WO1995012312A1 - Produits inhibiteurs de la penetration et de la traversee des racines - Google Patents

Produits inhibiteurs de la penetration et de la traversee des racines Download PDF

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Publication number
WO1995012312A1
WO1995012312A1 PCT/EP1994/003492 EP9403492W WO9512312A1 WO 1995012312 A1 WO1995012312 A1 WO 1995012312A1 EP 9403492 W EP9403492 W EP 9403492W WO 9512312 A1 WO9512312 A1 WO 9512312A1
Authority
WO
WIPO (PCT)
Prior art keywords
acid
phenoxycarboxylic acid
phenoxycarboxylic
carrier material
inorganic carrier
Prior art date
Application number
PCT/EP1994/003492
Other languages
German (de)
English (en)
Inventor
Lutz Heuer
Heinz-Joachim Rother
Lothar Puppe
Original Assignee
Bayer Aktiengesellschaft
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer Aktiengesellschaft filed Critical Bayer Aktiengesellschaft
Priority to AU80598/94A priority Critical patent/AU8059894A/en
Priority to EP94931545A priority patent/EP0726707A1/fr
Priority to JP7512986A priority patent/JPH10508001A/ja
Priority to PL94314176A priority patent/PL314176A1/xx
Publication of WO1995012312A1 publication Critical patent/WO1995012312A1/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N39/00—Biocides, pest repellants or attractants, or plant growth regulators containing aryloxy- or arylthio-aliphatic or cycloaliphatic compounds, containing the group or, e.g. phenoxyethylamine, phenylthio-acetonitrile, phenoxyacetone
    • A01N39/02—Aryloxy-carboxylic acids; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N39/00—Biocides, pest repellants or attractants, or plant growth regulators containing aryloxy- or arylthio-aliphatic or cycloaliphatic compounds, containing the group or, e.g. phenoxyethylamine, phenylthio-acetonitrile, phenoxyacetone
    • A01N39/02—Aryloxy-carboxylic acids; Derivatives thereof
    • A01N39/04—Aryloxy-acetic acids; Derivatives thereof

