WO1999043506A1 - Pneumatique electriquement conducteur et appareillages d'extrusion de profiles rendus conducteurs - Google Patents

Pneumatique electriquement conducteur et appareillages d'extrusion de profiles rendus conducteurs Download PDF

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Publication number
WO1999043506A1
WO1999043506A1 PCT/EP1999/001044 EP9901044W WO9943506A1 WO 1999043506 A1 WO1999043506 A1 WO 1999043506A1 EP 9901044 W EP9901044 W EP 9901044W WO 9943506 A1 WO9943506 A1 WO 9943506A1
Authority
WO
WIPO (PCT)
Prior art keywords
nozzle
extruder
insert
conductive
tread
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP1999/001044
Other languages
English (en)
French (fr)
Inventor
Didier Calvar
Serge Nicolas
Daniel Bardy
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Compagnie Generale des Etablissements Michelin SCA
Original Assignee
Compagnie Generale des Etablissements Michelin SCA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Compagnie Generale des Etablissements Michelin SCA filed Critical Compagnie Generale des Etablissements Michelin SCA
Priority to HU0101426A priority Critical patent/HUP0101426A3/hu
Priority to JP2000533284A priority patent/JP4486749B2/ja
Priority to EP99913169A priority patent/EP1060089B1/fr
Priority to CA002321910A priority patent/CA2321910A1/fr
Priority to DE69940193T priority patent/DE69940193D1/de
Priority to PL342613A priority patent/PL199364B1/pl
Priority to BR9908260-8A priority patent/BR9908260A/pt
Publication of WO1999043506A1 publication Critical patent/WO1999043506A1/fr
Priority to US09/645,097 priority patent/US6951233B1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60CVEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
    • B60C19/00Tyre parts or constructions not otherwise provided for
    • B60C19/08Electric-charge-dissipating arrangements
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/07Flat, e.g. panels
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/12Articles with an irregular circumference when viewed in cross-section, e.g. window profiles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/16Articles comprising two or more components, e.g. co-extruded layers
    • B29C48/18Articles comprising two or more components, e.g. co-extruded layers the components being layers
    • B29C48/19Articles comprising two or more components, e.g. co-extruded layers the components being layers the layers being joined at their edges
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/16Articles comprising two or more components, e.g. co-extruded layers
    • B29C48/18Articles comprising two or more components, e.g. co-extruded layers the components being layers
    • B29C48/20Articles comprising two or more components, e.g. co-extruded layers the components being layers one of the layers being a strip, e.g. a partially embedded strip
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/16Articles comprising two or more components, e.g. co-extruded layers
    • B29C48/18Articles comprising two or more components, e.g. co-extruded layers the components being layers
    • B29C48/21Articles comprising two or more components, e.g. co-extruded layers the components being layers the layers being joined at their surfaces
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/30Extrusion nozzles or dies
    • B29C48/35Extrusion nozzles or dies with rollers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/36Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
    • B29C48/49Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using two or more extruders to feed one die or nozzle
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60CVEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
    • B60C11/00Tyre tread bands; Tread patterns; Anti-skid inserts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60CVEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
    • B60C11/00Tyre tread bands; Tread patterns; Anti-skid inserts
    • B60C11/14Anti-skid inserts, e.g. vulcanised into the tread band
    • B60C11/18Anti-skid inserts, e.g. vulcanised into the tread band of strip form, e.g. metallic combs, rubber strips of different wear resistance
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29DPRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
    • B29D30/00Producing pneumatic or solid tyres or parts thereof
    • B29D30/06Pneumatic tyres or parts thereof (e.g. produced by casting, moulding, compression moulding, injection moulding, centrifugal casting)
    • B29D30/52Unvulcanised treads, e.g. on used tyres; Retreading
    • B29D2030/526Unvulcanised treads, e.g. on used tyres; Retreading the tread comprising means for discharging the electrostatic charge, e.g. conductive elements or portions having conductivity higher than the tread rubber

