WO1998004149A1 - Confiseries glacees composites - Google Patents

Confiseries glacees composites Download PDF

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Publication number
WO1998004149A1
WO1998004149A1 PCT/EP1997/003720 EP9703720W WO9804149A1 WO 1998004149 A1 WO1998004149 A1 WO 1998004149A1 EP 9703720 W EP9703720 W EP 9703720W WO 9804149 A1 WO9804149 A1 WO 9804149A1
Authority
WO
WIPO (PCT)
Prior art keywords
ice
water ice
water
confection
solution
Prior art date
Application number
PCT/EP1997/003720
Other languages
English (en)
Inventor
Donald Reginald Biggs
David Robert Graham Cox
Susan Elaine Jones
Paul Harvey Richardson
Original Assignee
Unilever Plc
Unilever N.V.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from GBGB9700231.5A external-priority patent/GB9700231D0/en
Application filed by Unilever Plc, Unilever N.V. filed Critical Unilever Plc
Priority to CA002261800A priority Critical patent/CA2261800A1/fr
Priority to SK109-99A priority patent/SK10999A3/sk
Priority to BR9710593-7A priority patent/BR9710593A/pt
Priority to PL97331484A priority patent/PL331484A1/xx
Priority to IL12824197A priority patent/IL128241A/en
Priority to GB9901509A priority patent/GB2331003B/en
Priority to EP97936639A priority patent/EP0963162A1/fr
Priority to AU39401/97A priority patent/AU713953B2/en
Priority to DE19781893T priority patent/DE19781893D2/de
Publication of WO1998004149A1 publication Critical patent/WO1998004149A1/fr

Links

Classifications

    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G9/00—Frozen sweets, e.g. ice confectionery, ice-cream; Mixtures therefor
    • A23G9/32—Frozen sweets, e.g. ice confectionery, ice-cream; Mixtures therefor characterised by the composition containing organic or inorganic compounds
    • A23G9/34—Frozen sweets, e.g. ice confectionery, ice-cream; Mixtures therefor characterised by the composition containing organic or inorganic compounds characterised by carbohydrates used, e.g. polysaccharides
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G7/00—Other apparatus or process specially adapted for the chocolate or confectionery industry
    • A23G7/02—Cooling or drying apparatus
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G9/00—Frozen sweets, e.g. ice confectionery, ice-cream; Mixtures therefor
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G9/00—Frozen sweets, e.g. ice confectionery, ice-cream; Mixtures therefor
    • A23G9/04—Production of frozen sweets, e.g. ice-cream
    • A23G9/22—Details, component parts or accessories of apparatus insofar as not peculiar to a single one of the preceding groups
    • A23G9/24—Details, component parts or accessories of apparatus insofar as not peculiar to a single one of the preceding groups for coating or filling the products
    • A23G9/245—Details, component parts or accessories of apparatus insofar as not peculiar to a single one of the preceding groups for coating or filling the products for coating the products
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G9/00—Frozen sweets, e.g. ice confectionery, ice-cream; Mixtures therefor
    • A23G9/04—Production of frozen sweets, e.g. ice-cream
    • A23G9/22—Details, component parts or accessories of apparatus insofar as not peculiar to a single one of the preceding groups
    • A23G9/26—Details, component parts or accessories of apparatus insofar as not peculiar to a single one of the preceding groups for producing frozen sweets on sticks
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23G—COCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G9/00—Frozen sweets, e.g. ice confectionery, ice-cream; Mixtures therefor
    • A23G9/44—Frozen sweets, e.g. ice confectionery, ice-cream; Mixtures therefor characterised by shape, structure or physical form
    • A23G9/48—Composite products, e.g. layered, laminated, coated, filled

