WO2003039279A2 - Procede ameliorant la resistance de vetements a l'usure - Google Patents

Procede ameliorant la resistance de vetements a l'usure Download PDF

Info

Publication number
WO2003039279A2
WO2003039279A2 PCT/GB2002/005035 GB0205035W WO03039279A2 WO 2003039279 A2 WO2003039279 A2 WO 2003039279A2 GB 0205035 W GB0205035 W GB 0205035W WO 03039279 A2 WO03039279 A2 WO 03039279A2
Authority
WO
WIPO (PCT)
Prior art keywords
fabric
article
triamine
abrasion
weight
Prior art date
Application number
PCT/GB2002/005035
Other languages
English (en)
Other versions
WO2003039279A3 (fr
Inventor
Christopher Michael Carr
Sona Swamima Nath
Original Assignee
Marks And Spencer Plc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Marks And Spencer Plc filed Critical Marks And Spencer Plc
Priority to AU2002363556A priority Critical patent/AU2002363556A1/en
Publication of WO2003039279A2 publication Critical patent/WO2003039279A2/fr
Publication of WO2003039279A3 publication Critical patent/WO2003039279A3/fr

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
    • D06M23/16—Processes for the non-uniform application of treating agents, e.g. one-sided treatment; Differential treatment
    • D06M23/18—Processes for the non-uniform application of treating agents, e.g. one-sided treatment; Differential treatment for the chemical treatment of borders of fabrics or knittings; for the thermal or chemical fixation of cuttings, seams or fibre ends
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M10/00—Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
    • D06M10/001—Treatment with visible light, infrared or ultraviolet, X-rays
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/59—Polyamides; Polyimides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/35—Abrasion, pilling or fibrillation resistance

Definitions

  • the present invention relates to a method for treating fabric, in particular collars and cuffs, to reduce dry and wet abrasion.
  • textile is used herein to include cotton, cellulosics (for example viscose, Tencel , Lyocell TM etc.), polyamides, acrylics, polyethylene, polypropylene, polyester, polyvinyl chloride and rubber or mixtures thereof.
  • fabric is used to mean any assembly of fibres such as woven, knitted, web or nonwoven material.
  • Abrasion of a textile can have an important detrimental influence on its appearance, strength and end-use properties.
  • the visual appearance of the collar and cuffs in textile garments can be adversely affected by both dry and wet abrasion to a greater extent than the rest of the garment. This leads to the overall acceptable wear lifetime of the garment being reduced even if the rest of the garment is relatively unabraded and visually acceptable and hence suitable for wear.
  • a method of producing a garment or other fabric article having increased resistance to wet or dry abrasion, particularly at edge portions comprising constructing at least those portions of the article having an abradable edge using pre-treated fabric, or untreated fabric and then subsequently treating the fabric during the course of the manufacture of the article, said treatment comprising treatment with
  • R is present or absent and R (when present), R and R are each independently an alkylene group with 1-4 carbon atoms or an arylene group; or with
  • the epichlorohydrin adducts (a) are cationically charged (typically by quatemisation of the nitrogen between R 2 and R 3 ).
  • Typical dicarboxylic acids include oxalic, malonic, succinic, glutaric and adipic acid; and typical triamines include dialkylene triamines, particularly diethylene triamine.
  • the fabric is a cellulosic fabric, particularly cotton or a cotton blend.
  • the cationic materials used according to the present invention are applied at about 0.1% to 10%, preferably 0.1%o to 1%> on weight of fabric.
  • the epichlorohydrin adducts are gently heat-treated after application, for example by a hot press or by hot air, in order to firmly adhere the coating to the fibres.
  • Radiation curable resins or pre-polymer systems are widely used in the coatings industry, in particular for application to wood, paper, plastic and metal substrates.
  • the coatings performance profile may also incorporate weather resistance, liquid repellency and colour into the surface varnish/coating.
  • Coloured pigments are also utilised in radiation curable lithographic and flexographic printing inks for the paper, packaging and plastics industries where high definition images are required.
  • Other end-use applications include solder-resist and etch-resist finishes for the electronics, or simply as a laminating adhesive combining two substances.
  • the resins in the present invention are applied preferably in the form of an aqueous emulsion, or a solvent based solution, or as an undiluted prepolymer formulation. Typically the application level is between 0.1% to 10%, preferably 0.1%) to 5%.
  • the fabric is dried and then subjected to a source of UV light in order to effect a suitable cure. It is noticeable that in comparison, magnesium chloride-catalysed urethane resins used to provide crease-resistance on fibres by providing a "memory", cause up to 30% loss in dry strength, with the fabric becoming more brittle. In conventional use, this problem is masked by the addition of polyethylene softeners as lubricants. Problems then arise by the removal ' of the softener in the washing processes which follow.
  • the present invention works by providing- a surface buffer which-protects-the fibres from abrasion, rather than providing internal cross-linking making the fibres more rigid.
  • the treatment can be provided by any conventional desired method, including "printing" it on with a soaked pad; localised spraying; etc.
  • the essential composition herein applied to improve the abrasion performance, and hence the garment lifetime comprises an aqueous cationic poly(aminoamide)- epichlorohydrin (PAE) type fabric treatment material.
  • PAE aqueous cationic poly(aminoamide)- epichlorohydrin
  • the cationic PAE materials useful herein will generally be applied at about 0.1 % to 10% on weight fabric, o.w.f, and can be applied by padding , exhaustion or spraying. Most preferably such cationic PAE materials will be applied at 0.1% to 1.0% o.w.f.
  • the collar or fabric is subsequently dried/ cured at from 30°C to 180°C though most preferably from 90°C and 150°C.
  • Other preferred compositions include, polyurethane acrylates and polyurethane methacrylates or mixtures thereof, which are cured by ultraviolet and/ or visible radiation.
  • Tests were conducted using 65%/ 35%> polyester/cotton, and 100% cotton collars.
  • the dry and wet flat abrasion tests were performed using a Martindale Abrasion tester and a standard wool fabric abradant following the guidelines in British Standard 5690 (1991) test method. Prior to dry testing the samples were conditioned at 20°C and 65% relative humidity for 24 hours. The wet abrasion test involved pre-soaking the test fabric and standard abradant fabric in distilled water, squeezing to 100%) wet pick up and performing the comparative abrasion test until two yarns were broken. This point was deemed as the fabric failure and the number of rub cycles to failure noted.
  • Table 1 shows the abrasion performance of a collar point under dry and wet conditions.
  • Table 3 shows the wet abrasion performance of untreated control collar points and ultraviolet cured polymer treated collar points.
  • Typical polyester acrylate or polyurethane acrylates radiation curable polymers were applied to the textile, together with 0.5%, on weight of radiation curable coatings of a photoinitiator, dried and ultraviolet radiation cured.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Coloring (AREA)

