WO1998020000A3 - Substituierte 3-benzylpyrazole und ihre verwendung als herbizide und zur senkung des blutzuckergehaltes - Google Patents

Substituierte 3-benzylpyrazole und ihre verwendung als herbizide und zur senkung des blutzuckergehaltes Download PDF

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Publication number
WO1998020000A3
WO1998020000A3 PCT/EP1997/006057 EP9706057W WO9820000A3 WO 1998020000 A3 WO1998020000 A3 WO 1998020000A3 EP 9706057 W EP9706057 W EP 9706057W WO 9820000 A3 WO9820000 A3 WO 9820000A3
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WIPO (PCT)
Prior art keywords
alkyl
halogen
stands
sulfonyl
iic
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PCT/EP1997/006057
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English (en)
French (fr)
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WO1998020000A2 (de
Inventor
Cyrill Zagar
Gerhard Hamprecht
Markus Menges
Olaf Menke
Peter Shaefer
Karl-Otto Westphalen
Ulf Misslitz
Helmut Walter
Robert Reinhard
Robert Brian Jones
Original Assignee
Basf Ag
Cyrill Zagar
Gerhard Hamprecht
Markus Menges
Olaf Menke
Peter Shaefer
Westphalen Karl Otto
Ulf Misslitz
Helmut Walter
Robert Reinhard
Robert Brian Jones
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Basf Ag, Cyrill Zagar, Gerhard Hamprecht, Markus Menges, Olaf Menke, Peter Shaefer, Westphalen Karl Otto, Ulf Misslitz, Helmut Walter, Robert Reinhard, Robert Brian Jones filed Critical Basf Ag
Priority to US09/297,529 priority Critical patent/US6451734B1/en
Priority to JP52103998A priority patent/JP2001503421A/ja
Priority to CA002270545A priority patent/CA2270545A1/en
Priority to AU70017/98A priority patent/AU7001798A/en
Priority to EP97948864A priority patent/EP0937046A2/de
Publication of WO1998020000A2 publication Critical patent/WO1998020000A2/de
Publication of WO1998020000A3 publication Critical patent/WO1998020000A3/de

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/10—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a carbon chain containing aromatic rings
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P3/00—Drugs for disorders of the metabolism
    • A61P3/08—Drugs for disorders of the metabolism for glucose homeostasis
    • A61P3/10—Drugs for disorders of the metabolism for glucose homeostasis for hyperglycaemia, e.g. antidiabetics
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
    • C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D231/18—One oxygen or sulfur atom
    • C07D231/20—One oxygen atom attached in position 3 or 5
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/12—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a chain containing hetero atoms as chain links
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D403/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00
    • C07D403/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing two hetero rings
    • C07D403/10—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing two hetero rings linked by a carbon chain containing aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D403/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00
    • C07D403/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing two hetero rings
    • C07D403/12—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing two hetero rings linked by a chain containing hetero atoms as chain links
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D405/00—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom
    • C07D405/02—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings
    • C07D405/12—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings linked by a chain containing hetero atoms as chain links

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Diabetes (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
  • Engineering & Computer Science (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • Hematology (AREA)
  • Obesity (AREA)
  • Emergency Medicine (AREA)
  • General Chemical & Material Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Endocrinology (AREA)
  • Pharmacology & Pharmacy (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

