WO1998030661A1 - Verfahren zur reinigung von oberflächen - Google Patents

Verfahren zur reinigung von oberflächen Download PDF

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Publication number
WO1998030661A1
WO1998030661A1 PCT/EP1998/000016 EP9800016W WO9830661A1 WO 1998030661 A1 WO1998030661 A1 WO 1998030661A1 EP 9800016 W EP9800016 W EP 9800016W WO 9830661 A1 WO9830661 A1 WO 9830661A1
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WO
WIPO (PCT)
Prior art keywords
acid
water
cleaning
independently
mixture
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP1998/000016
Other languages
German (de)
English (en)
French (fr)
Inventor
Andreas Gröschl
Torsten Groth
Volker Hassmann
Jürgen HORN
Ingo Janisch
Winfried Joentgen
Bernhard Lehmann
Wolfgang Zarges
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer AG
Original Assignee
Bayer AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer AG filed Critical Bayer AG
Priority to JP53051998A priority Critical patent/JP2001507750A/ja
Priority to CA002269988A priority patent/CA2269988A1/en
Priority to DE59813197T priority patent/DE59813197D1/de
Priority to KR10-1999-7003016A priority patent/KR100494284B1/ko
Priority to AT98904031T priority patent/ATE310071T1/de
Priority to US09/269,568 priority patent/US6387189B1/en
Priority to EP98904031A priority patent/EP0970167B1/de
Priority to AU62070/98A priority patent/AU724604B2/en
Priority to IL12950998A priority patent/IL129509A/xx
Priority to BR9806156-9A priority patent/BR9806156A/pt
Publication of WO1998030661A1 publication Critical patent/WO1998030661A1/de
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22—Organic compounds
    • C11D7/32—Organic compounds containing nitrogen
    • C11D7/3209—Amines or imines with one to four nitrogen atoms; Quaternized amines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D65/00—Accessories or auxiliary operations, in general, for separation processes or apparatus using semi-permeable membranes
    • B01D65/02—Membrane cleaning or sterilisation ; Membrane regeneration
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/33—Amino carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3719—Polyamides or polyimides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22—Organic compounds
    • C11D7/32—Organic compounds containing nitrogen
    • C11D7/3245—Aminoacids
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22—Organic compounds
    • C11D7/34—Organic compounds containing sulfur
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/50—Solvents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2321/00—Details relating to membrane cleaning, regeneration, sterilization or to the prevention of fouling
    • B01D2321/16—Use of chemical agents
    • B01D2321/162—Use of acids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2321/00—Details relating to membrane cleaning, regeneration, sterilization or to the prevention of fouling
    • B01D2321/16—Use of chemical agents
    • B01D2321/164—Use of bases
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2321/00—Details relating to membrane cleaning, regeneration, sterilization or to the prevention of fouling
    • B01D2321/16—Use of chemical agents
    • B01D2321/166—Use of enzymatic agents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2321/00—Details relating to membrane cleaning, regeneration, sterilization or to the prevention of fouling
    • B01D2321/16—Use of chemical agents
    • B01D2321/168—Use of other chemical agents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/10—Objects to be cleaned
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/10—Objects to be cleaned
    • C11D2111/14—Hard surfaces
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/10—Objects to be cleaned
    • C11D2111/14—Hard surfaces
    • C11D2111/18—Glass; Plastics