Definitions

  • the invention relates to ice confections and their method of preparation.
  • the invention relates to ice confections which comprise a mass of a milk containing ice confection, for example ice cream, with at least one discrete element of water ice which is preferably present as a surface layer covering the mass of milk containing ice confection.
  • a well known ice confection on the market is a traditional split product comprising an ice cream core and an outer layer of water ice on a stick. These products are produced by filling a mould with a water ice solution, cooling the mould such that a layer of water ice is frozen to the mould, removing the still liquid water ice solution from the centre, filling the centre with ice cream, inserting a stick and final cooling to fully freeze the product.
  • the consumer desires a soft water ice layer of high quality.
  • WO 95/20883 proposes to produce the water ice layer via a dipping process, whereby the surface of the ice cream core is pre-cooled to -15°C or below to effect the quick freezing of the water ice layer, the water ice layer is then hardened. This method indeed results in products of good quality having a soft water ice layer texture.
  • EP 500 940 discloses a process to provide a two component ice confection having a rugged surface .
  • An ice confection core is dipped into a semi-frozen ice mixture.
  • EP 560 052 discloses a process for coating a frozen confectionery product which comprises applying a gelatin sol to the confectionery product.
  • the gelatin sol may contain up to 10% gelatin and preferably contains from 1.5 to 3% by weight based on the total weight of the gelatin sol.
  • the gelatin sol is applied by a dipping process, the temperature of the sol being from 10 to 25°C during this dipping process.
  • the coated product may advantageously be re- frozen in a freezing tunnel to complete the setting process if necessary.
  • the gelatin sol must be at a relatively high temperature during the dipping process which results in some melting of the ice confection core, providing a loss of quality.
  • the finished coating has a tendency to become sticky and adhere to the paper in which the ice confection is packaged.
  • the invention relates to a process for producing an ice confection comprising a mass of milk containing ice confection and a discrete element of water ice, wherein;
  • a mass of milk containing ice confection is contacted with a water ice solution having a rheometry value of more than about 1.0 to cause the water ice solution to adhere to the mass of milk containing ice confection;
  • the water ice solution has a rheometry value of 1.1 to 1.8, more preferred 1.2 to 1.6.
  • a suitable method of measuring the rheometry value is described in the examples .
  • Suitable measures may for example be selected from variation of type and amount of solids, use of thickeners or gelling agents, inclusion of other phases e.g. aeration etc, and mixtures thereof.
  • the rheometry value will increase if the solids content of the water ice solution increases. For example a low amount of sugar in the formulation will provide low rheometry values, while an increase in sugar level will increase this parameter. Also the inclusion of high levels of fruit puree or other solids result in an increase .
  • Specific minor ingredients can also be used for increasing the rheometry value.
  • one or more thickeners or gelling agents can be used.
  • suitable ingredients are for example locust bean gum, xanthan, agar, guar, carrageenan, alginate, pectin, microcrystalline cellulose, gelatin, maltodextrin etc. Levels of these ingredients may be selected to obtain the desired rheometry values.
  • suitable levels are from 0.5 to 1.5 wt%, more preferred 0.65 to 1.2 wt% .
  • processing conditions of the water ice solution can be adapted to influence the rheometry index. For example aeration of the water ice solution may lead to a higher rheometry value .
  • the water ice solution is preferably maintained at a temperature at or below 8°C, preferably at or below 5°C.
  • the maintenance of a low temperature has two advantages . Firstly any melting of the surface of the mass of milk containing ice confection on application of the water ice solution is minimised and thus a high quality product is provided. Secondly it is hygienically advantageous to process at cooler temperatures.
