WO1995008521A1 - Fertilisers comprising nutrient and phosphate solubilising fungus - Google Patents
Fertilisers comprising nutrient and phosphate solubilising fungus Download PDFInfo
- Publication number
- WO1995008521A1 WO1995008521A1 PCT/NZ1994/000099 NZ9400099W WO9508521A1 WO 1995008521 A1 WO1995008521 A1 WO 1995008521A1 NZ 9400099 W NZ9400099 W NZ 9400099W WO 9508521 A1 WO9508521 A1 WO 9508521A1
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- WO
- WIPO (PCT)
- Prior art keywords
- composition
- liquid
- fertilising composition
- micro
- coating
- Prior art date
Links
- 235000015097 nutrients Nutrition 0.000 title claims abstract description 63
- 241000233866 Fungi Species 0.000 title claims abstract description 55
- 229910019142 PO4 Inorganic materials 0.000 title claims abstract description 25
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 title claims abstract description 19
- 239000010452 phosphate Substances 0.000 title claims abstract description 19
- 239000000203 mixture Substances 0.000 claims abstract description 149
- 239000007788 liquid Substances 0.000 claims abstract description 79
- 239000000463 material Substances 0.000 claims abstract description 79
- 244000005700 microbiome Species 0.000 claims abstract description 58
- 230000001850 reproductive effect Effects 0.000 claims abstract description 39
- 238000000576 coating method Methods 0.000 claims abstract description 38
- 239000011248 coating agent Substances 0.000 claims abstract description 35
- 230000012010 growth Effects 0.000 claims abstract description 11
- 239000007787 solid Substances 0.000 claims abstract description 8
- 239000003085 diluting agent Substances 0.000 claims abstract description 6
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 5
- 239000011230 binding agent Substances 0.000 claims abstract description 4
- 239000002367 phosphate rock Substances 0.000 claims description 24
- 241000251468 Actinopterygii Species 0.000 claims description 23
- 238000000034 method Methods 0.000 claims description 23
- 239000000499 gel Substances 0.000 claims description 17
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 12
- 241001474374 Blennius Species 0.000 claims description 7
- 229910021529 ammonia Inorganic materials 0.000 claims description 6
- 230000002538 fungal effect Effects 0.000 claims description 6
- 239000002245 particle Substances 0.000 claims description 6
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 5
- 239000011707 mineral Substances 0.000 claims description 5
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims description 5
- 241000589516 Pseudomonas Species 0.000 claims description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 4
- 150000004676 glycans Chemical class 0.000 claims description 4
- 229920001282 polysaccharide Polymers 0.000 claims description 4
- 239000005017 polysaccharide Substances 0.000 claims description 4
- 238000002360 preparation method Methods 0.000 claims description 4
- 241000131314 Aspergillus candidus Species 0.000 claims description 3
- 241000228197 Aspergillus flavus Species 0.000 claims description 3
- 241000228245 Aspergillus niger Species 0.000 claims description 3
- 241000122818 Aspergillus ustus Species 0.000 claims description 3
- 241001530056 Athelia rolfsii Species 0.000 claims description 3
- 241000122173 Cylindrocladium Species 0.000 claims description 3
- 241000192125 Firmicutes Species 0.000 claims description 3
- 241000223221 Fusarium oxysporum Species 0.000 claims description 3
- 241000427940 Fusarium solani Species 0.000 claims description 3
- 241000228129 Penicillium janthinellum Species 0.000 claims description 3
- 241000228168 Penicillium sp. Species 0.000 claims description 3
- 230000015556 catabolic process Effects 0.000 claims description 3
- 241000228212 Aspergillus Species 0.000 claims description 2
- 241000194107 Bacillus megaterium Species 0.000 claims description 2
- 238000010521 absorption reaction Methods 0.000 claims description 2
- 230000009471 action Effects 0.000 claims description 2
- 238000001704 evaporation Methods 0.000 claims description 2
- 230000008020 evaporation Effects 0.000 claims description 2
- 239000001828 Gelatine Substances 0.000 claims 2
- 229920000159 gelatin Polymers 0.000 claims 2
- 235000019322 gelatine Nutrition 0.000 claims 2
- 239000000741 silica gel Substances 0.000 claims 2
- 229910002027 silica gel Inorganic materials 0.000 claims 2
- 241000384508 Hoplostethus atlanticus Species 0.000 claims 1
- 241000223261 Trichoderma viride Species 0.000 claims 1
- 241000846734 Umbelopsis longicollis Species 0.000 claims 1
- 241000907980 Umbelopsis nana Species 0.000 claims 1
- 230000002745 absorbent Effects 0.000 claims 1
- 239000002250 absorbent Substances 0.000 claims 1
