WO1999043630A1 - Corps fritte en diamant a haute resistance et fortement resistant a l'usure et outil comprenant ledit diamant - Google Patents
Corps fritte en diamant a haute resistance et fortement resistant a l'usure et outil comprenant ledit diamant Download PDFInfo
- Publication number
- WO1999043630A1 WO1999043630A1 PCT/JP1998/005649 JP9805649W WO9943630A1 WO 1999043630 A1 WO1999043630 A1 WO 1999043630A1 JP 9805649 W JP9805649 W JP 9805649W WO 9943630 A1 WO9943630 A1 WO 9943630A1
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- WIPO (PCT)
- Prior art keywords
- diamond
- sintered body
- strength
- sintered
- less
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Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/515—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics
- C04B35/52—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbon, e.g. graphite
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C26/00—Alloys containing diamond or cubic or wurtzitic boron nitride, fullerenes or carbon nanotubes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12014—All metal or with adjacent metals having metal particles
- Y10T428/12028—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, etc.]
- Y10T428/12049—Nonmetal component
Definitions
- the present invention relates to a high-strength, high-abrasion-resistant diamond sintered body, and more particularly to a high-strength, high-abrasion-resistant diamond sintered body excellent in wear resistance, fracture resistance, impact resistance, and thermal conductivity.
- the present invention relates to a tool made of a sintered body. Background technique
- Diamond is the hardest material on earth.
- diamond sintered compacts are particularly used as cutting tool materials for non-ferrous metal materials such as aluminum-silicon alloys because they are unlikely to suffer from cleavage due to cleavage, which is a disadvantage of single crystal diamond.
- this diamond sintered body for example, Japanese Patent Publication No. 39-20483 and Japanese Patent Publication No. 52-121266 disclose that a diamond particle is made of a binder material of an iron-based metal such as cobalt. And sintering are disclosed.
- these diamond sintered bodies those with fine diamond particles with a particle size of less than 5 ⁇ m, and especially those with ultrafine particles with a particle size of 1 m or less, have excellent fracture resistance. are known.
- Japanese Patent Publication No. Sho 39-2 ⁇ 4833 discloses a diamond sintered body composed of a fine diamond powder and a powder of an iron-based metal or the like which dissolves and reprecipitates diamond.
- No. 2 224 discloses that sintered diamond particles having a particle diameter of 1 ⁇ m or less and carbides, nitrides, borides and solid solutions or mixtures of metals of Group 4a, 5a or 6a of the Periodic Table.
- a diamond sintered body made of an iron-based alloy is disclosed.
- the diamond sintered bodies those having a diamond particle diameter of 5 IX m or more and 100 im or less are generally known to have excellent wear resistance.
- a method of forming carbides on the surface of the diamond particles to facilitate sintering is known.
- Japanese Patent Application Laid-Open No. 63-135,655 discloses that a carbide is generated on the surface of a diamond particle to increase the bonding force of a sintering aid metal to each diamond particle, and the sintering is performed. A method is disclosed for making this easier.
- many sintering aids with tungsten carbide added have been commercialized.
- this invention was made in order to solve the above-mentioned problems, It is an object of the present invention to provide a diamond sintered body having more excellent wear resistance, chipping resistance, impact resistance and thermal conductivity than conventional diamond sintered bodies. Disclosure of the invention
- the present inventors have hereby studied to improve the fracture resistance, wear resistance and the like of the diamond sintered body, and as a result, the direct bonding between diamond particles has been further strengthened, so that the diamond sintered body has been improved.
- the defects referred to here are diamond particles with extremely large diameters in the diamond sintered body, pools of sintering aids such as solvent metals, and voids. And so on.
- the high-strength ⁇ high wear-resistant diamond sintered body of the present invention made on the basis of these findings contains sintered diamond particles, and the balance includes a sintering aid and unavoidable impurities.
- the content of sintered diamond particles is not less than 80% by volume and less than 99% by volume.
- the sintered diamond particles have a particle size in the range from 0.1 / m to 70 ⁇ . Adjacent sintered diamond particles are directly bonded to each other.