  • the requirement to maintain the water ice solution at a temperature of at or below 8°C, whilst still being able to apply the water ice solution to the mass of milk containing ice confection is achieved by producing a smooth paste of the gel .
  • the smooth paste is provided by shearing the water ice mixture either during or after gelation. Examples of suitable shearing devices include scraped surface heat exchangers, stirred vessel, spray driers followed by rehydration, static mixers and colloid mills.
  • the total soluble solids level of the water ice solution is between l and 70 wt%, most preferred 2-60 wt%.
  • Low soluble solids levels may for example advantageously be used for the formulation of isotonic water ice solutions. While higher soluble solids levels result in more traditional water ice solutions.
  • the water ice solution is chosen such that it forms a smooth layer on the mass of milk containing ice confection.
  • the water ice solution is substantially liquid and does not contain ice crystals.
  • the water ice solution will be at a temperature above its freezing point.
  • the smooth layer formed on the mass of milk containing ice confection preferably has a thickness of 0.5 to 6 mm, more preferred 1 to 5, most preferred 2 to 4 mm.
  • the layer is a single layer and not a composite layer e.g. produced by multiple applications.
  • the mass of milk containing ice confection contains proteins and this class of products includes, ice cream, frozen yoghurt, sherbet, sorbet, ice milk and frozen custards.
  • the usual form of protein will be animal milk, but vegetable sources e.g. soy milk are also usable.
  • the level of fat in the mass of milk containing ice confection may vary in a broad range, for example 0-3 wt% for zero to low fat products, 3 to 6 wt% for medium fat, 6-10 wt% for creamy products and above 10wt% for super- premium products.
  • the mass of milk containing ice confection is aerated to an overrun of 30 to 300%, more preferred 40 to 200%, most preferred 50 to 150%.
  • a problem of known ice confection coatings is that they have a tendency to become sticky and adhere to the inner surface of the wrapper in which the ice confection is packaged. Thus the consumer of the product has difficulty unwrapping the product for consumption.
  • the adhered water ice solution is subjected to a rapid cooling step such that a temperature of -15°C or below is achieved throughout the water ice.
  • rapid cooling is meant that the cooling environment has a temperature of -50°C or below (inclusive of wind chill factor) , preferably -60°C or below (inclusive of wind chill factor) , most preferably -70°C or below (inclusive of wind chill factor) .
  • a liquid cryogen such as liquid nitrogen
  • the rapid cooling is achieved by dipping in liquid nitrogen.
  • the wind chill factor may be calculated using the following formulation (as used by the US National Weather Service) ;
  • T ⁇ c is the wind chill (°C)
  • T is the actual temperature (°C)
  • V is the wind speed (km/hr) . This formula is only applicable at wind speeds above about
  • the invention also provides an ice confection comprising a mass of milk containing ice confection and a discrete element of water ice, wherein the water ice is essentially non-sticky and has a composition which in the form of a water ice solution has a rheometry value of more than about 1.0.
  • the surface of the mass of milk containing ice confection has a temperature of less than -5°C when contacting with the water ice, more preferred less than -8°C, most preferred less than -10°C.
  • the temperature will be more than -40°C, more preferred more than -25°C.
  • Especially preferred for low cost production are temperatures of more than -14 °C, more preferred more than -12°C.
  • the mass of milk containing ice confection can be contacted with the water ice solution in any convenient manner, for example spraying, dipping, smearing, rolling etc. Most preferred is the dipping of the mass of milk containing ice confection into the water ice solution. Also preferably the core is provided with a stick which can act as a grip during the dipping operation.
  • the discrete element of water ice is preferably present as a layer, most preferably as a surface layer. It is particularly preferred that the water ice solution is contacted with the mass of milk containing ice confection in such a way that a water ice layer is produced which predominantly covers the mass of milk containing ice confection without leaving substantial uncoated areas .