- 238000006731 degradation reaction Methods 0.000 claims 1
- 238000010586 diagram Methods 0.000 claims 1
- 239000008187 granular material Substances 0.000 claims 1
- 239000002689 soil Substances 0.000 abstract description 37
- 239000003337 fertilizer Substances 0.000 abstract description 27
- 239000000758 substrate Substances 0.000 abstract description 7
- 230000009286 beneficial effect Effects 0.000 abstract description 3
- 230000003190 augmentative effect Effects 0.000 abstract 1
- 230000000694 effects Effects 0.000 abstract 1
- 235000021317 phosphate Nutrition 0.000 description 21
- 235000013372 meat Nutrition 0.000 description 9
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 7
- 239000007921 spray Substances 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 241000528415 Moana Species 0.000 description 5
- 230000008901 benefit Effects 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 239000011343 solid material Substances 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 235000010755 mineral Nutrition 0.000 description 4
- 238000009331 sowing Methods 0.000 description 4
- 229920001817 Agar Polymers 0.000 description 3
- 241000894006 Bacteria Species 0.000 description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 3
- YYRMJZQKEFZXMX-UHFFFAOYSA-N calcium;phosphoric acid Chemical class [Ca+2].OP(O)(O)=O.OP(O)(O)=O YYRMJZQKEFZXMX-UHFFFAOYSA-N 0.000 description 3
- 239000000284 extract Substances 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 229910052698 phosphorus Inorganic materials 0.000 description 3
- 239000011574 phosphorus Substances 0.000 description 3
- 102000004169 proteins and genes Human genes 0.000 description 3
- 108090000623 proteins and genes Proteins 0.000 description 3
- 239000002426 superphosphate Substances 0.000 description 3
- 235000013619 trace mineral Nutrition 0.000 description 3
- 239000011573 trace mineral Substances 0.000 description 3
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 2
- 235000011941 Tilia x europaea Nutrition 0.000 description 2
- 238000007792 addition Methods 0.000 description 2
- 235000010419 agar Nutrition 0.000 description 2
- 239000008272 agar Substances 0.000 description 2
- 239000005557 antagonist Substances 0.000 description 2
- 230000001580 bacterial effect Effects 0.000 description 2
- 239000000084 colloidal system Substances 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 239000001963 growth medium Substances 0.000 description 2
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 2
- 239000002054 inoculum Substances 0.000 description 2
- 239000004571 lime Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 238000010899 nucleation Methods 0.000 description 2
- 230000008635 plant growth Effects 0.000 description 2
- 241000894007 species Species 0.000 description 2
- 230000007480 spreading Effects 0.000 description 2
- 238000003892 spreading Methods 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 239000002562 thickening agent Substances 0.000 description 2
- UHPMCKVQTMMPCG-UHFFFAOYSA-N 5,8-dihydroxy-2-methoxy-6-methyl-7-(2-oxopropyl)naphthalene-1,4-dione Chemical compound CC1=C(CC(C)=O)C(O)=C2C(=O)C(OC)=CC(=O)C2=C1O UHPMCKVQTMMPCG-UHFFFAOYSA-N 0.000 description 1
- 241000223218 Fusarium Species 0.000 description 1
- 241000235503 Glomus Species 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 241000244206 Nematoda Species 0.000 description 1
- 241001646398 Pseudomonas chlororaphis Species 0.000 description 1
- 241000589157 Rhizobiales Species 0.000 description 1
- 241000607717 Serratia liquefaciens Species 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000003868 ammonium compounds Chemical class 0.000 description 1
- 239000012681 biocontrol agent Substances 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- 210000000988 bone and bone Anatomy 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 239000000679 carrageenan Substances 0.000 description 1
- 235000010418 carrageenan Nutrition 0.000 description 1
- 229920001525 carrageenan Polymers 0.000 description 1
- 229940113118 carrageenan Drugs 0.000 description 1
- 239000002361 compost Substances 0.000 description 1
- 238000009264 composting Methods 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 238000012258 culturing Methods 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 239000010459 dolomite Substances 0.000 description 1
- 229910000514 dolomite Inorganic materials 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 230000035784 germination Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000003501 hydroponics Substances 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000010808 liquid waste Substances 0.000 description 1
- 239000002609 medium Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 244000052769 pathogen Species 0.000 description 1