- the sintering aid contains at least one selected from the group consisting of iron, cobalt and nickel, and tungsten in the form of metal.
- tungsten in the present specification refers to a mixture of tungsten in a metal form and a tungsten compound such as tungsten carbide. The content of tungsten in the sintered body is from 0.01% by weight to 8% by weight. In such a diamond sintered body, metallic tungsten is added to the sintering aid.
- the addition of metallic tungsten to the sintering aid provides excellent fracture resistance, wear resistance, impact resistance, and thermal conductivity. A high-strength, high-abrasion-resistant diamond sintered body can be obtained. Further, the addition amount of the sintering aid is not larger than before and the content of diamond is not smaller than before, so that the wear resistance and the like do not decrease.
- the content ratio of the sintered diamond particles was 8 0 vol 0/0 to 9 9 volume less than 0/0 for the following reason.
- the content of the sintered diamond particles is less than 80% by volume, the strength such as the fracture resistance and the impact resistance and the wear resistance are reduced, and the content of the diamond particles is reduced to 99% by volume. % Is technically difficult.
- the reason for setting the range of the particle size of the sintered diamond particles to 0.1 m or more and 70 / im or less is as follows. When the diameter of the sintered diamond particles is less than 0.1 ⁇ , the surface area of the diamond particles increases, so that abnormal growth of the diamond sintered body is likely to occur, and the wear resistance of the diamond sintered body is reduced. It is because it falls. If the particle size exceeds 70 / m, the strength of the diamond sintered body decreases due to cleavage of diamond particles.
- the content of tungsten in the sintered body was adjusted to 0.1% by weight or more and 8% by weight or less. Is for the following reasons. If the content of tungsten is less than 0.01% by weight, the effect of adding metal tungsten to the sintering aid cannot be obtained. In addition, the content of tundane stainless steel is 8 weight 0 /. If it exceeds 300, the content of diamond in the sintered body will decrease, and the solid solution of diamond in the sintering aid will be too small to complete sintering.
- the diamond sintered body contains tungsten carbide.
- the X-ray diffraction intensity I of (100) or (101) plane of tungsten carbide in the diamond sintered body and the (111) plane of sintered diamond particles Ratio (I wc / I D ) is less than 0.02, and the diamond sintered body contains cobalt.
- the diamond sintered body contains nickel, and the X-ray diffraction intensity of the nickel (200) plane of Ni in the diamond sintered body I and the X-ray diffraction intensity of the sintered diamond particles due to the (1 1 1) plane I.
- the ratio (I Ni Z ID ) is preferably less than 0.4.
- the diamond sintered body contains iron, and the X-ray diffraction intensity I Fe of the (200) plane of iron in the diamond sintered body and the X-ray diffraction intensity ID of the (1 1 1) plane of the sintered diamond particles are expressed as (I Zl is preferably less than 0.2.
- X-ray diffraction intensity refers to an X-ray diffraction pattern using CuKa line (characteristic X-ray generated by K shell of Cu). Refers to the height of the peak.
- sintering aid further comprises, proportion of palladium in the sintering aid is 0.005 weight 0/0 over 40 weight 0 /.
- proportion of palladium in the sintering aid is 0.005 weight 0/0 over 40 weight 0 /.
- the following is preferred. In this case, since palladium is added to the sintering aid, the melting point of the sintering aid is lowered, so that a diamond sintered body can be manufactured at a low temperature.
- Set the palladium ratio to 0. 0 0 5 weight 0 / greater than or equal to 0 4 0 weight 0 /. The following is based on the following reasons. If the proportion of palladium is less than 0.005% by weight, it is not sufficient to lower the melting point of the sintering aid. If the proportion of palladium exceeds 40% by weight, This is because the sinterability deteriorates because the melting point rises conversely.
- the sintering aid further contains at least one selected from the group consisting of tin, phosphorus and boron, and the total ratio of tin, phosphorus and boron in the sintering aid is 0.01% by weight. It is preferably at least 30% by weight. In this case, since at least one of tin, phosphorus and boron is contained in the sintering aid, these elements lower the melting point of the sintering aid. As a result, the diamond powder can be sintered at a relatively low temperature.