Abstract

Substituierte 3-Benzylpyrazole (I), deren Vorprodukte (IIa), (IIb), (IIc) und Nebenprodukte (III), sowie deren Salze, wobei R1 = H, C¿1?-C4-Alkyl, C1-C4-Halogenalkyl, C1-C4-Alkylsulfonyl, C1-C4-Halogenalkylsulfonyl; R?2 = C¿1-C4-Alkyl, C1-C4-Halogenalkyl, C1-C4-Alkoxy, C1-C4-Halogenalkoxy, C1-C4-Alkylthio, C1-C4-Halogenalkylthio, C1-C4-Alkylsulfinyl, C1-C4-Halogenalkylsulfinyl, C1-C4-Alkylsulfonyl, C1-C4-Halogenalkylsulfonyl; R3 = H, CN, NO¿2?, Halogen, C1-C4-Alkyl, C1-C4-Halogenalkyl; X?1 - X5¿ = chemische Bindung, gegebenenfalls substituierte Methylen-, Ethylen-, Ethen-1,2-diyl- oder über das Heteroatom an den Phenylring gebundene Oxymethylen- oder Thiamethylen-Kette; R4 - R8 = H, CN, NO¿2?, Halogen, -O-Y?1-R9¿, -O-CO-Y?1-R9, -N(Y1-R9) (Y2-R10), -N(Y1-R9)-SO¿2-Y2-R10, -N(SO¿2?-Y?1-R9) (SO¿2-Y?2-R10), -N(Y1-R9)-CO-Y2-R10, -N(Y1-R9) (O-Y2-R10), -S-Y1-R9, -SO-Y1-R9, -SO¿2-Y?1-R9, -SO¿2-O-Y?1-R9, -SO¿2-N(Y?1-R9) (Y2-R10¿), -CO-Y1-R9, -C(=NOR?11)-Y1-R9¿, -C(=NOR?11)-O-Y1-R9¿, -C(=NOR11)-CO-O-Y1-R9, -CO-O-Y1-R9, -CO-S-Y1-R9, -CO-N(Y?1-R9) (Y2-R10¿), -CO-N(Y?1R9) (O-Y2-R10); R12 = C¿1-C4-Alkyl, C1-C4-Halogenalkyl; Verwendung: (I) als Herbizide; zur Desikkation/Defoliation von Pflanzen; (I), (IIa), (IIb), (IIc) und (III) zur Senkung des Blutzuckergehaltes.
PCT/EP1997/006057 1996-11-04 1997-11-03 Substituierte 3-benzylpyrazole und ihre verwendung als herbizide und zur senkung des blutzuckergehaltes WO1998020000A2 (de)

Priority Applications (5)

Application Number Priority Date Filing Date Title
US09/297,529 US6451734B1 (en) 1996-11-04 1997-11-03 Substituted 3-benzylpyrazoles and their use as herbicides
JP52103998A JP2001503421A (ja) 1996-11-04 1997-11-03 置換３―ベンジルピラゾール
CA002270545A CA2270545A1 (en) 1996-11-04 1997-11-03 Substituted 3-benzylpyrazoles and their use as herbicides and for lowering the sugar content in blood
AU70017/98A AU7001798A (en) 1996-11-04 1997-11-03 Substituted 3-benzylpyrazoles and their use as herbicides and for lowering the sugar content in blood
EP97948864A EP0937046A2 (de) 1996-11-04 1997-11-03 Substituierte 3-benzylpyrazole und ihre verwendung als herbizide und zur senkung des blutzuckergehaltes

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19645313.5 1996-11-04
DE19645313A DE19645313A1 (de) 1996-11-04 1996-11-04 Substituierte 3-Benzylpyrazole

Publications (2)

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WO1998020000A2 WO1998020000A2 (de) 1998-05-14
WO1998020000A3 true WO1998020000A3 (de) 1998-10-29

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PCT/EP1997/006057 WO1998020000A2 (de) 1996-11-04 1997-11-03 Substituierte 3-benzylpyrazole und ihre verwendung als herbizide und zur senkung des blutzuckergehaltes

Country Status (7)

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US (1) US6451734B1 (de)
EP (1) EP0937046A2 (de)
JP (1) JP2001503421A (de)
AU (1) AU7001798A (de)
CA (1) CA2270545A1 (de)
DE (1) DE19645313A1 (de)
WO (1) WO1998020000A2 (de)

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Publication number Priority date Publication date Assignee Title
SG171307A1 (en) * 2008-11-21 2011-07-28 Glaxosmithkline Llc Chemical process
WO2010127067A1 (en) * 2009-04-30 2010-11-04 Glaxosmithkline Llc Chemical process

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US6451734B1 (en) 2002-09-17
EP0937046A2 (de) 1999-08-25
JP2001503421A (ja) 2001-03-13
AU7001798A (en) 1998-05-29
WO1998020000A2 (de) 1998-05-14
DE19645313A1 (de) 1998-05-07
CA2270545A1 (en) 1998-05-14

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