WO2001094285A1 - Procede permettant de preparer des composes non satures par pyrolyse - Google Patents
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- WO2001094285A1 WO2001094285A1 PCT/JP2001/001735 JP0101735W WO0194285A1 WO 2001094285 A1 WO2001094285 A1 WO 2001094285A1 JP 0101735 W JP0101735 W JP 0101735W WO 0194285 A1 WO0194285 A1 WO 0194285A1
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
- C07C41/01—Preparation of ethers
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C43/00—Ethers; Compounds having groups, groups or groups
- C07C43/02—Ethers
- C07C43/03—Ethers having all ether-oxygen atoms bound to acyclic carbon atoms
- C07C43/14—Unsaturated ethers
- C07C43/17—Unsaturated ethers containing halogen
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
- C07C41/01—Preparation of ethers
- C07C41/18—Preparation of ethers by reactions not forming ether-oxygen bonds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
- C07C41/01—Preparation of ethers
- C07C41/18—Preparation of ethers by reactions not forming ether-oxygen bonds
- C07C41/28—Preparation of ethers by reactions not forming ether-oxygen bonds from acetals, e.g. by dealcoholysis
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C43/00—Ethers; Compounds having groups, groups or groups
- C07C43/02—Ethers
- C07C43/03—Ethers having all ether-oxygen atoms bound to acyclic carbon atoms
- C07C43/14—Unsaturated ethers
- C07C43/17—Unsaturated ethers containing halogen
- C07C43/172—Unsaturated ethers containing halogen containing rings other than six-membered aromatic rings
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
- C07C2601/14—The ring being saturated
Definitions
- the present invention relates to a method for producing an unsaturated compound that can be a useful resin raw material and a method for producing a polymer using the unsaturated compound.
- Unsaturated compounds such as perfluoro (alkylalkenyl ether) are useful as starting monomers for fluororesins. Fluororesins are used in a wide range of fields because they have excellent heat and chemical resistance. Traditionally, Perfluoro
- Alkylalkenyl ether is obtained by dimerizing perfluoroepoxides or reacting perfluoroalkanoic acid fluoride with perfluoroepoxides in the presence of alkali metal fluoride to form perfluoroepoxides (2 —Alkoxyalkanoic acid) Fluorides, and then manufactured industrially by the reaction of applying heat in the presence of an alkali metal salt such as glass beads or soda ash (Methodsof Organic and hemi stry, 4, Vol. 10b, Part 1, p. 703, etc.).
- an alkali metal salt such as glass beads or soda ash
- the conventional method for producing perfluoro (alkylalkenyl ether) has problems that it is difficult to control the reaction, the cost of raw materials is high, and it is economically disadvantageous as an industrial production method. ⁇ Best mode for carrying out the invention>
- the present invention is the following invention made for the purpose of providing a production method for obtaining an unsaturated compound in one step by using a compound that can be obtained at low cost as a raw material.
- the present invention provides a method for producing a compound represented by the following formula 2 by thermally decomposing a compound having at least one partial structure represented by the following formula 1.
- R ⁇ R c, R d, e each independently represent full atom, a halogen atom, or a monovalent organic group which does not Heni spoon by thermal decomposition reaction.
- Two selected from R b , R c , R and R e are linked to each other to form a divalent organic group that does not change by thermal decomposition, and the remaining two are linked to each other and do not change by thermal decomposition.
- a divalent organic group may be formed, or the remaining two may be each independently a hydrogen atom, a halogen atom, or a monovalent organic group which is not changed by a thermal decomposition reaction.
- X a halogen atom
- the organic group in the present specification refers to a group having a carbon atom as an essential element, and may have a saturated or unsaturated structure.
- a hydrocarbon group, a hetero atom-containing hydrocarbon group, a halogeno hydrocarbon group, or a halogeno (hetero atom-containing hydrocarbon) group is preferable.
- the hydrocarbon group may be either an aliphatic hydrocarbon group or an aromatic hydrocarbon group, and is preferably an aliphatic hydrocarbon group.
- a single bond, a double bond or a triple bond may be present as a carbon-carbon bond.
- the aliphatic hydrocarbon group may have any of a linear structure, a branched structure, a ring structure, and a structure partially having a ring structure.
- a saturated hydrocarbon group is preferable.
- the monovalent saturated hydrocarbon group include alkyl groups, cycloalkyl groups, and monovalent saturated hydrocarbon groups having a cycloalkyl moiety.
- a hydrocarbon group such as a cycloalkylalkyl group.
- an alkyl group having 1 to 10 carbon atoms is preferable, and a methyl group, an ethyl group, and a propyl group are particularly preferable.
- the cycloalkyl group is preferably a 3- to 6-membered cycloalkyl group or a group in which one or more hydrogen atoms of the cycloalkyl group have been substituted with an alkyl group.
- cycloalkylalkyl group a group in which one hydrogen atom of an alkyl group having 1 to 3 carbon atoms is substituted with the cycloalkyl group is preferable, and a cyclohexylmethyl group and the like can be mentioned.
- divalent saturated hydrocarbon group examples include an alkylene group, a group having a cycloalkylene portion, and a divalent saturated hydrocarbon group having a cycloalkyl portion (such as a cycloalkylalkylene group).
- the halogen atom is a fluorine atom, a chlorine atom, a bromine atom or an iodine atom, preferably a fluorine atom, a chlorine atom or a bromine atom, particularly preferably a fluorine atom or a chlorine atom.