Definitions

  • the present invention relates to a nerfahr for cleaning surfaces made of glass, graphite, ceramics, polymer and metallic materials, artificial and vegetable fibers, e.g. Fabrics, textiles or waste paper, especially from
  • Membrane surfaces by detaching or dissolving organic and inorganic contaminants through a simple rinsing process.
  • Membranes as a special example of surfaces, are used in a variety of ways in industry and in the medical field. It is important for their economical use that a high flow rate be maintained.
  • EP 0 513 948 describes the cleaning of hard surfaces by a cleaning agent which is composed of different components and u. a. contains a complexing agent and an organic solvent.
  • a cleaning composition for hard surfaces is known from EP 0 261 874, which contains EDTA and an alkanesulfonate.
  • US Pat. No. 4,808,328 also discloses cleaning agents for hard surfaces which, in addition to EDTA, contain an alkanesulfonate.
  • R 1 , R 2 , R 3 and R 4 independently of one another H, Li, Na, K, NH 4 , H 3 NCH 2 CH 2 OH, H 2 N (CH 2 CH 2 OH) 2 or HN (CH 2 CH 2 OH) 3 mean
  • R 5 and R 6 are independently H or OH and
  • R 7 represents H, CH 2 CH 2 OH, CH 2 CH 2 CH 2 OH, CH 2 CH (OH) CH 3 , CH 2 COOR 8 or CH 2 CH 2 COOR 8 , in which R 8 is independent of R 1 the scope of R 1 ,
  • the invention relates to a method for cleaning surfaces made of glass, graphite, ceramic, polymeric and metallic materials, artificial and vegetable fibers and membranes by detaching or dissolving organic or inorganic contaminants or a mixture of both by a simple rinsing process with the solution of a cleaning agent in particular at 10 - 100 ° C and in particular a pH of 3 - 13, which is characterized in that at least one component of the series as a cleaning agent
  • R 1 , R 2 , R 3 and R 4 independently of one another H, Li, Na, K, NLU, H 3 NCH 2 CH 2 OH, H 2 N (CH 2 CH 2 OH) 2 or HN (CH 2 CH 2 OH ) 3 mean
  • R 5 and R 6 are independently H or OH and R 7 represents H, CH 2 CH 2 OH, CH 2 CH 2 CH 2 OH, CH 2 CH (OH) CH 3 , CH 2 COOR 8 or CH 2 CH 2 COOR 8 , in which R 8 is independent of R 1 the scope of R 1 ,
  • the invention further relates to agents for cleaning surfaces made of glass, graphite, ceramics, polymeric and metallic materials, artificial and vegetable fibers and membranes, based on at least one component of the series
  • R 1 , R 2 , R 3 and R 4 independently of one another H, Li, Na, K, NIL ,, H 3 NCH 2 CH 2 OH, H 2 N (CH 2 CH 2 OH) 2 or HN (CH 2 CH 2 OH) 3 mean
  • R 5 and R 6 are independently H or OH and R 7 represents H, CH 2 CH 2 OH, CH 2 CH 2 CH 2 OH, CH 2 CH (OH) CH 3 , CH 2 COOR 8 or CH 2 CH 2 COOR 8 , in which R 8 is independent of R 1 the scope of R 1 ,
  • a solvent from the group of water and a mixture of water and a -C 4 alcohol or a C 3 -C ketone, the solvent in particular 40-99.9 wt .-%, preferably 50-99 wt. -%, particularly preferably 60-90% by weight of the total agent.
  • the emulsifiers to be used according to the invention are preferably C 8 -C 25 alkanesulfonates, particularly preferably C 0 -C 20 alkanesulfonates, very particularly preferably C 12 -C 8 alkanesulfonates. Linear alkanesulfonates are also preferably used.
  • the iminodisuccinic acids of the formula (I) to be used according to the invention are used in aqueous solution.
  • R 6 preferably stands for H, particularly preferably R 5 and R 6 stand for H. R also preferably stands for H. R 5 , R 6 and R 7 stand for H in a further preferred manner, so that (I) which is unsubstituted iminodisuccinic acid (IDS) and its salts of the type described above.
  • IDS iminodisuccinic acid
  • R 1 , R 2 , R 3 and R 4 are replaced by R ", R 12 , R 13 and R 14 with the meaning of H, Na, K, NH, or H 3 NCH 2 CH 2 OH.
  • the iminodisuccinic acids of the formula (I) used according to the invention are in pure form or are associated with small amounts of secondary components from the preparation of (I), such as maleic acid, fumaric acid, aspartic acid, malic acid. Acid, asparagine, tartaric acid, hydroxyaspartic acid, condensates of aspartic acid etc. or their salts with the cations R 1 to R 4 indicated above.
  • the secondary components are present in the mixture in an amount of at most 35% by weight, preferably 30% by weight and particularly preferably 25% by weight; the rest is 100% by weight (I).
  • (I) is prepared by known processes in an aqueous medium, for example from maleic anhydride, maleic acid or epoxysuccinic acid and ammonia or aspartic acid. Methods of this type are described, for example, in GB 1 306 331, SU 0 639 863, JP 6/329 607, JP 6/330 020 and DE 37 39 610.
  • polyamino acids according to the invention are e.g. for homo- and copolymers of lysine, glutamic acid, alanine and aspartic acid and for protein hydrolysates.
  • Polyaspartic acids or polymers with recurring sucinyl units which can be prepared both from aspartic acid and from maleic anhydride, its secondary derivatives and ammonia, are preferably used.
  • polyamino acids to be used according to the invention are polymers with repeating succinyl units which have at least one of the following repeating structural units:
  • R 20 stands for H or for a cation, in particular alkali metal, ammonium, independently of one another in the case of multiple occurrences,
  • n, m, o stand for 0 or an integer from 1 to 300,
  • p, q stand for 0 or an integer from 1 to 10,
  • r represents 0 or an integer of 1 or 2
  • s represents 0 or an integer from 1 to 10
  • the polymers to be used according to the invention are taken to mean the corresponding free acids, their salts, but also derivatives of the acids, in particular anhydrides.
  • the recurring unit B1 is at least 50%, in particular at least 70%.
  • the average molecular weight (MW) can vary within a wide range, polyaspartic acids with molecular weights between 500 and 100,000 g / mol being usable, but preferred are 1,000 to 50,000 g / mol or, even better, 1,000 to 30,000 g / mol.
  • the polymers with recurring succinyl units to be used according to the invention are essentially polyaspartic acids.
  • the polymers can be prepared by known processes, for example according to US Pat. No. 4,839,461, US Pat. No. 5,371,180, US Pat. No. 5,288,783, J. Org.
  • the emulsifiers, iminocarboxylic acids and polyamino acids can be used alone or as mixtures.
  • the mixture proportions (mass proportions) of emulsifier, preferably C 8 -C 2 -alkanesulfonate, and iminocarboxylic acid or polyamino acid are in the range from 99: 1 to 1:99, preferably 20:80 to 80:20, particularly preferably 40:60 to 60:40.
  • the mixing proportions of iminocarboxylic acid and polyamino acids are likewise in the range from 99: 1 to 1:99, preferably 20:80 to 80:20, particularly preferably 40:60 to
  • the cleaning agent concentrates according to the invention are used with a water content of 99.9% by weight to 40% by weight, preferably 95% by weight to 50% by weight, particularly preferably 95% by weight to 60% by weight. %.
  • the cleaning agents according to the invention are used at pH values of 3-13, preferably at 4-12, particularly preferably at 4.5-11.5 and at temperatures of 10-100 ° C., preferably at 15-85 ° C.
  • the cleaning agents according to the invention are used for cleaning surfaces
  • Membranes that are cleaned according to the invention are those that are preferred in
  • the membranes can be constructed from the following materials: cellulose esters, such as, for example, cellulose acetate, cellulose acetopropionate, cellulose acetobutyrate, polyolefins, such as polyethylene or polypropylene, copolymers of ethylene and C 3 -C 8 -olefins, polyimides, polyamides, polyphenylene sulfones, polyphenylene ethers , Polyphenylene sulfone ester, polyphenylene ether ester, ceramic, SiO 2 , carbon, polypiperazinamide, polytetrafluoroethylene (PTFE), polyvinylidene fluoride (PVDF), polyacrylonitrile (PAN), polysulfone.
  • cellulose esters such as, for example, cellulose acetate, cellulose acetopropionate, cellulose acetobutyrate
  • polyolefins such as polyethylene or polypropylene, copolymers of ethylene and C 3
  • the membrane to be cleaned or the membrane module to be cleaned is washed with an aqueous, aqueous-alcoholic, aqueous-ketonic or aqueous-alcoholic-ketonic solution of the emulsifier, the iminocarboxylic acid, the polyamino acid or a mixture thereof, optionally with the addition of commercially available detergent enzymes, such as for example, proteases, lipases or amylases are treated in such a way that such a solution is pumped over the membrane surface or through the membrane module.
  • an alcohol comes a C 1 -C alcohol, such as methanol, ethanol,
  • Suitable ketones are acetone (C 3 ) or methyl ethyl ketone (C 4 ). Of these organic solvents, alcohols are preferred.
  • the duration of the cleaning treatment is of course in a manner familiar to the person skilled in the art from the degree of contamination, from the intensity of the pumping over, from the
  • the degree of purification can be controlled by determining the flow rate through the membrane.
  • the cleaning agents according to the invention are prepared by simply dissolving the emulsifier and / or the iminodisuccinic acid of the formula (I) and / or the polyamino acid and, if appropriate, the alkali carrier or the enzyme or a plurality of such substances in water, a water / alcohol mixture, a water / ketone mixture or a water / alcohol / ketone mixture in the amounts and ratios indicated.
  • a mixture of dry substances for example flake goods from one, can be used for storage or for shipping purposes
  • Drying roller or spray dryer granules can be produced.
  • liquid substances for example highly concentrated alkali metal lye or ethanolamine
  • a solution for example 10 to 60% by weight, is suitable for storage and shipping.
  • the cleaning solution according to the invention may contain other components such as. B. enzymes, alcohols, solubilizers and auxiliaries and fragrances.
  • An aqueous solution consisting of 30% by weight H SO 4 , 30% by weight naphthalenesulfonic acid and 40% by weight water was batch-operated at an operating pressure of 60 bar and an operating temperature of 40 ° C. for 20 hours diafiltered and then the membrane separation performance under standard conditions (1000 mg / 1 Na SO 4 , 25 bar, 30 ° C) determined.