- 235000010958 polyglycerol polyricinoleate Nutrition 0.000 description 1
- 150000003112 potassium compounds Chemical class 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 239000011253 protective coating Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 230000002786 root growth Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 230000004936 stimulating effect Effects 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05B—PHOSPHATIC FERTILISERS
- C05B17/00—Other phosphatic fertilisers, e.g. soft rock phosphates, bone meal
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01G—HORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
- A01G18/00—Cultivation of mushrooms
- A01G18/10—Mycorrhiza; Mycorrhizal associations
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
- C05F11/00—Other organic fertilisers
- C05F11/08—Organic fertilisers containing added bacterial cultures, mycelia or the like
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/20—Liquid fertilisers
- C05G5/23—Solutions
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/20—Liquid fertilisers
- C05G5/27—Dispersions, e.g. suspensions or emulsions
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G5/00—Fertilisers characterised by their form
- C05G5/30—Layered or coated, e.g. dust-preventing coatings
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/141—Feedstock
- Y02P20/145—Feedstock the feedstock being materials of biological origin
Definitions
- the present invention is directed towards fertilisers. More specifically, many embodiments are directed to provide fertilisers for the introduction and rapid establishment of useful fungi and micro organisms in the soil.
- a liquid carrier comprising a plant nutrient, and which includes fungus, micro organisms and/or reproductive material therefor, is investigated. Fertilising compositions based on the aforesaid liquid fertilising composition and a rock phosphate are also described.
- fungus and bacteria may have other roles in the soil, such assisting in the breakdown of plant matter, or making nutrients available to plants. Others having found to be beneficial for assisting in the germination of seeds, or in t ⁇ rapid growth of germinated seedlings. In some cases, seeds have been coated with fungus or micro ⁇ organism containing coatings.
- a liquid fertilising composition substantially free of solid matter, comprising a plant nutrient in a liquid form, and at least one introduced fungus, micro-organism, and/or reproductive material therefor.
- a liquid fertilising composition substantially free of solid matter, comprising: a plant nutrient, a diluent or carrier, at least one introduced fungus, micro-organism and/or reproductive material therefor, and - a binding agent, said composition being characterised that when applied to a surface, there is formed a coating having at least one of the properties of being porous, slowly soluble, and degradable through weathering or the action of the introduced fungus, micro-organism and/or reproductive material therefor, said coating retaining at least a portion of said introduced fungus, micro-organism and/or reproductive material therefor.
- liquid fertilising composition substantially as described above, wherein said introduced fungus, micro ⁇ organism, and/or reproductive material therefor, are phosphate solubilising.
- liquid fertilising composition substantially as described above wherein said introduced fungus, micro- organisms and/or reproductive material therefor, are able to act on a contained nitrogenous nutrient to liberate free ammonia.
- liquid fertilising composition substantially as described above in which said plant nutrient is a fish based nutrient composition.
- liquid fertilising composition substantially as described above which includes a viscosity increaSi.ig agent.
- a liquid fertilising composition in combination with a phosphate rock.
- a fertilising composition comprising a phosphate rock impregnated with a composition substantially as described above.
- a fertilising composition comprising a phosphate rock coated with a composition substantially as described above.
- liquid plant nutrient wherever used herein shall refer to a substance suitable as a plant nutrient, a substance commonly used or recognised as a plant fertilising or nutrient substance, and/or a prepared composition the equivalent of the foregoing. While a wide range of materials could fit the role as a plant nutrient, most liquid plant nutrients within the above definition shall be a source of at least one of the NPKS elements. Quite often, it will also be a source of two or more of these elements and may also be a source of plant available trace elements.