- a halogeno hydrocarbon group refers to a group in which one or more hydrogen atoms present in the above hydrocarbon group have been replaced by halogen atoms.
- a hydrogen atom may or may not be present in the halogenohydrocarbon group.
- the halogen atom in the halogeno hydrocarbon group is preferably a fluorine atom or a chlorine atom.
- a group in which a part of hydrogen atoms present in a hydrocarbon group is substituted by a halogen atom is referred to as a partial halogeno hydrocarbon group.
- a hydrogen atom is present in the partial halogenohydrocarbon group.
- a bellhalogeno hydrocarbon group refers to a group in which all of the hydrogen atoms present in the group have been replaced by halogen atoms. There are no hydrogen atoms in the hydrogen group of perhalogeno carbon. The number of halogen atoms present in the halogeno group and the perhalogeno group may be one or more.
- Halogeno The monovalent saturated hydrocarbon group may have a straight-chain structure or a branched structure, may have a partial ring structure, and may be a fluoroalkyl group or fluoro (partially alkyl) And the like.
- NO, LOGENO The monovalent hydrocarbon group preferably has 1 to 20 carbon atoms.
- a perfluoroalkyl group or a perfluoro (partially alkyl) group ie, That is, a group in which all of the hydrogen atoms in the partial alkyl group are fluorinated
- the halogeno monovalent hydrocarbon group preferably has 1 to 20 carbon atoms. Specific examples of these groups include the groups described in the following examples.
- the halogeno divalent saturated hydrocarbon group may have a linear structure or a branched structure, may have a partially cyclic structure, and may be a fluoroalkylene group or a fluoroalkylene (partially cycloalkylene). ) Groups are preferred.
- a perfluoroalkylene group or a perfluoro (partially alkylene) group that is, a group in which all of the hydrogen atoms in the partially cycloalkylene group are fluorinated is used. preferable.
- the hetero atom-containing hydrocarbon group refers to a group including a hetero atom such as an oxygen atom, a nitrogen atom, or a sulfur atom, a carbon atom, and a hydrogen atom.
- the heteroatom may be a heteroatom itself or a heteroatom bonded to form a heteroatom.
- the heteroatom and the heteroatom group are both preferably not changed by the thermal decomposition reaction, and the heteroatom is particularly preferably an etheric oxygen atom (10-).
- the carbon number of the hetero atom-containing hydrocarbon group is preferably 1 to 20.
- hetero atom-containing hydrocarbon group examples include a group in which a divalent hetero atom or a divalent heteroatom is inserted between carbon atoms of the hydrocarbon group, or a carbon atom in the hydrocarbon group.
- a group having a heteroatom bonded thereto, or a group having a divalent heteroatom or a divalent heteroatom group bonded to the carbon atom at the bonding terminal of the above-mentioned ⁇ carbon atom group is preferable.
- the hetero atom-containing group is particularly preferably an etheric oxygen atom-containing group from the viewpoint of the usefulness of the compound, and particularly preferably a group having an etheric oxygen atom at the bond terminal.
- the heteroatom-containing monovalent hydrocarbon group is preferably an etheric oxygen atom-containing alkyl group in view of availability, ease of production, and usefulness of the product. s is particularly preferred.
- the hetero atom-containing divalent hydrocarbon group is a group in which one hydrogen atom in the hetero atom-containing monovalent hydrocarbon group has a bond, and an etheric oxygen atom-containing alkylene group is preferable.
- Examples of the halogeno (hetero atom-containing hydrocarbon) group include fluoro (hetero atom-containing hydrocarbon). Preferred are a (hydrocarbon) group and a fluoro (partial chroma (hetero atom-containing hydrocarbon)) group.
- the halogeno (hetero atom-containing hydrocarbon) group preferably has 1 to 20 carbon atoms.
- Perhalogeno (heteroatom-containing carbon) groups include perfluoro
- heteroatom-containing hydrocarbons or perfluoro (partial chromato (heteroatom-containing hydrocarbons)) groups.
- the halogeno (heteroatom-containing monovalent saturated hydrocarbon) group may have a straight-chain structure or a branched structure.
- the halogeno (heteroatom-containing monovalent saturated hydrocarbon) group is preferably a fluoro (heteroatom-containing alkyl) group or a fluoro (partial fluoro (heteroatom-containing alkyl)) group.
- As the perhalogeno (heteroatom-containing monovalent saturated hydrocarbon) group a perfluoro (alkoxyl) group or a perfluoro (partially chloro (alkoxyl)) group is preferable.
- a halogeno (divalent saturated hydrocarbon containing a heteroatom) group is a group in which one hydrogen atom in a halogeno (a monovalent saturated hydrocarbon containing a heteroatom) has become a bond, and fluoro (etheric oxygen)
- An atom-containing divalent alkylene) group and a fluoro (partial port (etheric oxygen atom-containing divalent alkylene)) group are preferred.
- a perfluoro (ether'-oxygen atom-containing divalent alkylene) group and a perfluoro (partial chroma (etheric oxygen atom-containing divalent alkylene)) group are preferable.
- compound (I) a compound having one or more partial structures represented by Formula 1 (hereinafter, referred to as compound (I)) is thermally decomposed.
- R b to R e in the compound (I) is an organic group which does not change by the respective thermal decomposition, and the organic groups, before and after the thermal decomposition reaction in the present invention, an organic group that chemical structure does not Heni ⁇ Say.