  • a winding module was used as the module. The module was then treated with 50 l of an aqueous solution consisting of 0.5% by weight of the above emulsifier, 0.5% by weight of LDS-Na salt and 99% by weight of water at 40 ° C.
  • the module separation performance under standard conditions could be increased by 5% while the salt passage decreased from 5.4% to 2.2%.
  • aqueous solution consisting of 7% by weight of flavonic acid Na salt and traces of impurities was concentrated batchwise using the reverse osmosis to 50% of the input volume at an operating pressure of 40 bar and an operating temperature of 40 ° C.
  • the module from Example 3 was used. Subsequently, the module with 50 1 of an aqueous solution consisting of 0.5 wt .-% of the above emulsifier, 0.5 wt .-% EDTA and 99 wt .-% water at 40 ° C and a flow of 1.2 m 3 / h for 30 minutes without pressure in circulatory operation and the membrane separation capacity under standard conditions (1000 mg / 1 Na 2 SO,
  • a further rinse with 50 l of an aqueous solution consisting of 0.5% by weight of the above emulsifier, 0.5% by weight of IDS Na salt and 99% by weight of water was carried out at 40 ° C. and one Inflow of 1.2 m 3 / h for 30 minutes without pressure in the circulatory mode and a new measurement of the membrane separation performance under standard conditions.
  • the second rinsing with IDS Na salt enabled the module separation performance under standard conditions a salt passage of 0.3% can be increased by a further percentage point compared to the first flush.
  • Example 1 was repeated. However, as a rinse solution were 10 1 of an aqueous solution consisting of 1.5 wt .-% Ultrasil ® 40 (commercial product from. Henkel, Dusseldorf, consisting essentially of organic complexing agents and alkali carriers) and 98.5 wt .-% water, used ; it was flushed at 40 ° C and a flow of 1.2 m 3 / h without pressure for 20 minutes in a circulating mode. The module separation performance was then determined again under standard conditions.
  • Ultrasil ® 40 commercial product from. Henkel, Dusseldorf, consisting essentially of organic complexing agents and alkali carriers
  • the permeate flow was able to reach 98% of the permeate flow under standard conditions before exposure to the wastewater, i.e. almost to output power, with an unchanged salt passage (concentration in feed / concentration in permeate) of 2 , 9%.
  • Example 1 was repeated. However, 10 1 of an aqueous solution consisting of 1% by weight of Ultrasil 10 (commercial product from Henkel, Dusseldorf, consisting essentially of Na acetate, Na sulfate, Na phosphate, " alkylbenzenesulfonate and EDTA) were used as the rinsing solution. and 99% by weight of water, at 40 ° C. and an inflow of 1.2 m 3 / h for 20 minutes without pressure in a circulating mode Module separation performance determined under standard conditions.
  • Ultrasil 10 commercial product from Henkel, Dusseldorf, consisting essentially of Na acetate, Na sulfate, Na phosphate, " alkylbenzenesulfonate and EDTA
  • An aqueous solution of an optical brightener which was contaminated with defoamer lubricant, was applied batchwise at an operating pressure of 30 bar and an operating temperature of 50 ° C. over a period of 10 h, permeate and concentrate being returned to the receiver.
  • a plate module was used which, after determining the pure water flow, with 10 l of an aqueous solution consisting of 0.5% by weight of the above emulsifier, 0.25% by weight of polyaspartic acid Na salt and 99.25% by weight .-% water at 40 ° C for 20
  • Example 3 was repeated. However, an aqueous solution consisting of 0.5% by weight of Ultraperm 091 ® (commercial product from Henkel, consisting of anionic and amphoteric surfactants, alkali and complexing agents) and
  • Retentate were returned. In between, a concentration was carried out by withdrawing permeate. After 12 h the solution was drained, rinsed with water and the pure water flow was determined under standard conditions (25 ° C., 20 bar). A plate module was used as the module, which after determining the pure water flow with 10 l of an aqueous solution consisting of 0.5% by weight of the above
  • Emulsifier, 0.25 wt .-% iminodisuccinate Na salt and 99.25 wt .-% water at 40 ° C for 20 minutes without pressure in a circulating operation.
  • the pure water flow was then measured again under standard conditions (25 ° C., 20 bar).
  • Cleaning allowed the permeate output to be increased under standard conditions by 21% compared to the permeate output before rinsing.
  • Example 4 was repeated. However, an aqueous solution consisting of 0.5% by weight of Ultraperm 091 (commercial product from Henkel, consisting of anionic and amorphous surfactants, alkali and complexing agents) and 99.5% by weight of water was used as the rinsing solution. It was flushed at 40 ° C for 20 minutes without pressure in the cycle mode. Then the pure water flow was determined under standard conditions. Cleaning allowed the permeate output to be increased under standard conditions by 8% compared to the permeate output before rinsing. In contrast, in example 4 the permeate output was increased by 21%.
  • Ultraperm 091 commercial product from Henkel, consisting of anionic and amorphous surfactants, alkali and complexing agents