- Most embodiments of the present invention will be in liquid form and substantially solid free, other than introduced fungus, micro organisms and/or reproductive material therefor, and variations which include phosphate rock. Consequently, most of the nutrients will be in a liquid form, or in a very fine form. They may be present as a colloid or suspension, though typically a composition should be able to be applied with normal fluid spray application equipment. It is envisaged that occasionally solid material, which may accidentally escape any manufacturing process, may sometimes be present. However, as a general rule the compositions according to the present invention are fluid and substantially free of any, other than finely divided, solid material.
- a wide range of plant available nutrients may be used. Many inorganic fertilisers are known which are readily soluble in water and may be incorporated into compositions. Similarly, organic-derived nutrients may be employed, such as compositions prepared plant material, from fish and marine material, or waste from meat processing plants. These 'organic' based nutrients/fertilisers may in some cases be advantageous as they may contain other nutrients and substances which are better able to support introduced fungus, micro organisms and their reproductive material.
- a nitrogenous nutrient source In some instances it is desirable to include a nitrogenous nutrient source. This is especially so in the case where there is introduced fungi, micro-organisms or reproductive material therefor, whose primary purpose is the liberation of ammonia from nitrogenous materials. This may be desirable to assist, in some cases, with the break down and solubilisation of phosphate materials. In some-other instances, it may be desirable to rely on the liberation of ammonia for introducing nitrogen into the soil, or to adversely affect undesirable organisms in the soil.
- the liquid portion of a composition may be thickened to increase its viscosity.
- the degree of thickening is largely a matter of user choice though it is envisaged that up to gel like consistencies may be employed in some instances.
- the planting of seeds in a gel carrier is known and a gel like composition according to the present invention may be used in such an application. So that the newly germinating seed is not over fertilised, it may be desirable to reduce the plant nutrient proportion to a relatively low level or to incorporate such a composition into another gel-like preparation. In some cases it is desirable that a composition according to the present invention is able to coat materials to which it is applied. In many instances a gel-like coating will be acceptable.
- a coating may be useful for a number of functions.
- the coating may contain introduced fungii, micro-organisms and/or reproductive material therefor.
- the coating may provide a suitable growing support for the initial establishment of these organisms.
- the coating may serve to protect (until use) or to retard the rate of establishment or release of the contained nutrients and organisms.
- it is considered most likely that the compositions will be applied to coat a fertilising material such as natural rock phosphate.
- a significant proportion of the composition will be absorbed though a semi-protective coating may remain, depending on the nature of the compositions.
- Coatings may be formed in a variety of ways. Perhaps the simplest method of providing a coating is for there to be removal of a carrier or diluent present in the composition. This may be by evaporation (which may be accelerated by heating) or by absorption into the substance to which the composition is applied. Other coatings may set or cure when applied, or over a period of time. Various other techniques and varying combinations of techniques may also be employed.
- the properties of the coating, where provided, may vary.
- the coating should have at least one of the properties of: being porous, being at least slowly soluble, being degradable by weathering, being degradable by contained organisms, and/or being degradable during the growth and establishment of organisms in a composition.
- a wide variety of materials may therefore be relied upon to form a coating.
- Preferred substances include the use of a seaweed based materials (e.g. agars, carrageenan etc.), polysaccharide gums, other gums and resins (typically plant based), silica gels etc. In many cases these materials which are readily able to form gels which typically possess at least one of the preferred coating properties.
- the coating may itself contain at least a portion of the introduced organisms and/or nutrients of the composition. This may assist in the rapid establishment of fungal and/or micro-organism colonies in the coating while the more gradual or delayed release of other organisms within the substrate material may ensue over time.
- compositions according to the present invention are varied. Some of these organisms will be targeted because of their ability to breakdown substances in the soil and release plant available nutrients. An example is the inclusion of organisms which are able to release phosphorous from insoluble phosphate rock. Other organisms are noted as biological control agents and in another example, compositions according to the present invention may also act as a suitable vehicle for the introduction of these bacterial bio- control agents. For instance, Sayre and Walter (Annu .Rev. Phytopathal. 29 (1991) pl49-166) discuss nematode suppressive soils infected with fungal and bacterial antagonists. Such antagonists may be incorporated in embodiments of the present invention.
