WO1996019185A1 - Compositions recouvrantes pour rouge a levres contenant de l'huile de silicone et de la silice - Google Patents

Compositions recouvrantes pour rouge a levres contenant de l'huile de silicone et de la silice Download PDF

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Publication number
WO1996019185A1
WO1996019185A1 PCT/US1995/015418 US9515418W WO9619185A1 WO 1996019185 A1 WO1996019185 A1 WO 1996019185A1 US 9515418 W US9515418 W US 9515418W WO 9619185 A1 WO9619185 A1 WO 9619185A1
Authority
WO
WIPO (PCT)
Prior art keywords
groups
group
volatile
mixtures
composition
Prior art date
Application number
PCT/US1995/015418
Other languages
English (en)
Inventor
Lee Ellen Drechsler
Thomas Elliot Rabe
Original Assignee
The Procter & Gamble Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by The Procter & Gamble Company filed Critical The Procter & Gamble Company
Priority to JP8519805A priority Critical patent/JPH10508867A/ja
Priority to AU42889/96A priority patent/AU4288996A/en
Priority to EP95941483A priority patent/EP0794759A1/fr
Publication of WO1996019185A1 publication Critical patent/WO1996019185A1/fr
Priority to MXPA/A/1997/004720A priority patent/MXPA97004720A/xx

Links

Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89Polysiloxanes
    • A61K8/896Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate
    • A61K8/897Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate containing halogen, e.g. fluorosilicones
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/25Silicon; Compounds thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89Polysiloxanes
    • A61K8/891Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02Preparations containing skin colorants, e.g. pigments
    • A61Q1/04Preparations containing skin colorants, e.g. pigments for lips
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02Preparations containing skin colorants, e.g. pigments
    • A61Q1/04Preparations containing skin colorants, e.g. pigments for lips
    • A61Q1/06Lipsticks