Abstract

L'invention porte sur un procédé de production d'un vêtement ou d'autres articles en tissu présentant une résistance accrue à l'usure à sec ou à l'état mouillé et en partie leurs bords, consistant à réaliser l'aide d'un tissu prétraité ou non traité au moins les parties de ces articles présentant des bords soumis à l'usure; puis à traiter l'article en cours de réalisation par (a) un adduit d'épichlorohydrine, c.-à-d. une polyamide-polyamine dérivant de l'acide dicarboxylique et par une dihydrocarbonetriamine, c.-à-d. une polyamide-polyamine présentant une unité répétitive de formule générale (I) dans laquelle: R1 est présent ou absent et R1 (si présent), R2 et R3 sont chacun indépendamment un groupe alkylène à 1-4 atomes de carbone ou un groupe arylène; ou par (b) une résine de poids moléculaire élevé d'uréthane acrylate ou diméthacrylate durcissant aux UV que l'on soumet aux UV ou à la chaleur pour les durcir.
PCT/GB2002/005035 2001-11-07 2002-11-07 Procede ameliorant la resistance de vetements a l'usure WO2003039279A2 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU2002363556A AU2002363556A1 (en) 2001-11-07 2002-11-07 Method of improving resistance to abrasion in garments

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB0126759A GB2381798A (en) 2001-11-07 2001-11-07 Improving resistance to abrasion in garments
GB0126759.0 2001-11-07

Publications (2)

Publication Number Publication Date
WO2003039279A2 true WO2003039279A2 (fr) 2003-05-15
WO2003039279A3 WO2003039279A3 (fr) 2004-08-12

Family

ID=9925350

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/GB2002/005035 WO2003039279A2 (fr) 2001-11-07 2002-11-07 Procede ameliorant la resistance de vetements a l'usure

Country Status (3)

Country Link
AU (1) AU2002363556A1 (fr)
GB (1) GB2381798A (fr)
WO (1) WO2003039279A2 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102977335A (zh) * 2012-11-30 2013-03-20 深圳职业技术学院 一种以环氧氯丙烷为原料制备含光-热双重固化基团树脂的方法

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1399120B1 (it) * 2010-04-01 2013-04-05 Vinavil S P A Processo per il trattamento di resinatura con o senza memoria di forma di capi confezionati

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5295997A (en) * 1991-07-25 1994-03-22 Perfojet S. A. Process for the production of a cotton-based, washable nonwoven cloth and cloth thus obtained
WO1998029530A2 (fr) * 1996-12-31 1998-07-09 The Procter & Gamble Company Compositions de detergent de lessive contenant des polyamide-polyamines pour conferer des qualites esthetiques a des tissus laves avec lesdites compositions
EP0978556A1 (fr) * 1998-08-03 2000-02-09 The Procter & Gamble Company Composition pour rendre infroissable
DE19846531A1 (de) * 1998-10-09 2000-04-20 Cognis Deutschland Gmbh Textilausrüstungsverfahren
EP1096056A1 (fr) * 1999-10-27 2001-05-02 The Procter & Gamble Company Composition pour rendre infroissable