- an organic group a group in which a partial structure of “COOCF 2 c -cx a (where X a is a halogen atom)” does not exist in the group (hereinafter, the group is referred to as group (A)), heat group under the reaction conditions of decomposing no chemically unstable structure include force s.
- R b to R e include a hydrocarbon group or a hydrogen atom group.
- Heteroatom-containing hydrocarbon group or C Logeno (heteroatom-containing hydrocarbon) groups are usually modified by thermal decomposition, except when the heteroatoms or heteroatoms in the group are changed by a thermal decomposition reaction (for example, the group (A)). It is a group that does not dumb.
- the above description of the organic group whose chemical structure does not change before and after the thermal decomposition reaction applies whether the organic group is monovalent or divalent, and is based on the following description of R b to R e.
- Group (A) is excluded.
- R b to R e saturated hydrocarbon group, a halogeno saturated hydrocarbon group, a hetero atom-containing saturated hydrocarbon off originally is Harogenohetero atom-containing saturated hydrocarbon group.
- R b to R e are preferably those groups containing a fluorine atom, such as a perfluorinated group; ⁇ !] Hydrocarbon group, perfluoro (a saturated hydrocarbon containing an etheric oxygen atom) group, and perfluoro (partially saturated A hydrocarbon) group or a perfluoro (partial chroma (hydrocarbon containing an etheric oxygen atom)) group (hereinafter, these groups are collectively referred to as a group ( F )) are preferred.
- the number of carbon atoms is preferably 1 to 20.
- the group include a perfluoroalkyl group, a perfluoro (alkyl containing an etheric oxygen atom) group, a perfluoro (an alkyl partially containing alkyl) group, and a perfluoro (a partial alkyl (alkyl containing an etheric oxygen atom)) ) Group (hereinafter, these groups are collectively referred to as a group (R ").).
- the number of carbon atoms is preferably 1 to 20.
- the group include a perfluoroalkylene group, a perfluoro (alkylene containing an etheric oxygen atom) group, a perfluoro (a partially alkylene alkylene) group, or a perfluoro (a partially cycloalkylene (alkylene containing an etheric oxygen atom)) group (Hereinafter, these groups are collectively referred to as a group (R F 2 ).).
- the compound (I) is thermally decomposed.
- the compound (I) may have two or more partial structures represented by the formula 1, and in such a case, the compound (2) corresponding to the partial structure is generated. In a normal case, it is preferable that the number of the partial structure represented by Formula 1 is one. Further, as the compound (I), the compound (1A) is preferable. R a COOCF 2 CR b R c -CXR d R e -HA
- Ra represents a hydrogen atom, a halogen atom, or a monovalent organic group.
- Rb , Rc , Rd , Re , and X have the same meaning as described above.
- X is preferably a fluorine atom, but is preferably a chlorine atom from the viewpoint of the thermal decomposition reaction.
- RF CF 3
- R 2 OCF CF 3
- R 3 CF 2 CF 2 — or R 4 OCF 2 CF 2 —
- R 1 to: 4 each independently represent a monovalent organic group, preferably a monovalent group (R F ), and particularly preferably a group (R F1 ). preferable.
- R a is one of these groups
- R a is preferably a group represented by CXR d R e —CR b R c — (where R b to R e have the same meaning as described above, and X represents a halogen atom).
- ⁇ CF (CF 3) one, R 2 OCF (CF 3) -, R 3 CF 2 CF 2 -, or R 4 0 CF 2 CF 2 - preferably Ru der.
- reaction of the present invention is a particularly useful method for producing a fluorine-containing unsaturated compound.
- the compound (1A F ) is preferable, and particularly, the compound (1B) is preferable.
- R ai a fluorine atom or a perfluorinated monovalent organic group.
- R bi , R c R di , and R ei are each independently a fluorine atom or a fluorine-containing monovalent organic group which is not changed by a thermal decomposition reaction. Also, two selected from R bi , R ci , R di , and R ei are connected to each other to form a fluorinated divalent organic group that is not changed by the thermal decomposition reaction, and the remaining two are connected to each other. , May not form a fluorine-containing divalent organic group that is not changed by the thermal decomposition reaction, or the remaining two may be each independently a fluorine atom or a fluorine-containing monovalent compound that is not changed by the thermal decomposition reaction It may be a machine base. The number of fluorine-containing divalent organic groups may be one or two, preferably one.
- X a halogen atom
- a compound represented by the following formula 1B is preferable because compound (2) is a main product as a product of a thermal decomposition reaction. .
- it can be generated in the course of the reaction FCO- CR b R c - CXR d R e ( Equation 3 B) is converted to the compound under the conditions of the thermal decomposition reaction (2).
- FCO- CR b R c - CXR d R e Equation 3 B
- R bi , R ci , R di , R ef , and X have the same meaning as described above.
- R b, R c, R d, one or more groups selected from and R e from the viewpoint of usefulness of the resulting compound (2), A group having an etheric oxygen atom at the end thereof (for example, a perfluoro (alkoxyl group) or a perfluoro (partial cycloalkyl (alkoxyl)) group is preferable), and when the remaining group is present, the group is It is preferably a fluorine atom.
- any one group selected from R b , R c , and R: R e is a perfluoro (alkoxyl) group or a perfluoro (partially (alkoxyl)) group, and the remaining three groups are fluorine atoms. It is preferred that When R b , R c , R d , and R e form a divalent organic group, it is preferable that both bonding terminals of the divalent organic group are etheric oxygen atoms.