- the ratio of these elements is set to 0.01% by weight or more and 30% by weight or less for the following reason.
- the present inventors focused on oxygen and oxide adsorbed on the surface of diamond powder, which is a raw material for producing a diamond sintered body, and by removing these, the defects existing in the sintered body were reduced. And improved the strength of the diamond sintered body. Therefore, the proportion of oxygen in the diamond sintered body is preferably at least 0.05% by weight and less than 0.08% by weight. The ratio of oxygen is set to 0.05% by weight or more and less than 0.08% by weight. It is impossible with current technology to make the oxygen content less than 0.05% by weight. If the content is 8% by weight or more, the strength of the diamond sintered body becomes similar to that of the conventional one.
- the transverse rupture strength measured under the conditions is preferably 50 kgf Zmm 2 or more and 30 O kgf Zmm 2 or less.
- the transverse rupture strength measured under the conditions of 4 mm span using a test piece made of the diamond sintered body thus obtained and dissolved in hydrofluoric acid was 50 kgf. / mm 2 or more.
- the tool made of a high-strength, high-wear-resistant diamond sintered body contains sintered diamond particles, and the balance includes a sintering aid and unavoidable impurities.
- the content of sintered diamond particles is not less than 80% by volume and less than 99% by volume.
- the sintered diamond particles have a particle size in the range of 0.1 ⁇ to 70 / xm. Adjacent sintered diamond particles are directly bonded to each other.
- the sintering aid contains at least one selected from the group consisting of iron, cobalt and nickel, and tungsten in a metallic form.
- the content of tungsten in the sintered body is from 0.01% by weight to 8% by weight.
- the sintering aid is uniformly distributed and that unnecessary components are not included.
- a CVD (Chemical Vapor Deposition) method a PVD (Physical Vapor Deposition) method or a solution precipitation method can be used.
- the uniformity of the sintering aid coated on the surface of the diamond particles is extremely important for improving the sinterability of the diamond powder and the strength of the sintered body. Considering that the method must be excellent in performance, it is most preferable to use the electroless plating method disclosed by the present inventors in Japanese Patent Application Laid-Open No. 8-225875. BEST MODE FOR CARRYING OUT THE INVENTION
- Diamond powders having different particle diameters shown in Table 1 and sintering aids (1A to 1H) having different components were prepared.
- electroless plating for 1 C and 1 G, mix ultrafine powder, and for 1 D and 1 H, add sintering aid to diamond powder by carbide ball mill.
- For the mixing of ultrafine powder ultrafine cobalt powder with a particle size of 0.5 ⁇ m or less and diamond powder are specified.
- the composition was charged into a Teflon ball mill container so as to have the following composition, and then a Teflon ball was charged into the container to perform a ball mill for 3 hours to prepare a powder sample.
- the term “sintering aid” refers to the ratio of each component in the sintering aid. For example, “0.90.85 Co” indicates that 90.85% by weight of the sintering aid is cobalt.
- a plurality of rectangular parallelepiped test pieces of 6 mm in length, 3 mm in width, and 0.4 mm in thickness were cut from each diamond sintered body.
- the strength (flexural strength) of the sintered body was measured by a three-point bending test under the condition that the span distance was 4 mm.
- each sample was placed in a hydrofluoric / nitric acid solution in which 40 ml of nitric acid having a molar concentration of 30% and 1 Om 1 of hydrofluoric acid having a molar concentration of 45% were mixed. Then place the sample in a closed container at a temperature of 1-30. The solution was kept at C for 3 hours for dissolution treatment.
- the strength (flexural strength) of the sintered body was measured by a three-point bending test under the condition that the span distance was 4 mm for each of the sample subjected to the melting treatment and the sample not subjected to the melting treatment.
- Plasma emission spectroscopy was used to measure the total content of tungsten (W) and tungsten carbide in metal form with respect to the weight of the diamond sintered body. (Measurement of diamond content)
- the diamond content of the sintered body was determined by observing the diamond sintered body surface with a microscope and measuring the diamond particle area.
- a cutting tool was prepared from the sintered body, and the cutting performance was evaluated under the following conditions.
