WO1998034160A1 - Procede pour transferer des illustrations sur des substrats par xerographie a l'aide de papiers-transfert - Google Patents

Procede pour transferer des illustrations sur des substrats par xerographie a l'aide de papiers-transfert Download PDF

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Publication number
WO1998034160A1
WO1998034160A1 PCT/EP1998/000062 EP9800062W WO9834160A1 WO 1998034160 A1 WO1998034160 A1 WO 1998034160A1 EP 9800062 W EP9800062 W EP 9800062W WO 9834160 A1 WO9834160 A1 WO 9834160A1
Authority
WO
WIPO (PCT)
Prior art keywords
paper
ethylene
polymer
substrates
sealing
Prior art date
Application number
PCT/EP1998/000062
Other languages
German (de)
English (en)
Inventor
Bülent Öz
Original Assignee
Oez Buelent
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Oez Buelent filed Critical Oez Buelent
Priority to AU57659/98A priority Critical patent/AU5765998A/en
Priority to EP98901344A priority patent/EP0956519A1/fr
Publication of WO1998034160A1 publication Critical patent/WO1998034160A1/fr

Links

Classifications

    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G7/00—Selection of materials for use in image-receiving members, i.e. for reversal by physical contact; Manufacture thereof
    • G03G7/0006—Cover layers for image-receiving members; Strippable coversheets
    • G03G7/002—Organic components thereof
    • G03G7/0026—Organic components thereof being macromolecular
    • G03G7/004—Organic components thereof being macromolecular obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/025—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet
    • B41M5/0256—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet the transferable ink pattern being obtained by means of a computer driven printer, e.g. an ink jet or laser printer, or by electrographic means
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M7/00—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock
    • B41M7/0027—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock using protective coatings or layers by lamination or by fusion of the coatings or layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C1/00—Processes, not specifically provided for elsewhere, for producing decorative surface effects
    • B44C1/16—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like
    • B44C1/165—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like for decalcomanias; sheet material therefor
    • B44C1/17—Dry transfer
    • B44C1/1712—Decalcomanias applied under heat and pressure, e.g. provided with a heat activable adhesive
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06Q—DECORATING TEXTILES
    • D06Q1/00—Decorating textiles
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/10—Coatings without pigments
    • D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • D21H19/20—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/10—Coatings without pigments
    • D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • D21H19/20—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H19/22—Polyalkenes, e.g. polystyrene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M2205/00—Printing methods or features related to printing methods; Location or type of the layers
    • B41M2205/10—Post-imaging transfer of imaged layer; transfer of the whole imaged layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B41M5/5254—Macromolecular coatings characterised by the use of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds, e.g. vinyl polymers

