WO1997028212A1 - Absorbeur de rayons lumineux hors du spectre visible - Google Patents

Absorbeur de rayons lumineux hors du spectre visible Download PDF

Info

Publication number
WO1997028212A1
WO1997028212A1 PCT/JP1997/000197 JP9700197W WO9728212A1 WO 1997028212 A1 WO1997028212 A1 WO 1997028212A1 JP 9700197 W JP9700197 W JP 9700197W WO 9728212 A1 WO9728212 A1 WO 9728212A1
Authority
WO
WIPO (PCT)
Prior art keywords
absorber
infrared
parts
mass
visible light
Prior art date
Application number
PCT/JP1997/000197
Other languages
English (en)
Japanese (ja)
Inventor
Masuhiro Shouji
Hiroki Katono
Takeo Ogihara
Teruo Sakagami
Original Assignee
Kureha Kagaku Kogyo Kabushiki Kaisha
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kureha Kagaku Kogyo Kabushiki Kaisha filed Critical Kureha Kagaku Kogyo Kabushiki Kaisha
Publication of WO1997028212A1 publication Critical patent/WO1997028212A1/fr

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/0091—Complexes with metal-heteroatom-bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K3/2279—Oxides; Hydroxides of metals of antimony

Definitions

  • infrared rays increase the indoor temperature of a house or the like, and reduce the cooling efficiency of an air conditioner or the like in a high temperature, for example, in a summer period, thereby wasting wasteful energy.
  • Infrared absorber c phthalocyanine compound
  • Infrared absorbent c 0.001 to 10 parts by mass
  • the out-of-visible light absorber of the present invention comprises: a transparent substrate;
  • R 1 is an alkyl group having 1 to 20 carbon atoms, or
  • CH 2 CXC ⁇ 0 (C2H4O) m- (where X represents a hydrogen atom or a methyl group, m is an integer of 0 to 5), and n is 1 or 2. ]
  • conductive zinc antimonate anhydride is, Z n O / S b 2 0 5 molar ratio is from 0.8 to 1.2, primary particle size 5-2 0 0 It is preferably a powder of nm.
  • conductive anhydrous zinc antimonate and a specific infrared absorbing agent are used as the out-of-visible light absorbing component.
  • Alkyl amines such as amines, diisobutylamines, triamines, amines such as monoethanolamine, diamines such as ethylene diamine and lactic acid, tartaric acid, lingoic acid, An oxycarboxylic acid such as an acid can be added as a stabilizer.
  • examples of the organic solvent include alcohols such as methyl alcohol, ethyl alcohol, propyl alcohol, and butyl alcohol; glycols such as ethylene glycol, diethylene glycol, and hexylene glycol; ethyl sorb and propyl cellosolve. Amides such as cellosolves, dimethylformamide and dimethylacetamide, and the like can be used.
  • Infrared absorber a Metal ion consisting of divalent copper ion
  • Infrared absorber b Indium oxide, tin oxide or particulate metal oxide composed of both
  • Specific examples of the specific phosphoric acid ester having such a polymerizable functional group include 2-acryloyloxyshetyl acid phosphate, 2-methacryloyloxyshetyl acid phosphate, bis (2 —Medium chromolyoxyshechil ash dofosfu).
  • Such a specific phosphoric ester having a polymerizable functional group is contained in a monomer composition for obtaining a synthetic resin to be contained, and is subjected to a polymerization treatment so that the specific phosphate in the molecular structure of the synthetic resin is obtained. May be contained.
  • Certain mono (2-ethylhexyl) 2-ethylhexyl phosphonates have excellent compatibility with synthetic resins, have a large complex-forming ability with divalent copper ions, and have an infrared absorber a. It is preferable because it can increase dispersibility.
  • a compound oxide of tin oxide and antimony oxide hereafter, “ATO” (hereinafter referred to as “antimony Ti”) with an increased carrier electron density in tin. n O xide). ) Is preferable.
  • an ultrafine particle powder having a particle size distribution in the range of 0.001 to 0.05 m is preferable.
  • phthalocyanine-based compound used as the infrared absorber c include 4,5—tactakisanilino-1 (3,6—octakisphenylthio) oxyvana dimethyphthalocyanine and 41-tetrakisanilinino-1 (3, 5,6-dodekisphenylthio) zinc phthalocyanine, 4-tetrakisanilinino (3,5,6-dodecakisphenoxy) zinc phthalocyanine and the like.
  • Such a furendiamine derivative has a characteristic that it can efficiently absorb infrared rays having a wavelength of 760 to 1500 nm without impairing light transmittance in a visible light region.
  • this phenylenediamine conductor include N, N, N ', N'—tetrakis (p-g-n-butylaminophenyl) -p-benzoquinone-bis (immonium). N, N, N ', N'-tetrakis (p-Jethylaminophenyl) -p-benzoquinone-bis (hexafluoroantimonate of immonium), N , N, ⁇ ', ⁇ ' 1-tetrakis ( ⁇ -di-1 ⁇ -hexylaminophenol) 1 ⁇ -benzoquinone-bis (imodidium borofluoride), ⁇ , ⁇ , ⁇ ', N' — tetrakis ( ⁇ -diisopropylaminophenyl) ⁇ -benzoquinone-bis (imonidium nitrate), ⁇ , ⁇ , ⁇ ', N' one Tetrakis ( ⁇ -di-1
