WO1998005713B1 - Compositions faibles de bromine isobutylene-co-4-bromomethylstyrene pour contraintes lourdes dans les applications elastomeres - Google Patents
Compositions faibles de bromine isobutylene-co-4-bromomethylstyrene pour contraintes lourdes dans les applications elastomeresInfo
- Publication number
- WO1998005713B1 WO1998005713B1 PCT/US1997/013474 US9713474W WO9805713B1 WO 1998005713 B1 WO1998005713 B1 WO 1998005713B1 US 9713474 W US9713474 W US 9713474W WO 9805713 B1 WO9805713 B1 WO 9805713B1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- bromomethylstyrene
- phr
- isobutylene
- poly
- mole percent
- Prior art date
Links
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 title claims abstract 8
- WKBOTKDWSSQWDR-UHFFFAOYSA-N bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 title claims abstract 8
- 239000000203 mixture Substances 0.000 title claims 6
- 229920001971 elastomer Polymers 0.000 title 1
- 239000000806 elastomer Substances 0.000 title 1
- XLOMVQKBTHCTTD-UHFFFAOYSA-N zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract 14
- AKHNMLFCWUSKQB-UHFFFAOYSA-L Sodium thiosulphate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 claims abstract 7
- 235000019345 sodium thiosulphate Nutrition 0.000 claims abstract 7
- 239000011787 zinc oxide Substances 0.000 claims abstract 7
- 125000001743 benzylic group Chemical group 0.000 claims abstract 6
- 210000003932 Urinary Bladder Anatomy 0.000 claims abstract 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N Stearic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims 4
- 235000014113 dietary fatty acids Nutrition 0.000 claims 4
- 239000000194 fatty acid Substances 0.000 claims 4
- 150000004665 fatty acids Chemical class 0.000 claims 4
- RUROFEVDCUGKHD-UHFFFAOYSA-N 3-bromoprop-1-enylbenzene Chemical compound BrCC=CC1=CC=CC=C1 RUROFEVDCUGKHD-UHFFFAOYSA-N 0.000 claims 2
- 235000021355 Stearic acid Nutrition 0.000 claims 2
- 229910052751 metal Inorganic materials 0.000 claims 2
- 239000002184 metal Substances 0.000 claims 2
- 150000003839 salts Chemical class 0.000 claims 2
- 239000011780 sodium chloride Substances 0.000 claims 2
- 239000008117 stearic acid Substances 0.000 claims 2
- XYLMUPLGERFSHI-UHFFFAOYSA-N α-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 claims 2
- VTPQLJUADNBKRM-UHFFFAOYSA-N 1-(bromomethyl)-4-ethenylbenzene Chemical compound BrCC1=CC=C(C=C)C=C1 VTPQLJUADNBKRM-UHFFFAOYSA-N 0.000 claims 1
- 229920001577 copolymer Polymers 0.000 claims 1
- 238000010438 heat treatment Methods 0.000 claims 1
- 229920000642 polymer Polymers 0.000 claims 1
- 229920005555 halobutyl Polymers 0.000 abstract 1
- 125000004968 halobutyl group Chemical group 0.000 abstract 1
Abstract
Enveloppes de réparation de pneus fabriquées dans du poly(isobutylène-co-4-bromométhylstyrène) à contenu bromine benzylique de 0,15 à 0,45 molécule-gramme en pourcentage, vulcanisé par un agent de vulcanisation de 1,6-hexaméthylène-bis(sodium thiosulfate) et de l'oxyde de zinc. Le vulcanisât possède un contenu bromine benzylique résiduel faible conduisant à une stabilité renforcée sous des applications de charges lourdes, à une tension thermique réduite et à une adhérence réduite ou co-curative des gommes intérieures halobutylées du pneumatique.
