
Title |
---|
See also references of EP1495793A4 |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8574346B2 (en) | 2006-09-25 | 2013-11-05 | L'air Liquide Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | PSA method using a composite adsorption bed comprising an adsorbent and PCM agglomerates |
WO2012136913A1 (fr) | 2011-04-08 | 2012-10-11 | L'air Liquide,Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Mélange d'un adsorbant et d'un matériau à changement de phase à densité adaptée |
US9314768B2 (en) | 2011-04-08 | 2016-04-19 | L'Air Liquide Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude | Mixture of an adsorbent and a phase change material with an adapted density |
JP7429563B2 (ja) | 2020-02-28 | 2024-02-08 | 株式会社アドバン理研 | ガス発生装置およびガス製造方法 |
Also Published As
Publication number | Publication date |
---|---|
TW200404598A (en) | 2004-04-01 |
JP2004000819A (ja) | 2004-01-08 |
AU2003236218A1 (en) | 2003-10-27 |
EP1495793A4 (en) | 2006-10-04 |
CN1646207A (zh) | 2005-07-27 |
EP1495793A1 (en) | 2005-01-12 |
US7300497B2 (en) | 2007-11-27 |
IL164456A0 (en) | 2005-12-18 |
JP3899282B2 (ja) | 2007-03-28 |
KR100984796B1 (ko) | 2010-10-04 |
CN1299800C (zh) | 2007-02-14 |
KR20040111508A (ko) | 2004-12-31 |
TW589222B (en) | 2004-06-01 |
US20050199122A1 (en) | 2005-09-15 |
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