- Ra in compound (1A) is selected such that compound (3) produced by the thermal decomposition reaction has a large difference in boiling point from compound (2), the compound (2) And compound It is preferable because it can be easily separated from the substance (3).
- Ra is a fluorine atom, or when the molecular weight of Ra is increased.
- the difference in boiling point is preferably 2 ° C or more, particularly preferably 20 ° C or more.
- the boiling point of compound (3) be higher than that of compound (2) by 2 ° C or more, particularly preferably 20 ° C or more. .
- C y F shows the Perufuruoro (cyclohexyl) group below.
- the compound (2) is obtained by a thermal decomposition reaction of the compound (I).
- the thermal decomposition reaction can be performed by heating.
- the reaction is usually performed in a gas phase reaction or a liquid phase reaction, and is preferably performed efficiently in a gas phase reaction.
- the method and reaction temperature of the thermal decomposition reaction depend on the boiling point and stability of compound (I). It is preferred to choose.
- the compound (I) preferably has a boiling point of 350 ° C. or less at normal pressure, because it can undergo a thermal decomposition reaction in a gas phase reaction. Further, the boiling point of compound (I) is preferably 50 ° C. or higher.
- the gas phase reaction is preferably performed by a continuous reaction. The continuous reaction is carried out by passing the vaporized compound (I) into a heated reaction tube, obtaining the produced compound (2) as an outlet gas, condensing the gas, and continuously collecting the gas. Is preferred.
- the reaction temperature in the case of performing pyrolysis in a gas phase reaction can be appropriately changed depending on the structure of compound (I), but is generally preferably 150 ° C. or more, and more preferably 200 ° C. (: to 500 ° C.). Is particularly preferred, and particularly preferably 250 ° (: up to 450 ° C. If the reaction temperature is too high, the decomposition reaction of the product may occur and the yield may be reduced. too low, FCOCR b R c - CXR d R generates a large amount becomes unfavorably e.
- the residence time is preferably about 0.1 second to 10 minutes on an empty tower basis.
- the reaction pressure is not particularly limited.
- the reaction is preferably performed under reduced pressure.
- the compound (I) is a low-boiling compound, it is preferable to carry out the reaction under pressure because decomposition of the product is suppressed and the reaction rate is increased.
- the reaction tube When a gas phase reaction is carried out using a tubular reactor, it is preferable to fill the reaction tube with a glass, an alkali metal salt, or an alkaline earth metal salt from the viewpoint of accelerating the reaction.
- a glass As the alkali metal salt or alkaline earth metal salt, a carbonate or a fluoride is preferable.
- the glass include common soda glass, and particularly, glass beads in a bead form and having improved fluidity are preferable.
- Alkali metal salts include sodium carbonate, sodium fluoride, potassium carbonate, or lithium carbonate.
- the alkaline earth metal carbonate include calcium carbonate, calcium fluoride, and magnesium carbonate.
- the reaction tube is filled with glass, alkali metal salt, alkaline earth metal salt, etc. When the substance is filled, it is particularly preferable to use glass beads or light ash of sodium carbonate having a particle size of about 100 to 250 because a fluidized bed type reaction system can be employed.
- These fillers are preferably subjected to a dehydration treatment in advance.
- the dehydration treatment is preferably performed by flowing an inert gas such as nitrogen gas at a reaction temperature for performing a gas phase reaction. By performing the dehydration treatment, the yield of the thermal decomposition reaction can be significantly improved.
- the thermal decomposition may be carried out in the presence of an inert gas which is not directly involved in the thermal decomposition reaction in order to promote the reaction of the compound (I).
- the inert gas include nitrogen, carbon dioxide, helium, and argon.
- the amount of the inert gas is preferably about 0.01 to 50% by volume based on the compound (I). If the amount of the inert gas is too large, the amount of the recovered product may be low, which is not preferable. On the other hand, when the boiling point of compound (I) is high, the thermal decomposition may be performed by a liquid phase reaction.
- the it ⁇ compound (2), I ⁇ compound (1 A F) compound produced by thermal decomposition of (2 F) is preferred.
- one or more groups selected from R b , R c , R d , and Re are bonded from the viewpoint of ease of polymerization when the compound is polymerized to form a polymer.
- a group having a terminal ether monoprotonic atom for example, a perfluoro (alkoxyl group) or a perfluoro (partially chloro (alkoxyl)) group is preferable. 1/01735
- the group is a fluorine atom.
- any one group selected from R b , R c , R d , and R e is a perfluoro (alkoxyl group) or a perfluoro (partial chroma (alkoxyl)) group, and the remaining three groups are Particularly preferred is a fluorine atom.
- R b , R c , R d , and Re form a divalent organic group, it is preferable that both ends of the bond of the divalent organic group are etheric oxygen atoms.
- Specific examples of the compound (2) include the following compounds. Among the following compounds, the compound (2A) and the compound (2B) are novel compounds useful as monomers for producing a fluororesin.
- CF 2 CFOCF 2 CF 2 CF 3 ,
- CF 2 CF0CF 2 CF, CFC 1CF 2 C
- the product of the thermal decomposition reaction is preferably separated and purified by a usual method. Separation and purification method For example, distillation, silica gel column chromatography and the like can be mentioned. Since the compounds (2) and (3) have a lower molecular weight than the starting material for the thermal decomposition reaction and are usually low boiling compounds, the unreacted starting compounds are efficiently removed by distillation. Can be done.
