CN112342091A - 一种汽车清洁剂及其制备方法 - Google Patents
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- 239000012459 cleaning agent Substances 0.000 title abstract description 24
- 238000002360 preparation method Methods 0.000 title abstract description 11
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims abstract description 39
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 34
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims abstract description 33
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims abstract description 28
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 14
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 claims abstract description 14
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229920000570 polyether Polymers 0.000 claims abstract description 14
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims abstract description 14
- 235000017557 sodium bicarbonate Nutrition 0.000 claims abstract description 14
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 claims abstract description 14
- XMSXQFUHVRWGNA-UHFFFAOYSA-N Decamethylcyclopentasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 XMSXQFUHVRWGNA-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229940086555 cyclomethicone Drugs 0.000 claims abstract description 13
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims abstract description 13
- 238000003756 stirring Methods 0.000 claims description 21
- 239000003599 detergent Substances 0.000 claims description 20
- 239000007788 liquid Substances 0.000 claims description 14
- 238000005303 weighing Methods 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 4
- 230000000694 effects Effects 0.000 abstract description 10
- 238000004140 cleaning Methods 0.000 abstract description 9
- 239000008367 deionised water Substances 0.000 abstract description 6
- 229910021641 deionized water Inorganic materials 0.000 abstract description 6
- 239000002253 acid Substances 0.000 abstract description 4
- 230000007797 corrosion Effects 0.000 abstract description 4
- 238000005260 corrosion Methods 0.000 abstract description 4
- 238000004018 waxing Methods 0.000 abstract description 3
- 239000003973 paint Substances 0.000 description 3