- compositions according to the present invention represent a useful vehicle for the introduction of such micro organisms to soils, and their inclusion at the time of sowing (see gel planting method above) represents a useful method of the introduction of beneficial organisms into the soil.
- compositions according to the present invention can be specifically targeted for applica t i on to effective specific areas.
- VAMs may be introduced in seed drills at the time of sowing seed by sowing the seeds in the gel comprising a suitable composition according to the present invention.
- a liquid composition could be sprayed or injected into seed drills immediately after sowing.
- a desirable fungus, micro-organism and/or their reproductive material may be efficiently and selectively introduced to soil (or plant support medium) using existing farm and agricultural equipment.
- organisms which may be included in embodiments of the present invention include members of the genus Aspergillus, Fusarium and Penicilliwn. Most members of these fungal groups are useful though in particular the following may be specifically targeted:
- micro-organisms which may be targeted for establishment include bacillus Megatherium phosphaticum and strains thereof, gram-positive bacteria and members of the genus Pseudomonas.
- bacillus Megatherium phosphaticum and strains thereof include bacillus Megatherium phosphaticum and strains thereof, gram-positive bacteria and members of the genus Pseudomonas.
- the above listed organisms will generally be included where is desirable to release for plants, nutrients locked into the soil. Many of the foregoing exhibit phosphate solubilising properties and are useful where less soluble forms of phosphate fertilisers (e.g. rock phosphate) have been applied to a soil. Some of the micro-organisms are also able to liberate free ammonia from nutrients present in the soil. This may be useful for some plants, though it has been noted that the liberation of free ammonia can sometimes increase the solubility of phosphates in the soil.
- phosphate fertilisers e.g. rock phosphate
- Some of the micro-organisms are also able to liberate free ammonia from nutrients present in the soil. This may be useful for some plants, though it has been noted that the liberation of free ammonia can sometimes increase the solubility of phosphates in the soil.
- Examples of other organisms which may be included in various composition include VAMs (refer article by I R Hall in Bio-Technology in Agriculture, p 141-174 (1988) Publ. Alan R Liss, Inc.).
- VAMs (refer article by I R Hall in Bio-Technology in Agriculture, p 141-174 (1988) Publ. Alan R Liss, Inc.).
- Other mycorrhizal fungi may be incorporated.
- Ericoid and Ectomycorrhizal fungi inoculum can be growth in artificial cultures and may be commercially produced. These may be readily introduced into compositions according to the present invention.
- Plant growth-promoting rhizobacteria (PGPR) are also known and may be included in various compositions according to the present invention. It is noted however that some of the fungi and micro-organisms are sensitive to their environment and thus some consideration will need to be given to the liquid carrier and plant nutrient.
- fungi, micro organisms and reproductive material may be introduced from a suitable culture or inoculum.
- a composition may also be created which is able to act as a growth medium for the included organisms.
- a composition may be used as a culture medium, from which aliquots are drawn and added to new, non-inoculated batches of a liquid carrier for the preparation of a fertilising composition.
- the shelf life of such products may be relatively short if they are stored under conditions overly amenable to the rapid growth and advancement of the contained species. As the conditions will differ for each possible species, some minor experimentation may be required to determine likely shelf lives of various possible compositions.
- Substantially liquid or gel like compositions may be readily applied to soil, pasture, seeds, and plants etc. It may be desirable in some instances to apply the liquid fertilising composition to other substrates before introduction to soil etc.
- compositions of the present invention may be impregnated into normal materials. These may include natural phosphates, as well as other minerals (e.g. dolomite, lime etc.) commonly applied to plants and their growing media. Where compositions include a binding or coating material, then the application will typically be more of a coating rather than solely impregnation, though typically there will be a combination of both. The resulting products may then be applied as required to plants and/or their growing media, or according to other uses as may be envisaged.
- the liquid carrier in this example comprises a fish based fertiliser such as available from Sieber Agricultural Research Limited or Moana Fertilisers Limited, both of Baldhill Road, Waiuku, New Zealand. Another option is the use of a nutrient broth or extract such as the liquid waste of many meat and offal processing plants. It each case, the nutrients should be relatively free of solid material.
- Each of the above nutrients are relatively rich in proteins and amines. These are typically plentiful in plant available nitrogen and both of these types of nutrients will commonly be suitable for the rapid establishment of fungal or microbial colonies.