Definitions

  • the subject of the present invention is a tire having several mixtures comprising, as the majority filler, a non-conductive filler such as silica, or mixtures lightly loaded in black, at least one of these mixtures being the tread. It relates more particularly to a tire which can have significant internal temperature rises during driving, such as a tire intended, for example, to carry heavy loads. It also relates to a method intended for obtaining such a tire, and to apparatus for the implementation of such a method.
  • Static electricity thus accumulated in a tire is likely to cause, when certain particular conditions are met, an unpleasant electric shock to the occupant of a vehicle, when it is brought into contact with the body of the vehicle. It is also likely to hasten the aging of the tire due to the ozone generated by the electric discharge. It can also be the cause, depending on the nature of the ground and of the vehicle, of a malfunction of the on-board radio in the vehicle due to the interference it generates.
  • Application EP 0 658 452 A1 describes the adaptation of principles known for a long time to a so-called modern tire, an adaptation which makes it possible to solve the main problems relating to the solutions proposed in various old documents and in particular the harmful heterogeneities introduced into the architectures of pneumatic.
  • the proposed solution consists in inserting a strip of conductive rubber mixture or insert, preferably extending over the entire circumference of the tire and connecting the surface of the tread either to - 3 - one of the crown plies, either to the carcass reinforcement, or to any other part of the tire sufficiently electrically conductive, the necessary electrical conductivity being imparted by the presence of a suitable carbon black.
  • a first solution to obtain a conductive tread, consists in coextruding the inner and outer parts of the tread, and in providing the assembly thus constituted with a circumferential conductive insert. Said solution is not satisfactory for several reasons; we can cite two: in the type of - 4 - tire considered, the total thickness of the tread is too large; moreover, it may be advantageous for the conductive inserts, respectively of the inner and outer layers of the tread, not to be produced with the same quality of rubber mixture.
  • Another solution consists, as described in French application FR 97/02276 of the applicant, in ensuring the electrical connection between two conductive layers or rendered conductive, separated by a non-conductive layer, by at least one strip of thin rubbery mixture , width and length, placed between the two faces of the solder of the non-conductive layer, and in contact with the means making the two layers connected by the connection conductive.
  • said method requires an additional product to be laid, and entails an additional manufacturing cost.
  • a third solution consists in providing each non-conductive part with a circumferential insert with a circular rectilinear trace or circular stripe after extrusion of said part by usual means of extrusion, and then bringing the two products together before laying on the frame. of summit. Since the welts are generally very fine so as not to disturb the physical properties of the compositions constituting the two parts of the tread, the thickness of these inserts being, on the tire seen in cross section, of the order from 0.01 to 2.0 mm, such a solution requires that the trace of the stripe on the outside of the tread on the contact wall between the two parts is perfectly aligned with or centered on the trace on said wall of the stripe on the inside of the same tread. - 5 -
  • one of the objects of the invention is to dissipate, in a tire having several non-electrically conductive mixtures, the electrostatic charges induced by the rolling of the tire, without significantly affecting the level of the properties of the tire, the another aim is to be able to obtain a tire as simply as possible and at a lower cost, whether it be material cost and / or manufacturing cost.
  • the invention proposes, according to a first aspect, a tire comprising at least two layers of rubber mixtures which do not conduct electricity, the said two layers having a common contact wall, characterized in that each layer contains a circumferential mixture insert conductor, with a rectilinear circular layout, the insert of at least a first layer having, seen in cross section, a surface S with two bases, a first base, on the contact wall - 6 - between the two layers, having a width at least equal to 10 times the width of the first base on said contact surface of the surface S 'of the insert of the second layer, said first bases being on the wall common contact opposite one another, and the mean axes of the two opposite bases being parallel to and distant from the equatorial plane of the tire by quantities, the difference of which is at most equal to the half-width of the first base of the first layer, so that there are circumferentially between the two traces on the common contact wall several contact points ensuring the electrical connection between two conductive elements.