- 239000003945 anionic surfactant Substances 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
- 239000003093 cationic surfactant Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 239000003513 alkali Substances 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 229920006351 engineering plastic Polymers 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000011086 high cleaning Methods 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/65—Mixtures of anionic with cationic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2041—Dihydric alcohols
- C11D3/2044—Dihydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
- C11D3/3734—Cyclic silicones
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
- C11D3/3738—Alkoxylated silicones
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
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- C11D2111/18—Glass; Plastics
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Abstract
本发明公开了一种汽车清洁剂及其制备方法，以重量组分计包括：硅酮季铵盐3～6份；二乙醇胺3～6份；环甲基硅油6～8份；丙二醇25～30份；聚醚硅氧烷2～4份；十二烷基苯磺酸钠2～3份；碳酸氢钠30～34份；去离子水50～60份。本发明提供的汽车清洁剂对汽车进行清洗之后，下雨或其他因素打湿了汽车表面后就会形成分散的水滴，就像给表面上蜡一样；本汽车清洗剂不含有强酸及强碱，对车体没有腐蚀作用，清洗用量少效率高。
Description
技术领域
本发明涉及汽车清洁用具技术领域，更具体地说，它涉及一种汽车清洁剂及其制备方法。
背景技术
汽车清洁剂能除去汽车玻璃表面粘贴的各种胶纸、标签、并能除去车轮周围、挡泥板、保险杠、车体及各种工具上的油污。汽车清洁剂属于汽车用品，汽车用品市场越来越细分化，车品汇专注于汽车用品服务。汽车清洁剂使用后还可形成薄膜以保护车漆。另外，汽车内饰清洁剂就是清洁车内的化纤、木质、皮革、布艺、丝绒、工程塑料等制品(如：顶棚、座椅、仪表台、地毯等)的。
但是，现有的汽车清洁剂市场，产品质量良莠不齐。许多清洗效果好、对车漆无损害的专用清洁剂，因其产品配方复杂，往往价格不菲。许多配方简单成本低的汽车清洁剂，又大多数都非强碱即强酸，对车漆腐蚀严重，长期使用不但损害汽车，还对环境造成污染。传统的清洁剂清洗时用水量大，容易造成浪费。
发明内容
本发明的目的是提供一种汽车清洁剂及其制备方法，其中汽车清洁剂不含有强酸或强碱，对汽车无腐蚀作用，且清洗效率高。
为实现上述目的，通过以下技术手段实现：一种汽车清洁剂，以重量组分计包括：
进一步优化为：一种汽车清洁剂，以重量组分计包括：
进一步优化为：一种汽车清洁剂，以重量组分计包括：
所述硅酮季铵盐为6922硅酮季铵盐、5851硅酮季铵盐中的至少一种。
一种汽车清洁剂的制备方法，包括如下步骤：
(1)按照重量份称取各组分；
(2)将十二烷基苯磺酸钠、碳酸氢钠、硅酮季铵盐与水混合，于50～60℃的条件下搅拌均匀；
(3)将二乙醇胺、环甲基硅油、丙二醇与聚醚硅氧烷混合，在50～60℃条件下搅拌均匀；
(4)将步骤(2)与步骤(3)得到的液体混合，搅拌均匀即可得汽车清洁剂。
本发明与现有技术相比的优点在于：本发明提供的汽车清洗剂不含有强酸及强碱，对车体没有腐蚀作用，清洗用量少效率高；由于硅酮季铵盐是阳离子性的而具有清洁功效，但同时由于他它对基质具有良好的亲和性，使用后其硅酮主链可起到与蜡相似的效果，使得使用了本清洁剂后，下雨或其他因素打湿了汽车表面后就会形成分散的水滴，就像给表面上蜡一样；本清洁剂中十二烷基苯磺酸钠、碳酸氢钠为阴离子表面活性剂，硅酮季铵盐为阳离子表面活性剂，相比如传统的清洁剂配方来说，用硅酮季铵盐为阳离子表面活性剂不会与阴离子表面活性剂形成阴阳离子结合物，活性也不会改变，因而使得所得清洁剂具有较好的清洁效果，同时聚醚硅氧烷对清洗效果有协调改善作用；本发明的汽车清洁剂可以稀释到1∶200甚至更低浓度进行使用，用量少效率高。
具体实施方式
