WO2000071655A1 - Car wash cleaner - Google Patents

Car wash cleaner Download PDF

Info

Publication number
WO2000071655A1
WO2000071655A1 PCT/US2000/013925 US0013925W WO0071655A1 WO 2000071655 A1 WO2000071655 A1 WO 2000071655A1 US 0013925 W US0013925 W US 0013925W WO 0071655 A1 WO0071655 A1 WO 0071655A1
Authority
WO
WIPO (PCT)
Prior art keywords
vehicle
composition
cleaning
water
anionic surfactant
Prior art date
Application number
PCT/US2000/013925
Other languages
English (en)
French (fr)
Inventor
Richard E. Rudin
Robert H. Lohr
Original Assignee
S.C. Johnson & Son, Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by S.C. Johnson & Son, Inc. filed Critical S.C. Johnson & Son, Inc.
Priority to EP00932659A priority Critical patent/EP1180128B1/en
Priority to MXPA01012081A priority patent/MXPA01012081A/es
Priority to CA002374488A priority patent/CA2374488A1/en
Priority to AT00932659T priority patent/ATE312153T1/de
Priority to JP2000620036A priority patent/JP2003500524A/ja
Priority to DE60024614T priority patent/DE60024614T2/de
Priority to BR0010894-4A priority patent/BR0010894A/pt
Publication of WO2000071655A1 publication Critical patent/WO2000071655A1/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/83Mixtures of non-ionic with anionic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2072Aldehydes-ketones
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/37Polymers
    • C11D3/3703Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3707Polyethers, e.g. polyalkyleneoxides
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29Sulfates of polyoxyalkylene ethers
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38Cationic compounds
    • C11D1/42Amino alcohols or amino ethers
    • C11D1/44Ethers of polyoxyalkylenes with amino alcohols; Condensation products of epoxyalkanes with amines
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/722Ethers of polyoxyalkylene glycols having mixed oxyalkylene groups; Polyalkoxylated fatty alcohols or polyalkoxylated alkylaryl alcohols with mixed oxyalkylele groups

Definitions

  • the present invention relates to vehicle cleaners which do not require hand drying. More particularly, it relates to car wash cleaners which permit rinse water to readily sheet off the vehicle during the rinsing process, yet which do not adversely affect beading properties after the car has dried .
  • a rinae aid which improves sheeting during the car wash process, but also destroys the ability of car wax to cause beading is a commercially unacceptable additive (as consumers would believe that the cleaner had destroyed the wax job) .
  • the invention provides a composition for cleaning a vehicle containing a copolymer of ethylene oxide and propylene oxide, anionic surfactant and water.
  • the copolymer is selected from the group consisting of:
  • the copolymer can be selected from the group consisting of: CH 3 CH 3 H-(OCH 2 CH 2 )y"-(OCHCH 2 ) x - ⁇ ⁇ CHzCHO ⁇ — (CH 2 CH 2 0) y — H — CH 2 -CH 2 -N
  • each of x, x' , x " , x "' , y, y' , y " , and y '" is 2-500.
  • Overall molecular weights of the copolymers are preferably between 1,000 and 50,000, with total EO and total PO units each preferably under 150 (even more preferably each under 50) .
  • compositions contain at least 50% water, between 0.5% and 8% block copolymer, and 20% to 45% anionic surfactant.
  • the preferred anionic surfactants are sulfates, sulfonates, and mixtures thereof, especially sodium dodecylbenzene sulfonate, sodium laureth sulfate and mixtures thereof .
  • the compositions can also contain a preservative such as formaldehyde, and other ingredients such as dyes, fragrances, other rinse aids, and fillers.
  • the composition can be applied in concentrated form to deal with particularly soiled areas, diluted with water in a bucket and directly applied with a sponge or the like, or diluted with water and sprayed onto a vehicle.
  • the invention provides methods for cleaning the surface of a vehicle by applying the above compositions to the vehicle, followed by rinsing with water.
  • the vehicle can then air dry (either from a stationary position, or while moving) .
  • a variety of the copolymers within the block copolymer formulae of claim 2 are sold by BASF under the trade designation Pluronics * .
  • a variety of the copolymers within the "block" copolymer formulae of claim 10 are sold by BASF under the trade designation Tetronics ⁇ .
  • anionic surfactants can be used such as sodium alkyl aryl ethoxy sulfates, sodium lauryl sulfate, sodium linear alkylate sulfonates, disodium sulfosuccinate , and diammonium lauryl sulfosuccinate .
  • other types of surfactants may be used in minor amounts.
  • a preservative e.g. formaldehyde
  • preservatives include anti-microbials such as Kathon (Rohm & Haas) , Dowicil (Dow Chemical) , and Canguard (Angus Chemical) .
  • Water is preferably 50% to 70% of a concentrated form of the composition.
  • the compositions can be diluted with water (e.g. one part of the concentrated composition diluted with 60-175 parts of water, or even more) . As noted above with respect to the spot use of the concentrated formula, no such dilution is required. However, absent such dilution the cost of washing an entire vehicle using the concentrate could be quite expensive.
  • the cleaners of the present invention can be used to wash vehicles such as automobiles, vans and trucks from a bucket.
  • the cleaners can be applied by hand (e.g. via a rag, pad or sponge) and subsequently rinsed off with a hose.
  • the cleaner can be sprayed onto the vehicles in more diluted form using an automated sprayer, and then rinsed off using an automated rinsing system. In either case, the vehicles dry by evaporation.
  • the objects of the present invention therefore include providing cleaners of the above kind:
  • EXAMPLE 1 EXAMPLE 2 Ingredient % wt . % wt .
  • the present invention provides chemicals that are particularly useful for cleaning vehicle exteriors, and methods of using these cleaners.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)
  • Mechanical Treatment Of Semiconductor (AREA)
  • Vehicle Cleaning, Maintenance, Repair, Refitting, And Outriggers (AREA)
PCT/US2000/013925 1999-05-24 2000-05-19 Car wash cleaner WO2000071655A1 (en)