Definitions

  • the present invention relates to a method for transferring images by means of xerocopy to substrates such as textile documents, in particular T-shirts, cups, magnetic foils, mirrors or other smooth surfaces made of metal, leather, ceramic, wood, plexiglass, cardboard or plastic by means of transfer papers.
  • the transfer paper is preferably provided with a plastic layer which adheres to the substrate when it is sealed and is detached from the transfer paper.
  • the paper must be easily detached from the plastic layer after sealing.
  • the coatings contain a wax.
  • this wax shows the serious disadvantage that it evaporates in the copier at the prevailing temperatures, sometimes up to 160 ° C., and lies on the surfaces of the device, which leads to the optics becoming dirty and the paper transport means (rollers) being reduced as a result Do not transport friction coefficients properly anymore, the copying machines are therefore very often and cumbersome to clean.
  • a method for this purpose is known, for example, from DE 39 20 864 A1, wherein a xerocopy is produced on a coated paper and this is ironed onto the fabric.
  • the coating consists of three layers, it consists of a polyethylene (copolymer) layer, onto which a hardness layer is applied by screen printing and then a stabilizer layer is applied by screen printing.
  • a polyethylene (copolymer) layer onto which a hardness layer is applied by screen printing and then a stabilizer layer is applied by screen printing.
  • a stabilizer layer is applied by screen printing.
  • the disadvantage of this procedure is the very complex coating by extrusion of the base layer and after curing by screen printing each of the two other essential layers.
  • Another disadvantage of such printed fabrics is that the prints fade after only a few washes. In addition, the print quality is not satisfactory.
  • DE 40 24 419 A1 describes a print carrier for the same purposes as described here. This consists of two polymer layers applied to a carrier paper, a first rubber layer as a melt coating and a second layer made of polyethylene or polyacrylate lying above it. Detaching the paper after applying pressure to the textile requires keeping the paper at the melting temperature of the rubber. Although wax is not used as a release agent here, since the rubber bonds very well to the paper, the removal process may need to be heated (see e.g. Claim 19) in order to maintain the high temperature of 150 to 220 ° C required for this.
  • DE 26 14 078 C2 discloses a hot printing film consisting of a carrier and an EVA copolymer coating in a mixture with a tackifier and wax in a single-layer coating on a carrier together with pigment. This material does not serve the purpose of xerocopying prints and would have the disadvantages outlined above because of the evaporation of wax.
  • DE 39 42 021 A1 uses a single-layer coating for the same purposes.
  • paraffin is added to the plastic layer and, if necessary, additionally paper coated with silicone is used, which has exactly the above disadvantages.
  • DE 39 01 340 C2 describes heat-sensitive image transfer and recording materials for use in computer printers.
  • a heat-meltable layer of paint is melted over a thermal head, transferred to a paper and assembled there into an image.
  • the coating is on an ink ribbon and, in order to improve the image quality, should have a rubber as a release layer which should be free from paraffin and, above it, a heat-melting ink layer composed of colorant and resin component.
  • an applied image is not taken over by a carrier over the entire surface, but rather is put together on the paper after individual points have been removed from the ribbon.
  • the object of the present invention is therefore to create a method and a transfer paper which contain images on print originals.
  • Xerocopy can be transferred to substrates such as textile underlays, in particular T-shirts, cups, magnetic foils, mirrors or other smooth surfaces made of metal, leather, ceramic, wood, plexiglass, cardboard or plastic by means of transfer papers, both in terms of quality and washability
  • substrates such as textile underlays, in particular T-shirts, cups, magnetic foils, mirrors or other smooth surfaces made of metal, leather, ceramic, wood, plexiglass, cardboard or plastic
  • transfer papers both in terms of quality and washability
  • the transferred images meet high demands, but at the same time do not cause the previously unavoidable contamination of the copier.
  • Either only the toner from the xerography or also part or all of the plastic coating of the transfer paper should be able to be transferred.
  • the transfer papers according to the invention consist of machine-smooth papers suitable for xerocopiers with basis weights of z. B. 80-150, preferably 90-100 g / m 2 , which are coated on one side with polyolefins or polyolefin copolymers with a layer thickness of 20-50 g / m 2 , preferably 25-40 g / m 2 .
  • the polyolefins used are, for example, LDPE, EVA with 7-28%, preferably 7-15% VA, ethylene-acrylic acid copolymers or ethylene-methyl acrylate copolymers with 5-12% acrylic acid, ethylene-butyl-acrylate copolymers with 5-20% acrylate, which have a melt index according to ASTM-D-1238 (MFI) of 3.5-22, preferably 7-15 g / 10 min at 2.16 kg / 190 ° C.
  • MFI melt index according to ASTM-D-1238
  • the plastic coating should have a limited adhesion of ⁇ 2 N / 15 mm to the backing paper in the cold so that it can be separated therefrom after the sealing process, on the other hand it should have good adhesion (stickiness) at temperatures of> 80 ° C have a Vyer softening point according to ASTM D 15025 of 70 - 180 ° C so that they do not adhere to the contours of the substrate during sealing, have good adhesion to the toners at the usual xerography temperatures, without causing it to surface mixing comes.
  • high temperature cohesion should be lower than adhesion to the substrate and substrate.
  • the desired image can be applied to the transfer paper thus produced in all commercially available xerocopiers, the toners being commercially available from the corresponding color pigments in a plastic matrix, usually made of polyester with a melting range of e.g. B. 80 - 120 ° C, and auxiliaries exist.
  • This copy can now be pressed onto the substrate at temperatures of 80 - 200 ° C.
  • a cohesive break occurs in the polymer layer, so that parts of the polymer with the toner adhere to the substrate, and some adhere to the paper, so that a very thin flexible Plastic layer remains on the substrate.
  • This is particularly advantageous for textile surfaces that have high adhesiveness for washing resistance. If the detachment takes place at medium temperatures up to room temperature, remains on non-absorbent surfaces of the substrate, e.g. B. glass, ceramic, metal, plastic only the toner on the substrate back and paper and polymer coating are removed together.
  • the paper leads to the desired image properties mentioned above.
  • the paper has the advantage over the known transfer papers that it can be produced in only one coating process, since the separating layer and sealing layer are one.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • General Engineering & Computer Science (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • General Physics & Mathematics (AREA)
  • Textile Engineering (AREA)
  • Decoration By Transfer Pictures (AREA)