下面通过具体实施例对发明作进一步详述，以下实施例只是描述性的，不是限定性的本发明的保护范围。
实施例1
一种汽车清洁剂，以重量组分计包括：硅酮季铵盐3份；二乙醇胺3份；环甲基硅油6份；丙二醇25份；聚醚硅氧烷2份；十二烷基苯磺酸钠2份；碳酸氢钠30份；去离子水50份。所述硅酮季铵盐选用6922硅酮季铵盐。
以上所述汽车清洁剂的制备方法，按照以下步骤进行：
(1)按照重量份称取各组分；
(2)将十二烷基苯磺酸钠、碳酸氢钠、硅酮季铵盐与水混合，于50℃的条件下搅拌均匀；
(3)将二乙醇胺、环甲基硅油、丙二醇与聚醚硅氧烷混合，在50℃条件下搅拌均匀；
(4)将步骤(2)与步骤(3)得到的液体混合，搅拌均匀即可得汽车清洁剂。
实施例2
一种汽车清洁剂，以重量组分计包括：硅酮季铵盐4份；二乙醇胺4份；环甲基硅油7份；丙二醇26份；聚醚硅氧烷2份；十二烷基苯磺酸钠2份；碳酸氢钠31份；去离子水52份。所述硅酮季铵盐选用6922硅酮季铵盐。
以上所述汽车清洁剂的制备方法，按照以下步骤进行：
(1)按照重量份称取各组分；
(2)将十二烷基苯磺酸钠、碳酸氢钠、硅酮季铵盐与水混合，于52℃的条件下搅拌均匀；
(3)将二乙醇胺、环甲基硅油、丙二醇与聚醚硅氧烷混合，在52℃条件下搅拌均匀；
(4)将步骤(2)与步骤(3)得到的液体混合，搅拌均匀即可得汽车清洁剂。
实施例3
一种汽车清洁剂，以重量组分计包括：硅酮季铵盐5份；二乙醇胺5份；环甲基硅油8份；丙二醇28份；聚醚硅氧烷4份；十二烷基苯磺酸钠3份；碳酸氢钠33份；去离子水58份。所述硅酮季铵盐选用5851硅酮季铵盐。
以上所述汽车清洁剂的制备方法，按照以下步骤进行：
(1)按照重量份称取各组分；
(2)将十二烷基苯磺酸钠、碳酸氢钠、硅酮季铵盐与水混合，于54℃的条件下搅拌均匀；
(3)将二乙醇胺、环甲基硅油、丙二醇与聚醚硅氧烷混合，在54℃条件下搅拌均匀；
(4)将步骤(2)与步骤(3)得到的液体混合，搅拌均匀即可得汽车清洁剂。
实施例4
一种汽车清洁剂，以重量组分计包括：硅酮季铵盐6份；二乙醇胺6份；环甲基硅油8份；丙二醇30份；聚醚硅氧烷4份；十二烷基苯磺酸钠3份；碳酸氢钠34份；去离子水60份。所述硅酮季铵盐选用5851硅酮季铵盐。
以上所述汽车清洁剂的制备方法，按照以下步骤进行：
(1)按照重量份称取各组分；
(2)将十二烷基苯磺酸钠、碳酸氢钠、硅酮季铵盐与水混合，于58℃的条件下搅拌均匀；
(3)将二乙醇胺、环甲基硅油、丙二醇与聚醚硅氧烷混合，在58℃条件下搅拌均匀；
(4)将步骤(2)与步骤(3)得到的液体混合，搅拌均匀即可得汽车清洁剂。
实施例5
一种汽车清洁剂，以重量组分计包括：硅酮季铵盐4.5份；二乙醇胺4.5份；环甲基硅油7份；丙二醇27份；聚醚硅氧烷3份；十二烷基苯磺酸钠2.5份；碳酸氢钠32份；去离子水55份。所述硅酮季铵盐选用6922硅酮季铵盐与5851硅酮季铵盐1∶1混合。
以上所述汽车清洁剂的制备方法，按照以下步骤进行：
(1)按照重量份称取各组分；
(2)将十二烷基苯磺酸钠、碳酸氢钠、硅酮季铵盐与水混合，于60℃的条件下搅拌均匀；
(3)将二乙醇胺、环甲基硅油、丙二醇与聚醚硅氧烷混合，在60℃条件下搅拌均匀；
(4)将步骤(2)与步骤(3)得到的液体混合，搅拌均匀即可得汽车清洁剂。
本发明提供的汽车清洁剂对汽车进行清洗之后，下雨或其他因素打湿了汽车表面后就会形成分散的水滴，就像给表面上蜡一样；本清洁剂可以用机洗，也可以用手洗，使用时可以加入200倍量的水进行稀释，机洗时常温喷淋30～40秒，40℃喷淋15秒即可清洗干净，手洗时加水稀释后用布擦拭于车身，再用水冲洗干净即可。
以上所述仅是本发明的优选实施方式，本发明的保护范围并不仅局限于上述实施例，凡属于本发明思路下的技术方案均属于本发明的保护范围。应当指出，对于本技术领域的普通技术人员来说，在不脱离本发明原理前提下的若干改进和润饰，这些改进和润饰也应视为本发明的保护范围。
Claims (5)
1.一种汽车清洁剂，其特征在于，以重量组分计包括：
2.根据权利要求1所述的一种汽车清洁剂，其特征在于，以重量组分计包括：
3.根据权利要求2所述的一种汽车清洁剂，其特征在于，以重量组分计包括：
4.根据权利要求1至3中任一项所述的一种汽车清洁剂，其特征在于，所述硅酮季铵盐为6922硅酮季铵盐、5851硅酮季铵盐中的至少一种。
5.根据权利要求1至3中任一项所述的一种汽车清洁剂的制备方法，其特征在于，包括如下步骤：
(1)按照重量份称取各组分；
(2)将十二烷基苯磺酸钠、碳酸氢钠、硅酮季铵盐与水混合，于50～60℃的条件下搅拌均匀；
(3)将二乙醇胺、环甲基硅油、丙二醇与聚醚硅氧烷混合，在50～60℃条件下搅拌均匀；
(4)将步骤(2)与步骤(3)得到的液体混合，搅拌均匀即可得汽车清洁剂。
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| PCT/CN2020/127382 WO2022094996A1 (zh) | 2020-11-04 | 2020-11-08 | 一种汽车清洁剂及其制备方法 |
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