  • the out-of-visible light absorber of the present invention is in any one of the following (a) to (c).
  • a substrate made of a transparent synthetic resin contains conductive anhydrous zinc antimonate and at least one selected from infrared absorber a, infrared absorber b and infrared absorber c. Outside visible light absorber
  • deposited layer (Hereinafter also referred to as a “deposited layer”).
  • the synthetic resin constituting the base material may be any transparent material.
  • specific examples thereof include, but are not limited to, acrylic resins such as methyl methacrylate, polyvinyl chloride, vinyl chloride-vinyl acetate copolymer, and chlorinated vinyl chloride resins.
  • Styrene resins such as vinyl resin, polystyrene, acrylonitrile-releasing styrene resin, polyester resins such as polycarbonate, polyethylene terephthalate, polybutylene terephthalate, polyurethane resin, Polyamide resin, fluorinated resin, polyvinyl alcohol resin, polyvinyl butyral resin, vinyl acetate resin Aruki' de tree Examples thereof include thermoplastic resins such as fats and epoxy resins, and thermosetting resins or photocurable resins having transparency.
  • Such a non-visible light absorber in the form of (a) is prepared by, for example, mixing the above-mentioned synthetic resin, conductive zinc anhydride antimonate and an infrared absorber to prepare a resin composition. It is obtained by molding a product.
  • a high-speed stirring mixer such as a Henschel mixer, a method of mixing a synthetic resin with conductive anhydrous zinc antimonate using another blender, a roll kneader or A method in which a synthetic resin and conductive anhydrous zinc antimonate are kneaded and mixed using an extruder.
  • thermosetting resin or a photocurable resin As a method for producing a substrate by molding a resin composition, an injection molding method, a calender molding method, an extrusion molding method, or another molding method of a synthetic resin can be used.
  • a thermosetting resin or a photocurable resin When a thermosetting resin or a photocurable resin is used as the synthetic resin, it contains a monomer for obtaining the curable resin, conductive anhydrous zinc antimonate, and an infrared absorber.
  • the out-of-visible light-absorbing material can also be produced by cast polymerization of the resulting monomer composition.
  • the material constituting the substrate is a material having transparency.
  • the thermoplastic resin exemplified as the synthetic resin constituting the base in the above embodiment (a) a transparent thermosetting resin or a photocurable resin, glass And other inorganic materials.
  • the synthetic resin constituting the dispersion type layer has a large light transmittance in a visible light region, that is, a synthetic resin having excellent transparency.
  • Any resin may be used. Specific examples thereof include the thermoplastic resin exemplified as the synthetic resin constituting the base in the above-described embodiment (a), a thermosetting resin having transparency, or a photocuring resin. Resin.
  • the dispersion type layer is formed by applying a dispersion type layer forming liquid containing a powder of conductive anhydrous zinc antimonate and an infrared absorber to the surface of the substrate and performing necessary treatment.
  • a thermoplastic resin is used as the synthetic resin constituting the dispersion layer
  • an organic solvent is used as a medium in preparing the dispersion layer forming liquid.
  • organic solvent examples include alcohols such as methyl alcohol, ethyl alcohol, butyl alcohol, and hexyl alcohol, and ketones such as acetone, methylethylketone, methylisobutylketone, and hexanone.
  • alcohols such as methyl alcohol, ethyl alcohol, butyl alcohol, and hexyl alcohol
  • ketones such as acetone, methylethylketone, methylisobutylketone, and hexanone.
  • Esters esters such as ethyl acetate, butyl acetate, and cellosolve acetate; cyclic ethers such as dioxane and tetrahydrofuran; halogenated hydrocarbons such as methylene chloride and chloroform; xylene, toluene; Aromatic hydrocarbons such as benzene, organic compounds such as cycle hexane, dimethylformamide, dimethylacetamide, and acetonitrile, mixtures of these compounds, and others are used.
  • an acrylic resin or a thermosetting resin or a photocurable resin is used as the synthetic resin constituting the dispersed layer
  • a precursor of the resin for example, an acrylate-based monomer
  • the polymer, a powder of conductive anhydrous zinc antimonate, an infrared absorber, and the same organic solvent used as necessary are mixed to prepare a polymerizable dispersion-type layer-forming solution,