Definitions

  • the present invention is a composition which when applied over a lipstick composition prevents transference of the lipstick to objects such as cups, glasses and other table wear coming in contact with the lips. This invention, therefore, extends the time between re-applications of said lipstick. Said invention adds luster and shine to the lips while providing the user with good skin feel properties.
  • Lipstick treatment products whose primary purpose is to extend wear, improve the blot transfer resistance and heighten the gloss of said lipstick are well known in the art.
  • overcoats utilize a variety of polymeric fluids and film forming technologies.
  • acrylic film-formers incorporated in overcoats such as CSI, Incorporated's "Sealed with a Kiss" are delivered in a volatile vehicle, alcohol, which is spread over the lipstick surface.
  • CSI, Incorporated's "Sealed with a Kiss” are delivered in a volatile vehicle, alcohol, which is spread over the lipstick surface.
  • alcohol which is spread over the lipstick surface.
  • These products have a solid nature and impart a dry, draggy feel to the lip surface.
  • these polymeric overcoats are perceived as sticky during the first few minutes after application when the volatile vehicle commences to evaporate.
  • overcoat products to those described above are disclosed in Japanese Patent Application Number HEI 5[1993]-221829, published August 31, 1993. Said overcoats are reputed to exhibit improved durability of makeup effect, suppression of color transfer, and improved applicability. Said overcoats comprise from 0.2 to 25% of silica powder and/or alumina powder and from 75% to 99.8% of a perfluoropolyether of general formula:
  • R 1 though R 5 are independent fluorine atoms, perfluoroalkyl groups, or oxyperfluoroalkyl groups; the value of p, q, and r is at least zero; wherein the perfluoropolyether molecular weight is from about 500 to about 10,000, wherein P, Q and R may be equal, but, not zero.
  • the preferred perfluoropolyether disclosed therein is a commercially available product known as Fomblin HC-04, HC-25, and HC-R available from Montefluosu of Milano, Italy.
  • compositions comprising silicones and hydrocarbon oils wherein the compositions are in applied over the lips in order to extend the life of the lipstick and provide a sealing effect to protect the lips.
  • the present invention is a composition comprising from about 75% to about 99% of a non- volatile silicone fluid having a viscosity from about 10 cs to about 1000 cs and from about 1% to about 25% of a thickening agent.
  • the non-volatile silicone fluid mentioned above corresponds to the formula:
  • R 3 R5 wherein K ⁇ and R5 are independently selected from the group consisting of hydroxyl end groups, lower alkyl end groups having carbon chain lengths from about C ⁇ to about C ⁇ and mixtures thereof; and R2 through R5 are independently selected from the group consisting of lower alkyl groups having carbon chain lengths from about C ⁇ to about C , fluoroalkyi groups, phenyl groups, aminoalkyl groups and mixtures thereof.
  • one objective of the present invention is to provide an overcoat composition to avoid transferring the lipstick onto to objects coming in contact with the lips.
  • Another object of the present invention is to extend the period of time between applications of lipstick.
  • Still another objective is to provide a composition which improves the application and wear feel characteristics sought by consumers as well as improve luster and shine of the lipstick composition applied to the lips. All of these objectives are delivered in a product that is less expensive than comparable products known in the art.
  • the non- volatile silicone fluid used in the present invention conforms to the formula:
  • end groups R and Rg are independently selected from the group consisting of hydroxyl groups, lower alkyl groups having carbon chain lengths from about C ⁇ to about Cg and mixtures thereof, preferably methyl groups.
  • the non-end groups R2,, R3, R4 and R5 are independently selected from the group consisting of lower alkyl groups having carbon chain lengths from about C ⁇ to about Cg, fluoroalkyi groups, phenyl groups, aminoalkyl groups and mixtures thereof.
  • Said non- volatile silicone fluids have a viscosity from about 10 cs to 1,000 cs, preferably 50 cs to about 500 cs, at 25° C and one atmosphere.
  • compositions comprise from about 75% to 99%, preferably about 90% to about 99%, and most preferably from about 90% to about 95% of said non-volatile silicone fluid.
  • Silicone fluids with non-end groups R2, R3, R4 and R5) comprising branched and straight chained lower alkyl groups having carbon chain lengths from C ⁇ to Cg are known in the art. In the present invention it is preferable that the C ⁇ to Cg chain length be as short as possible in order to provide the final product with a relatively non-lipohilic character. Therefore, methyl groups are the most preferred alkyl non-end groups in the present invention.
  • Commercially available non-volatile silicone fluids having such non-end groups include those available from Dow Corning as the 200 Fluids, and those available from General Electric as SF-96 Series.
  • Silicone fluids with non-end groups comprising fluoroalkyi groups are also useful herein. It is preferable, however, that the fluorine atom is attached to alkyl groups having a C3 to Cg chain length wherein the fluorine atom is attached to attached to said alkyl group at a point no closer than third carbon atoms from the silicone/carbon bond.
  • Commercially available non-volatile silicone fluids having such non-end groups include those available from Dow Corning as the 1265 Fluid series, and those available from General Electric as the SF- 1153 Series, most preferred is the 1265 Fluid Series, most preferably those of having a viscosity from about lOOcs to about 350cs.
  • Silicone fluids with the non-end groups comprising allyl groups are also useful in the present invention.
  • the allyl groups which are particularly useful in the present invention are phenyl groups.
  • Particularly useful allyl-substituted silicone fluids commercially available are available as the 556 Series from Dow Corning.
  • the non-end groups mentioned above also include aminoalkyl groups which make up the amino-f ⁇ nctional silicones such as methylsilicone and can be structurally represented as:
  • x equals the number of repeat units in the polymer chain and y equals the length of the alkyl group, wherein y is greater than about 2, but, less than about 10; (2 ⁇ y ⁇ 10).
  • silicone fluid is aminopropyl methylsilicone, available from Dow
  • the preferable non-volatile silicone fluid used in the present invention is selected from the group consisting of dimethicone, phenyl dimethicone, phenyl trimethicone, flurosilicone, aminosilicone and mixtures thereof.
  • the above non-volatile silicone fluid is combined with a thickening agent to provide a overcoat composition having a viscosity sufficient to prevent the composition running off the lips immediately after applying.
  • Said thickening agents are used at levels from about 1% to about 25%, preferably about 1% to about 10%, and most preferably from about 5% to about 10% of the composition.
  • Preferred thickening agents are selected from the group consisting of organic/inorganic thickening agents, fumed silica, fumed titania, fumed alumina, and mixtures thereof.
  • fumed silica Fumed silica is commonly found in cosmetic compositions since it sets up a hydrogen-bonded associative network with itself and with silicone polymer chains present in such compositions.
  • the fumed silica useful in the present invention is selected from the group consisting of hydrophobic silica, hydrophiiic silica and mixtures thereof.
  • the hydrophiiic fumed silica most preferred include the Aerosol Series available from Degussa Corporation, as disclosed in the published supplier information sheet, herein incorporated by reference.
  • the hydrophobic fumed silica most preferred are also supplied by Degussa and are the Aerosols that have been treated with organic material, as disclosed in the above-mentioned supplier information sheet.
  • Most preferred hydrophobic fumed silica is Aerosil R974.
  • compositions of the present invention further include optional ingredients which may be added to the composition disclosed above to provide various consumer desirable characteristics to the product.
  • Said optional ingredients include those routinely used in the cosmetic arts to produce a specific cosmetic effect which is deemed desirable.
  • said optional ingredients include humectants, occlusives, flavorings, perfumes, colorants and other such routinely used ingredients. Volatile fluids are particularly useful optional ingredient. They reduce the initial viscosity of a gelled silicone overcoat, thereby improving the ease of application of the composition over the lipstick.
  • compositions of the present invention may comprise from about 1% to 50%, preferably 1% to 25%, and most preferably from 1% to 10% volatile fluids.
  • Preferred volatile hydrocarbons fluids include isododecane, available as for example Permethyl 99A from Permethyl Corporation corresponding to the formula:
  • Preferred volatile silicone fluids include cyclomethicones having 3,4 and 5 membered ring structures corresponding to the formula:
  • volatile silicones include 244 Fluid, 344 Fluid and 345 Fluid from Dow Corning Corporation.
  • the volatile silicone is therein gelled, preferably with fumed silica powder. D. Examples
  • Aerosil 200 available from Degussa Corp.
  • Aerosil R974 available from Degussa Corp.
  • composition of the present invention is applied to the surfaces of the lips covered by at least one layer of lipstick.
  • Said product is spread evenly over said lip surface by any means including by motion of the lips over each other, the user's finger tip, a typical lipstick applicator.

