WO2000009765A1 - Schachtofen - Google Patents
Schachtofen Download PDFInfo
- Publication number
- WO2000009765A1 WO2000009765A1 PCT/EP1999/004875 EP9904875W WO0009765A1 WO 2000009765 A1 WO2000009765 A1 WO 2000009765A1 EP 9904875 W EP9904875 W EP 9904875W WO 0009765 A1 WO0009765 A1 WO 0009765A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- shaft furnace
- gas supply
- gas
- annular space
- cavity
- Prior art date
Links
- 239000000463 material Substances 0.000 claims abstract description 28
- 230000009467 reduction Effects 0.000 claims abstract description 17
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims abstract description 13
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229910052742 iron Inorganic materials 0.000 claims abstract description 5
- 238000004140 cleaning Methods 0.000 claims description 9
- 230000007704 transition Effects 0.000 claims description 3
- 238000011144 upstream manufacturing Methods 0.000 claims description 2
- 239000011819 refractory material Substances 0.000 description 6
- 238000009434 installation Methods 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- 239000000428 dust Substances 0.000 description 4
- 239000013590 bulk material Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 239000011449 brick Substances 0.000 description 2
- 230000005484 gravity Effects 0.000 description 2
- 230000035699 permeability Effects 0.000 description 2
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000007257 malfunction Effects 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 238000007669 thermal treatment Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B7/00—Blast furnaces
- C21B7/02—Internal forms
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27B—FURNACES, KILNS, OVENS, OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
- F27B1/00—Shaft or like vertical or substantially vertical furnaces
- F27B1/10—Details, accessories, or equipment peculiar to furnaces of these types
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B13/00—Making spongy iron or liquid steel, by direct processes
- C21B13/02—Making spongy iron or liquid steel, by direct processes in shaft furnaces
Definitions
- the invention relates to a shaft furnace, in particular a direct reduction shaft furnace, with a bed of lumpy material, in particular iron oxide and / or sponge containing lumpy material, which can be fed into the shaft furnace from above and with a plurality of gas inlet openings arranged in one plane for a reducing gas in the region of the lower one Third of the shaft furnace, the shaft furnace being surrounded on the outside by an annular space which is connected at the bottom to the gas inlet openings by gas supply channels.
- Shaft furnaces in particular direct reduction shaft furnaces of the type described above, are widely known from the prior art.
- a shaft furnace designed essentially as a cylindrical hollow body, contains, for example, a bed of lumpy material containing iron oxide and / or sponge iron, the material containing iron oxide being fed into the upper part of the shaft furnace.
- a reducing gas originating, for example, from a melter gasifier is blown into the shaft furnace and thus into the solid bed.
- the hot dust-laden reducing gas flows upwards through the solid bed and thereby reduces the iron oxide of the bed completely or partially to sponge iron.
- the wholly or partially reduced iron oxide is conveyed out of the shaft furnace by discharge devices arranged between the bottom region of the shaft furnace and the region of the gas inlet openings, the bed column located in the shaft furnace sinking downwards due to gravity.
- a shaft furnace Due to its design, a shaft furnace must ensure that the reaction can take place in an even and as complete a manner as possible, and that the bulk material can be lowered evenly.
- AT PS 387 037 discloses a shaft furnace for the thermal treatment of feedstocks with gaseous media. Gas inlet openings are provided for the supply of reducing gas, which are covered by an annular skirt opposite the feed materials introduced into the shaft furnace. Between the annular apron and an annular extension of the casing of the shaft furnace there is an annular one Cavity provided so that the introduced reducing gas over the circumference of the
- the shaft furnace can be distributed to the feed materials.
- annular apron produced in this way would also collapse when the shaft furnace was first loaded.
- the lateral forces from fillings, for example due to process-dependent volume increases, are considerable.
- the ring-shaped apron would break away immediately.
- DE PS 34 22 185 discloses an arrangement of a carburetor and a direct reduction shaft furnace.
- the direct reduction shaft furnace has conveyor screws arranged above it in a star shape, with which lumpy material is conveyed out of the shaft furnace.
- the inner ends of the screw conveyors are mounted in a conical installation in the middle of the shaft furnace. This conical installation is connected at the bottom to the melter gasifier, so that reducing gas can flow from the melter gasifier through the cone-shaped installation into the shaft furnace.
- Reduction gas is further fed to the shaft furnace via at least one gas inlet opening which opens into an annular space formed by an annular skirt and the shaft furnace shell.
- this ring apron as to that in AT PS 387 037, ie it would immediately break away to the side and / or be ground off due to the abrasive forces of the bed moving past it.