Definitions

  • the present invention relates to substances and preparations which protect buildings, seals and insulation against ingrowth and through-growth of roots.
  • the substances are used for the production of root-resistant building materials such as bitumen mixtures, sealants and insulating materials.
  • Root growth in building materials leads to unwanted material damage. Particularly plastic materials, such as sealing compounds, roofing membranes, but also asphalt can be destroyed by plant roots.
  • plastic materials such as sealing compounds, roofing membranes, but also asphalt can be destroyed by plant roots.
  • the penetration of roots in the seals of sewers and sewage pipes, in flat roof covers, in bitumen insulation of pipes, bridges and water structures as well as the ingrowth and ingrowth of roots on light bitumen roads are generally known problems. This can result in leaks, corrosion, damage to buildings, roads and pipelines.
  • herbicides such as, for example, 2,4-dichlorophenoxyacetic acid, 2,4,5-trichlorophenoxyacetic acid and ⁇ -naphthylacetic acid or their salts, amides or esters, for example isooctyl ester or esters of l-hydroxy-2-butoxyethane, furthermore phenyl- N-isopropyl carbaminate and p-chlorophenyldimethylurea can be used as root inhibitors (DE 1 108 833).
  • phenoxycarbon acids as herbicides has long been known (see, eg, The Agrochemicals Handbook, 3 r d Ed, Royal Soc Chem., Cambridge 1993).
  • Building materials include to understand bituminous building materials as well as concrete or building materials containing concrete, as well as those that e.g. be described in WO 92/10 537.
  • the application therefore relates to the use of phenoxycarboxylic acid bonded to an inorganic support material for protecting buildings, insulation and seals against root penetration.
  • R 1 to R 5 independently of one another represent F_-Br, CI, F, CF3, CF2H, methyl, ethyl, propyl, methoxy, OCF3 and R 6 stands for H, Me, Et
  • Preferred compounds of the formula (I) are those in which R 1 represents Me, CI, CF 3 , R 2 to R 5 represent H, CI, F, methyl, CF 3 and R 6 represents H, Me.
  • R 2 , R 4 , R 5 stand for H, R 3 is CI and R 6 is Me.
  • Suitable support materials include: e.g. nat. and synthetic zeolites, layered silicates, clays, precipitated silicas, diatomaceous earth, silica gels, aerosils, bentonites, kaolins, activated carbons, natural and synthetic clay minerals, TiO 2, ZnO, calcium carbonate, dolomites, pumice stones, attapulgites, sepiolites, ball clays, clays, as well as aluminophosphates , Metal aluminophosphates and crystalline silicas with pore structure.
  • zeolites or molecular sieves which come under the following formula, have proven to be particularly suitable support materials:
  • M is an exchangeable cation
  • E ⁇ means a trivalent element
  • E 2 is a tetravalent element, E ⁇ and E 2 being the anionic skeleton,
  • n / m is the ratio of the elements E ⁇ and E 2 and can have values of 1 to 3,000, preferably 1 to 2,000,
  • the zeolites having pore sizes of at least 4 ⁇ , for example pore sizes in the range from 4 to 8 ⁇ , preferably in the range 5 to 8 ⁇ .
  • the basic structure is made of zeolites from a network of SiO-4 and AIO4
  • Tetrahedron constructed, whereby the individual tetrahedra are linked with each other by oxygen bridges via their corners and form a spatial network that is moderately crisscrossed by channels and cavities.
  • the aluminum as a representative of the element E * can be partially replaced by other trivalent or divalent elements such as B, Ga, In, Fe, Cr, V, As, Sb or Be, Cu and Co.
  • the silicon as a representative of the element E 2 can be replaced by other tetravalent elements, such as Ge. Interchangeable cations are stored to compensate for the negative charge of the lattice caused by the trivalent elements.
  • the individual zeolite structures (types) also differ in the arrangement and size of the channels and cavities.
  • Zeolites always contain q H 2 O as a sorbed water phase, which can be removed reversibly without the structure losing its structure.
  • a detailed description of zeolites can be found, for example, in the monograph "Introduction to Zeolite Science and Practice” Ed. H. van Bekkum, EM Flanigen, JC Jansen in the series Studies in Surface Science and Catalysis, Vol. 58, Elsevier, Amsterdam, Oxford, New York, Tokyo, 1991.
  • aluminophosphates such as e.g. A1PO-5, A1PO-11, AJPO-8, A1PO-17 and silicoaluminophosphates such as e.g. S.APO-5, SAPO-11, SAPO-34, SAPO 17 and others.
  • layered silicates such as e.g. Magadiit or SKS-6 suitable as a carrier material.
  • zeolites Preferred among the zeolites are the easily accessible zeolite structures such as zeolite A and faujasite with the types zeolite X and zeolite Y and the following formulas: Type A Na 12 [(AlO 2 ) ⁇ 2 • (SiO 2 ) ⁇ ] • 2 ? H 2 0
  • Type X Na 86 [AlO 2 ) 86 • (SiO 2 ) 106 ] • 2 64 H 2 O
  • the various ion-exchanged forms are also suitable as a carrier material.
  • the carriers are loaded with the phenoxycarboxylic acids in different ways adapted to the respective carrier material. Such techniques would e.g. described in DE 1 219 008.
  • the loading of molecular sieves or zeolites e.g. in that the molecular sieve is first freed of water by heating, which e.g. can be done by heating to 400 to 450 ° C for several hours, and then brought into contact with the active substance.
  • Loading takes place in any way, e.g. by passing the active substance brought into the vapor form through the zeolite or by immersing the zeolite in the liquid or molten active substance or a solution of the active substance in a non-polar, volatile solvent with subsequent evaporation of the solvent.
  • the amount of active substance with which the carrier material is loaded can vary within wide limits. It depends on the active ingredient used and the conditions under which the carrier / active ingredient combination is to be used.
  • amounts of from 0.1 to about 90% by weight of active compound, preferably 5 to 70%, particularly preferably 10 to 50%, based on the carrier material, are applied.
  • the maximum loading is preferably selected in order to achieve a high active ingredient concentration per mass of starting material.
  • the phenoxycarboxylic acid is preferably mixed in its crystalline form with the carrier material and together to a temperature above its melting point warmed up.
  • the carrier material water, oxygen, air etc. may have to be excluded.
  • auxiliaries can also be added to the mixture of carrier material and phenoxycarboxylic acid, e.g. reduce dusting of the mixture or sensitivity to water.
  • phenoxycarboxylic acid / carrier combinations are used directly or in the form of other preparations such as e.g. mixed with bitumen, tar pitch, building materials or insulating materials. It is also possible to separate the carrier material and the phenoxycarboxylic acid separately but at the same time to add it to the building materials.
  • the content of phenoxycarboxylic acid in the bitumen is 0.01 to 20% by weight, preferably 0.1 to 5%, particularly preferably 0.3 to 2%.
  • the content of phenoxycarboxylic acid in bituminous building * _ ⁇ n results from the application concentration of the acid in the bitumen and the bitumen content in the building materials. It is generally 0.05 to 0.5%.
  • the fixed phenoxycarboxylic acid can also be added to these and worked in together with them.
  • Example 2 Analogously to Example 1, only with H zeolite Y, a dealuminated zeolite Y with an SiO 2 / Al 2 ⁇ 3 ratio of 90.