Priority Applications (7)

Application Number Priority Date Filing Date Title
EP00932659A EP1180128B1 (en) 1999-05-24 2000-05-19 Car wash cleaner
MXPA01012081A MXPA01012081A (es) 1999-05-24 2000-05-19 Limpiador para lavado automatico.
CA002374488A CA2374488A1 (en) 1999-05-24 2000-05-19 Car wash cleaner
AT00932659T ATE312153T1 (de) 1999-05-24 2000-05-19 Autowaschmittel
JP2000620036A JP2003500524A (ja) 1999-05-24 2000-05-19 洗車用洗剤
DE60024614T DE60024614T2 (de) 1999-05-24 2000-05-19 Autowaschmittel
BR0010894-4A BR0010894A (pt) 1999-05-24 2000-05-19 Limpador para lavagem de carro

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US31750899A 1999-05-24 1999-05-24
US09/317,508 1999-05-24

Publications (1)

Publication Number Publication Date
WO2000071655A1 true WO2000071655A1 (en) 2000-11-30

Family

ID=23233978

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2000/013925 WO2000071655A1 (en) 1999-05-24 2000-05-19 Car wash cleaner

Country Status (10)

Country Link
EP (1) EP1180128B1 (ja)
JP (1) JP2003500524A (ja)
AT (1) ATE312153T1 (ja)
BR (1) BR0010894A (ja)
CA (1) CA2374488A1 (ja)
DE (1) DE60024614T2 (ja)
ES (1) ES2252007T3 (ja)
MX (1) MXPA01012081A (ja)
WO (1) WO2000071655A1 (ja)
ZA (1) ZA200109697B (ja)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7318871B2 (en) 2004-06-16 2008-01-15 The Clorox Company Vehicular cleaning concentrate
WO2020132575A1 (en) * 2018-12-21 2020-06-25 Henkel IP & Holding GmbH Use of ethyleneoxy and propyleneoxy copolymer to control rheology of unit dose detergent pack

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4595526A (en) * 1984-09-28 1986-06-17 Colgate-Palmolive Company High foaming nonionic surfacant based liquid detergent
JPH04268399A (ja) * 1991-02-25 1992-09-24 Nikka Chem Co Ltd 自動車用洗浄剤組成物
US5250230A (en) * 1991-12-20 1993-10-05 Henkel Corporation Composition and process for cleaning metals
WO1998051767A1 (en) * 1997-05-16 1998-11-19 The Procter & Gamble Company LIGHT-DUTY LIQUID OR GEL DISHWASHING DETERGENT COMPOSITIONS HAVING CONTROLLED pH AND DESIRABLE FOOD SOIL REMOVAL AND SUDSING CHARACTERISTICS
US5871590A (en) * 1997-02-25 1999-02-16 Ecolab Inc. Vehicle cleaning and drying compositions
WO2000012659A1 (en) * 1998-08-28 2000-03-09 Huntsman Petrochemical Corporation Solubilization of low 2-phenyl alkylbenzene sulfonates

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4595526A (en) * 1984-09-28 1986-06-17 Colgate-Palmolive Company High foaming nonionic surfacant based liquid detergent
JPH04268399A (ja) * 1991-02-25 1992-09-24 Nikka Chem Co Ltd 自動車用洗浄剤組成物
US5250230A (en) * 1991-12-20 1993-10-05 Henkel Corporation Composition and process for cleaning metals
US5871590A (en) * 1997-02-25 1999-02-16 Ecolab Inc. Vehicle cleaning and drying compositions
WO1998051767A1 (en) * 1997-05-16 1998-11-19 The Procter & Gamble Company LIGHT-DUTY LIQUID OR GEL DISHWASHING DETERGENT COMPOSITIONS HAVING CONTROLLED pH AND DESIRABLE FOOD SOIL REMOVAL AND SUDSING CHARACTERISTICS
WO2000012659A1 (en) * 1998-08-28 2000-03-09 Huntsman Petrochemical Corporation Solubilization of low 2-phenyl alkylbenzene sulfonates

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
DATABASE WPI Week 199245, Derwent World Patents Index; AN 1992-368626, XP002146947 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7318871B2 (en) 2004-06-16 2008-01-15 The Clorox Company Vehicular cleaning concentrate
WO2020132575A1 (en) * 2018-12-21 2020-06-25 Henkel IP & Holding GmbH Use of ethyleneoxy and propyleneoxy copolymer to control rheology of unit dose detergent pack
US10907118B2 (en) 2018-12-21 2021-02-02 Henkel IP & Holding GmbH Use of ethyleneoxy and propyleneoxy copolymer to control rheology of unit dose detergent pack

Also Published As

Publication number Publication date
EP1180128B1 (en) 2005-12-07
ZA200109697B (en) 2002-11-26
CA2374488A1 (en) 2000-11-30
EP1180128A1 (en) 2002-02-20
ATE312153T1 (de) 2005-12-15
JP2003500524A (ja) 2003-01-07
BR0010894A (pt) 2002-03-05
DE60024614D1 (de) 2006-01-12
MXPA01012081A (es) 2002-06-04
DE60024614T2 (de) 2006-07-20
ES2252007T3 (es) 2006-05-16

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