WO2003042151A8 - Verfahren zur herstellung von (meth) acrylsäureestern mehrwertiger alkohole - Google Patents

Verfahren zur herstellung von (meth) acrylsäureestern mehrwertiger alkohole

Info

Publication number
WO2003042151A8
WO2003042151A8 PCT/EP2002/012491 EP0212491W WO03042151A8 WO 2003042151 A8 WO2003042151 A8 WO 2003042151A8 EP 0212491 W EP0212491 W EP 0212491W WO 03042151 A8 WO03042151 A8 WO 03042151A8
Authority
WO
WIPO (PCT)
Prior art keywords
meth
acrylic acid
polyhydric alcohols
producing
acid esters
Prior art date
Application number
PCT/EP2002/012491
Other languages
English (en)
French (fr)
Other versions
WO2003042151A1 (de
Inventor
Alexander Wartini
Matthias Dernbach
Juergen Schroeder
Friedrich-Georg Martin
Tilman Sirch
Original Assignee
Basf Ag
Alexander Wartini
Matthias Dernbach
Juergen Schroeder
Friedrich-Georg Martin
Tilman Sirch
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Ag, Alexander Wartini, Matthias Dernbach, Juergen Schroeder, Friedrich-Georg Martin, Tilman Sirch filed Critical Basf Ag
Priority to AU2002356570A priority Critical patent/AU2002356570A1/en
Priority to KR10-2004-7007399A priority patent/KR20040066121A/ko
Priority to JP2003543988A priority patent/JP2005509018A/ja
Priority to EP02802997A priority patent/EP1448506A1/de
Priority to US10/494,522 priority patent/US20050010065A1/en
Priority to BR0214133-7A priority patent/BR0214133A/pt
Priority to MXPA04004349A priority patent/MXPA04004349A/es
Publication of WO2003042151A1 publication Critical patent/WO2003042151A1/de
Publication of WO2003042151A8 publication Critical patent/WO2003042151A8/de

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/42—Separation; Purification; Stabilisation; Use of additives
    • C07C51/50—Use of additives, e.g. for stabilisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/08—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/48—Separation; Purification; Stabilisation; Use of additives
    • C07C67/62—Use of additives, e.g. for stabilisation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Verfahren zur Herstellung von (Meth) acrylsäureestern von mehrwertigen Alkoholen durch Umsetzung von (Meth) acrylsäure und dem entsprechenden mehrwertigen Alkohol in Gegenwart mindestens eines sauren Katalysators und gegebenenfalls mindestens eines Polymerisationsinhibitors sowie gegebenenfalls in Gegenwart eines Lösungsmittels, wobei der eingesetzte mehrwertige Alkohol einen Gehalt an gebundenem Formaldehyd unter 500 ppm aufweist.
PCT/EP2002/012491 2001-11-15 2002-11-08 Verfahren zur herstellung von (meth) acrylsäureestern mehrwertiger alkohole WO2003042151A1 (de)

Priority Applications (7)

Application Number Priority Date Filing Date Title
AU2002356570A AU2002356570A1 (en) 2001-11-15 2002-11-08 Method for producing (meth) acrylic acid esters of polyhydric alcohols
KR10-2004-7007399A KR20040066121A (ko) 2001-11-15 2002-11-08 다가 알콜의 (메트)아크릴산 에스테르의 제조 방법
JP2003543988A JP2005509018A (ja) 2001-11-15 2002-11-08 多価アルコールの（メタ）アクリル酸エステルの製造方法
EP02802997A EP1448506A1 (de) 2001-11-15 2002-11-08 Verfahren zur herstellung von (meth) acrylsäureestern mehrwertiger alkohole
US10/494,522 US20050010065A1 (en) 2001-11-15 2002-11-08 Method for producing (meth) acrylic acid esters of polyhydric alcohols
BR0214133-7A BR0214133A (pt) 2001-11-15 2002-11-08 Processo para a preparação de ésteres de ácido (met)acrìlico de álcoois polivalentes, e, uso de um álcool polivalente
MXPA04004349A MXPA04004349A (es) 2001-11-15 2002-11-08 Preparacion de (met) acrilatos de alcoholes polihidricos.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE10156116.4 2001-11-15
DE10156116A DE10156116A1 (de) 2001-11-15 2001-11-15 Verfahren zur Herstellung von (Meth)acrylsäureestern mehrwertiger Alkohole

Publications (2)

Publication Number Publication Date
WO2003042151A1 WO2003042151A1 (de) 2003-05-22
WO2003042151A8 true WO2003042151A8 (de) 2004-06-24

Family

ID=7705846

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2002/012491 WO2003042151A1 (de) 2001-11-15 2002-11-08 Verfahren zur herstellung von (meth) acrylsäureestern mehrwertiger alkohole

Country Status (10)