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

L'invention concerne des matériaux de construction, des matériaux d'étanchéité et des matières isolantes renfermant une combinaison d'acides phénoxycarboxyliques spéciaux qui sont liés à un matériau-support inorganique.
PCT/EP1994/003492 1993-11-05 1994-10-24 Produits inhibiteurs de la penetration et de la traversee des racines WO1995012312A1 (fr)

Priority Applications (4)

Application Number Priority Date Filing Date Title
AU80598/94A AU8059894A (en) 1993-11-05 1994-10-24 Rooting inhibitors
EP94931545A EP0726707A1 (fr) 1993-11-05 1994-10-24 Produits inhibiteurs de la penetration et de la traversee des racines
JP7512986A JPH10508001A (ja) 1993-11-05 1994-10-24 根侵入抑制剤
PL94314176A PL314176A1 (en) 1993-11-05 1994-10-24 Root system development inhibitors

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DEP4337844.7 1993-11-05
DE19934337844 DE4337844A1 (de) 1993-11-05 1993-11-05 Durchwurzelungsinhibitoren

Publications (1)

Publication Number Publication Date
WO1995012312A1 true WO1995012312A1 (fr) 1995-05-11

Family

ID=6501924

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP1994/003492 WO1995012312A1 (fr) 1993-11-05 1994-10-24 Produits inhibiteurs de la penetration et de la traversee des racines

Country Status (7)

Country Link
EP (1) EP0726707A1 (fr)
JP (1) JPH10508001A (fr)
AU (1) AU8059894A (fr)
CZ (1) CZ130796A3 (fr)
DE (1) DE4337844A1 (fr)
PL (1) PL314176A1 (fr)
WO (1) WO1995012312A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1068662B1 (fr) * 1998-03-30 2009-09-02 Höganäs Ab Element de machine electrique

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004000953A1 (fr) 2002-06-19 2003-12-31 Thor Gmbh Materiau d'enduction contenant des microcapsules de biocide
GB0822004D0 (en) * 2008-12-02 2009-01-07 Syngenta Participations Ag Building materials resistant to root penetration and methods for making the same
DE202015105377U1 (de) * 2015-10-12 2017-01-13 Rehau Ag + Co Rohranordnung
AT517786A1 (de) * 2015-10-13 2017-04-15 Zsifkovits Wilhelm Verwendung von Aryloxyphenoxypropionsäure-Herbiziden zum Schutz für Bauwerksabdichtungen und diese enthaltende Bitumenbahnen
JP7430878B2 (ja) * 2020-01-23 2024-02-14 ユニチカ株式会社 防つるシート