- the method for obtaining the compound (I) of the present invention is not particularly limited, and a commercially available compound or a compound produced by a known production method can be used.
- Compound (1A F) is of compound (3 H) and the compound (4) compounds can be prepared by reacting a (5) preferably produced by Ekishofu Tsu fluorination of.
- the method of producing the compound (1 AF ) by a liquid phase fluorination reaction in a liquid phase is preferable because the raw material (compound ( 3H )) is inexpensive and various structures are available.
- R bH , R cH , R dH , R eH independently fluorinated by liquid phase fluorination, R bH becomes R bi , R cH becomes R ci , R dH becomes R df , R dH becomes A group that becomes R df .
- X 1 each independently represents a hydrogen atom or a halogen atom, and is preferably a fluorine atom from the viewpoint of simplicity of the continuous production method described later.
- X 2 is an atom corresponding to X; when X is a fluorine atom, it is a hydrogen atom or a fluorine atom; and when X is a halogen atom other than a fluorine atom, the same halogen as the halogen atom atom.
- R a 1 is a group to be fluorinated, a group selected from an alkyl group, an etheric oxygen atom-containing alkyl group, a partial chromate alkyl group, and a partial chromate (etheric oxygen atom-containing alkyl) group
- RbH, R C H, RdH, R eH are each independently a group (RH), a hydrogen atom, or fluorine atom is preferred. Or, R bH, R cH, R dH, two selected from R eH are linked to one another, an alkylene group, an etheric oxygen atom-containing alkylene group, part minute black port alkylene group, and partially black port (etheric oxygen An atom-containing alkylene) group, a group in which at least one hydrogen atom in the group is substituted with a fluorine atom, or at least one carbon-carbon single bond in the group has a carbon-carbon double bond.
- R H 2 It is preferably a bond or a group substituted by a carbon-carbon triple bond (hereinafter, these groups are collectively referred to as a group (R H 2 )).
- the remaining two may be linked to each other to form a group (R H2 ), or the remaining two may be each independently a group (R H ⁇ element atom or fluorine atom
- R bi , R ci , R di , and: R ef contain a perfluorocyclohexyl group or a perfluorocyclohexylene group
- R bH, R cH, R dH I ⁇ product corresponding moieties in R eH is Hue alkylsulfonyl group Ya phenylene group (4) may be used.
- the reaction between compound ( 3H ) and compound (4) can be carried out under ordinary esterification conditions.
- Compound (5) produced by the esterification reaction undergoes liquid-phase fluorination to produce compound (1 AF ).
- the esterification reaction is preferably carried out using I ⁇ compound (4) in pairs to magnification molar excess of the compound (3 F).
- I ⁇ compound (3 F) acts as a solvent for the esterification reaction, the product of the esterification reaction will mix of the compound (5 F) and the compound (3 F).
- a liquid phase fluorination reaction described later is preferably performed using the mixture as it is. In such a case, This is particularly preferable because the time and labor required for the treatment can be omitted and the compound ( 3F ) acts as a liquid phase in the liquid phase fluorination reaction.
- the liquid-phase fluorination reaction of compound (5) is preferably performed by a liquid-phase fluorination method in which compound (5) is reacted with fluorine (F 2 ) in a liquid phase.
- the liquid phase fluorination reaction is preferred because the compound (1 AF ) can be obtained with a high yield and the control of the reaction is easy.
- the amount of fluorine used for fluorination is always iif! With respect to the hydrogen atoms in (5).
- Fluorine gas is preferably charged so as to have an equivalent weight (ie, more than 1 mole).
- the fluorine gas is added so as to always be at least 1.5 times equivalent (ie, at least 1.5 times mol) with respect to the hydrogen atom in the conjugate (5). It is particularly preferable to carry out the method from the viewpoint of selectivity.
- the compound (5) is introduced into the reaction system, it is preferable to continuously introduce the compound (5). At that time, the compound (5) may be introduced after being diluted or may be introduced as it is.
- the amount of fluorine is always in excess with respect to the hydrogen atoms in the compound (5). .
- Fluorine may be present in the liquid phase in advance, fluorine gas may be continuously introduced into the reaction system, and the latter is preferred because the amount of compound (5) relative to fluorine gas can be adjusted. Further, it is particularly preferable that fluorine is previously present in the liquid phase, and that fluorine gas is continuously introduced into the system during the reaction.
- a solvent that does not contain a C—H bond but requires a C—F bond is preferable.
- a perfluoroalkane or a chlorine atom, a nitrogen atom, and a nitrogen atom are selected.
- An organic solvent obtained by perfluorinating a known organic solvent having at least one atom in its structure is preferred.
- the solvent it is preferable to use a solvent which dissolves the compound (5) (1) which has a long life.
- the solvent is selected from inert solvents, such as perfluoroalkanes (trade name: FC-72 ⁇ ), perfluoroethers (trade names: FC-75, FC-77, etc.), Fluoropolyethers (trade names: Kryttox, Fonpurin, Galden, Demnum, etc.), chlorofluorocarbons (trade name: CFC), chlorofluoropolyethers, perfluoroalkylamines (for example, Fluorotrialkylamines, etc., inert fluids (trade name: Florinert), berhalogenoester compounds (for example, I-Fidasoh (1 AF )), perfluoroethers and black-mouth fluoropolyethers the solvent terminal etc.