- the conical installation at the same height as the ring skirt represents a reduction in the free cross-section of the shaft furnace from the perspective of the fill material.
- the laterally effective forces from the bed in the area of the conical installation and the ring skirt are much greater than in other areas of the Shaft furnace.
- the fill in areas of reduced cross-section preferably forms caking, agglomerations and bridges. This will make it even
- Shaft furnaces are known from the prior art, for example US Pat. No. 3,816,101 or US Pat. No. 4,046,557, in which a reducing gas is first introduced into a cavity which surrounds the shaft furnace, from which a plurality of gas supply ducts form a frustoconical shell Extension of the shaft furnace jacket open.
- this annular cavity has a rectangular cross-sectional area, the gas supply channels opening into the shaft furnace leading away from the bottom and / or from the inner wall of this annular space.
- This gas supply system is unsuitable if the reducing gas is to be supplied evenly distributed over the circumference of the shaft furnace. Since the bulk material lies directly at each gas inlet opening, the number of gas entry points into the shaft furnace and thus into the bed is only as large as the number of gas inlet openings.
- the object of the invention is therefore to provide a shaft furnace, in particular a direct reduction shaft furnace, the gas supply system of which is designed in such a way that the disadvantages known from the prior art are avoided.
- this gas supply system should be able to be produced in a simple manner from conventional refractory material and have sufficient mechanical stability with respect to the have lateral forces from the bed. Dust-laden reducing gas should spread evenly around the circumference of the shaft furnace and therefore also in the
- the shaft contour has a diameter expansion in the area of the gas inlet openings and the wall of the shaft furnace is designed in such a way that an annular cavity is formed between the gas inlet openings arranged in the area of this diameter expansion and the bed.
- a number of means - for dividing the annular cavity into separate sections - are arranged in the area of the diameter expansion and fastened to or in the wall of the shaft furnace.
- annular cavity for example 2 to 16, but preferably 4 to 8 are arranged approximately equally spaced from one another in the region of the diameter widening, so that the annular cavity is divided into as many sections.
- These means for dividing the cavity are preferably formed by vertically arranged sheets and / or plates, which are in any case dimensioned in such a way that in each case such means penetrate the vertical cross section of the cavity at least completely.
- further means - for dividing the annular space into mutually separate sections are arranged in the annular space, each of the separate sections being able to be supplied with gas independently from the outside of the shaft furnace.
- the division of the annular cavity into separate sections together with the division of the annular space into separate sections proves to be advantageous, because it avoids or reduces the risk that the reducing gas - in the event of temporary disturbances in the gas flow through the fill - the path of the least
- the means for dividing the annular space and the means for dividing the cavity are arranged such that a section of the annular space is assigned to a number of sections of the cavity, so that gas passes through the respective section of the corresponding section (s) ) can be supplied.
- the number of means for dividing the annular space is the same as the number of means for dividing the cavity and a section is assigned to a section.
- each section of the annular space is tapered in the circumferential direction from the location of the gas supply to the respective section ends.
- a number of gas supply channels can each be operated from outside the shaft furnace Associated cleaning device, by means of which caking from the
- Gas supply channels or the annular space upstream of the gas supply channels in the gas flow direction can be cleaned.
- a cleaning device is expediently designed as a poking device, the poking device essentially penetrating the outer wall of the annular space in the extension of one gas supply channel.
- the diameter expansion forms a truncated cone-shaped lateral surface, the generatrix of which includes an angle with the horizontal which is smaller than the angle of repose of the material in the shaft furnace.
- the angle of repose is to be understood as the natural angle of repose which the generatrix of the lateral surface of a cone of pouring includes with the horizontal.
- the angle which the generatrix of the lateral surface forms with the horizontal is preferably 0 to 25 °, the diameter widening widening from top to bottom.
- the angle of repose of lumpy iron sponge, ore pellets or lumpy ore is about 35 to 40 °. The difference between these two angles is sufficiently large to create an annular space in which the reducing gas can be optimally distributed.
- Shell surface or the gas inlet openings arranged in the shell surface so large that the risk of dusty or lumpy material from the bed in one of the
- Gas supply channels can reach is minimized.
- the gas supply system also has excellent mechanical stability, since the dimensions of the gas supply ducts which penetrate the wall of the shaft furnace can be kept so small that the gas inlet openings or the gas supply system formed by the gas supply ducts and the refractory material surrounding the gas supply ducts is made up of the Can withstand bulk acting side forces.
- the gas supply system can also be produced in a simple manner from conventional refractory material, for example firebrick bricks, since each part of the gas supply system is supported by underlying parts. There are no devices, such as a ring apron, which would only be connected to the wall of the shaft furnace via an upper edge.