  • the dispersion-type layer is formed by applying the aqueous dispersion-type layer forming liquid to the surface of the substrate, drying and removing the organic solvent, and performing heat treatment or irradiation treatment with ultraviolet rays or the like.
  • a monofunctional monomer or a polyfunctional monomer is used as the acrylate monomer, and examples thereof include methyl (meth) acrylate and ethyl.
  • a crosslinked polymer obtained from a composition mainly composed of a photocurable resin, particularly a photopolymerizable monomer which is easily polymerized by irradiation with ultraviolet rays or the like is usually a precursor of the precursor.
  • the polymerizable dispersion layer forming liquid which is a mixed liquid, has a long pot life, is easy to handle, can be cured without heating, has high surface hardness, and has high chemical resistance, heat resistance, etc. It is preferable because a dispersed layer having excellent performance is formed.
  • the dispersion layer is formed by laminating and adhering a molded article for a dispersion layer in which a synthetic resin containing anhydrous zinc antimonate and an infrared absorber is contained on the surface of the substrate. It may be.
  • the molded article for a dispersion layer can be produced by the same method as that for the above-mentioned out-of-visible light absorber of the embodiment (a).
  • thermosetting or light-curing adhesive having excellent transparency, for example, epoxy
  • urethane-based or acrylic-based adhesive or an acrylic-based adhesive excellent in transparency and weather resistance
  • the conductive anhydrous zinc antimonate is contained in the substrate or the dispersion layer together with the infrared absorber.
  • the content ratio of zinc antimonate is 0.1 to 500 parts by mass, preferably 1 to 500 parts by mass with respect to 100 parts by mass of the synthetic resin constituting the base or the dispersible layer. Selected in a range of parts.
  • the content ratio of the conductive anhydrous zinc antimonate is selected according to the thickness of the substrate or the dispersion type layer.For example, when the substrate or the dispersion type layer is a sheet or plate having a large thickness.
  • the conductive anhydrous zinc antimonate is contained in an amount of 0.1 to 10 parts by mass, preferably 0.1 to 5 parts by mass, based on 100 parts by mass of the synthetic resin.
  • the conductive zinc anhydride antimonate is contained in a proportion of 10 to 500 parts by mass. Have.
  • this ratio is less than 0.1 part by mass, good out-of-visible light absorption characteristics may not be obtained. On the other hand, if this proportion exceeds 500 parts by mass, it becomes difficult to uniformly disperse the conductive anhydrous zinc antimonate in the synthetic resin, and it is difficult to obtain the substrate itself or the dispersion type layer itself. May be difficult.
  • the infrared absorber is used in the following range.
  • the proportion of the metal ion used is 100 mass of the synthetic resin constituting the base or the dispersion layer containing the infrared absorbent a. It is 0.01 to 20 parts by mass, preferably 0.1 to 15 parts by mass.
  • the ratio of use is limited to 100 parts by mass of the synthetic resin constituting the base or the dispersion layer containing the infrared absorbent b.
  • the amount is 0.1 to 500 parts by mass, preferably 1 to 500 parts by mass.
  • the ratio of use is 100 parts by mass of the synthetic resin constituting the substrate when the infrared absorbent c is contained in the substrate. 0.01! 0 parts by mass, preferably 0.001 to 5 parts by mass, and when the dispersion type layer contains the infrared absorbent c, it is based on 100 parts by mass of the synthetic resin constituting the dispersion type layer. And 0.01 to 10 parts by mass, preferably 0.01 to 5 parts by mass.
  • the proportion of the infrared absorbing agent d depends on the composition of the base or the dispersion layer containing the infrared absorbing agent d.
  • the amount is preferably from 0.01 to 1 part by mass, more preferably from 0.01 to 0.7 part by mass, per 100 parts by mass of the resin.
  • the thickness of the deposition type layer is from 0.1 to 100 m, particularly from 0.1 to 100 m. Preferably, it is 10 ⁇ m. If the thickness of the deposition type layer is excessively large, the transmittance of visible light in the deposition type layer becomes low, which is not preferable. Meanwhile, this sedimentary layer If the thickness is too small, the light transmittance of light outside the visible range will increase, making it difficult to obtain the desired optical characteristics.