  • Ice confections according to the invention may contain a number of optional ingredients normally present in ice cream or water ice.
  • optional ingredients are flavouring materials, emulsifier ⁇ , stabilisers, colorants etc .
  • a water ice solution having the following composition was prepared by mixing the ingredients into water at 60°C under gentle stirring:
  • pick-up amounts of approximately 20 to 50g, more preferably approximately 25 to 40g, typically correspond to rheometry values according to the invention.
  • the rheometry value can be measured as shown in Example II.
  • the rheometry value can be determined as follows:
  • a solid stainless steel cylinder having a length of 80mm and a diameter of 38 mm was provided with 1.2 pitch diamond knurl grooves of depth 0.5mm extending for 40mm along the length of the cylinder.
  • a 1.2 pitch knurl defines that the distance between the grooves is 1.2mm.
  • the diamond knurl defines that the grooves intersect to form a diamond pattern.
  • the included angle at the top and bottom apex is 60°, whilst the included angle between is 120°
  • the grooves are at an angle of 30° to the vertical.
  • the cross-section of the groove is triangular, w th a right angle at the tip.
  • the total depth is 0.5mm
  • the remaining 40mm length of the cylinder was smooth.
  • the cylinder was cooled to 2°C and the patterned end of the cylinder was dipped into the water ice solution at 2°C for 5 seconds.
  • the depth of dipping was 40 mm (i.e. for the full extent of the grooves) .
  • the bottom surface was wiped clean and the cylinder was weighed to determine the amount of water ice solution adhered to it From the surface area of the cylinder (exclusive of grooves), the weight of pick-up and the density of the water ice solution, the average layer thickness adhering to the cylinder is calculated in mm's. This is the rheometry value.
  • the surface area (excluding the grooves) is 4780mm 2 . If 7g of water ice solution of density 1.1 g cm 3 is adhered, the volume of water ice is 6360mm"'. Therefore the rheometry value is
  • An ice cream formulation was prepared of the following composition:
  • the ice cream was prepared with an overrun of 60% and extruded through a shaped nozzle to give a cylinder of 52g and a stick was inserted.
  • the ice cream was frozen in a blast freezer such that the surface temperature was -10°C.
  • the ice cream was then dipped for 5 seconds into water ice solutions at 2°C having the following formulations;
  • the adhering water ice solution was then rapidly cooled in a blast freezer operating between -32°C and -34°C (wind speed factor of 5 ms "1 ) for 15 minutes (cooling environment of the blast freezer was therefore -5l°C inclusive of wind chill factor) .
  • the rheometry value for each formulation was measured as in Example II.
  • the rheometry value was 0.8, for formulation B 1.4, and for formulation C 0.8.
  • Formulation B resulted in highly preferred products having a smooth appearance, good thickness of the single water ice layer and with a soft attractive texture.
  • Formulations A and C resulted in a layer which was too thin after the single dip in water ice solution.
  • Example III was repeated except that the ice cream was cooled to -12°C prior to dipping in the water ice solution.
  • formulation A (measured as in example I) was 11 g, while for formulation B this was 32 g and for formulation C this was I2g.
  • Formulation B resulted in highly preferred products having a smooth appearance, good thickness of the single water ice layer and with a soft attractive texture.
  • Formulations A and C resulted in a layer which was too thin after a single dip in the water ice solution.
  • a water ice solution of formulation B in Example III was produced and cooled to 2oC.
  • the water ice solution provided was a soft gel -type substance. This gel was sheared for approximately 30 seconds in a domestic blender to form a smooth flowable paste.
  • Ice cream prepared as in Example III was frozen in a blast freezer such that the surface temperature was -9°C.
  • the ice cream was then dipped for 5 seconds in the water ice solution at 3°C.
  • the adhering water ice solution was then rapidly cooled by immersion in liquid nitrogen for 12 seconds.
  • the product was then wrapped in a waxed paper wrapper and stored at -25°C.
  • the product did not significantly adhere to the wrapper.
  • Example V was repeated except that the product was not rapidly cooled after immersion in the water ice solution but cooled in a cold store at -25°C.