- the gas supply channels have an essentially rectangular cross section and are tapered from bottom to top, the inner edges of the gas supply channels being rounded. This ensures that gas supply channels in which a material jam occurs in spite of the material-free annular cavity formed in the interior of the shaft furnace, i.e. clean again with the downward movement of the goods in the shaft furnace.
- the transition between the annular space, which surrounds the shaft furnace on the outside in a ring, and the gas supply ducts are designed to slope downwards.
- Fig. 1 Overall view of the shaft furnace
- Fig. 2 diameter expansion of the shaft furnace with gas supply channel
- FIG. 1 shows the shaft furnace 1 according to the invention with a bed of lumpy material 2 which can be loaded onto the shaft furnace 1 from above (feed device not shown).
- a large number of gas inlet openings 3 are arranged in one plane in the region of the lower third of the shaft furnace 1.
- a reduction gas is blown into the bed 2 through these gas inlet openings 3.
- screw conveyors 4 are arranged, through which the piece goods are discharged from the shaft furnace 1.
- FIG. 2 shows one of the gas inlet openings 3 with the annular space 5 surrounding the shaft furnace 1 on the outside and one of the gas supply channels 6, which connect the gas inlet openings to the annular space 5.
- the diameter widening 7 of the shaft contour is designed as a horizontal recess in the casing of the shaft furnace 1, so that an annular cavity 8 is formed between the gas inlet openings 3 and the bed 2.
- the reducing gas supplied through the gas supply channels 6 and the gas inlet openings 3 can be optimally distributed in this cavity 8.
- a means 11 for dividing the cavity and a means 12 for dividing the annular space 5, here each formed as a vertically arranged sheet, are shown in dashed lines.
- a cleaning opening 13 passes through the outer jacket of the annular space 5 in such a way that the central axis of the cleaning opening 13 coincides with the central axis of the gas supply channel 6.
- the cleaning opening 13 is sealingly closable on the outside. If this is necessary, the gas supply channel 6 and part of the annular space 5 can be cleaned of deposits, for example by means of a rod 14 (straight or curved).
- FIG. 3 shows a section through AA of FIG. 1, the viewing direction being selected vertically from below in the direction of one of the gas supply channels 6.
- the inner edges 9 of the Gas supply channels 6 are rounded and the gas supply channels 6 are tapered upwards. This ensures that dusty material from the
- Reducing gas is not deposited in the gas supply channels 6, or that the
- Fig. 4 shows a section through B-B of Fig. 2, viewed from the inside of the shaft.
- the gas supply channels 6 widen from top to bottom and the transitions 10 from the annular space 5 to the gas supply channels 6 are designed to slope downwards. This is also intended to ensure that dust-like material from the reducing gas is not deposited in the annular space 5, but is introduced into the shaft furnace 1 together with the reducing gas.
- FIG. 5 shows a section through C-C of FIG. 2, the annular space 5 being shown with a decreasing cross section in the circumferential direction from the location of the gas feed 15 to the section ends 12.
- the sheets or plates are not limited to the shape and size shown in FIG. 2, but, depending on the material and process-related requirements, can also have, for example, rectangular or circular segment-like outlines and also have smaller dimensions, so that they are not as far as in Fig. 2 protrude into the bed.
- the annular space can be structurally connected to the shaft, but it is also possible for the annular space to be formed by an annular pipeline which concentrically surrounds the shaft - spaced apart from it. The connection between the ring pipeline and the gas supply channels then takes place via downward-widening stub lines.
- This brings further advantages in the design of the reduction shaft, in particular the refractory construction, as well as improved accessibility of the annular space for the purpose of cleaning.