  • the ratio of the anhydrous zinc antimonate powder to the specific particulate metal oxide in the deposited layer is 0.1% by mass or more for the anhydrous zinc antimonate powder.
  • the deposition-type layer is formed by applying an appropriate method, for example, applying a dispersion of a deposition-type layer formed by dispersing a conductive anhydrous zinc antimonate powder and a specific particulate metal oxide to the surface of the substrate and drying the dispersion. Formed by
  • an organic solvent can be used as a medium, and specific examples thereof include those exemplified in the preparation of the dispersion type layer forming liquid described above.
  • a protective layer on the surface of the deposition layer, whereby a practically necessary surface hardness can be obtained.
  • a synthetic resin having excellent transparency can be used as a material constituting such a protective layer. Specific examples thereof include thermoplastic resins exemplified as the synthetic resin constituting the substrate, and transparent resins. Thermosetting resin or photocurable resin having properties.
  • Such a protective layer can be formed by an appropriate means.
  • a protective layer forming solution in which a synthetic resin is dissolved in an organic solvent is prepared, and this protective layer forming solution is used for forming a deposition type layer.
  • the surface of the substrate is coated with a known surface treatment method, for example, a primer coating, corona treatment or other method, in order to enhance the adhesion between the two.
  • a known surface treatment method for example, a primer coating, corona treatment or other method, in order to enhance the adhesion between the two.
  • Physical or chemical pretreatment can be applied.
  • a stabilizer, a lubricant, a plasticizer, an antioxidant, an ultraviolet absorber, a pigment, an impact strength improver, and a filler are contained in the substrate, the dispersion layer, or the protective layer.
  • a workability improver and other additives may be contained.
  • a phosphate ester such as triglyceryl phosphate or triphenyl phosphate is used.
  • Plasticizers such as phthalic acid-based plasticizers such as octyl phthalate and dibutyl phthalate, fatty acid-based plasticizers such as dibutyl sebacate, butyl ricinoleate, methyl acetyl ricinoleate, and butyl succinate, butyl phthalyl butyl dali Glycol plasticizers such as collet, triethylene glycol dibutylate, triethylene glycol dibutyl butyrate, and polyethylene glycol can be used.
  • Industrial applicability such as collet, triethylene glycol dibutylate, triethylene glycol dibutyl butyrate, and polyethylene glycol can be used.
  • the out-of-visible light absorber of the present invention uses conductive anhydrous zinc antimonate and a specific infrared absorber, the light transmittance in the ultraviolet and infrared regions is low, and the light transmittance in the visible region is low. It is expensive. Therefore, the out-of-visible light absorber of the present invention is useful for applications where it is required to prevent irradiation of infrared rays and / or ultraviolet rays.
  • the out-of-visible light absorber of the present invention as an agricultural covering material for constructing a greenhouse facility covering a plant cultivation atmosphere, the temperature inside the facility can be increased during a high temperature period. It can control and extend the use period of greenhouse facilities.
  • the out-of-visible light absorber of the present invention can be applied to window materials of buildings, automobiles, vehicles, and the like.
  • parts means “parts by mass”
  • % for content ratio means “% by mass”.
  • Conductive oxide sol “CELNAX CX—Z200M” (manufactured by Nissan Chemical Industries, Ltd.) The methanol in the sol was evaporated to dryness to obtain a fine powder of anhydrous zinc antimonate. Fine powder of the obtained zinc antimonate anhydride is in the range of Z n OZ S b 2 0 5 molar ratio is from 0.8 to 1.2, the range of the primary particle diameter. 5 to 2 0 0 nm It was confirmed that there was.
  • this anhydrous zinc antimonate fine powder 2.5 parts, 100 parts of polyvinyl chloride resin “PVCS-903” (produced by Kureha Chemical Co., Ltd.) having an average degree of polymerization of 130, and acetic anhydride It consists of 4.4 parts of copper (the amount of divalent copper ions is 1.5 parts per 100 parts of vinyl chloride resin), 15.6 parts of di (2-ethylhexyl) phosphate, and a phthalocyanine-based compound.
  • PVCS-903 polyvinyl chloride resin having an average degree of polymerization of 130
  • acetic anhydride It consists of 4.4 parts of copper (the amount of divalent copper ions is 1.5 parts per 100 parts of vinyl chloride resin), 15.6 parts of di (2-ethylhexyl) phosphate, and a phthalocyanine-based compound.