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Inorganic Chemistry (AREA)
  • Confectionery (AREA)

Abstract

Confiserie glacée constituée d'une masse de confiserie glacée contenant du lait et d'un élément discontinu de glace à l'eau. La glace à l'eau est sensiblement non collante et sa composition, sous forme de solution de glace à l'eau, a une rhéométrie supérieure à 1,0. La confiserie glacée comporte un élément glace à l'eau à l'italienne. Elle est fabriquée par un procédé selon lequel (i) on met en contact une masse de confiserie glacée contenant du lait avec une solution de glace à l'eau ayant une rhéométrie supérieure à 1,0 environ, de façon que ladite solution, en collant sur la masse de confiserie glacée contenant du lait, se présente au moins partiellement sous forme de glace à l'eau; et (ii) on refroidit rapidement la solution de glace à l'eau collée jusqu'à -15 °C ou au-dessous.
PCT/EP1997/003720 1996-07-26 1997-07-10 Confiseries glacees composites WO1998004149A1 (fr)

Priority Applications (9)

Application Number Priority Date Filing Date Title
CA002261800A CA2261800A1 (fr) 1996-07-26 1997-07-10 Confiseries glacees composites
SK109-99A SK10999A3 (en) 1996-07-26 1997-07-10 Composite ice confections
BR9710593-7A BR9710593A (pt) 1996-07-26 1997-07-10 Processo para produzir um confeito gelado,confeito gelado, confeito de sorvete cremosoenvolvido, e, confeito gelado dentro de umenvoltório não aderente
PL97331484A PL331484A1 (en) 1996-07-26 1997-07-10 Composite ice-cream type products
IL12824197A IL128241A (en) 1996-07-26 1997-07-10 Process for producing composite ice confections
GB9901509A GB2331003B (en) 1996-07-26 1997-07-10 Composite ice confections
EP97936639A EP0963162A1 (fr) 1997-01-08 1997-07-10 Confiseries glacees composites
AU39401/97A AU713953B2 (en) 1996-07-26 1997-07-10 Composite ice confections
DE19781893T DE19781893D2 (de) 1996-07-26 1997-07-10 Zusammengesetzte Eiszubereitungen

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
EP96305500.9 1996-07-26
EP96305500 1996-07-26
GB9700231.5 1997-01-08
GBGB9700231.5A GB9700231D0 (en) 1997-01-08 1997-01-08 Low temperature food product

Publications (1)

Publication Number Publication Date
WO1998004149A1 true WO1998004149A1 (fr) 1998-02-05

Family

ID=26143814

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP1997/003720 WO1998004149A1 (fr) 1996-07-26 1997-07-10 Confiseries glacees composites

Country Status (15)

Country Link
CN (1) CN1078809C (fr)
AR (1) AR008080A1 (fr)
AU (1) AU713953B2 (fr)
BR (1) BR9710593A (fr)
CA (1) CA2261800A1 (fr)
CZ (1) CZ25999A3 (fr)
DE (1) DE19781893D2 (fr)
GB (1) GB2331003B (fr)
IL (1) IL128241A (fr)
PA (1) PA8434701A1 (fr)
PL (1) PL331484A1 (fr)
SK (1) SK10999A3 (fr)
TR (1) TR199900585T2 (fr)
UY (1) UY24645A1 (fr)
WO (1) WO1998004149A1 (fr)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1159879A1 (fr) * 2000-05-31 2001-12-05 Societe Des Produits Nestle S.A. Article de confiserie glacée et procédé de préparation.
US6379724B1 (en) 1999-10-22 2002-04-30 Nestec S.A. Slow melting coating for ice confections
US6399134B1 (en) 2000-02-22 2002-06-04 Nestec S.A. Soft textured, aqueous-based ice confection
WO2002071854A1 (fr) * 2001-03-09 2002-09-19 Unilever N.V. Produit a base de lait fermente
EP1557092A1 (fr) * 2004-01-20 2005-07-27 Unilever Plc Denrée alimentaire congelée
EP2095721A1 (fr) * 2008-02-29 2009-09-02 Nestec S.A. Produit de confiserie surgelé
WO2009109437A2 (fr) * 2008-02-29 2009-09-11 Nestec S.A. Produit de confiserie congelé

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2691400A1 (fr) * 2006-06-12 2007-12-21 Vita Nutrition Group Inc. Confiseries surgelees et leur procede de fabrication