- the reduction in cross section of the sections of the annular space is not only carried out - as shown in FIG. 5 - as a reduction in the horizontal diameter, but - alternatively or additionally - as a reduction in the vertical diameter of the annular space or - in the case of a ring pipeline - as a conical constriction.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Vertical, Hearth, Or Arc Furnaces (AREA)
- Manufacture Of Iron (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Crucibles And Fluidized-Bed Furnaces (AREA)
- Waste-Gas Treatment And Other Accessory Devices For Furnaces (AREA)
Abstract
Description
Claims
Priority Applications (11)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
SK178-2001A SK286273B6 (sk) | 1998-08-13 | 1999-07-12 | Systém šachtovej pece |
US09/762,785 US6511629B1 (en) | 1998-08-13 | 1999-07-12 | Shaft furnace |
JP2000565198A JP4467796B2 (ja) | 1998-08-13 | 1999-07-12 | シャフト炉 |
BR9912796-2A BR9912796A (pt) | 1998-08-13 | 1999-07-12 | Forno de chaminé de redução direta |
DE59908260T DE59908260D1 (de) | 1998-08-13 | 1999-07-12 | Schachtofen |
AU50359/99A AU756280B2 (en) | 1998-08-13 | 1999-07-12 | Shaft furnace |
CA002338069A CA2338069C (en) | 1998-08-13 | 1999-07-12 | Shaft furnace |
AT99934663T ATE257520T1 (de) | 1998-08-13 | 1999-07-12 | Schachtofen |
PL99346054A PL193740B1 (pl) | 1998-08-13 | 1999-07-12 | Piec szybowy |
EP99934663A EP1105542B1 (de) | 1998-08-13 | 1999-07-12 | Schachtofen |
UA2001031477A UA60371C2 (uk) | 1998-08-13 | 1999-12-07 | Шахтна піч |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ATA1392/98 | 1998-08-13 | ||
AT0139298A AT407192B (de) | 1998-08-13 | 1998-08-13 | Schachtofen |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2000009765A1 true WO2000009765A1 (de) | 2000-02-24 |
Family
ID=3512884
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP1999/004875 WO2000009765A1 (de) | 1998-08-13 | 1999-07-12 | Schachtofen |
Country Status (21)
Country | Link |
---|---|
US (1) | US6511629B1 (de) |
EP (1) | EP1105542B1 (de) |
JP (1) | JP4467796B2 (de) |
KR (1) | KR100641466B1 (de) |
CN (1) | CN1243835C (de) |
AT (1) | AT407192B (de) |
AU (1) | AU756280B2 (de) |
BR (1) | BR9912796A (de) |
CA (1) | CA2338069C (de) |
CZ (1) | CZ299007B6 (de) |
DE (1) | DE59908260D1 (de) |
ID (1) | ID27806A (de) |
MY (1) | MY123031A (de) |
PL (1) | PL193740B1 (de) |
RU (1) | RU2226552C2 (de) |
SK (1) | SK286273B6 (de) |
TR (1) | TR200100405T2 (de) |
TW (1) | TW490490B (de) |
UA (1) | UA60371C2 (de) |
WO (1) | WO2000009765A1 (de) |
ZA (1) | ZA200100679B (de) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8124005B2 (en) | 2007-06-28 | 2012-02-28 | Siemens Vai Metals Technologies Gmbh | Process and apparatus for producing sponge iron |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US12084730B2 (en) * | 2020-03-24 | 2024-09-10 | Midrex Technologies, Inc. | Methods and systems for increasing the carbon content of direct reduced iron in a reduction furnace |
CN115058553B (zh) * | 2022-06-20 | 2023-11-03 | 水木明拓氢能源科技有限公司 | 适用于氢气直接还原铁反应的竖炉反应器及其应用 |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3816101A (en) * | 1969-12-10 | 1974-06-11 | Midrex Corp | Method for reducing iron oxides in a gaseous reduction process |
US4046557A (en) * | 1975-09-08 | 1977-09-06 | Midrex Corporation | Method for producing metallic iron particles |
DE3422185A1 (de) * | 1984-06-12 | 1985-12-12 | Korf Engineering GmbH, 4000 Düsseldorf | Anordnung aus einem vergaser und direktreduktionsofen |
US4720299A (en) * | 1985-05-13 | 1988-01-19 | Voest-Alpine Aktiengesellschaft | Method for the direct reduction of particulate iron-oxide-containing material |
US4725309A (en) * | 1986-03-17 | 1988-02-16 | Hylsa, S.A. | Method and apparatus for producing hot direct reduced iron |
AT387037B (de) * | 1987-06-15 | 1988-11-25 | Voest Alpine Ag | Schachtofen zur thermischen behandlung von einsatzstoffen mit gasfoermigen medien |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5702246A (en) * | 1996-02-22 | 1997-12-30 | Xera Technologies Ltd. | Shaft furnace for direct reduction of oxides |
