WO2003045886A3 - Procede de fabrication d'acide acrylique a partir de propane et en l'absence d'oxygene moleculaire - Google Patents

Procede de fabrication d'acide acrylique a partir de propane et en l'absence d'oxygene moleculaire Download PDF

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Publication number
WO2003045886A3
WO2003045886A3 PCT/FR2002/004089 FR0204089W WO03045886A3 WO 2003045886 A3 WO2003045886 A3 WO 2003045886A3 FR 0204089 W FR0204089 W FR 0204089W WO 03045886 A3 WO03045886 A3 WO 03045886A3
Authority
WO
WIPO (PCT)
Prior art keywords
propane
catalyst
acrylic acid
molecular oxygen
producing acrylic
Prior art date
Application number
PCT/FR2002/004089
Other languages
English (en)
Other versions
WO2003045886A2 (fr
Inventor
Jean-Luc Dubois
Stephanie Serreau
Julien Jacquel
Original Assignee
Atofina
Jean-Luc Dubois
Stephanie Serreau
Julien Jacquel
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Atofina, Jean-Luc Dubois, Stephanie Serreau, Julien Jacquel filed Critical Atofina
Priority to KR10-2004-7008068A priority Critical patent/KR20040058339A/ko
Priority to JP2003547344A priority patent/JP2005510553A/ja
Priority to EP02799759A priority patent/EP1453785A2/fr
Priority to US10/497,210 priority patent/US7161028B2/en
Priority to AU2002364406A priority patent/AU2002364406A1/en
Publication of WO2003045886A2 publication Critical patent/WO2003045886A2/fr
Publication of WO2003045886A3 publication Critical patent/WO2003045886A3/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/215—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of saturated hydrocarbyl groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/20—Vanadium, niobium or tantalum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/28—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8876—Arsenic, antimony or bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8877—Vanadium, tantalum, niobium or polonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
    • B01J27/057—Selenium or tellurium; Compounds thereof
    • B01J27/0576—Tellurium; Compounds thereof
    • B01J35/19—
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0236—Drying, e.g. preparing a suspension, adding a soluble salt and drying

Abstract

L'invention concerne un procédé de production d'acide acrylique à partir de propane en l'absence d'oxygène moléculaire. Selon ce procédé, on fait passer un mélange gazeux dépourvu d'oxygène moléculaire et comprenant du propane, de la vapeur d'eau, ainsi que, le cas échéant, un gaz inerte, sur un catalyseur comprenant du molybdène, du vanadium, du tellure, de l'oxygène et au moins un autre élément X choisi parmi le niobium, le tantale, le tungstène, le titane, l'aluminium, le zirconium, le chrome, le manganèse, le fer, le ruthénium, le cobalt, le rhodium, le nickel, le palladium, le platine, l'antimoine, le bismuth, le bore, l'indium et le cerium, ainsi que sur un co-catalyseur de formule (II) MolBia,Feb,Coc,Nid,Ke,Sbf,Tig,Sih,CaI,Nbj,Tek,Pbl,Wm,.Cun, (II). L'invention concerne également une composition solide catalytique comprenant lesdits catalyseur et co-catalyseur ainsi que l'utilisation de cette composition dans la fabrication d'acide acrylique à partir du propane.
PCT/FR2002/004089 2001-11-30 2002-11-28 Procede de fabrication d'acide acrylique a partir de propane et en l'absence d'oxygene moleculaire WO2003045886A2 (fr)

Priority Applications (5)

Application Number Priority Date Filing Date Title
KR10-2004-7008068A KR20040058339A (ko) 2001-11-30 2002-11-28 분자 산소 없이 프로판으로부터 아크릴산을 제조하는 방법
JP2003547344A JP2005510553A (ja) 2001-11-30 2002-11-28 酸素分子が存在しない条件でプロパンからアクリル酸を製造するための方法
EP02799759A EP1453785A2 (fr) 2001-11-30 2002-11-28 Procede de fabrication d acide acrylique a partir de propane et en l'absence d'oxygene moleculaire
US10/497,210 US7161028B2 (en) 2001-11-30 2002-11-28 Method for producing acrylic acid from propane in the absence of molecular oxygen
AU2002364406A AU2002364406A1 (en) 2001-11-30 2002-11-28 Method for producing acrylic acid from propane in the absence of molecular oxygen

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR0115524A FR2833005B1 (fr) 2001-11-30 2001-11-30 Procede de fabrication d'acide acrylique a partir de propane et en l'absence d'oxygene moleculaire
FR01/15524 2001-11-30

Publications (2)

Publication Number Publication Date
WO2003045886A2 WO2003045886A2 (fr) 2003-06-05
WO2003045886A3 true WO2003045886A3 (fr) 2004-02-12

Family

ID=8869982

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/FR2002/004089 WO2003045886A2 (fr) 2001-11-30 2002-11-28 Procede de fabrication d'acide acrylique a partir de propane et en l'absence d'oxygene moleculaire

Country Status (8)

Country Link
US (1) US7161028B2 (fr)
EP (1) EP1453785A2 (fr)
JP (1) JP2005510553A (fr)
KR (1) KR20040058339A (fr)
CN (1) CN1286794C (fr)
AU (1) AU2002364406A1 (fr)
FR (1) FR2833005B1 (fr)
WO (1) WO2003045886A2 (fr)