- 1A and 1E of the present invention show higher strength and less flank wear width compared to 1D and 1H of the conventional products, and also have higher fracture resistance and higher cutting resistance. It turns out that it is excellent as a tool. As a result of microscopic observation, adjacent sintered diamond particles were directly bonded to each other.
- Example 2 A test was conducted to compare the characteristics of the sintered body according to the diameter of the diamond particles.
- diamond powders of various particle sizes were prepared. The ratio of this diamond powder is 93 volumes. / 0 , a sintering aid was added by an electroless plating method so that the ratio of the sintering aid having a predetermined composition was 7% by volume, followed by heat treatment, and a diamond sintered body was produced in the same manner as in Example 1.
- Example 3 The strength and flank wear width of this diamond sintered body were measured in the same manner as in Example 1. The results are shown in Table 3.
- diamond powder particles with various diameters were prepared.
- a sintering agent having a different proportion of tungsten was added to the powder particles by an electroless plating method, followed by heat treatment, followed by sintering in the same manner as in Example 1 to obtain a diamond sintered body.
- the strength and flank wear width of the obtained diamond sintered body were measured in the same manner as in Example 1. Table 4 shows the obtained results. Table 4
- 3 ⁇ and 3D are diamond sintered compacts manufactured from the same powder as samples 1A and 1E prepared in Example 1. It is. Sample Nos. 3B3C3E and 3F were obtained by changing the addition amount of metal tungsten in the sintering aid.
- diamond powder particles having different particle diameters were prepared.
- Tests were performed on the properties of the sintered body with additional sintering aids.
- diamond powder particles having a particle diameter of 0.1 to 30 / m were prepared. The diamond powder was degreased and pickled in order to add a sintering aid to the diamond powder particles by an electroless plating method.
- the diamond powder particles were immersed in a solution containing palladium chloride, stannous chloride and hydrochloric acid at room temperature for 2 minutes. Subsequently, these diamond powder particles were immersed in a sulfuric acid aqueous solution at room temperature for 2 minutes. Then, after washing the powder with water, the diamond powder covered with the sintering aid is immersed in a 90 ° C.
- “Additional sintering aid composition” in Table 6 indicates the composition of the metal plate.
- “the coating amount of the sintering aid” indicates the volume% of the sintering aid in the diamond sintered body.
- the tantalum container was kept at a temperature of 150 ° C. for 10 minutes at a pressure of 60 kbar by a girdle type high pressure device. As a result, a diamond sintered body was obtained.
- Each of the sintered bodies was processed into a rod-shaped test piece having a length of 6 mm, a width of 3 mm, and a thickness of 0.3 mm, and a three-point bending test with a span distance of 4 mm was performed to evaluate the strength.
- Table 7 shows the results.
- the total content of tin, phosphorus, and boron in the sintering aid is not less than 0.01% by weight.
- the content is preferably in a range from / o to 30% by weight.
- Example 1 The characteristics of the diamond sintered body when the heat treatment temperature of the diamond powder was changed were tested. 1A and 1E produced in Example 1 were subjected to heat treatment under various conditions. Next, the heat-treated powder was sintered under the same conditions as in Example 1 to obtain a diamond sintered body. The strength of the diamond sintered body was measured in the same manner as in Example 1, and the oxygen content in the sintered body was measured by plasma emission spectroscopy. Table 8 shows the results.
- the powder sample 1A had graphite remaining in the sintered body because the surface of the diamond powder was remarkably graphitized when heat-treated at a temperature of 140 ° C or higher.
- this method was not suitable for reducing sintering and cutting performance.
- a sample having a diamond particle diameter of 0.1 to 15 ⁇ m was prepared, and the same sintering aid as that added to the powder sample 1 A of Example 1 was added.
- Heat treated in vacuum of C Next, the heat-treated powder is filled in a container made of a sintered body having an outer diameter of 2 O mm, an inner diameter of 12 mm, and a height of 18 mm made of an alloy containing 10% by weight of tungsten force. Ultra high pressure. Sintered under high temperature conditions. From the obtained sintered body, a wire diameter of 3 mm A drawing die was prepared. Using this die, a wire drawing test of copper-coated steel wire was performed using a water-soluble lubricating oil at a wire drawing speed of 50 OmZmin. As a result, it was possible to draw 80 tons of steel wire and the wire surface was good.