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2360559A (en) * 1943-09-25 1944-10-17 Glazer Daniel Coated frozen confectionery
DE1243508B (de) * 1962-04-04 1967-06-29 Atlantic Refining Co UEberzugsmasse fuer Verpackungspappe
US4548045A (en) * 1984-03-30 1985-10-22 General Foods Corporation Method for continuously producing pop-shaped frozen confections
US5082032A (en) * 1989-10-06 1992-01-21 George W. Massey Volumetric packaging apparatus for frozen food and method
EP0500940A1 (fr) * 1990-06-06 1992-09-02 Kanebo, Ltd. Glace du type "esquimau" a composition combinee, procede de production d'une telle glace et dispositif utilise a cet effet
WO1995020883A1 (fr) * 1994-02-04 1995-08-10 Unilever Plc Confiserie glacee

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2360559A (en) * 1943-09-25 1944-10-17 Glazer Daniel Coated frozen confectionery
DE1243508B (de) * 1962-04-04 1967-06-29 Atlantic Refining Co UEberzugsmasse fuer Verpackungspappe
US4548045A (en) * 1984-03-30 1985-10-22 General Foods Corporation Method for continuously producing pop-shaped frozen confections
US5082032A (en) * 1989-10-06 1992-01-21 George W. Massey Volumetric packaging apparatus for frozen food and method
EP0500940A1 (fr) * 1990-06-06 1992-09-02 Kanebo, Ltd. Glace du type "esquimau" a composition combinee, procede de production d'une telle glace et dispositif utilise a cet effet
WO1995020883A1 (fr) * 1994-02-04 1995-08-10 Unilever Plc Confiserie glacee

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6379724B1 (en) 1999-10-22 2002-04-30 Nestec S.A. Slow melting coating for ice confections
US6399134B1 (en) 2000-02-22 2002-06-04 Nestec S.A. Soft textured, aqueous-based ice confection
EP1159879A1 (fr) * 2000-05-31 2001-12-05 Societe Des Produits Nestle S.A. Article de confiserie glacée et procédé de préparation.
WO2001091573A1 (fr) * 2000-05-31 2001-12-06 Societe Des Produits Nestle S.A. Article de confiserie glacee et procede de preparation
WO2001091572A1 (fr) * 2000-05-31 2001-12-06 Societe Des Produits Nestle S.A. Article de confiserie glacee et procede de preparation
AU2001262324B2 (en) * 2000-05-31 2005-04-07 Societe Des Produits Nestle S.A. Ice confectionery product and preparation method
WO2002071854A1 (fr) * 2001-03-09 2002-09-19 Unilever N.V. Produit a base de lait fermente
EP1557092A1 (fr) * 2004-01-20 2005-07-27 Unilever Plc Denrée alimentaire congelée
EP2095721A1 (fr) * 2008-02-29 2009-09-02 Nestec S.A. Produit de confiserie surgelé
WO2009109437A2 (fr) * 2008-02-29 2009-09-11 Nestec S.A. Produit de confiserie congelé
WO2009109437A3 (fr) * 2008-02-29 2009-11-12 Nestec S.A. Produit de confiserie congelé

Also Published As

Publication number Publication date
GB2331003B (en) 2000-05-24
SK10999A3 (en) 1999-07-12
AU3940197A (en) 1998-02-20
AU713953B2 (en) 1999-12-16
DE19781893D2 (de) 1999-07-15
IL128241A (en) 2002-02-10
AR008080A1 (es) 1999-12-09
GB9901509D0 (en) 1999-03-17
UY24645A1 (es) 1997-09-16
BR9710593A (pt) 2001-12-04
CN1231579A (zh) 1999-10-13
CZ25999A3 (cs) 1999-11-17
GB2331003A (en) 1999-05-12
TR199900585T2 (xx) 1999-06-21
PL331484A1 (en) 1999-07-19
CA2261800A1 (fr) 1998-02-05
IL128241A0 (en) 1999-11-30
PA8434701A1 (es) 2000-05-24
CN1078809C (zh) 2002-02-06

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