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2937081A1 (de) * 1978-09-11 1980-03-20 Unisearch Ltd Verfahren zum verleihen von permanentbuegeleigenschaften
JPS62125076A (ja) * 1985-11-20 1987-06-06 日本ペイント株式会社 編地のカ−ル防止方法

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5295997A (en) * 1991-07-25 1994-03-22 Perfojet S. A. Process for the production of a cotton-based, washable nonwoven cloth and cloth thus obtained
WO1998029530A2 (fr) * 1996-12-31 1998-07-09 The Procter & Gamble Company Compositions de detergent de lessive contenant des polyamide-polyamines pour conferer des qualites esthetiques a des tissus laves avec lesdites compositions
EP0978556A1 (fr) * 1998-08-03 2000-02-09 The Procter & Gamble Company Composition pour rendre infroissable
DE19846531A1 (de) * 1998-10-09 2000-04-20 Cognis Deutschland Gmbh Textilausrüstungsverfahren
EP1096056A1 (fr) * 1999-10-27 2001-05-02 The Procter & Gamble Company Composition pour rendre infroissable

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102977335A (zh) * 2012-11-30 2013-03-20 深圳职业技术学院 一种以环氧氯丙烷为原料制备含光-热双重固化基团树脂的方法

Also Published As

Publication number Publication date
GB2381798A (en) 2003-05-14
GB2381798A8 (en) 2003-05-20
GB0126759D0 (en) 2002-01-02
WO2003039279A3 (fr) 2004-08-12
AU2002363556A1 (en) 2003-05-19

Similar Documents

Publication Publication Date Title
TWI591078B (zh) An article having an antimicrobial agent fixed thereto and a method for producing the same
KR20110019712A (ko) 피혁용재의 제조 방법 및 피혁용재
TW502073B (en) Treatment composition which provides anti-wrinkling properties to textiles
CN111601923B (zh) 使用非甲醛技术改进棉织物的耐久定形性质的平衡
Choudhury Advances in the finishing of silk fabrics
GB2241515A (en) Flame retardant composition
WO2003039279A2 (fr) Procede ameliorant la resistance de vetements a l'usure
KR100260239B1 (ko) 염색된 텍스타일 섬유의 내표백성을 개선하는 방법 및 상기 방법에 의해 제조된 생성물
US8877288B2 (en) High abrasion resistance coating process
CA1336996C (fr) Produits ignifugeants et methode d'utilisation
JPS63120172A (ja) 織物の処理方法
JP3615827B2 (ja) 制電性および撥水性を有する繊維布帛およびその製造方法
EP2089570A1 (fr) Compositions traitantes de textile et procédés correspondants
Dodd et al. Ultraviolet Radiation Curing Treatments for Shrink-Resistant Wool Fabric: Part I: Monomer Systems
KR100509689B1 (ko) 내 드라이크리닝성이 우수한 코팅 포지의 제조방법
JP2021107599A (ja) 合成繊維用耐久帯電防止剤、耐久帯電防止性繊維製品及び耐久帯電防止性繊維製品の製造方法
CN114717855B (zh) 用于制造生物基且纯素人造皮革材料的方法
CN107709654B (zh) 具有拒水整理剂的纺织品及其制造方法
CN111712268A (zh) 气味控制组合物以及使用方法
JP2000192371A (ja) セルロース系繊維含有布帛
JP2010144277A (ja) デニム製品及びその製造方法
US20240060232A1 (en) Dispersion
Kar Rot Resistance and Antimicrobial Finish of Cotton Khadi Fabrics
US20090092572A1 (en) Modification of cellulosic substrates to control body odor
WO2024058205A1 (fr) Répulsif

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A2

Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BY BZ CA CH CN CO CR CU CZ DE DK DM DZ EC EE ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NO NZ OM PH PL PT RO RU SC SD SE SG SI SK SL TJ TM TN TR TT TZ UA UG US UZ VC VN YU ZA ZM ZW

AL Designated countries for regional patents

Kind code of ref document: A2

Designated state(s): GH GM KE LS MW MZ SD SL SZ TZ UG ZM ZW AM AZ BY KG KZ MD RU TJ TM AT BE BG CH CY CZ DE DK EE ES FI FR GB GR IE IT LU MC NL PT SE SK TR BF BJ CF CG CI CM GA GN GQ GW ML MR NE SN TD TG

121 Ep: the epo has been informed by wipo that ep was designated in this application
DFPE Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101)
122 Ep: pct application non-entry in european phase
NENP Non-entry into the national phase in:

Ref country code: JP

WWW Wipo information: withdrawn in national office

Country of ref document: JP