Country Link
US (1) US20050010065A1 (de)
EP (1) EP1448506A1 (de)
JP (1) JP2005509018A (de)
KR (1) KR20040066121A (de)
CN (1) CN1585736A (de)
AU (1) AU2002356570A1 (de)
BR (1) BR0214133A (de)
DE (1) DE10156116A1 (de)
MX (1) MXPA04004349A (de)
WO (1) WO2003042151A1 (de)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10301902A1 (de) * 2003-01-17 2003-12-04 Basf Ag Verfahren zur Herstellung von (Meth)acrylsäureestern
DE102005039536A1 (de) * 2005-08-18 2007-02-22 Basf Ag Verfahren zur Herstellung von (Meth)acrylsäureestern
CN1332928C (zh) * 2005-09-05 2007-08-22 上海华谊丙烯酸有限公司 一种多功能团（甲基）丙烯酸酯的合成及提纯方法
CN100443460C (zh) * 2005-12-27 2008-12-17 中国石油化工股份有限公司 一种羧酸酯的制备方法
JP4951967B2 (ja) * 2005-12-28 2012-06-13 東亞合成株式会社 多官能（メタ）アクリレートの製造方法
JP4951966B2 (ja) * 2005-12-28 2012-06-13 東亞合成株式会社 多官能（メタ）アクリレートの製造方法
DE102011118953B4 (de) * 2011-11-19 2014-06-05 Oxea Gmbh Destillatives Verfahren zur Gewinnung von Di-Trimethylolpropan
WO2014103676A1 (ja) * 2012-12-27 2014-07-03 東亞合成株式会社 多官能（メタ）アクリル酸エステルの製造方法
US9505880B2 (en) * 2013-06-04 2016-11-29 Corning Incorporated Synthesis of polyfunctional polyol acrylates
CN103342644B (zh) * 2013-07-23 2015-11-18 天津市天骄辐射固化材料有限公司 一种多元醇丙烯酸酯的制备方法
CN108997113A (zh) * 2018-06-25 2018-12-14 南通百川新材料有限公司 一种三羟甲基丙烷三丙烯酸酯的制备方法
CN113825723A (zh) 2019-04-02 2021-12-21 埃科莱布美国股份有限公司 具有减少的酸用量的纯二氧化氯生成系统
CN112830793A (zh) * 2019-11-22 2021-05-25 福建臻璟新材料科技有限公司 一种凝胶法注模制备高导热和高强度氮化铝陶瓷的制备工艺
CN112300306B (zh) * 2020-11-09 2022-03-29 广东石油化工学院 一种生物降解性可辐射固化的(甲基)丙烯酸酯及其制备方法
CN113292423B (zh) * 2021-05-31 2023-12-12 武汉理工大学 邻甲基环已基醋酸酯的合成方法

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2129722A (en) * 1934-07-14 1938-09-13 Du Pont Esters of methacrylic acid
US3639459A (en) * 1968-04-24 1972-02-01 Polaroid Corp Method of preparing polymerizable monomeric esters
DE2552987C2 (de) * 1975-11-26 1983-09-29 Hoechst Ag, 6230 Frankfurt Verfahren zur kontinuierlichen Herstellung ätherfreier Acrylsäurealkylester
DE2653096C2 (de) * 1976-11-23 1985-04-11 Bayer Ag, 5090 Leverkusen Verfahren zur Herstellung von 2,2-disubstituierten Propan-1,3-diolen
US4187383A (en) * 1976-12-28 1980-02-05 Union Carbide Corporation Process for producing low color residue acrylate esters
US4529786A (en) * 1981-03-30 1985-07-16 Celanese Corporation Acrylate and methacrylate monoesters of pentaerythritol and pentaerythritol orthoesters and polymers and copolymers derived therefrom
EP0338540B1 (de) * 1988-04-20 1994-08-10 Kuraray Co., Ltd. Trimethylolheptane und ihre Anwendung
US5171888A (en) * 1989-05-16 1992-12-15 Betz Laboratories, Inc. Methods and compositions for inhibiting (meth)acrylic acid polymerization
TW224108B (de) * 1992-05-06 1994-05-21 Ciba Geigy
DE19838426A1 (de) * 1998-08-24 2000-03-02 Degussa Verfahren zum Trennen von Trimethylolpropan von wasserlöslichen Salzen aus einer Lösung

Also Published As

Publication number Publication date
WO2003042151A1 (de) 2003-05-22
DE10156116A1 (de) 2003-06-26
MXPA04004349A (es) 2004-08-11
AU2002356570A1 (en) 2003-05-26
KR20040066121A (ko) 2004-07-23
CN1585736A (zh) 2005-02-23
EP1448506A1 (de) 2004-08-25
US20050010065A1 (en) 2005-01-13
JP2005509018A (ja) 2005-04-07
BR0214133A (pt) 2004-10-13

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