Priority Applications (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EA199900155A EA199900155A1 (ru) | 1996-08-01 | 1997-07-28 | Композиция изобутилен-4-бромметилстирольного сополимера с низким содержанием брома в качестве эластомера для применения в жестких условиях |
| EP97937073A EP0915932A2 (fr) | 1996-08-01 | 1997-07-28 | Compositions faibles de bromine isobutylene-co-4-bromomethylstyrene pour contraintes lourdes dans les applications elastomeres |
| PL97331386A PL331386A1 (en) | 1996-08-01 | 1997-07-28 | Composition of isobutylene copolymer with 4-bromomethylstyrene of low bromine content for elastomeric applications requiring elastomers capable to withstand high loads |
| AT0908697A AT410093B (de) | 1996-08-01 | 1997-07-28 | Vulkanisierbare mischung von poly(isobutylen-co-4-brommethylstyrol) und einer vulkanisierpackung, verfahren zum vulkanisieren und vulkanisat sowie daraus hergestellte produkte |
| BR9711610A BR9711610A (pt) | 1996-08-01 | 1997-07-28 | Composi-{es de isobutileno-co-4-bromometilestireno de baixo teor de bromo para aplica-{es elastom-ricas de servi-o pesado |
| JP50805598A JP2001506286A (ja) | 1996-08-01 | 1997-07-28 | 過酷さに耐えるエラストマーの用途用の低臭素イソブチレン―４―ブロモメチルスチレンコポリマー組成物 |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/691,109 US5698640A (en) | 1996-08-01 | 1996-08-01 | Low bromine isobutylene-co-4-bromomethylstyrene compositions for severe duty elastomer applications |
| US08/691,109 | 1996-08-01 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| WO1998005713A2 WO1998005713A2 (fr) | 1998-02-12 |
| WO1998005713A3 WO1998005713A3 (fr) | 1998-03-19 |
| WO1998005713B1 true WO1998005713B1 (fr) | 1998-06-04 |
Family
ID=24775194
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/US1997/013474 WO1998005713A2 (fr) | 1996-08-01 | 1997-07-28 | Compositions faibles de bromine isobutylene-co-4-bromomethylstyrene pour contraintes lourdes dans les applications elastomeres |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US5698640A (fr) |
| EP (1) | EP0915932A2 (fr) |
| JP (1) | JP2001506286A (fr) |
| KR (1) | KR20000029670A (fr) |
| CN (1) | CN1226269A (fr) |
| AT (1) | AT410093B (fr) |
| BR (1) | BR9711610A (fr) |
| CA (1) | CA2259167A1 (fr) |
| CZ (1) | CZ432898A3 (fr) |
| EA (1) | EA199900155A1 (fr) |
| HU (1) | HUP9904493A3 (fr) |
| PL (1) | PL331386A1 (fr) |
| WO (1) | WO1998005713A2 (fr) |
Families Citing this family (31)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6448322B1 (en) * | 1997-03-06 | 2002-09-10 | Exxon Mobil Chemical Patents Inc. | Stabilization of halogenated rubber |
| US6060549A (en) * | 1997-05-20 | 2000-05-09 | Exxon Chemical Patents, Inc. | Rubber toughened thermoplastic resin nano composites |
| JP4521074B2 (ja) * | 1998-06-08 | 2010-08-11 | 株式会社ブリヂストン | ゴム組成物及びそれを用いた空気入りタイヤ |
| US6809137B2 (en) * | 1998-06-08 | 2004-10-26 | Bridgestone Corporation | Rubber composition and pneumatic tire using said rubber composition |
| CA2282900C (fr) | 1999-09-20 | 2011-02-01 | Bayer Inc. | Terpolymeres halogenes comprenant de l'isobutylene, du monomere diolefinique et du monomere styrenique |
| US7328733B2 (en) * | 1999-12-28 | 2008-02-12 | Exxonmobil Chemical Patents Inc. | Inner tube compositions having improved heat resistance characteristics |
| CA2395434C (fr) | 1999-12-28 | 2010-04-27 | Donald S. Tracey | Compositions de tube interieur presentant des caracteristiques de resistance a la chaleur amelioree |