  • the two non-conductive layers will be the inner and outer parts of the tread, and the electrical connection must be ensured between the ground and the crown reinforcement, composed of calendered metallic cables in a mixture of rubber made conductive by the presence in its composition of carbon black.
  • the non-conductive layers may also be, on the one hand the axially external part of the profile of triangular transverse shape separating the carcass reinforcement from an edge of crown reinforcement, and on the other hand the internal and external parts of the strip. of rolling, the connection must be ensured between the three layers.
  • one of the parts of said tread, and more particularly the outer part of tread will be provided with an insert having a transverse surface at two bases of different widths , the first base having a width much greater than the width of the second base lying on the tread surface, while the other - 7 - part, preferably the inner part of the tread, will be provided with a weld whose transverse surface is rectangular, the two bases of said surface being equal.
  • the transverse surface of the insert comprising two bases of different widths, can have several shapes.
  • the transverse surface of the insert of the outer tread layer will have an inverted T shape, with a rectangular part of small width, and a triangular or rectangular part with a base of large width, base on the common wall of the two layers.
  • a layer whether a part of the tread or an intermediate profile between carcass reinforcement and crown reinforcement, can for example be obtained in the unvulcanized state by means of an extrusion in an extruder than the in known manner, nose-to-roller extruder, the profile or section of the extruded product being defined on the one hand by the surface of the roller on which the rubber mixture is extruded and on the other hand by the fixed wall of a blade extrusion which cooperates with said surface to define an extrusion orifice.
  • the method intended to obtain a set of two conductive layers, for example the inner and outer parts of a tire tread, consists of:
  • each layer for example each part of the tread, a strip of conductive mixture in the unvulcanized state, circumferential and with a transverse surface with two bases, by means of the nozzle of a micro -extruder, said nozzle being fixed and applied against a wall of said extrusion device, for example the wall of the roller of the main extrusion device, and
  • Coextrusion can advantageously be carried out at three different places: either in the flow channel between the upper arch and the lower arch delimiting said channel, or between the upper arch and the wall of the rotary roller, or between the upper wall of the extrusion orifice and the wall of the roller.
  • the devices, in accordance with the invention and intended for implementing the process for obtaining a rubber profile with insert or stripe of cross section with two bases, are of two kinds.
  • the apparatus of the first kind comprises a main extruder with a roller nose for extruding the rubber layer or profile, for example, the upper part of an unvulcanized tread, and a micro-extruder, fixedly mounted on a support. and mainly comprising an extrusion head, provided at its end with a nozzle, intended to extrude, according to the desired profile and trace, the circumferential insert in the profile of unvulcanized mixture leaving the main extruder, the head d extrusion and the nozzle being placed in the flow channel or accumulation chamber of the rubber to be extruded either between the upper arch and the lower arch of the main extruder, or between the arch - 9 - upper and the rotary roller, the nozzle having a head whose end is pressed against the lower arch or against the roller of the main extruder.
  • the invention also relates to the nozzle or extrusion orifice of the micro-extruder used.
  • Said nozzle is characterized in that it comprises an annular support and attachment piece to the nose of the micro-extruder with the attachment elements necessary for fixing, a hollow and cylindrical supply chamber, straight or bent , having on its cylindrical surface an extrusion orifice, through which the conductive rubber material is extruded and occupying substantially the entire height of said nozzle and whose cross section has a shape adapted to the desired section of the conductive insert: two bases of different widths if it is the extrusion of an insert to two different bases, or section to two bases of equal width if it is the extrusion of an insert of rectangular section.