- inert solvents such as perfluoroalkanes (trade name: FC-72 ⁇ ), perfluoroethers (trade names: FC-75, FC-77, etc.), Fluoropolyethers (trade names: Krytto
- the compound (3) or the compound ( 1AF ) is selected as the solvent, it is particularly preferable because the above conditions are satisfied and the product after the fluorination reaction does not need to be separated.
- the liquid phase is particularly preferably the compound ( 3F ) used in excess in the esterification reaction.
- the amount of the solvent used as the liquid phase is preferably at least 5 times, more preferably at least 10 to 100 times the mass of the compound (5).
- compound (5) When compound (5) is reacted with fluorine in the liquid phase, compound (5) is a compound having a fluorine content that is sufficiently soluble in the liquid phase, and is at least as large as the gas phase reaction can be suppressed. It is preferable to adjust the structure of compound (5) so that the compound has a sufficient molecular weight. That is, a solvent that usually dissolves fluorine gas is used as the liquid phase. In order to easily dissolve the compound (5) in the solvent, the compound (5) is preferably a fluorinated compound, and particularly preferably the compound (5).
- the fluorine content of the compound (5) is preferably preferably at least 10 mass%,:., especially preferably in the range of I 0 to 86 weight 0/0, it is preferred that especially 30-76 wt 0/0 the compound (5) is sufficient molecular weight
- the compound (5) preferably has a molecular weight of 200 to 1000 because the compound (5) can prevent volatilization in the gas phase during the fluorination reaction to cause a decomposition reaction. Is preferably a compound wherein R al in compound (5) is the same group as R ai .
- an alkali metal fluoride (preferably NaF or KF) may be present in the system as an HF scavenger.
- the yield of the fluorination reaction product can be increased by adding a compound capable of generating elemental radicals or irradiating the reaction system with ultraviolet rays.
- the compound capable of generating a fluorine radical include aromatic compounds such as benzene and toluene.
- a particularly preferred method as the production method of the present invention by performing the Esuterui spoon reaction using 1 fold molar excess of the compound of the compound (4) (3 F), I ⁇ compound (5 F) and the compound
- This is a method in which a mixture with ( 3F ) is obtained, the mixture is subjected to a liquid phase fluorination reaction to obtain a mixture of compound ( 1AF ) and compound ( 3F ), and the mixture is thermally decomposed.
- R af is one CR bf R f —CXR df R ef because the labor for separating the product of the thermal decomposition reaction can be simplified.
- the compound ( 3F ) which is a solvent for the esterification reaction and also acts as a liquid phase for the fluorination reaction, becomes the target unsaturated compound (2) by the thermal decomposition reaction. Therefore, it is particularly preferable.
- the compound (2) having a desired structure can be produced 1
- the yield of the thermal decomposition reaction is preferably not less than 5.0%, and particularly preferably not less than 75%.
- the reaction temperature is low pyrolysis reaction, FCO-CR b R c CX d R e (3 B) but may sometimes be by-produced, the compound (3 B) yields 1 0%
- the reaction conditions are determined as follows. Since the obtained compound (2) contains a polymerizable unsaturated group, the compound (2) can be polymerized or the compound (2) can be polymerized with the compound (2). A useful polymer can be produced by copolymerizing a polymerizable monomer.
- Examples thereof include vinyl ethers having a group that can be converted into an acid group and a sulfonic acid group, and olefins such as ethylene, propylene, and isobutylene.
- the polymer obtained according to the present invention can be a useful resin.
- the compound (2) is a fluorine-containing compound
- the fluorine-containing polymer obtained by polymerizing the compound is useful as a fluororesin. Fluororesins are used in a wide range of fields because of their excellent properties of heat resistance and chemical resistance.
- reaction mechanism of the thermal decomposition reaction of the compound (I) is not necessarily clear, but the following two reaction mechanisms are conceivable.
- reaction mechanism 2 Compound (I) by decomposition FCOCR b R c - CXR d R e are generated, one reacts as one CO F group is an alkali metal salt, an alkaline earth metal salt or glass surfaces It is converted to CO OM (M is an alkali metal atom, alkaline earth metal atom, or Si ⁇ ), from which carbon dioxide and MX are released, and the compound
- the thermal decomposition reaction is a reaction which can occur due to the structure of one COOCF 2 C—CX— existing in the compound (I), and various compounds (2) can be easily produced by utilizing the reaction.
- L is used for L
- SUS for stainless steel
- GC gas chromatograph
- HR-MS for high resolution mass spectrum
- GC-MS gas chromatograph mass spectrometer
- R-113 1,1,2-trichloro- 1, 2, 2-trifluoroethane is denoted as R-113.
- the pressure is indicated by gauge pressure.
- a dry ice Z ethanol trap was installed at the reactor outlet to collect the product.
- 1 F-N MR product (5 64. 6 MH z, solvent CDC 1 3, reference: CFC 1 3) the peak of were consistent with those of the authentic sample.
- CF 2 CF 2 was introduced into the system, and the reaction pressure was maintained at 13.5 kg / cm 2 .
- the polymerization initiator was charged intermittently so that the polymerization rate became almost constant, and a total of 7 cc was charged. 3.
- 125 g of a white copolymer was obtained in a slurry state.
- This copolymer had a melting point of 307 ° (the starting point of thermal decomposition was 480 ° C, and gave a good compression molded product at a molding temperature of 340 ° C.
- the tensile strength of the molded product was 392 kg gZcm 2 , The tensile elongation was 367%.