Abstract

L'invention concerne un procédé permettant de transférer des illustrations sur des substrats par xérocopie, à l'aide de papiers-transfert recouverts d'un revêtement à base d'un composé polymère, par scellement sur le substrat. Selon ce procédé, on utilise un papier-transfert composé d'un papier fini machine, adapté pour machines de xérocopie et ayant un grammage compris entre 80 et 150 g/m<2>, qui est recouvert d'un revêtement à base de polyoléfine ou de copolymérisat polyoléfinique, à raison d'une épaisseur de couche de 20 à 50 g/m<2> et un indice de fusion MFI compris entre 3 et 22 kg/10 mn, à 2,16 kg/190 DEG C.
PCT/EP1998/000062 1997-01-31 1998-01-08 Procede pour transferer des illustrations sur des substrats par xerographie a l'aide de papiers-transfert WO1998034160A1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
AU57659/98A AU5765998A (en) 1997-01-31 1998-01-08 Method of transferring illustrations to substrates by means of xerography via transfer papers
EP98901344A EP0956519A1 (fr) 1997-01-31 1998-01-08 Procede pour transferer des illustrations sur des substrats par xerographie a l'aide de papiers-transfert

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE1997103731 DE19703731A1 (de) 1997-01-31 1997-01-31 Verfahren zum Übertragen von Abbildungen auf Substrate mittels Xerographie über Transferpapiere
DE19703731.3 1997-01-31

Publications (1)

Publication Number Publication Date
WO1998034160A1 true WO1998034160A1 (fr) 1998-08-06

Family

ID=7818987

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP1998/000062 WO1998034160A1 (fr) 1997-01-31 1998-01-08 Procede pour transferer des illustrations sur des substrats par xerographie a l'aide de papiers-transfert

Country Status (4)

Country Link
EP (1) EP0956519A1 (fr)
AU (1) AU5765998A (fr)
DE (1) DE19703731A1 (fr)
WO (1) WO1998034160A1 (fr)

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2310393A1 (de) * 1972-03-03 1973-09-13 Canon Kk Uebertragungspapier fuer die elektrophotographie
WO1991000385A1 (fr) * 1989-06-26 1991-01-10 Hagedorn Juergen Procede pour transferer des illustrations sur un support
EP0466503A1 (fr) * 1990-07-13 1992-01-15 Denny Damodar Kalro Procédé pour transfert d'image et matériau de support
DE4210976A1 (de) * 1991-10-17 1993-04-22 Buelent Oez Verfahren zum uebertragen von auf druckvorlagen befindlichen abbildungen auf stoffe
EP0683057A1 (fr) * 1994-05-19 1995-11-22 FELIX SCHOELLER JR. FOTO- UND SPEZIALPAPIERE GmbH &amp; Co. KG. Papier pour transfert d'images par chaleur sur des surfaces plates et poreuses

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2310393A1 (de) * 1972-03-03 1973-09-13 Canon Kk Uebertragungspapier fuer die elektrophotographie
WO1991000385A1 (fr) * 1989-06-26 1991-01-10 Hagedorn Juergen Procede pour transferer des illustrations sur un support
EP0466503A1 (fr) * 1990-07-13 1992-01-15 Denny Damodar Kalro Procédé pour transfert d'image et matériau de support
DE4210976A1 (de) * 1991-10-17 1993-04-22 Buelent Oez Verfahren zum uebertragen von auf druckvorlagen befindlichen abbildungen auf stoffe
EP0683057A1 (fr) * 1994-05-19 1995-11-22 FELIX SCHOELLER JR. FOTO- UND SPEZIALPAPIERE GmbH &amp; Co. KG. Papier pour transfert d'images par chaleur sur des surfaces plates et poreuses

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
L.R.SAGNERI: "Non-contaminating heat seal formulation", XEROX DISCLOSURE JOURNAL, vol. 5, no. 3, 1 May 1980 (1980-05-01) - 30 June 1980 (1980-06-30), STAMFORD USA, pages 229, XP002061718 *

Also Published As

Publication number Publication date
EP0956519A1 (fr) 1999-11-17
DE19703731A1 (de) 1998-08-06
AU5765998A (en) 1998-08-25

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