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1108833B (de) * 1958-08-05 1961-06-15 Bayer Ag Wurzelfeste bzw. wurzelabweisende Dichtungs- und Vergussmassen fuer unterirdisch verlegte Wasserleitungen
DE1567066A1 (de) * 1959-03-17 1970-04-16 Shell Res Ltd Pflanzenbiologisch wirksame feste Zubereitungen
DD98102A1 (fr) * 1972-09-04 1973-06-12
DD130269A1 (de) * 1977-03-28 1978-03-15 Gerhard Schmaland Verfahren zum schutz von dichtungselementen im wasserbau gegen pflanzendurchwuchs
EP0001328A1 (fr) * 1977-09-23 1979-04-04 FISONS plc Procédé et composition pour la lutte contre les mauvaises herbes
DE3329100A1 (de) * 1983-08-11 1985-02-28 Oskar Dipl.-Ing. Innsbruck Hohenbruck Verfahren zum schutz erdverlegter gegenstaende vor einer beschaedigung durch pflanzenwurzeln
JPH0227004A (ja) * 1988-07-15 1990-01-29 Seiki Tokyu Kogyo Kk アスファルト舗装側端部とコンクリート構造物との継目部の雑草成育抑制を目的とした継目用充填接合材，継目用成形接合材及び継目処理方法
EP0456108A2 (fr) * 1990-05-10 1991-11-13 BASF Aktiengesellschaft Agent herbicide comprenant un N-phényl-3,4,5,6-tétrahydrophtalimide et un dérivé d'acide phénoxyalcane carboxylique

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1108833B (de) * 1958-08-05 1961-06-15 Bayer Ag Wurzelfeste bzw. wurzelabweisende Dichtungs- und Vergussmassen fuer unterirdisch verlegte Wasserleitungen
GB916489A (en) * 1958-08-05 1963-01-23 Bayer Ag Root-resistant and root-repellent packing and sealing compounds for underground water pipes
DE1567066A1 (de) * 1959-03-17 1970-04-16 Shell Res Ltd Pflanzenbiologisch wirksame feste Zubereitungen
DD98102A1 (fr) * 1972-09-04 1973-06-12
DD130269A1 (de) * 1977-03-28 1978-03-15 Gerhard Schmaland Verfahren zum schutz von dichtungselementen im wasserbau gegen pflanzendurchwuchs
EP0001328A1 (fr) * 1977-09-23 1979-04-04 FISONS plc Procédé et composition pour la lutte contre les mauvaises herbes
DE3329100A1 (de) * 1983-08-11 1985-02-28 Oskar Dipl.-Ing. Innsbruck Hohenbruck Verfahren zum schutz erdverlegter gegenstaende vor einer beschaedigung durch pflanzenwurzeln
JPH0227004A (ja) * 1988-07-15 1990-01-29 Seiki Tokyu Kogyo Kk アスファルト舗装側端部とコンクリート構造物との継目部の雑草成育抑制を目的とした継目用充填接合材，継目用成形接合材及び継目処理方法
EP0456108A2 (fr) * 1990-05-10 1991-11-13 BASF Aktiengesellschaft Agent herbicide comprenant un N-phényl-3,4,5,6-tétrahydrophtalimide et un dérivé d'acide phénoxyalcane carboxylique

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
DATABASE WPI Week 6800, Derwent World Patents Index; AN 67-08080G [00] *
DATABASE WPI Week 9010, Derwent World Patents Index; AN 90-072577 [10] *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1068662B1 (fr) * 1998-03-30 2009-09-02 Höganäs Ab Element de machine electrique

Also Published As

Publication number Publication date
PL314176A1 (en) 1996-08-19
DE4337844A1 (de) 1995-05-11
EP0726707A1 (fr) 1996-08-21
JPH10508001A (ja) 1998-08-04
CZ130796A3 (en) 1996-07-17
AU8059894A (en) 1995-05-23

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