  • Dye “EXCOLOR 901 Bj” (manufactured by Nippon Shokubai) 0.1 part, plasticizer octyl phthalate (hereinafter referred to as “D ⁇ P”) 40 parts, and a barium / zinc composite stabilizer ( Made by Katsuta Kako; BZ-350 MNO PSE-102 B-1.5 / 1.0 parts) 2.5 parts, epoxidized soybean oil 4.0 parts, and bisamide 0.3 parts Into a hensil mixer, and stirred and mixed in a state where the powder temperature was heated to 110 ° C to prepare a vinyl chloride resin composition. .
  • D ⁇ P plasticizer octyl phthalate
  • This butyl chloride resin composition was molded into a film having a thickness of 10 using a calender molding machine to produce an out-of-visible range light absorber.
  • polyvinyl butyral resin "ESLEX B MB-1" manufactured by Sekisui Chemical Co., Ltd.
  • a TO fine powder manufactured by Sumitomo Cement Co., Ltd., particle size: 0.005 to 0.015 jum
  • plasticizer DOP 30 parts plasticizer DOP 30 parts
  • anhydrous copper acetate 4.4 The amount of divalent copper ions to 100 parts of polyvinyl butyral resin is 1.5 parts
  • 15.6 parts of di (2-ethylhexyl) phosphate are combined with a surface temperature of 15 parts.
  • a polyvinyl butyral resin composition was prepared by sufficiently kneading and mixing with a kneading roll machine at 0 ° C.
  • This polyvinyl butyral resin composition was applied to two glass plates each having a thickness of 1 mm. Outside the visible range, where a light absorbing layer outside the visible range is provided between the two glass plates by pressing with a maximum pressure of 0.1 MPa using a press machine with a pressing surface temperature of 150 ° C. A light absorber was produced.
  • Acrylic adhesive resin solution “TS-15B” (manufactured by Sekisui Chemical, resin content: 30% ')
  • 3 parts of fine powder of anhydrous zinc antimonate obtained in the same manner as in Example 1 was added and mixed well with sufficient stirring.
  • 30 parts of a reaction mixture of 28 parts of copper acetate and 100 parts of di (2-ethylhexyl) phosphate (the amount of divalent copper ions relative to 100 parts of the acrylic resin is reduced). (7.7 parts) was added and mixed to prepare a dispersion type layer forming liquid.
  • This dispersion layer forming liquid was applied to one surface of a substrate made of a polyester film “E-501 # 50” (manufactured by Toyobo) having a thickness of 50 m using a bar coater. By heating in an oven at 0 ° C for 2 minutes to remove the solvent, an out-of-visible light absorber having a 50 m-thick dispersion type layer formed on one surface of a substrate made of a polyester film was manufactured. .
  • Example 3 in place of the mixture of copper acetate and di (2-ethylhexyl) phosphate, a dye consisting of a phthalocyanine-based compound “EXCOLOR 910B” (manufactured by Nippon Shokubai) 0.06 parts A light absorber outside the visible range was manufactured in the same manner except that was used.
  • Conductive oxide sol "CELLNAX CX-Z200M” (Nissan Chemical Industries, Ltd. 20 parts of ATO fine powder (manufactured by Sumitomo Cement, particle size: 0.005 to 0.015 m) was added to 100 parts of water zinc antimonate content: 20%). By sufficiently stirring and mixing, a dispersion for forming a deposition type layer was prepared.
  • this dispersion liquid for forming a deposition type layer was applied to one surface of a glass plate having a thickness of 1 mm to form a deposition type layer composed of conductive anhydrous zinc antimonate and ATO fine particles.
  • the transparent protective layer with a thickness of 10 m is formed on the deposition-type layer using a clear paint containing clear resin, Clearcoater (manufactured by AtomPaint).
  • Clearcoater manufactured by AtomPaint
  • An out-of-visible light absorber was produced in which a deposition type layer and a transparent protective layer were laminated in this order on the surface of a substrate consisting of a plate.
  • the light absorbers outside the visible range according to Examples to 5 have sufficiently high light transmittance in the wavelength range of 400 to 800 nm, that is, in the visible range.
  • the light transmittance in both the ultraviolet region on the shorter wavelength side than this wavelength region and the infrared region on the longer wavelength side than this wavelength region is low, that is, it has good light absorption characteristics outside the visible region. Was done.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Optical Filters (AREA)
  • Laminated Bodies (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Protection Of Plants (AREA)
  • Greenhouses (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)