- the GC also confirmed that the main components contained in fractions (1) and (3) were CF 3 CF 2 CF 2 OCF (CF 3 ) COOCH 2 CH (OCH 2 CH 2 CH 3 ) CH 3 confirmed.
- Example 4-1 Fraction obtained in Example 4-1 (2) fraction and (3) were mixed, the 19. 5 ⁇ of which was dissolved in 1 ⁇ over 1 13 (250 g), to obtain a fraction solution.
- NaF (26.1) was added to 50 OmL nickel auto crepe, and -l 13 (324 g) was added, and ⁇ ® was halved, followed by cooling to -10 ° C. After blowing nitrogen gas for 1 hour, fluorine gas diluted to 20% with nitrogen gas was blown at a flow rate of 5.66 LZh for 1 hour, and the same stream was blown while maintaining the same flow. Injected over time.
- ⁇ mulberry crops were repeated four times while raising the temperature from 110 ° C to room temperature, and then five times at room temperature. During this time, a total of 0.291 g of benzene and a total of 45.0 g of Rl13 were injected. Thereafter, nitrogen gas was blown for 2 hours, and the mixture was taken out by decantation. The obtained crude liquid was concentrated by an evaporator, and the product was quantified by 1 F-NM. The yield was 69%. A part of the crude liquid was distilled under reduced pressure to obtain purified CF 3 CF 2 CF 2 OCF (CF 3 ) COOCF 2 CF (CF 3 ) OCF 2 CF 2 CF 3 . The product was a mixture of diastereomers. Boiling point: 46-51 ° C / 5.2 kPa.
- CF 3 CF 2 CF 2 OCF (CF 3 ) COF (2340 g) was added and stirred, 25. Kept at C.
- a cooler kept at 20 ° C, a packed bed of NaF pellets, and a cooler kept at 110 ° C were installed in series. Note that a cooler maintained at 10 ° C Set up a liquid and return line for returning the aggregated liquid to the autoclave. After blowing nitrogen gas for 1.5 hours, fluorine gas diluted to 20 vo 1% with nitrogen gas was blown at a flow rate of 8.91 LZh for 3 hours.
- Example 5-1 the reaction mixture (106 g) obtained in Example 5-1 was injected over 45.6 hours while blowing the diluted fluorine gas at the same flow rate.
- the CF 3 CF 2 CF 2 OCF (CF 3 ) COF solution with a benzene concentration of 0.01 g / mL was heated from 25 ° C to 40 ° C.
- the autoclave benzene inlet was closed, the autoclave outlet valve was closed, and when the pressure reached 0.20 MPa, the autoclave fluorine gas inlet valve was closed, and stirring was continued for 1 hour.
- 6 mL of the above benzene solution was injected, the benzene inlet of the autoclave was closed, and the outlet valve of the autoclave was closed.
- the fluorine gas inlet valve of the autoclave was closed, and stirring was continued for 1 hour. The same operation was repeated once.
- the total injection amount of benzene was 0.309 g, and the total injection amount of CF 3 CF 2 CF 2 OCF (CF 3 ) C 0 F was 30 mL. Furthermore, nitrogen gas was blown for 2.0 hours. After the reaction, to give a mixture of the title compound purified by distillation and (85. 3 g) CF 3 CF 2 CF 2 OC F (CF 3) and C 0 F as the coating solution had. The purity of the title compound was found to be 95%.
- Example 6 Production of gas phase pyrolysis by CF 3 CF 2 CF 2 OCF two CF 2 (3) up and down the porous plate (filtration accuracy 0. 5 / m, stainless steel superficial fitted with a stainless steel> container (inner diameter 5 lmm, 400 mm length) with N a 2 C 0 3 powder in a fluidized bed reactor consisting filled with 390.
- N a 2 C 0 3 is in the range of particle size 100 to 250 m using one.
- the reactor was placed in a molten salt bath heated to 260 ° C, and dehydrated handle Na 2 C0 3 flowing reactor bottom 8 hours with nitrogen gas at the time of 234 NLZ than.
- Example 5 95% pure CF 3 CF 2 CF 2 OCF (CF 3 ) COOCF 2 CF (CF 3 ) OCF 2 CF 2 C obtained in Example 5 F 3
- the crude liquid was Fuido continuously from the bottom of the reactor is diluted with nitrogen gas, and the gas leaving the top of the reactor was liquefied recovered by a dry ice trap. Feed rate is for crude liquid; At 60 g / h, the nitrogen gas was adjusted at 205 LZ.
- Example 1 CF 3 CF 2 CF 2 OCF (CF 3 ) COOCF 2 CF (CF 3 ) 0 CF 2 CF 2 CF 3 in Example 1 is replaced with Cy F CF 2 OCF (CF 3 ) CO ⁇ CF 2 CF (CF 3 ) OC F 2 Changed to CF 2 CF 3 and similarly injected from the injection. Analysis of the product by HR-MS confirmed that the title compound was formed quantitatively.
- the compound (2) which had been difficult to synthesize so far, or the compound (2), which had been synthesized by an economically disadvantageous method, was converted from the compound (I) to the And it can be produced in high yield.
- the compound (1A) is generally easily available, easy to synthesize, inexpensive, and has various structures, and various unsaturated compounds can be produced using the compound as a starting material. .
- R al in formula 1A further R bH, R cH, R dH , to 3 ⁇ 4 ⁇ select the structure of R eH This makes it easier to dissolve in the solvent during fluorination and promotes the liquid phase fluorinated TO.