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Mechanical Treatment Of Semiconductor (AREA)
  • Crystals, And After-Treatments Of Crystals (AREA)
  • Cleaning By Liquid Or Steam (AREA)
PCT/EP1998/000016 1997-01-09 1998-01-03 Verfahren zur reinigung von oberflächen Ceased WO1998030661A1 (de)

Priority Applications (10)

Application Number Priority Date Filing Date Title
JP53051998A JP2001507750A (ja) 1997-01-09 1998-01-03 表面のクリーニング法
CA002269988A CA2269988A1 (en) 1997-01-09 1998-01-03 Surface-cleaning method
DE59813197T DE59813197D1 (de) 1997-01-09 1998-01-03 Verfahren zur reinigung von oberflächen
KR10-1999-7003016A KR100494284B1 (ko) 1997-01-09 1998-01-03 표면 세정 방법
AT98904031T ATE310071T1 (de) 1997-01-09 1998-01-03 Verfahren zur reinigung von oberflächen
US09/269,568 US6387189B1 (en) 1997-01-09 1998-01-03 Surface-cleaning method
EP98904031A EP0970167B1 (de) 1997-01-09 1998-01-03 Verfahren zur reinigung von oberflächen
AU62070/98A AU724604B2 (en) 1997-01-09 1998-01-03 Method of cleaning surfaces
IL12950998A IL129509A (en) 1997-01-09 1998-01-03 Method of cleaning surfaces
BR9806156-9A BR9806156A (pt) 1997-01-09 1998-01-03 Método de limpeza de superfìcies

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19700493.8 1997-01-09
DE19700493A DE19700493A1 (de) 1997-01-09 1997-01-09 Verfahren zur Reinigung von Oberflächen

Publications (1)

Publication Number Publication Date
WO1998030661A1 true WO1998030661A1 (de) 1998-07-16

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Application Number Title Priority Date Filing Date
PCT/EP1998/000016 Ceased WO1998030661A1 (de) 1997-01-09 1998-01-03 Verfahren zur reinigung von oberflächen

Country Status (11)

Country Link
US (1) US6387189B1 (https=)
EP (1) EP0970167B1 (https=)
JP (1) JP2001507750A (https=)
KR (1) KR100494284B1 (https=)
AT (1) ATE310071T1 (https=)
AU (1) AU724604B2 (https=)
BR (1) BR9806156A (https=)
CA (1) CA2269988A1 (https=)
DE (2) DE19700493A1 (https=)
IL (1) IL129509A (https=)
WO (1) WO1998030661A1 (https=)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003022980A1 (en) * 2001-09-10 2003-03-20 Johnsondiversey, Inc. Cleaning composition and method for using the same
EP1362512A1 (de) * 2002-05-17 2003-11-19 Goldschmidt AG Wässrige Desinfektionsmittel auf Basis von Alkylaminverbindungen und Aminopolycarbonsäuren
US6855576B2 (en) 2001-11-01 2005-02-15 Ngk Insulators, Ltd. Method for cleaning a ceramic member for use in a system for producing semiconductors, a cleaning agent and a combination of cleaning agents
WO2014053365A1 (de) * 2012-10-02 2014-04-10 Henkel Ag & Co. Kgaa Leistungsgesteigerte wasch- oder reinigungsmittel mit komplexbildnern i
WO2014053367A1 (de) * 2012-10-02 2014-04-10 Henkel Ag & Co. Kgaa Leistungsgesteigerte wasch- oder reinigungsmittel mit komplexbildnern ii