Abstract

Cette invention concerne un absorbeur de rayons lumineux se trouvant hors du spectre visible, lequel absorbeur comprend une base de résine transparente qui possède une transmissivité élevée dans le spectre visible, et une faible transmissivité tant dans le domaine des infrarouges que celui des ultraviolets. Cette base de résine transparente contient un anhydride d'antimoniate de zinc conducteur et l'un au moins des trois absorbeurs (a-c) de rayonnement infrarouge suivants: (a) des ions métalliques comprenant des ions cuivre bivalents; (b) un oxyde métallique particulaire comprenant de l'oxyde d'indium ou de l'oxyde d'étain, ou encore, les deux; et (c) un composé phtalocyanine. Dans un autre mode de réalisation, cet absorbeur peut comprendre une base transparente sur laquelle est déposée l'une des deux couches suivantes: soit une couche absorbant les rayons lumineux se trouvant hors du spectre visible, laquelle couche contient de l'anhydride d'antimoniate de zinc conducteur ainsi que l'une au moins des substances choisies dans le groupe a à c et contenues dans la résine synthétique de la base; soit une couche absorbant les rayons lumineux se trouvant hors du spectre visible, laquelle couche contient un corps issu de l'accumulation, d'une part, d'un oxyde métallique particulaire se composant d'anhydride d'antimoniate de zinc anhydre et, d'autre part, d'oxyde d'indium ou d'oxyde d'étain, ou encore des deux.
PCT/JP1997/000197 1996-01-30 1997-01-29 Absorbeur de rayons lumineux hors du spectre visible WO1997028212A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP1390496A JPH09208840A (ja) 1996-01-30 1996-01-30 可視域外光線吸収体
JP8/13904 1996-01-30