Landscapes

  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Cosmetics (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

La présente invention est une composition qui, une fois appliquée par-dessus une composition de rouge à lèvres, empêche ledit rouge à lèvres de se transférer sur des objets tels que tasses, des verres et autres articles de table entrant en contact avec les lèvres. Lesdites compositions augmentent le laps de temps entre deux réapplications dudit rouge à lèvres et ajoutent lustre et brillant aux lèvres, tout en offrant à l'utilisateur une sensation agréable lorsqu'il les porte.
PCT/US1995/015418 1994-12-21 1995-11-28 Compositions recouvrantes pour rouge a levres contenant de l'huile de silicone et de la silice WO1996019185A1 (fr)

Priority Applications (4)

Application Number Priority Date Filing Date Title
JP8519805A JPH10508867A (ja) 1994-12-21 1995-11-28 シリコーンオイルとシリカを含有する口紅被覆用組成物
AU42889/96A AU4288996A (en) 1994-12-21 1995-11-28 Lipstick overcoat compositions comprising silicone oil and silica
EP95941483A EP0794759A1 (fr) 1994-12-21 1995-11-28 Compositions recouvrantes pour rouge a levres contenant de l'huile de silicone et de la silice
MXPA/A/1997/004720A MXPA97004720A (en) 1994-12-21 1997-06-23 Lipstick covering compositions comprising silicon and sil oil

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US36124694A 1994-12-21 1994-12-21
US08/361,246 1994-12-21

Publications (1)

Publication Number Publication Date
WO1996019185A1 true WO1996019185A1 (fr) 1996-06-27

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1995/015418 WO1996019185A1 (fr) 1994-12-21 1995-11-28 Compositions recouvrantes pour rouge a levres contenant de l'huile de silicone et de la silice

Country Status (7)

Country Link
EP (1) EP0794759A1 (fr)
JP (1) JPH10508867A (fr)
CN (1) CN1173125A (fr)
AU (1) AU4288996A (fr)
CA (1) CA2208443A1 (fr)
CO (1) CO4700279A1 (fr)
WO (1) WO1996019185A1 (fr)