| WO2002032993A2 (fr) * | 2000-10-18 | 2002-04-25 | Exxonmobil Chemical Patents Inc. | Composition d'elastomere |
| US7425591B2 (en) * | 2001-10-16 | 2008-09-16 | Exxonmobil Chemical Patents Inc | Elastomeric composition |
| EP1357831A2 (fr) * | 2001-02-09 | 2003-11-05 | Sensomotoric Instruments GmbH | Systeme de mesure de position de l'oeil et de poursuite oculaire a dimensions multiples pour le diagnostic et le traitement de l'oeil |
| WO2002098984A1 (fr) * | 2001-06-04 | 2002-12-12 | Exxonmbil Chemical Patents Inc. | Revetements de protection pour conduits et citernes |
| US7282269B2 (en) | 2001-06-04 | 2007-10-16 | Exxonmobil Chemical Patents Inc. | Cured rubber components for use with pharmaceutical devices |
| RU2003137562A (ru) | 2001-06-08 | 2005-05-20 | Эксонмобил Кемикэл Пейтентс Инк. (Us) | Нанокомпозиты с низкой проницаемостью |
| CN1268673C (zh) | 2001-06-13 | 2006-08-09 | 埃克森美孚化学专利公司 | 低渗透性纳米复合材料 |
| US6939921B2 (en) * | 2001-10-16 | 2005-09-06 | Exxonmobil Chemical Patents Inc. | Colorable elastomeric composition |
| US20040030036A1 (en) * | 2001-10-16 | 2004-02-12 | Waddell Walter H. | Elastomeric composition |
| WO2003054032A1 (fr) * | 2001-12-10 | 2003-07-03 | Exxonmobil Chemical Patents Inc. | Compositions elastomeres |
| US7329697B2 (en) * | 2001-12-10 | 2008-02-12 | Exxonmobil Chemical Patents Inc. | Elastomeric compositions |
| US20040249085A1 (en) * | 2001-12-10 | 2004-12-09 | Waddell Walter Harvey | Halogenated isoolefin based terpolymers |
| US7060757B2 (en) * | 2003-02-06 | 2006-06-13 | Bridgestone Corporation | Rubber composition and pneumatic tire using the same |
| US7605205B2 (en) * | 2005-11-07 | 2009-10-20 | Exxonmobil Chemical Patents, Inc. | Nanocomposite compositions and processes for making the same |
| CA2633491C (fr) * | 2005-12-05 | 2011-06-07 | Exxonmobil Chemical Patents Inc. | Auxiliaires de transformation pour compositions elastomeres |
| JP5421525B2 (ja) * | 2007-10-19 | 2014-02-19 | 住友ゴム工業株式会社 | ブラダー用ゴム組成物およびそれを用いたタイヤ加硫用ブラダー |
| US7923491B2 (en) * | 2008-08-08 | 2011-04-12 | Exxonmobil Chemical Patents Inc. | Graphite nanocomposites |
| US20110060086A1 (en) * | 2009-09-10 | 2011-03-10 | Michael Brendan Rodgers | Elastomeric Copolymers, Copolymer Compositions, and Their Use in Articles |
| US8415431B2 (en) | 2010-08-05 | 2013-04-09 | Exxonmobil Chemical Patents Inc. | Thermoplastic elastomeric compositions |
| JP7143604B2 (ja) * | 2018-03-22 | 2022-09-29 | 住友ゴム工業株式会社 | 加硫ブラダー用ゴム組成物及び加硫ブラダー |
| EP3814124A1 (fr) * | 2018-06-27 | 2021-05-05 | ExxonMobil Chemical Patents Inc. | Vessies de vulcanisation d'élastomère d'isobutylène et de paraméthyl-styrène bromé |
| JP2021095445A (ja) * | 2019-12-13 | 2021-06-24 | Ｔｏｙｏ Ｔｉｒｅ株式会社 | インナーライナー用ゴム組成物、及びそれを用いた空気入りタイヤ |
| CN114106477B (zh) * | 2020-09-01 | 2023-07-21 | 中国石油化工股份有限公司 | 用于丁基橡胶封口塞的橡胶基体、组合物、硫化胶及其制备方法 |
| CN118414379A (zh) | 2021-12-21 | 2024-07-30 | 埃克森美孚化学专利公司 | 组合物、硫化橡胶和硫化方法 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5162445A (en) * | 1988-05-27 | 1992-11-10 | Exxon Chemical Patents Inc. | Para-alkylstyrene/isoolefin copolymers and functionalized copolymers thereof |
| US5013793A (en) * | 1990-07-26 | 1991-05-07 | Exxon Chemical Patents Inc. | Dynamically cured thermoplastic olefin polymers and process for producing the same |
| US5246778A (en) * | 1990-05-14 | 1993-09-21 | Exxon Chemical Patents Inc. | Hose composition |