  • the apparatus of the second kind likewise comprises a main extruder, with roller nose or flat nose, for extruding the layer or profile of rubber, for example, the inner part of an unvulcanized tread, and a micro- extruder mainly comprising an extrusion head, provided at its end with a nozzle, intended to extrude, according to the desired profile and trace, the circumferential insert in the profile of unvulcanized mixture leaving the main extruder.
  • the invention relates more particularly to the fixing of the micro-extruder and the nozzle or extrusion orifice of the micro-extruder used.
  • micro-extruder or at least its extrusion head in part, is inserted and fixed in the upper part of the extrusion blade, said extrusion head being bent at its end to allow the application of the nozzle against the roller or against the lower part of the extrusion blade, depending on the type of main extruder used.
  • Said nozzle is characterized in that it comprises an annular support and attachment piece to the nose of the micro-extruder with the attachment elements necessary for fixing, a hollow and cylindrical supply chamber, provided on the cylindrical surface of an extrusion orifice through which the conductive rubbery material is extruded and of cross section chosen according to the desired transverse shape of the conductive insert.
  • the extrusion nozzle is advantageously provided with a movable die in translation along an axis substantially perpendicular to the axis of the roller, and allowing under the action of the pressure of the conductive mixture which passes through it, ensure the manufacture of products of different thicknesses, while guaranteeing, during their manufacture, a minimum gap between the end of the nozzle and the roller of the main extruder.
  • FIG. 1A schematically represents, seen in perspective, the crown part of a tire with a non-conductive tread
  • FIG. 1B is a plan view of part of the tread of said tire
  • FIG. 2 represents the main components of a device used, in accordance with the invention.
  • FIG. 3 is an enlarged view of the device according to FIG. 3,
  • FIGS. 4 and 5. represent the components of other extrusion devices which can be used for the formation of a conductive insert
  • FIG. 6 is an enlarged view of an extrusion nozzle which can be used on the apparatus of FIG. 5. - 11 -
  • the tire of dimension 315 / 80.R.22.5, designed to have a low rolling resistance, comprises a carcass reinforcement (1), composed of a metallic ply formed of inextensible metallic cables coated in a mixture of rubberized calendering, made conductive of electrostatic charges by means of a carbon black commonly used as reinforcing charge in mixtures.
  • Said carcass reinforcement (1) is, as known, anchored to at least one rod in each bead to form a reversal (not shown).
  • Inside said carcass reinforcement (1) are the usual reinforcing layers, and the so-called inner layers made of mixtures generally impermeable to known inflation gases.
  • this internal layer is (are) generally covered by the axially internal part of the protective layer of the bead (not shown), wear layer whose axially external part comes to bear on the mounting rim, said layer being generally very loaded with carbon black, therefore highly conductive.
  • the carcass reinforcement (1) is surmounted at its top by a crown reinforcement, composed, in the example described, of two so-called triangulation half-plies (20) formed of inextensible metallic cables oriented relative to the direction circumferential at an angle which may be between 30 ° and 90 °; then radially above, two plies (21) and (22) called working composed of inextensible metallic cables crossed from one ply to the next by making angles with the circumferential direction which may be equal or unequal and of absolute value included between 10 ° and 30 °; then generally, lastly at least one so-called protective ply (23) formed of elastic cables making with the circumferential direction an angle equal in direction and value to the angle of the ply of - 12 - Radially outermost work. All the cables of this crown reinforcement (2) are coated in one or more mixture (s) of rubberized calendering, conductor (s) of electrostatic charges thanks to a carbon black commonly used as reinforcing charge in mixtures.
  • the crown reinforcement (2) not having the same transverse profile as that of the underlying carcass reinforcement (1), is separated from said carcass reinforcement (1) by a thin rubber assembly on the central axial part (61), where the two reinforcements are substantially parallel and, on either side of said central part (61), of increasing thickness going towards the outside of the tire to form triangular corners or sections ( 62).
  • the said wedges (62) of rubber and the axial part (61) are not produced with mixtures of conductive rubber, since very little loaded with carbon black.