- Example 2 In the same manner as in Example 1, a sintering aid containing various ratios of cobalt, tungsten, iron, and palladium was applied to diamond particles having a particle size of 0.1 to 60 m by an electroless melting method. After the heat treatment, it was sintered. X-ray diffraction was performed on each of the obtained sintered bodies in the same manner as in Example 1 to obtain a diffraction intensity I Ni of the nickel (200) plane, a diffraction intensity I Fe of the iron (200) plane, and Fe particles and diamond particles. Diffraction intensity by (1 1 1) plane of I. The measures, these ratios I Ni l D, was determined I Fe Zl D. The strength and flank wear width of each sintered body were examined in the same manner as in Example 1. Was.
- the high-strength 'high-wear-resistant diamond sintered body according to the present invention is used for cutting tools such as cutting tools, milling tools and end mills, wear-resistant tools such as drawing dies, and golf clubs. It can be applied to impact-resistant parts such as a pad ⁇ impact type powder grinding jig.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Ceramic Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Manufacturing & Machinery (AREA)
- Structural Engineering (AREA)
- Cutting Tools, Boring Holders, And Turrets (AREA)
- Polishing Bodies And Polishing Tools (AREA)
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Description
Claims
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CA002281546A CA2281546C (en) | 1998-02-26 | 1998-12-14 | Diamond sintered body having high strength and high wear resistance, andtool including the same |
US09/367,248 US6261329B1 (en) | 1998-02-26 | 1998-12-14 | Diamond sintered body having high strength and high wear resistance, and tool including the same |
EP98959203A EP0982276A4 (en) | 1998-02-26 | 1998-12-14 | HIGH-STRENGTH HIGH-WEAR-RESISTANT SINTER BODY ON A DIAMOND BASE AND TOOL CONTAINING THIS |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP10045468A JPH11240762A (ja) | 1998-02-26 | 1998-02-26 | 高強度・高耐摩耗性ダイヤモンド焼結体およびそれからなる工具 |
JP10/45468 | 1998-02-26 |
Publications (1)
Publication Number | Publication Date |
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WO1999043630A1 true WO1999043630A1 (fr) | 1999-09-02 |
Family
ID=12720225
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP1998/005649 WO1999043630A1 (fr) | 1998-02-26 | 1998-12-14 | Corps fritte en diamant a haute resistance et fortement resistant a l'usure et outil comprenant ledit diamant |
Country Status (7)
Country | Link |
---|---|
US (1) | US6261329B1 (ja) |
EP (1) | EP0982276A4 (ja) |
JP (1) | JPH11240762A (ja) |
KR (1) | KR100312573B1 (ja) |
CA (1) | CA2281546C (ja) |
WO (1) | WO1999043630A1 (ja) |
ZA (1) | ZA99968B (ja) |
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Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6414271B2 (en) | 2000-05-25 | 2002-07-02 | Kyocera Corporation | Contact heating device |
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JP7359522B2 (ja) * | 2020-11-30 | 2023-10-11 | 住友電工ハードメタル株式会社 | 焼結体及び切削工具 |
WO2023228324A1 (ja) * | 2022-05-25 | 2023-11-30 | 住友電工ハードメタル株式会社 | 焼結体及び切削工具 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5756381A (en) * | 1980-09-17 | 1982-04-03 | Kuratomi Tatsuro | Manufacture of diamond solidified body |