| US5063268A (en) * | 1990-06-08 | 1991-11-05 | Exxon Chemical Patents Inc. | Composition for tire treads (E-235) |
| DE69412399T2 (de) * | 1993-09-10 | 1999-01-21 | R.T. Vanderbilt Co., Inc., Norwalk, Conn. | Härtersystem für halogenierte Elastomere |
| US5504164A (en) * | 1994-05-03 | 1996-04-02 | Exxon Chemical Patents Inc. | Curing systems for compositions containing halogenated copolymers of isobutylene and para-methylstrene |
| US5538218A (en) * | 1994-09-28 | 1996-07-23 | The Goodyear Tire & Rubber Company | Tire curing bladder with improved release from the tire innerliner |
| US6207764B1 (en) * | 1995-04-26 | 2001-03-27 | Monsanto Company | Halogenated elastomer compositions |
-
1996
- 1996-08-01 US US08/691,109 patent/US5698640A/en not_active Expired - Fee Related
-
1997
- 1997-07-28 CA CA002259167A patent/CA2259167A1/fr not_active Abandoned
- 1997-07-28 PL PL97331386A patent/PL331386A1/xx unknown
- 1997-07-28 EP EP97937073A patent/EP0915932A2/fr not_active Withdrawn
- 1997-07-28 KR KR1019997000748A patent/KR20000029670A/ko not_active Application Discontinuation
- 1997-07-28 HU HU9904493A patent/HUP9904493A3/hu unknown
- 1997-07-28 JP JP50805598A patent/JP2001506286A/ja active Pending
- 1997-07-28 AT AT0908697A patent/AT410093B/de not_active IP Right Cessation
- 1997-07-28 BR BR9711610A patent/BR9711610A/pt unknown
- 1997-07-28 CN CN97196826A patent/CN1226269A/zh active Pending
- 1997-07-28 WO PCT/US1997/013474 patent/WO1998005713A2/fr not_active Application Discontinuation
- 1997-07-28 CZ CZ984328A patent/CZ432898A3/cs unknown
- 1997-07-28 EA EA199900155A patent/EA199900155A1/ru unknown
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| WO1998005713B1 (fr) | Compositions faibles de bromine isobutylene-co-4-bromomethylstyrene pour contraintes lourdes dans les applications elastomeres | |
| US5698640A (en) | Low bromine isobutylene-co-4-bromomethylstyrene compositions for severe duty elastomer applications | |
| EP0376558B1 (fr) | Récipients imperméables à l'air | |
| RU2008121213A (ru) | Конструкция, включающая соединительный слой | |
| CA2688501A1 (fr) | Elastomeres d'iso-olefine halogenes durcissables, charges et pouvant etre traites | |
| JP3323921B2 (ja) | 熱可塑性材料の様に加工できる架橋エラストマー、その製造方法及びその用途 | |
| EP0560182B1 (fr) | Pneumatique et composition de caoutchouc pour couche de base de la bande de roulement | |
| JPH08500385A (ja) | ホース組成物 | |
| EP2033989B1 (fr) | Systèmes de durcissement plus sûrs pour des composés de caoutchoucs acryliques | |
| US3712360A (en) | Production of composite vehicle tires by covulcanization of layers of olefin terpolymers and natural rubber | |
| CN101977781A (zh) | 层合材料和使用该层合材料的充气轮胎 | |
| EP0785056A3 (fr) | Vessie de vulcanisation contenant de la poudre de polytétrafluoréthylène et son utilisation | |
| CA2395434C (fr) | Compositions de tube interieur presentant des caracteristiques de resistance a la chaleur amelioree | |
| KR937000596A (ko) | 호스 조성물 | |
| JPH10182896A (ja) | 吹込み成形可能な動的に加硫されたアロイ | |
| EP0801106A1 (fr) | Pneumatique avec faces caoutchouteuses | |
| JPH10130441A (ja) | 加硫用ブラダー用ゴム組成物 | |
| KR960002978B1 (ko) | 타이어 인너라이너용 고무 조성물 | |
| JPH0649284A (ja) | エチレンアクリルゴム組成物 | |
| JP2005054049A (ja) | ゴム組成物及びそれを用いたタイヤ加硫用ブラダー | |
| JPS6234264B2 (fr) | ||
| KR0180700B1 (ko) | 공기압타이어의 인너라이너용 고무조성물 | |
| MXPA99001101A (en) | Low bromine isobutylene-co | |
| JPH0945106A (ja) | ランプ構造体およびその製造方法 | |
| KR20040002079A (ko) | 파워스티어링용 고무 호스 조성물 |