  • the tread (3) composed of the radially inner layer (31), called underlay, formed of a mixture loaded mainly with silica, underlay (31) itself radially surmounted by the radially outer layer (32), or wearing course, very heavily loaded with silica.
  • the tread (3) is connected to the beads by the sidewall mixes (4), which are also very heavily loaded with silica.
  • the wearing course (32) is made conductive by means of the rubber insert (11), being in the form of a circumferential ring over the entire height of the wearing course (32) to connect the surface of the strip of bearing coming into contact with the ground with the radially upper face (310) of - 13 - the underlay (31).
  • This insert (11) of very small axial width e on the tread surface, equal to 0.5 mm, is, in the case shown, unique and theoretically centered on the equatorial plane XX 'of the tire, and its trace on the contact surface (310) between the two parts (31) and (32) of the tread is straight and circular.
  • the insert (11) could be off-center, in particular in the case of the presence on the tread of a central groove; there could be two inserts (11), placed for example symmetrically with respect to the equatorial plane, or more, but in any case placed axially so that contact with the ground can be established whatever the rate of wear of the strip of rolling.
  • This insert seen in cross section, has a surface with two bases (110) and (111), the base (110) being the base of small width e on the tread surface.
  • the other base (111) on the contact surface between the two parts (31) and (32) of the tread, it is comparatively very wide since its width E is equal, in the example described, 20 mm, that is to say 40 times the width e, and the cross section of the insert (11) can be considered as the radial superposition of a rectangular part of small width e and large thickness at a rectangular part of large width E and small thickness ( Figure 1B).
  • the electrical connection between the wearing course (32) or more exactly between the insert (s) (11) and the radially outer ply (23) of the crown reinforcement (2), formed of coated metallic cables in a mixture of rubber loaded with a usual and conductive carbon black, is produced by a circumferential insert (12) over the entire height of the portion (31) of the tread, and the width of which is e ', on the contact wall (310) between the two parts (31) and (32) of the tread (3), is also circular, the width e 'being, in the case described, equal to the width e.
  • the rubber composition constituting the conductive connection (12) of the electrostatic charges - 14 - is, like the composition of the insert (11), based on natural rubber and / or synthetic rubbers, usually used in the manufacture of tires and particularly treads, and having as reinforcing filler a conductive carbon black, preferably usually used in the manufacture of tires.
  • said insert (12) has, like the insert (11) a trace or trace, on the contact surface between the two layers (31) and (32), of circular shape and whose the transverse surface is presented as a rectangular surface of width e 'and of depth equal to the thickness of the layer (31).
  • the inserts (11) and (12) have on the cited contact wall, circumferential surfaces such that the surface of width e ′ is included in the surface of width E, significantly larger.
  • the arrangement thus adopted makes it possible, after positioning the two tread parts, whether on a tire-making drum or on any other means of joining said two parts, to have between the two inserts (11) and ( 12) in contact, whatever the normally accepted errors in positioning the two tread parts relative to one another or centering errors in manufacturing (offset of the mean axes of the two inserts (11) and (12 ) noticeable in Figures 1 A and 1B).
  • the electrical connection between the crown reinforcement (2) and the carcass reinforcement (1) is carried out, in the case described, by means of an insert (13) of rectangular cross section and having on the common surface with the carcass reinforcement and the common surface with the crown reinforcement of the rectilinear and circular traces of width e ′, equal to e and to 0.5 mm, said insert (13) being able to be circumferentially, continuous or discontinuous. - 15 -
  • the insert (s) (11, 12) conducting electrostatic charges, due to their rubber composition with a high carbon black content, can be produced by any suitable means, both when the tire is made in the state not vulcanized until after vulcanization.
  • the conductive insert (s) (11) can be produced, for example, by extrusion during the making of the radially upper layer (32) of the tread (3) in the unvulcanized state. The same applies to the inserts (12) and (13) for the radially inner layer (31), obtained separately by extrusion, or for the layer (6).