Families Citing this family (55)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE69740003D1 (de) 1996-12-20 2010-11-04 Siemens Water Tech Corp Reinigungsmethode
US20040052826A1 (en) * 2000-09-11 2004-03-18 Elena Fernandez-Kleinlein Cosmetic and pharmaceutical compositions and their use
AUPR421501A0 (en) 2001-04-04 2001-05-03 U.S. Filter Wastewater Group, Inc. Potting method
AUPR692401A0 (en) 2001-08-09 2001-08-30 U.S. Filter Wastewater Group, Inc. Method of cleaning membrane modules
ATE333318T1 (de) * 2001-11-16 2006-08-15 Us Filter Wastewater Group Inc Methode zur reinigung von membranen
US7247238B2 (en) 2002-02-12 2007-07-24 Siemens Water Technologies Corp. Poly(ethylene chlorotrifluoroethylene) membranes
AUPS300602A0 (en) 2002-06-18 2002-07-11 U.S. Filter Wastewater Group, Inc. Methods of minimising the effect of integrity loss in hollow fibre membrane modules
CA2501628C (en) 2002-10-10 2012-12-04 U.S. Filter Wastewater Group, Inc. A filtration and backwashing arrangement for membrane modules
AU2002953111A0 (en) 2002-12-05 2002-12-19 U. S. Filter Wastewater Group, Inc. Mixing chamber
US7250114B2 (en) * 2003-05-30 2007-07-31 Lam Research Corporation Methods of finishing quartz glass surfaces and components made by the methods
KR101115173B1 (ko) 2003-08-29 2012-02-24 지멘스 워터 테크놀로지스 코포레이션 역류
WO2005046849A1 (en) 2003-11-14 2005-05-26 U.S. Filter Wastewater Group, Inc. Improved module cleaning method
US7247210B2 (en) * 2004-02-23 2007-07-24 Ecolab Inc. Methods for treating CIP equipment and equipment for treating CIP equipment
US7392811B2 (en) * 2004-02-23 2008-07-01 Ecolab Inc. Delivery head for multiple phase treatment composition, vessel including a delivery head, and method for treating a vessel interior surface
US7220358B2 (en) * 2004-02-23 2007-05-22 Ecolab Inc. Methods for treating membranes and separation facilities and membrane treatment composition
WO2005092799A1 (en) 2004-03-26 2005-10-06 U.S. Filter Wastewater Group, Inc. Process and apparatus for purifying impure water using microfiltration or ultrafiltration in combination with reverse osmosis
AU2005240524C1 (en) 2004-04-22 2009-12-24 Evoqua Water Technologies Llc Filtration apparatus comprising a membrane bioreactor and a treatment vessel for digesting organic materials
NZ588094A (en) 2004-08-20 2012-04-27 Siemens Water Tech Corp Potting head for hollow fibre filter module
US8790515B2 (en) 2004-09-07 2014-07-29 Evoqua Water Technologies Llc Reduction of backwash liquid waste
AU2005284677B2 (en) 2004-09-14 2010-12-23 Evoqua Water Technologies Llc Methods and apparatus for removing solids from a membrane module
NZ553771A (en) 2004-09-15 2010-11-26 Siemens Water Tech Corp Continuously variable aeration of membrane filtration system and flow control device when used in such application
US7591950B2 (en) 2004-11-02 2009-09-22 Siemens Water Technologies Corp. Submerged cross-flow filtration
DE102004053015A1 (de) * 2004-11-03 2006-05-04 Lanxess Deutschland Gmbh Rußreiniger
ZA200703570B (en) * 2004-11-03 2008-08-27 Johnson Diversey Inc Method of cleaning containers for recycling
US8758622B2 (en) 2004-12-24 2014-06-24 Evoqua Water Technologies Llc Simple gas scouring method and apparatus