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1997017058A1 (fr) * 1995-11-07 1997-05-15 The Procter & Gamble Company Compositions cosmetiques resistant au transfert
EP0829254A1 (fr) * 1996-08-26 1998-03-18 Shiseido Company Limited Composition de rouge a lèvres
FR2756174A1 (fr) * 1996-11-26 1998-05-29 Oreal Composition notamment cosmetique comprenant au moins un compose volatil, au moins une cire et au moins un compose fluorosilicone, et utilisation dudit compose fluorosilicone dans une telle composition
US5948394A (en) * 1996-01-16 1999-09-07 The Procter & Gamble Company Transfer-resistant lip compositions
US6071503A (en) * 1995-11-07 2000-06-06 The Procter & Gamble Company Transfer resistant cosmetic compositions
US6139823A (en) * 1995-11-07 2000-10-31 The Procter & Gamble Company Transfer resistant cosmetic compositions
US6406683B1 (en) 1995-11-07 2002-06-18 The Procter & Gamble Company Transfer resistant cosmetic compositions
WO2003086333A1 (fr) * 2002-04-08 2003-10-23 The Procter & Gamble Company Compositions cosmetiques anhydres pour les levres, a phase unique et resistant au transfert
WO2004091560A2 (fr) * 2003-04-14 2004-10-28 The Procter & Gamble Company Polymeres fluores modifies par la silicone, anhydres destines a des compositions cosmetiques pour les levres resistant au transfert
WO2004091559A2 (fr) 2003-04-14 2004-10-28 The Procter & Gamble Company Compositions cosmetiques anhydres pour les levres, resistant au transfert
FR2924929A1 (fr) * 2007-12-13 2009-06-19 Oreal Composition cosmetique comprenant des particules de perlite.
WO2020223026A1 (fr) * 2019-04-30 2020-11-05 Dow Global Technologies Llc Mélange polymère/huile de silice hydrophile
US20210251855A1 (en) * 2020-02-19 2021-08-19 L'oréal Two-step reactive lip system

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002087929A (ja) * 2000-09-12 2002-03-27 Kose Corp ゲル状組成物およびそれを含有してなる化粧料
US20030072780A1 (en) * 2001-09-06 2003-04-17 Ionita-Manzatu Mirela Cristina Fluid-to-powder compositions
JP5026728B2 (ja) * 2006-04-03 2012-09-19 花王株式会社 メイクアップ化粧料
CN101584647B (zh) 2008-05-20 2012-10-31 赢创德固赛特种化学(上海)有限公司 高维生素c含量油包多元醇组合物及其制备方法
US10105307B2 (en) 2010-02-05 2018-10-23 Shiseido Company, Ltd. Makeup cosmetic and makeup kit comprising the makeup cosmetic and a top coating agent
US20160198800A1 (en) * 2015-01-08 2016-07-14 Kimberly Anna O'NEILL High heel hydrogel grip pads
CN113647388A (zh) * 2021-08-12 2021-11-16 广东莱雅新化工科技有限公司 一种抑菌除臭空气清新剂及其制备方法

Citations (5)

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JPS6124512A (ja) * 1984-07-13 1986-02-03 Kobayashi Kooc:Kk 口紅オ−バ−コ−ト
EP0485012A1 (fr) * 1990-11-08 1992-05-13 The Procter & Gamble Company Composition antiperspirante liquide
JPH05221829A (ja) * 1992-02-13 1993-08-31 Kose Corp 口紅オーバーコート
JPH0624932A (ja) * 1992-03-18 1994-02-01 Isehan:Kk リップコート
JPH07196448A (ja) * 1994-01-10 1995-08-01 Isehan:Kk 口紅ニジミ止め組成物

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JPS5470437A (en) * 1977-11-16 1979-06-06 Kobayashi Kose Co Lip overcoat

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JPS6124512A (ja) * 1984-07-13 1986-02-03 Kobayashi Kooc:Kk 口紅オ−バ−コ−ト
EP0485012A1 (fr) * 1990-11-08 1992-05-13 The Procter & Gamble Company Composition antiperspirante liquide
JPH05221829A (ja) * 1992-02-13 1993-08-31 Kose Corp 口紅オーバーコート
JPH0624932A (ja) * 1992-03-18 1994-02-01 Isehan:Kk リップコート
JPH07196448A (ja) * 1994-01-10 1995-08-01 Isehan:Kk 口紅ニジミ止め組成物