AT405332B (de) * | 1997-07-14 | 1999-07-26 | Voest Alpine Ind Anlagen | Schachtofen |
-
1998
- 1998-08-13 AT AT0139298A patent/AT407192B/de not_active IP Right Cessation
-
1999
- 1999-07-12 KR KR1020017001884A patent/KR100641466B1/ko not_active IP Right Cessation
- 1999-07-12 SK SK178-2001A patent/SK286273B6/sk not_active IP Right Cessation
- 1999-07-12 AU AU50359/99A patent/AU756280B2/en not_active Ceased
- 1999-07-12 BR BR9912796-2A patent/BR9912796A/pt not_active IP Right Cessation
- 1999-07-12 EP EP99934663A patent/EP1105542B1/de not_active Expired - Lifetime
- 1999-07-12 DE DE59908260T patent/DE59908260D1/de not_active Expired - Lifetime
- 1999-07-12 JP JP2000565198A patent/JP4467796B2/ja not_active Expired - Fee Related
- 1999-07-12 CN CNB998095990A patent/CN1243835C/zh not_active Expired - Lifetime
- 1999-07-12 ID IDW20010320A patent/ID27806A/id unknown
- 1999-07-12 CA CA002338069A patent/CA2338069C/en not_active Expired - Fee Related
- 1999-07-12 PL PL99346054A patent/PL193740B1/pl not_active IP Right Cessation
- 1999-07-12 RU RU2001107018/02A patent/RU2226552C2/ru not_active IP Right Cessation
- 1999-07-12 US US09/762,785 patent/US6511629B1/en not_active Expired - Fee Related
- 1999-07-12 TR TR2001/00405T patent/TR200100405T2/xx unknown
- 1999-07-12 WO PCT/EP1999/004875 patent/WO2000009765A1/de active IP Right Grant
- 1999-07-12 CZ CZ20010506A patent/CZ299007B6/cs not_active IP Right Cessation
- 1999-07-15 TW TW088112031A patent/TW490490B/zh not_active IP Right Cessation
- 1999-07-26 MY MYPI99003130A patent/MY123031A/en unknown
- 1999-12-07 UA UA2001031477A patent/UA60371C2/uk unknown
-
2001
- 2001-01-24 ZA ZA200100679A patent/ZA200100679B/xx unknown
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3816101A (en) * | 1969-12-10 | 1974-06-11 | Midrex Corp | Method for reducing iron oxides in a gaseous reduction process |
US4046557A (en) * | 1975-09-08 | 1977-09-06 | Midrex Corporation | Method for producing metallic iron particles |
DE3422185A1 (de) * | 1984-06-12 | 1985-12-12 | Korf Engineering GmbH, 4000 Düsseldorf | Anordnung aus einem vergaser und direktreduktionsofen |
US4720299A (en) * | 1985-05-13 | 1988-01-19 | Voest-Alpine Aktiengesellschaft | Method for the direct reduction of particulate iron-oxide-containing material |
US4725309A (en) * | 1986-03-17 | 1988-02-16 | Hylsa, S.A. | Method and apparatus for producing hot direct reduced iron |
AT387037B (de) * | 1987-06-15 | 1988-11-25 | Voest Alpine Ag | Schachtofen zur thermischen behandlung von einsatzstoffen mit gasfoermigen medien |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8124005B2 (en) | 2007-06-28 | 2012-02-28 | Siemens Vai Metals Technologies Gmbh | Process and apparatus for producing sponge iron |
US8361190B2 (en) | 2007-06-28 | 2013-01-29 | Siemens Vai Metals Technologies Gmbh | Process and apparatus for producing sponge iron |
Also Published As
Publication number | Publication date |
---|---|
DE59908260D1 (de) | 2004-02-12 |
PL346054A1 (en) | 2002-01-14 |
PL193740B1 (pl) | 2007-03-30 |
US6511629B1 (en) | 2003-01-28 |
CN1243835C (zh) | 2006-03-01 |
EP1105542A1 (de) | 2001-06-13 |
JP4467796B2 (ja) | 2010-05-26 |
CZ299007B6 (cs) | 2008-04-02 |
BR9912796A (pt) | 2001-05-02 |
JP2002522641A (ja) | 2002-07-23 |
EP1105542B1 (de) | 2004-01-07 |
AU5035999A (en) | 2000-03-06 |
AT407192B (de) | 2001-01-25 |
CA2338069C (en) | 2005-01-11 |
CZ2001506A3 (cs) | 2001-10-17 |
AU756280B2 (en) | 2003-01-09 |
MY123031A (en) | 2006-05-31 |
TR200100405T2 (tr) | 2001-07-23 |
KR20010072469A (ko) | 2001-07-31 |
SK286273B6 (sk) | 2008-06-06 |
RU2226552C2 (ru) | 2004-04-10 |
CA2338069A1 (en) | 2000-02-24 |
ID27806A (id) | 2001-04-26 |
CN1312861A (zh) | 2001-09-12 |
ZA200100679B (en) | 2002-03-27 |
UA60371C2 (uk) | 2003-10-15 |
KR100641466B1 (ko) | 2006-10-31 |
SK1782001A3 (en) | 2001-10-08 |
ATA139298A (de) | 2000-05-15 |
TW490490B (en) | 2002-06-11 |
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