NZ583228A (en) 2004-12-24 2012-05-25 Siemens Industry Inc Cleaning in membrane filtration systems
NZ562786A (en) 2005-04-29 2010-10-29 Siemens Water Tech Corp Chemical clean for membrane filter
SG140229A1 (en) 2005-08-22 2008-03-28 Siemens Water Tech Corp An assembly for water filtration using a tube manifold to minimise backwash
WO2007044345A2 (en) 2005-10-05 2007-04-19 Siemens Water Technologies Corp. Method and apparatus for treating wastewater
WO2007044415A2 (en) 2005-10-05 2007-04-19 Siemens Water Technologies Corp. Method and apparatus for treating wastewater
US7455765B2 (en) 2006-01-25 2008-11-25 Siemens Water Technologies Corp. Wastewater treatment system and method
US8293098B2 (en) 2006-10-24 2012-10-23 Siemens Industry, Inc. Infiltration/inflow control for membrane bioreactor
US8318028B2 (en) 2007-04-02 2012-11-27 Siemens Industry, Inc. Infiltration/inflow control for membrane bioreactor
US9764288B2 (en) 2007-04-04 2017-09-19 Evoqua Water Technologies Llc Membrane module protection
EP2463017A1 (en) 2007-05-29 2012-06-13 Siemens Industry, Inc. Membrane cleaning with pulsed airlift pump
DE102008010750B4 (de) 2008-02-21 2010-02-18 Engel Oberflächentechnik GmbH Anordnung und Verfahren zur Reinigung von Solarkollektoren
CN102112213B (zh) 2008-07-24 2016-08-03 伊沃夸水处理技术有限责任公司 用于膜过滤模块的框架系统
JP2012500117A (ja) 2008-08-20 2012-01-05 シーメンス ウォーター テクノロジース コーポレイション 膜濾過システムの逆洗エネルギ効率の改善
AU2010101488B4 (en) 2009-06-11 2013-05-02 Evoqua Water Technologies Llc Methods for cleaning a porous polymeric membrane and a kit for cleaning a porous polymeric membrane
CN102869432B (zh) 2010-04-30 2016-02-03 伊沃夸水处理技术有限责任公司 流体流分配装置
US9022224B2 (en) 2010-09-24 2015-05-05 Evoqua Water Technologies Llc Fluid control manifold for membrane filtration system
JP2014528354A (ja) 2011-09-30 2014-10-27 エヴォクア ウォーター テクノロジーズ エルエルシーＥｖｏｑｕａ Ｗａｔｅｒ Ｔｅｃｈｎｏｌｏｇｉｅｓｌｌｃ 隔離バルブ
CN103958024B (zh) 2011-09-30 2016-07-06 伊沃夸水处理技术有限责任公司 改进的歧管排列
AU2013280452B2 (en) 2012-06-28 2017-07-20 Evoqua Water Technologies Llc A potting method
DE112013004713T5 (de) 2012-09-26 2015-07-23 Evoqua Water Technologies Llc Membransicherungsvorrichtung
AU2013231145B2 (en) 2012-09-26 2017-08-17 Evoqua Water Technologies Llc Membrane potting methods
KR20150059788A (ko) 2012-09-27 2015-06-02 에보쿠아 워터 테크놀로지스 엘엘씨 침지된 막을 위한 가스 스코어링 장치
HUE061765T2 (hu) 2013-10-02 2023-08-28 Rohm & Haas Electronic Mat Singapore Pte Ltd Berendezés membrán filtrációs modul javítására
JP6090362B2 (ja) * 2015-05-20 2017-03-08 栗田工業株式会社 ポリアミド系逆浸透膜の洗浄液、および洗浄方法
WO2017011068A1 (en) 2015-07-14 2017-01-19 Evoqua Water Technologies Llc Aeration device for filtration system
JP6090376B2 (ja) * 2015-07-27 2017-03-08 栗田工業株式会社 水処理用ポリアミド系逆浸透膜用洗浄剤、洗浄液、および洗浄方法
JP6090377B2 (ja) * 2015-07-27 2017-03-08 栗田工業株式会社 水処理用ポリアミド系逆浸透膜用洗浄剤、洗浄液、および洗浄方法
EP3500657A1 (en) 2016-08-16 2019-06-26 Diversey, Inc. A composition for aesthetic improvement of food and beverage containers and methods thereof
AR112957A1 (es) 2017-09-29 2020-01-08 Ecolab Usa Inc Proceso de limpieza de membrana
US11738310B2 (en) * 2019-12-31 2023-08-29 Industrial Technology Research Institute Method for cleaning membrane