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"Takon skin protectant ointment", DIALOG INFORMATION SERVICES, INC. FILE 158 DIOGENES, AN=02947228 *
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CHEMICAL ABSTRACTS, vol. 123, no. 18, 30 October 1995, Columbus, Ohio, US; abstract no. 237561, IGARASHI, HIROSHI: "Lip preparations for prevention of lip rouge blurring" *
DATABASE WPI Derwent World Patents Index; AN 94-071809 [09] *
PATENT ABSTRACTS OF JAPAN vol. 010, no. 172 (C - 354) 18 June 1986 (1986-06-18) *
PATENT ABSTRACTS OF JAPAN vol. 017, no. 674 (C - 1140) 10 December 1993 (1993-12-10) *

Cited By (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6139823A (en) * 1995-11-07 2000-10-31 The Procter & Gamble Company Transfer resistant cosmetic compositions
WO1997017059A1 (fr) * 1995-11-07 1997-05-15 The Procter & Gamble Company Compositions cosmetiques resistant au transfert
US6406683B1 (en) 1995-11-07 2002-06-18 The Procter & Gamble Company Transfer resistant cosmetic compositions
US6340466B1 (en) 1995-11-07 2002-01-22 The Procter & Gamble Company Transfer resistant cosmetic compositions
WO1997017058A1 (fr) * 1995-11-07 1997-05-15 The Procter & Gamble Company Compositions cosmetiques resistant au transfert
US6071503A (en) * 1995-11-07 2000-06-06 The Procter & Gamble Company Transfer resistant cosmetic compositions
US6074654A (en) * 1995-11-07 2000-06-13 The Procter & Gamble Company Transfer resistant cosmetic compositions
US5948394A (en) * 1996-01-16 1999-09-07 The Procter & Gamble Company Transfer-resistant lip compositions
US6063391A (en) * 1996-08-26 2000-05-16 Shiseido Co., Ltd. Lipstick composition
EP0829254A1 (fr) * 1996-08-26 1998-03-18 Shiseido Company Limited Composition de rouge a lèvres
FR2756174A1 (fr) * 1996-11-26 1998-05-29 Oreal Composition notamment cosmetique comprenant au moins un compose volatil, au moins une cire et au moins un compose fluorosilicone, et utilisation dudit compose fluorosilicone dans une telle composition
WO2003086333A1 (fr) * 2002-04-08 2003-10-23 The Procter & Gamble Company Compositions cosmetiques anhydres pour les levres, a phase unique et resistant au transfert
AU2004229575B2 (en) * 2003-04-14 2007-04-19 The Procter & Gamble Company Anhydrous, transfer-resistant cosmetic lip compositions
WO2004091559A2 (fr) 2003-04-14 2004-10-28 The Procter & Gamble Company Compositions cosmetiques anhydres pour les levres, resistant au transfert
WO2004091559A3 (fr) * 2003-04-14 2004-12-02 Procter & Gamble Compositions cosmetiques anhydres pour les levres, resistant au transfert
WO2004091560A2 (fr) * 2003-04-14 2004-10-28 The Procter & Gamble Company Polymeres fluores modifies par la silicone, anhydres destines a des compositions cosmetiques pour les levres resistant au transfert
KR100762154B1 (ko) * 2003-04-14 2007-10-04 더 프록터 앤드 갬블 캄파니 무수의 내이전성의 화장용 입술 조성물
WO2004091560A3 (fr) * 2003-04-14 2008-01-10 Procter & Gamble Polymeres fluores modifies par la silicone, anhydres destines a des compositions cosmetiques pour les levres resistant au transfert
US7871633B2 (en) 2003-04-14 2011-01-18 The Procter & Gamble Company Anhydrous, transfer-resistant cosmetic lip compositions
FR2924929A1 (fr) * 2007-12-13 2009-06-19 Oreal Composition cosmetique comprenant des particules de perlite.
WO2020223026A1 (fr) * 2019-04-30 2020-11-05 Dow Global Technologies Llc Mélange polymère/huile de silice hydrophile
US11931447B2 (en) 2019-04-30 2024-03-19 Dow Global Technologies Llc Polymer/hydrophilic silica oil blend
US20210251855A1 (en) * 2020-02-19 2021-08-19 L'oréal Two-step reactive lip system

Also Published As

Publication number Publication date
CO4700279A1 (es) 1998-12-29
MX9704720A (es) 1997-10-31
AU4288996A (en) 1996-07-10
CN1173125A (zh) 1998-02-11
JPH10508867A (ja) 1998-09-02
EP0794759A1 (fr) 1997-09-17
CA2208443A1 (fr) 1996-06-27

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