  • FIG 2 is shown a first extruder (10) forcing using the extrusion screw (101) the unvulcanized rubber mixture, intended for the manufacture of the upper part (32) of tread, in an extrusion head (102), delimited by upper (104) and lower (103) arches, and comprising a flow channel (105) bringing on the one hand the mixture onto the rotary roller (15), associated with the extruder (10), and on the other hand the said mixture towards an extrusion orifice (107) delimited by the cylindrical surface (150) of the roller (15) and the fixed wall of a blade (106), orifice extrusion to give the extruded mixture the desired profile.
  • a micro-extruder 40
  • This extruder armed with a screw (401) and an extrusion head (402), comprises at its end a nozzle (403) fixed to the nose of the micro-extruder (40), and intended to extrude, according to desired profile and trace, the circumferential insert (11) in the unvulcanized and hot mixture profile leaving the orifice (107) of the extruder (10).
  • the support (41) is such that the extrusion head (402) and the nozzle (403) of said micro-extruder are placed in the flow channel (105) of the extruder - 16 - main (10), upstream of the extrusion orifice (107). The conductive rubber mixture is thus extruded into the flow of non-conductive mixture.
  • FIGs 3 which shows an enlargement of the extrusion nozzle (403) of the micro-extruder (40) of Figure 2, said nozzle (403) of the extrusion head (402) placed in the flow channel (105) of the main extruder (10), comprises an annular part (404). allowing the support and the attachment of the nozzle to the nose of the extrusion head (402) of the micro- extruder (40), due to the presence of several attachment holes (405).
  • a hollow cylindrical supply chamber (406) has on its cylindrical surface an extrusion orifice (407), through which the conductive rubber material is extruded and occupying substantially the entire height of said nozzle and whose cross section is a section at two bases of different widths.
  • the extrusion nozzle (403) is placed in the flow channel (105) as the flow flow F of the rubber mixture to be extruded by the main extruder (10) initially strikes the side of the hollow body opposite the side where is the extrusion hole.
  • the end (408) of the nozzle (403) being pressed against the surface (150) of an extrusion roller (15) of the main extruder (10), the conductive mixture to be extruded takes exactly the shape imparted by the extrusion orifice.
  • the nozzle (403) shown in Figure 4 differs mainly from the nozzle in Figure 3 in that the conductive mixture supply chamber has a bent shape so that the end (408) of the nozzle (403) is pressed, not against the roller (15) of the extruder (10), but against the wall of the lower arch (103) of the extrusion head (102) of said main extruder (l ⁇ ) . - 17 -
  • FIG. 5 are only represented the upper arch (104), the flow channel (105) bringing the mixture to an extrusion orifice (107), delimited by the cylindrical surface (150) of the roller (15) and the fixed wall of a blade (106), and thus on said rotary roller (15), associated with the extruder (10), said extrusion orifice making it possible to give the extruded mixture the desired profile.
  • a micro-extruder 40
  • This extradeuse armed with a screw (401) and an extrusion head (402), comprises at its end a nozzle (403) intended to extrude, according to desired profile and trace, the circumferential insert (12) in the unvulcanized and hot mixture profile leaving through the orifice (107) of the extruder (10).
  • the extrusion head (402) is bent at its end, so that the extrusion nozzle (403), fixed to the nose of the extrusion head and placed in the extrusion orifice (107) of the main extruder can be applied against the surface (150) of the roller (15).
  • the conductive rubber mixture is thus extruded into the flow of non-conductive mixture.
  • the principle of fixing the micro-extradeuse on the extrusion blade of the main extruder also applies advantageously to an extradeuse with a flat nose, said extradeuse being different from the previous one by the fact that there is no longer a roller, and that the extrusion orifice (107) is delimited by the lower and upper walls of the extrusion blade (not shown).
  • Figure 6 shows, in enlargement, an extrusion nozzle (403) with a movable die used with the micro-extruder of Figure 5, said die being in position of contact with the roller of the main extruder.
  • the extrusion blade (106) receives in a bore perpendicular to the extrusion head (402) the nozzle (403) with die - 18 - mobile, split in an appropriate section over part of its height.
  • the contact between the base (408) of the moving die nozzle (403) and the wall (150) of the roller (15) is maintained by the pressure of the conductive mixture acting on the section (409), which optionally allows the extrusion of the conductive mixture batchwise.