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU2003278285A1 (en) 2002-09-10 2004-04-30 Arkema Method for producing acrylic acid from propane
AU2003278286A1 (en) 2002-09-10 2004-04-30 Arkema Method for producing acrylic acid from propane, in the presence of molecular oxygen
FR2844262B1 (fr) * 2002-09-10 2004-10-15 Atofina Procede de fabrication d'acide acrylique a partir de propane, en l'absence d'oxygene moleculaire
JP5094459B2 (ja) * 2007-03-09 2012-12-12 ローム アンド ハース カンパニー アルカンを不飽和カルボン酸に変換するための改良法
JP4822559B2 (ja) * 2007-09-19 2011-11-24 ローム アンド ハース カンパニー （メタ）アクリル酸生成物流からのプロピオン酸の選択的減少のための改良された方法
CA2737946C (fr) 2008-09-26 2016-11-15 The Ohio State University Transformation des combustibles carbones en vecteurs energetiques sans carbone
CN102597173A (zh) 2009-09-08 2012-07-18 俄亥俄州立大学研究基金会 具有原位co2捕集的合成燃料和化学品生产
CN102695670B (zh) 2009-09-08 2016-02-24 俄亥俄州立大学研究基金会 具有集成的碳捕集的重整/水裂解和用于发电的电化学系统的集成
US10010847B2 (en) 2010-11-08 2018-07-03 Ohio State Innovation Foundation Circulating fluidized bed with moving bed downcomers and gas sealing between reactors
CA2835419C (fr) 2011-05-11 2020-06-02 Ohio State Innovation Foundation Systemes pour convertir un combustible
EP2707583B1 (fr) 2011-05-11 2019-07-10 Ohio State Innovation Foundation Matériaux vecteurs d'oxygène
DE102011109816B4 (de) 2011-08-09 2017-04-06 Clariant Produkte (Deutschland) Gmbh Katalysatormaterial für die Oxidation von Kohlenwasserstoffen
DE102011109774B4 (de) * 2011-08-09 2017-04-20 Clariant Produkte (Deutschland) Gmbh Katalysatormaterial für die Oxidation von Kohlenwasserstoffen
CN105358475B (zh) 2013-02-05 2018-12-04 俄亥俄州国家创新基金会 用于燃料转化的方法
US9616403B2 (en) 2013-03-14 2017-04-11 Ohio State Innovation Foundation Systems and methods for converting carbonaceous fuels
US20150238915A1 (en) 2014-02-27 2015-08-27 Ohio State Innovation Foundation Systems and methods for partial or complete oxidation of fuels
CN105983421A (zh) * 2015-02-02 2016-10-05 中国石油天然气股份有限公司 催化氧化丙烷制取丙烯酸的催化剂及其制备方法
EP3429738A4 (fr) 2016-04-12 2019-09-18 Ohio State Innovation Foundation Production de gaz de synthèse en boucle chimique à partir de combustibles carbonés
US11090624B2 (en) 2017-07-31 2021-08-17 Ohio State Innovation Foundation Reactor system with unequal reactor assembly operating pressures
US10549236B2 (en) 2018-01-29 2020-02-04 Ohio State Innovation Foundation Systems, methods and materials for NOx decomposition with metal oxide materials
WO2020033500A1 (fr) 2018-08-09 2020-02-13 Ohio State Innovation Foundation Systèmes, procédés et matières de conversion de sulfure d'hydrogène
US11453626B2 (en) 2019-04-09 2022-09-27 Ohio State Innovation Foundation Alkene generation using metal sulfide particles
CN112439441B (zh) * 2019-09-05 2023-03-21 中石油吉林化工工程有限公司 丙烯醛氧化制丙烯酸的催化剂制备方法
CN114534750B (zh) * 2020-11-24 2024-03-01 中国石油天然气股份有限公司 用于丙烷选择性氧化制丙烯酸催化剂的制备方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4341717A (en) * 1973-03-08 1982-07-27 The Standard Oil Company Reactor for contacting gases and a particulate solid
EP0608838A2 (fr) * 1993-01-28 1994-08-03 Mitsubishi Chemical Corporation Procédé pour la préparation d'un acide carboxylique insaturé
WO2001004079A1 (fr) * 1999-07-09 2001-01-18 E.I. Du Pont De Nemours And Company Oxydation catalytique en phase vapeur de propylene produisant de l'acide acrylique
US6281384B1 (en) * 1998-06-26 2001-08-28 E. I. Du Pont Nemours And Company Vapor phase catalytic oxidation of propylene to acrylic acid

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4341717A (en) * 1973-03-08 1982-07-27 The Standard Oil Company Reactor for contacting gases and a particulate solid
EP0608838A2 (fr) * 1993-01-28 1994-08-03 Mitsubishi Chemical Corporation Procédé pour la préparation d'un acide carboxylique insaturé
US6281384B1 (en) * 1998-06-26 2001-08-28 E. I. Du Pont Nemours And Company Vapor phase catalytic oxidation of propylene to acrylic acid
WO2001004079A1 (fr) * 1999-07-09 2001-01-18 E.I. Du Pont De Nemours And Company Oxydation catalytique en phase vapeur de propylene produisant de l'acide acrylique

Also Published As

Publication number Publication date
WO2003045886A2 (fr) 2003-06-05
JP2005510553A (ja) 2005-04-21
CN1596244A (zh) 2005-03-16
US7161028B2 (en) 2007-01-09
AU2002364406A8 (en) 2003-06-10
FR2833005A1 (fr) 2003-06-06
CN1286794C (zh) 2006-11-29
US20050054880A1 (en) 2005-03-10
AU2002364406A1 (en) 2003-06-10
FR2833005B1 (fr) 2004-01-23
EP1453785A2 (fr) 2004-09-08
KR20040058339A (ko) 2004-07-03

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