JPS5782176A (en) * | 1980-11-04 | 1982-05-22 | Kuratomi Tatsuro | Diamond solidified body and manufacture |
JPS63134565A (ja) * | 1986-11-27 | 1988-06-07 | 倉富 龍郎 | ダイアモンド焼結体およびその製造法 |
JPH05105910A (ja) * | 1991-10-17 | 1993-04-27 | Tatsuro Kuratomi | ダイヤモンド結合組織積層焼結体およびその製造法 |
Family Cites Families (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3745623A (en) | 1971-12-27 | 1973-07-17 | Gen Electric | Diamond tools for machining |
JPS5212126A (en) | 1975-07-16 | 1977-01-29 | Hitachi Chem Co Ltd | Process for preparation of methacrylic acid |
JPS5792578A (en) * | 1980-11-28 | 1982-06-09 | Toshiba Tungaloy Co Ltd | Cutting high hardness sintered body |
JPS5832224A (ja) | 1981-08-18 | 1983-02-25 | Seiko Epson Corp | ビデオテ−プレコ−ダ−ヘツド・シリンダ−ユニツト |
US4610699A (en) * | 1984-01-18 | 1986-09-09 | Sumitomo Electric Industries, Ltd. | Hard diamond sintered body and the method for producing the same |
JPS6158432A (ja) | 1984-08-29 | 1986-03-25 | 神鋼電機株式会社 | 交流発電機と静止形インバ−タ電源の切替方法 |
US4636253A (en) * | 1984-09-08 | 1987-01-13 | Sumitomo Electric Industries, Ltd. | Diamond sintered body for tools and method of manufacturing same |
JPH04371546A (ja) * | 1991-06-17 | 1992-12-24 | Tatsuro Kuratomi | ダイヤモンド系焼結体およびその製造法 |
JPH06297206A (ja) * | 1993-04-09 | 1994-10-25 | Sumitomo Electric Ind Ltd | 硬質焼結体工具およびその製造方法 |
SE516786C2 (sv) * | 1994-11-18 | 2002-03-05 | Sandvik Ab | PCD- eller PcBN-verktyg för träindustrin |
CA2163953C (en) * | 1994-11-30 | 1999-05-11 | Yasuyuki Kanada | Diamond sintered body having high strength and high wear-resistance and manufacturing method thereof |
JP3327080B2 (ja) | 1994-11-30 | 2002-09-24 | 住友電気工業株式会社 | 高強度で高耐摩耗性のダイヤモンド焼結体とその製造方法 |
JP4297987B2 (ja) * | 1996-05-29 | 2009-07-15 | 住友電工ハードメタル株式会社 | 高強度微粒ダイヤモンド焼結体およびそれを用いた工具 |
-
1998
- 1998-02-26 JP JP10045468A patent/JPH11240762A/ja active Pending
- 1998-12-14 EP EP98959203A patent/EP0982276A4/en not_active Withdrawn
- 1998-12-14 WO PCT/JP1998/005649 patent/WO1999043630A1/ja active IP Right Grant
- 1998-12-14 US US09/367,248 patent/US6261329B1/en not_active Expired - Lifetime
- 1998-12-14 CA CA002281546A patent/CA2281546C/en not_active Expired - Lifetime
-
1999
- 1999-02-08 ZA ZA9900968A patent/ZA99968B/xx unknown
- 1999-10-25 KR KR1019997009856A patent/KR100312573B1/ko active IP Right Grant
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5756381A (en) * | 1980-09-17 | 1982-04-03 | Kuratomi Tatsuro | Manufacture of diamond solidified body |
JPS5782176A (en) * | 1980-11-04 | 1982-05-22 | Kuratomi Tatsuro | Diamond solidified body and manufacture |
JPS63134565A (ja) * | 1986-11-27 | 1988-06-07 | 倉富 龍郎 | ダイアモンド焼結体およびその製造法 |
JPH05105910A (ja) * | 1991-10-17 | 1993-04-27 | Tatsuro Kuratomi | ダイヤモンド結合組織積層焼結体およびその製造法 |
Also Published As
Publication number | Publication date |
---|---|
US6261329B1 (en) | 2001-07-17 |
EP0982276A4 (en) | 2004-10-20 |
JPH11240762A (ja) | 1999-09-07 |
KR100312573B1 (ko) | 2001-11-14 |
CA2281546A1 (en) | 1999-09-02 |
KR20010020258A (ko) | 2001-03-15 |
ZA99968B (en) | 1999-08-10 |
EP0982276A1 (en) | 2000-03-01 |
CA2281546C (en) | 2002-04-09 |
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