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Tires In General (AREA)
  • Extrusion Moulding Of Plastics Or The Like (AREA)
  • Tyre Moulding (AREA)
PCT/EP1999/001044 1998-02-26 1999-02-17 Pneumatique electriquement conducteur et appareillages d'extrusion de profiles rendus conducteurs Ceased WO1999043506A1 (fr)

Priority Applications (8)

Application Number Priority Date Filing Date Title
HU0101426A HUP0101426A3 (en) 1998-02-26 1999-02-17 Electrically conductive tyre and apparatus for extruding sections made conductive
JP2000533284A JP4486749B2 (ja) 1998-02-26 1999-02-17 導電性タイヤ、および導電性を有するセクションの押出し成形装置
EP99913169A EP1060089B1 (fr) 1998-02-26 1999-02-17 Pneumatique electriquement conducteur et appareillages d'extrusion de profiles rendus conducteurs
CA002321910A CA2321910A1 (fr) 1998-02-26 1999-02-17 Pneumatique electriquement conducteur et appareillages d'extrusion de profiles rendus conducteurs
DE69940193T DE69940193D1 (de) 1998-02-26 1999-02-17 Elektrisch leitender reifen und vorrichtungen zum extrudieren von leitenden profilen
PL342613A PL199364B1 (pl) 1998-02-26 1999-02-17 Urządzenie do wytwarzania części bieżnika opony przewodzącej elektryczność i dysza wytłaczająca do tego urządzenia
BR9908260-8A BR9908260A (pt) 1998-02-26 1999-02-17 Pneumático que possui pelo menos duas camadas de misturas borrachosas não condutoras de eletricidade, processo destinado a obter o conjunto das duas camadas, aparelhagem para a execução do processo de obtenção de uma parte de banda de rodagem condutora de eletricidade e bico de extrusão de uma micro extrusora
US09/645,097 US6951233B1 (en) 1998-02-26 2000-08-24 Electrically conductive tire and apparatus and process for extruding elements which have been made conductive

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR9802462 1998-02-26
FR98/02462 1998-02-26

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US09/645,097 Continuation US6951233B1 (en) 1998-02-26 2000-08-24 Electrically conductive tire and apparatus and process for extruding elements which have been made conductive

Publications (1)

Publication Number Publication Date
WO1999043506A1 true WO1999043506A1 (fr) 1999-09-02

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PCT/EP1999/001044 Ceased WO1999043506A1 (fr) 1998-02-26 1999-02-17 Pneumatique electriquement conducteur et appareillages d'extrusion de profiles rendus conducteurs

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Country Link
EP (2) EP1060089B1 (https=)
JP (1) JP4486749B2 (https=)
KR (1) KR100649908B1 (https=)
CN (2) CN1159171C (https=)
BR (1) BR9908260A (https=)
CA (1) CA2321910A1 (https=)
DE (1) DE69940193D1 (https=)
HU (1) HUP0101426A3 (https=)
PL (1) PL199364B1 (https=)
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EP1103391A1 (fr) * 1999-11-23 2001-05-30 Société de Technologie Michelin Appareillage de coextrusion de mélanges caoutchouteux
WO2002018159A1 (fr) * 2000-09-01 2002-03-07 Societe De Technologie Michelin Procede pour ameliorer l'adherence sur sol sec d'un pneumatique
WO2002092322A1 (fr) * 2001-05-16 2002-11-21 Societe De Technologie Michelin Appareillage de coextrusion de melanges caoutchouteux
WO2004028779A1 (fr) * 2002-09-25 2004-04-08 Societe De Technologie Michelin Appareil d'application d'un melange caoutchouteux sur une surface en mouvement pour la fabrication de pneumatiques
GB2407794A (en) * 2003-11-04 2005-05-11 Kumho Tire Co Inc Die set of moulding extruder for a tyre with a slanted conductive ring
US6951233B1 (en) * 1998-02-26 2005-10-04 Compagnie Generale Des Etablissements Michelin-Michelin & Cie Electrically conductive tire and apparatus and process for extruding elements which have been made conductive