Publications (1)

Publication Number Publication Date
WO1997028212A1 true WO1997028212A1 (fr) 1997-08-07

Family

ID=11846171

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP1997/000197 WO1997028212A1 (fr) 1996-01-30 1997-01-29 Absorbeur de rayons lumineux hors du spectre visible

Country Status (2)

Country Link
JP (1) JPH09208840A (fr)
WO (1) WO1997028212A1 (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6093749A (en) * 1997-10-16 2000-07-25 Nissan Chemical Industries, Ltd. Anhydrous zinc antimonate sol and method for producing the same
WO2001018101A1 (fr) * 1999-09-06 2001-03-15 Bayer Aktiengesellschaft Matieres de moulage

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1994002679A1 (fr) * 1992-07-27 1994-02-03 Kanebo, Ltd. Tissu imprime et procede de fabrication
JPH11105437A (ja) * 1997-10-02 1999-04-20 Dainippon Printing Co Ltd 熱転写シートおよび印画物
WO1999026952A1 (fr) * 1997-11-21 1999-06-03 Kureha Kagaku Kogyo Kabushiki Kaisha Composes de phosphate, composes de phosphate et de cuivre et leurs procedes de preparation, substance et composition absorbant les infrarouges proches et leur produit de mise en application
WO1999026951A1 (fr) * 1997-11-21 1999-06-03 Kureha Kagaku Kogyo Kabushiki Kaisha Compose de phosphate et de cuivre, composition contenant ce compose et produit de mise en application
JP2000007871A (ja) * 1998-06-23 2000-01-11 Kureha Chem Ind Co Ltd 樹脂組成物およびその製造法、光学フィルターおよびこれを備えた装置、熱線吸収フィルター、光ファイバーおよび眼鏡レンズ
JP4016385B2 (ja) * 2002-07-02 2007-12-05 健次 斉藤 紫外線・赤外線遮蔽体
JP2005008515A (ja) * 2003-05-26 2005-01-13 Nissan Chem Ind Ltd 金属酸化物粒子及びその製造方法
JP2007269818A (ja) * 2004-04-07 2007-10-18 Kureha Corp 重合性組成物、重合体及び積層体
JP4605375B2 (ja) * 2004-04-21 2011-01-05 日産化学工業株式会社 無水アンチモン酸亜鉛ゾル及びその製造方法
WO2012026522A1 (fr) * 2010-08-27 2012-03-01 日産化学工業株式会社 Dispersion dans un solvant organique hydrophobe de particules colloïdales d'antimonate de zinc anhydre modifiées en surface, composition de revêtement la contenant, et élément revêtu

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02136230A (ja) * 1988-11-16 1990-05-24 Takiron Co Ltd 赤外線吸収性合成樹脂成型品
JPH06219743A (ja) * 1993-01-29 1994-08-09 Nissan Chem Ind Ltd 無水アンチモン酸亜鉛及びその製造法
JPH06264050A (ja) * 1993-01-13 1994-09-20 Nippon Shokubai Co Ltd 熱線遮蔽材
JPH06306203A (ja) * 1993-04-27 1994-11-01 Daicel Chem Ind Ltd 近赤外線遮断透明樹脂組成物およびその成形体
JPH0811266A (ja) * 1994-06-30 1996-01-16 Aisin Seiki Co Ltd 赤外線遮蔽積層体及びその製造方法