Description
Claims
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP01908356A EP1288183A4 (en) | 2000-06-02 | 2001-03-06 | PROCESS FOR PREPARING NON-SATURATED COMPOUNDS BY PYROLYSIS |
AU2001236108A AU2001236108A1 (en) | 2000-06-02 | 2001-03-06 | Process for preparing unsaturated compounds by pyrolysis |
JP2002501803A JP4802438B2 (ja) | 2000-06-02 | 2001-03-06 | 熱分解反応による不飽和化合物の製造方法 |
US10/307,388 US7071272B2 (en) | 2000-06-02 | 2002-12-02 | Method for preparing unsaturated compound by pyrolysis reaction |
HK03104748.4A HK1052494A1 (zh) | 2000-06-02 | 2003-07-03 | 通過熱解製備不飽和化合物的方法 |
Applications Claiming Priority (2)
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JP2000-166773 | 2000-06-02 | ||
JP2000166773A JP2001139509A (ja) | 1999-08-31 | 2000-06-02 | 熱分解反応による不飽和化合物の製造方法 |
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US10/307,388 Continuation US7071272B2 (en) | 2000-06-02 | 2002-12-02 | Method for preparing unsaturated compound by pyrolysis reaction |
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WO2001094285A1 true WO2001094285A1 (fr) | 2001-12-13 |
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PCT/JP2001/001735 WO2001094285A1 (fr) | 2000-06-02 | 2001-03-06 | Procede permettant de preparer des composes non satures par pyrolyse |
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US (1) | US7071272B2 (ja) |
EP (1) | EP1288183A4 (ja) |
JP (1) | JP4802438B2 (ja) |
KR (1) | KR20030009503A (ja) |
CN (1) | CN1209331C (ja) |
AU (1) | AU2001236108A1 (ja) |
HK (1) | HK1052494A1 (ja) |
RU (1) | RU2281280C2 (ja) |
WO (1) | WO2001094285A1 (ja) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2001240576A (ja) * | 1999-12-20 | 2001-09-04 | Asahi Glass Co Ltd | フルオリド化合物の製造方法 |
US6586626B2 (en) | 1999-03-23 | 2003-07-01 | Asahi Glass Company, Limited | Process for producing a fluorine-containing compound by liquid phase fluorination |
US6956138B2 (en) | 2000-07-11 | 2005-10-18 | Asahi Glass Company, Limited | Method for producing a fluorine-containing compound |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1288183A4 (en) | 2000-06-02 | 2005-01-26 | Asahi Glass Co Ltd | PROCESS FOR PREPARING NON-SATURATED COMPOUNDS BY PYROLYSIS |
RU2268876C2 (ru) * | 2000-09-27 | 2006-01-27 | Асахи Гласс Компани, Лимитед | Способ получения фторированного поливалентного карбонильного соединения |
JP4285000B2 (ja) * | 2001-01-16 | 2009-06-24 | 旭硝子株式会社 | 含フッ素エステル、含フッ素アシルフルオリドおよび含フッ素ビニルエーテルの製造方法 |
TWI322709B (en) | 2001-12-04 | 2010-04-01 | Bp Chem Int Ltd | Oxidation process in fluidised bed reactor |
JP2009203172A (ja) * | 2008-02-26 | 2009-09-10 | Fujifilm Corp | パーフルオロ多官能ビニルエーテル化合物の製造方法 |
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- 2001-03-06 EP EP01908356A patent/EP1288183A4/en not_active Withdrawn
- 2001-03-06 CN CNB018105289A patent/CN1209331C/zh not_active Expired - Fee Related
- 2001-03-06 KR KR1020027016110A patent/KR20030009503A/ko not_active Application Discontinuation
- 2001-03-06 WO PCT/JP2001/001735 patent/WO2001094285A1/ja not_active Application Discontinuation
- 2001-03-06 AU AU2001236108A patent/AU2001236108A1/en not_active Abandoned
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- 2001-03-06 RU RU2002132264/04A patent/RU2281280C2/ru not_active IP Right Cessation
-
2002
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6586626B2 (en) | 1999-03-23 | 2003-07-01 | Asahi Glass Company, Limited | Process for producing a fluorine-containing compound by liquid phase fluorination |
US6951957B2 (en) | 1999-03-23 | 2005-10-04 | Asahi Glass Company, Limited | Process for producing a fluorine-containing compound by liquid phase fluorination |
US7083705B2 (en) | 1999-03-23 | 2006-08-01 | Asahi Glass Company, Limited | Process for producing a fluorine-containing compound by liquid phase fluorination |
JP2001240576A (ja) * | 1999-12-20 | 2001-09-04 | Asahi Glass Co Ltd | フルオリド化合物の製造方法 |
US6956138B2 (en) | 2000-07-11 | 2005-10-18 | Asahi Glass Company, Limited | Method for producing a fluorine-containing compound |
Also Published As
Publication number | Publication date |
---|---|
EP1288183A1 (en) | 2003-03-05 |
US20030139570A1 (en) | 2003-07-24 |
CN1209331C (zh) | 2005-07-06 |
EP1288183A4 (en) | 2005-01-26 |
HK1052494A1 (zh) | 2003-10-03 |
JP4802438B2 (ja) | 2011-10-26 |
US7071272B2 (en) | 2006-07-04 |
RU2281280C2 (ru) | 2006-08-10 |
KR20030009503A (ko) | 2003-01-29 |
CN1431985A (zh) | 2003-07-23 |
AU2001236108A1 (en) | 2001-12-17 |
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