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JP4212923B2 (ja) * 2003-02-27 2009-01-21 横浜ゴム株式会社 タイヤ用トレッドゴムの成形装置
RU2381911C2 (ru) * 2005-03-16 2010-02-20 Бриджстоун Корпорейшн Пневматическая шина
DE202005018857U1 (de) * 2005-12-01 2007-04-12 Sonnendorfer Horst Transportrolle für einen Einkaufswagen
FR2914581B1 (fr) * 2007-04-05 2009-07-03 Michelin Soc Tech Dispositif, installation et procede pour l'application d'une bande de gomme sur une ebauche de pneumatique.
US8869856B2 (en) 2007-06-15 2014-10-28 Sumitomo Rubber Industries, Ltd. Pneumatic tire
RU2389612C2 (ru) * 2007-06-15 2010-05-20 Сумитомо Раббер Индастриз, Лтд. Пневматическая шина
CN101980852B (zh) * 2008-03-31 2014-08-13 米其林研究和技术股份有限公司 将减震胶涂覆至外胎的方法和装置
DE102009048980A1 (de) * 2009-10-09 2011-04-14 Troester Gmbh & Co. Kg Spritzkopf sowie eine mit einem solchen Spritzkopf ausgestattete Extrusionsvorrichtung
JP5389868B2 (ja) * 2011-07-26 2014-01-15 東洋ゴム工業株式会社 空気入りタイヤ
JP5764101B2 (ja) * 2012-09-04 2015-08-12 住友ゴム工業株式会社 トレッドゴム押出方法及びトレッドゴム押出装置
FR3006620B1 (fr) * 2013-06-10 2015-12-11 Batscap Sa Filiere pour la fabrication d'un film par extrusion
DE102017108943A1 (de) * 2016-12-02 2018-06-07 Kraussmaffei Berstorff Gmbh Verfahren zum Herstellen eines Laufstreifens und Laufstreifen-Herstellvorrichtung
CN108215118A (zh) * 2018-01-25 2018-06-29 正新橡胶(中国)有限公司 一种生产导电轮胎的挤出口型
FR3117919B1 (fr) * 2020-12-23 2022-12-02 Michelin & Cie Procédé de fermeture en deux temps d’une installation d’extrusion a rouleau permettant un ajustement précis de l’entrefer de génération d’un profilé
FR3119566A1 (fr) * 2021-02-08 2022-08-12 Compagnie Generale Des Etablissements Michelin Pneumatique presentant un nouveau chemin conducteur

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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6951233B1 (en) * 1998-02-26 2005-10-04 Compagnie Generale Des Etablissements Michelin-Michelin & Cie Electrically conductive tire and apparatus and process for extruding elements which have been made conductive
EP1103391A1 (fr) * 1999-11-23 2001-05-30 Société de Technologie Michelin Appareillage de coextrusion de mélanges caoutchouteux
WO2002018159A1 (fr) * 2000-09-01 2002-03-07 Societe De Technologie Michelin Procede pour ameliorer l'adherence sur sol sec d'un pneumatique
WO2002092322A1 (fr) * 2001-05-16 2002-11-21 Societe De Technologie Michelin Appareillage de coextrusion de melanges caoutchouteux
US6994817B2 (en) 2001-05-16 2006-02-07 Michelin Recherche Et Technique S.A. Process and apparatus for the coextrusion of rubber mixtures
RU2286255C2 (ru) * 2001-05-16 2006-10-27 Сосьете Де Текноложи Мишлен Устройство для соэкструзии резиновых смесей
WO2004028779A1 (fr) * 2002-09-25 2004-04-08 Societe De Technologie Michelin Appareil d'application d'un melange caoutchouteux sur une surface en mouvement pour la fabrication de pneumatiques
GB2407794A (en) * 2003-11-04 2005-05-11 Kumho Tire Co Inc Die set of moulding extruder for a tyre with a slanted conductive ring
GB2407794B (en) * 2003-11-04 2006-05-10 Kumho Tire Co Inc Die set of molding extruder for tire with slanted conductive ring
AU2004203820B2 (en) * 2003-11-04 2006-10-05 Kumho Tire Co., Inc. Die set of molding extruder for tire with slanted conductive ring

Also Published As

Publication number Publication date
KR20010041330A (ko) 2001-05-15
CN1159171C (zh) 2004-07-28
CN1325786A (zh) 2001-12-12
JP4486749B2 (ja) 2010-06-23
DE69940193D1 (de) 2009-02-12
HUP0101426A2 (hu) 2001-08-28
RU2225299C2 (ru) 2004-03-10
JP2002504455A (ja) 2002-02-12
BR9908260A (pt) 2000-10-31
EP1060089A1 (fr) 2000-12-20
EP1095798A1 (fr) 2001-05-02
HUP0101426A3 (en) 2002-02-28
PL342613A1 (en) 2001-06-18
CA2321910A1 (fr) 1999-09-02
CN1291947A (zh) 2001-04-18
KR100649908B1 (ko) 2006-11-27
CN1174850C (zh) 2004-11-10
PL199364B1 (pl) 2008-09-30
EP1060089B1 (fr) 2008-12-31

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