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02136230A (ja) * 1988-11-16 1990-05-24 Takiron Co Ltd 赤外線吸収性合成樹脂成型品
JPH06264050A (ja) * 1993-01-13 1994-09-20 Nippon Shokubai Co Ltd 熱線遮蔽材
JPH06219743A (ja) * 1993-01-29 1994-08-09 Nissan Chem Ind Ltd 無水アンチモン酸亜鉛及びその製造法
JPH06306203A (ja) * 1993-04-27 1994-11-01 Daicel Chem Ind Ltd 近赤外線遮断透明樹脂組成物およびその成形体
JPH0811266A (ja) * 1994-06-30 1996-01-16 Aisin Seiki Co Ltd 赤外線遮蔽積層体及びその製造方法

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6093749A (en) * 1997-10-16 2000-07-25 Nissan Chemical Industries, Ltd. Anhydrous zinc antimonate sol and method for producing the same
WO2001018101A1 (fr) * 1999-09-06 2001-03-15 Bayer Aktiengesellschaft Matieres de moulage

Also Published As

Publication number Publication date
JPH09208840A (ja) 1997-08-12

Similar Documents

Publication Publication Date Title
JP5245284B2 (ja) 熱線遮蔽ポリエステルフィルムおよび熱線遮蔽ポリエステルフィルム積層体
JP3746824B2 (ja) 可視域外光線吸収体
WO1997028212A1 (fr) Absorbeur de rayons lumineux hors du spectre visible
AU2018365930A1 (en) Surface-treated infrared absorbing fine particles, surface-treated infrared absorbing fine powder, infrared absorbing fine particle dispersion liquid using the surface-treated infrared absorbing fine particles, infrared absorbing fine particle dispersion body and method for producing them
JP4292634B2 (ja) 反射防止積層体の製造方法
JP3530085B2 (ja) 金属酸化物系粒子、その製造方法および用途
JP3933215B2 (ja) 熱線吸収性複合体
JPWO2011074619A1 (ja) 近赤外線吸収色素及び近赤外線吸収組成物
JP2003277045A (ja) ６ホウ化物粒子とこの６ホウ化物粒子が分散された分散体および６ホウ化物粒子若しくは分散体を用いた物品
JP2010202495A (ja) 熱線遮蔽合わせガラスおよびその製造方法
KR20130066754A (ko) 하드 코팅 조성물
JP3945836B2 (ja) アクリル系樹脂組成物
JPH09208863A (ja) 熱線吸収性コーティング組成物および熱線吸収性付与方法
KR20070077815A (ko) 투명패널의 대전방지 코팅액의 제조방법 및 이를 이용한대전방지 물건의 코팅방법
JPWO2010055899A1 (ja) 樹脂組成物とそれを用いた透明な樹脂成形体および塗膜
AU2019267798A1 (en) Surface-treated infrared-absorbing fine particle dispersion and infrared-absorbing transparent substrate
US6037394A (en) Primer composition and article obtained using the same
JP3651583B2 (ja) 曝露汚れ防止シート及びその製造方法
KR101288366B1 (ko) 자외선과 적외선 차단용 자외선 경화 조성물
JP3588419B2 (ja) 酸化亜鉛系粒子、その製造方法および用途
JP2017002182A (ja) 水性赤外線・紫外線遮蔽コーティング剤、及びこれを利用した赤外線・紫外線遮蔽処理方法
JP3623013B2 (ja) 赤外線非透過性光学フィルター
JP5061665B2 (ja) マスターバッチとその製造方法、及びこのマスターバッチを用いた成形体並びに該成形体を用いた積層体
JP2011184523A (ja) 熱線遮蔽ポリエステルフィルム及び熱線遮蔽ポリエステルフィルム積層体
JP2007126491A (ja) 反応性有機−無機ハイブリット成分含有の重合性有機モノマー液状組成物、その製造方法及びその用途

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A1

Designated state(s): KR US

AL Designated countries for regional patents

Kind code of ref document: A1

Designated state(s): AT BE CH DE DK ES FI FR GB GR IE IT LU MC NL PT SE

DFPE Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101)
121 Ep: the epo has been informed by wipo that ep was designated in this application
122 Ep: pct application non-entry in european phase