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0261874A2 (en) * 1986-09-22 1988-03-30 The Procter & Gamble Company Concentrated hard-surface cleaning compositions
US4808328A (en) * 1987-05-08 1989-02-28 Joseph N. Cooper Iodine-based antiseptic cleanser composition
DE3739610A1 (de) * 1987-11-23 1989-06-01 Basf Ag Nitrilo-di-aepfel-mono-essigsaeuren, verfahren zu ihrer herstellung und ihre verwendung
EP0513948A2 (en) * 1991-05-15 1992-11-19 Hampshire Chemical Corporation Hard-surface cleaning compositions containing biodegradable chelants
EP0561464A1 (en) * 1992-03-20 1993-09-22 Unilever N.V. Polyaminoacids as builder for rinse aid compositions
US5318726A (en) * 1990-08-02 1994-06-07 Henkel Kommanditgesellschaft Auf Aktien Derivative of aminosuccinic acid as a complexing agent
WO1995016767A1 (en) * 1993-12-14 1995-06-22 The Procter & Gamble Company Liquid laundry detergents containing polyamino acid and polyalkylene glycol
EP0757094A2 (de) * 1995-07-31 1997-02-05 Bayer Ag Wasch- und Reinigungsmittel mit Iminodisuccinaten

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1306331A (https=) 1970-12-07 1973-02-07
SU639863A1 (ru) 1977-06-16 1978-12-30 Калининский Ордена Трудового Красного Знамени Политехнический Институт Калининский Сельско-Хозяйственный Институт Способ получени комплексона-иминоди нтарной кислоты
DE3626672A1 (de) 1986-08-07 1988-02-11 Bayer Ag Polyasparaginamidsaeure
US5288783A (en) 1992-05-14 1994-02-22 Srchem Incorporated Preparation of salt of polyaspartic acid by high temperature reaction
JPH06330020A (ja) 1993-05-20 1994-11-29 Nippon Shokubai Co Ltd キレート性組成物及びその製法並びに洗剤組成物
JP3326867B2 (ja) 1993-05-24 2002-09-24 株式会社日本触媒 イミノジコハク酸金属塩の製造方法
DE4322410A1 (de) 1993-07-06 1995-01-12 Bayer Ag Verfahren zur Herstellung von Polysuccinimid und Polyasparaginsäure
US5703033A (en) * 1996-02-06 1997-12-30 The Procter & Gamble Company Low sudsing, low streaking and filming hard surface cleaners

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0261874A2 (en) * 1986-09-22 1988-03-30 The Procter & Gamble Company Concentrated hard-surface cleaning compositions
US4808328A (en) * 1987-05-08 1989-02-28 Joseph N. Cooper Iodine-based antiseptic cleanser composition
DE3739610A1 (de) * 1987-11-23 1989-06-01 Basf Ag Nitrilo-di-aepfel-mono-essigsaeuren, verfahren zu ihrer herstellung und ihre verwendung
US5318726A (en) * 1990-08-02 1994-06-07 Henkel Kommanditgesellschaft Auf Aktien Derivative of aminosuccinic acid as a complexing agent
EP0513948A2 (en) * 1991-05-15 1992-11-19 Hampshire Chemical Corporation Hard-surface cleaning compositions containing biodegradable chelants
EP0561464A1 (en) * 1992-03-20 1993-09-22 Unilever N.V. Polyaminoacids as builder for rinse aid compositions
WO1995016767A1 (en) * 1993-12-14 1995-06-22 The Procter & Gamble Company Liquid laundry detergents containing polyamino acid and polyalkylene glycol
EP0757094A2 (de) * 1995-07-31 1997-02-05 Bayer Ag Wasch- und Reinigungsmittel mit Iminodisuccinaten

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003022980A1 (en) * 2001-09-10 2003-03-20 Johnsondiversey, Inc. Cleaning composition and method for using the same
US6855576B2 (en) 2001-11-01 2005-02-15 Ngk Insulators, Ltd. Method for cleaning a ceramic member for use in a system for producing semiconductors, a cleaning agent and a combination of cleaning agents
US7211156B2 (en) 2001-11-01 2007-05-01 Ngk Insulators, Ltd. Method for cleaning a ceramic member for use in a system for producing semiconductors, a cleaning agent and a combination of cleaning agents
EP1362512A1 (de) * 2002-05-17 2003-11-19 Goldschmidt AG Wässrige Desinfektionsmittel auf Basis von Alkylaminverbindungen und Aminopolycarbonsäuren
WO2014053365A1 (de) * 2012-10-02 2014-04-10 Henkel Ag & Co. Kgaa Leistungsgesteigerte wasch- oder reinigungsmittel mit komplexbildnern i
WO2014053367A1 (de) * 2012-10-02 2014-04-10 Henkel Ag & Co. Kgaa Leistungsgesteigerte wasch- oder reinigungsmittel mit komplexbildnern ii

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IL129509A0 (en) 2000-02-29
DE19700493A1 (de) 1998-07-16
EP0970167B1 (de) 2005-11-16
ATE310071T1 (de) 2005-12-15
AU724604B2 (en) 2000-09-28
US6387189B1 (en) 2002-05-14
DE59813197D1 (de) 2005-12-22
KR20000068729A (ko) 2000-11-25
AU6207098A (en) 1998-08-03
CA2269988A1 (en) 1998-07-16
BR9806156A (pt) 1999-10-19
EP0970167A1 (de) 2000-01-12
IL129509A (en) 2003-02-12
JP2001507750A (ja) 2001-06-12

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