- a fish fertiliser composition (such as available from Sieber Moana) will readily support the growth of many of the desired fungi and micro-organisms.
- a nutrient broth comprising the liquid fish based fertiliser has been used to culture a range of various fungi and micro-organisms. Portions have been removed from this master culture (which has been subsequently replenished) and added to non-inoculated portions of fish based fertiliser. If only a trace amount of the master culture is added, then a period of time may be required for the level of the introduced organisms to increase in the new product batch. Alternatively, higher levels may be introduced into the non-inoculated batch if it is to be used in the immediate future.
- one option is to supply users with both inoculated and non-inoculated batches which can be subsequently used to prepare compositions for application to pasture etc. This may solve problems of a sometimes limited shelf life, and the problems of storing large volumes of a 'living' product.
- the fish base liquid fertiliser may be that marketed by Moana Fertilisers/Sieber Agricultural Research Limited of Baldhill Road, Waiuku, New Zealand. Other equivalent fertiliser compositions may also be substituted.
- composition comprising, by weight up to a total of 100%:
- liquid fish based fertiliser 0.001 - 10% at least one fungus, micro-organism or reproductive material therefor
- additional nutrients and/or trace elements may be incorporated into the mixture.
- At least Moana Fertilisers/Sieber Agricultural Research produce a liquid fish base fertiliser which is fortified by the addition of additional nutrients and/or trace elements. This may be a convenient way of introducing additional nutrients, or altering the nutrient balance of the composition.
- a finely divided phosphate material, blood and bone, and other substantially insoluble fertilisers/nutrients may also be included. It may be desirable to follow the guidelines on particle size mentioned previously.
- Example 2 B A composition comprising, by weight up to a total of 100%:
- protein based fertiliser composition such as from meat processing plant 0.001 - 10% at least one fungus, micro organism or reproductive material therefor
- composition comprising, by weight up to a total of 100%: Percentage by weight Component
- 0-98% protein based fertiliser composition from meat processing plant 0.001 - 10% at least one fungus, micro organism or reproductive material therefor
- Moana Fertilisers/Sieber Agriculture Research will commercially produce a thickened (predominantly by seaweed) fish based fertiliser on request. This may be useful for growing cultures as an alternative to the laboratory agar plates. It is also noted that this thickened composition will also be useful for embodiments where a coating is to be applied to a substrate material.
- the seaweed component can be used to form a gel like coating about substrate materials such as granular or paniculate rock phosphate.
- the viscosity of the gel coating will affect the thickness and integrity of the resulting coating.
- the viscosity will also affect the manner in which the liquid composition can be introduced to the phosphate material.
- Traditional blending techniques may be relied upon to introduce the liquid component to the solid material.
- One technique is the spray or drip application of the liquid or gel portions to the solid matter in a rotating drum or blending vat. Similar techniques have long been used for confectionery manufacture.
- Example Three The compositions of Example Three are based on inorganic fertiliser compositions and nutrients.
- composition comprising, by weight up to a total of 100%:
- Percentage by weight Component 0-99.999% solution or composition including plant available nutrients comprising at least a plant available source of at least one of the NPKS elements 0-99.9% liquid fish based fertiliser and/or meat-based fertiliser 0.001-10% at least on fungus micro organism or reproductive material therefor
- plant available nutrients comprising at least a plant available source of at least one of the NPKS elements 0-99.9% liquid fish based fertiliser and/or meat-based fertiliser 0.001-10% at least on fungus micro organism or reproductive material therefor
- inorganic and mineral type fertilising elements though organic and semi-organic derived nutrients may also be included.
- examples of some inorganic type nutrients include urea, the nitrates of many metals, ammonium compounds, soluble phosphate compounds, soluble sulphur and oxysulfur, soluble potassium compounds.
- organically derived nutrients include liquid nutrients, substantially free of solid matter (other than in the form of a colloid or suspension, or very finely divided form
- Example Four describe compositions directed to solubilising nutrients which may already be present in the soil and/or making them available to plants. It is noted that the list of fungi and micro organisms given is not meant to be restrictive, but merely by way of example only.
- Example 4 A composition comprising, by weight up to a total of $ 100% :
- the fungus and micro-organisms may comprise at least one member of a group comprising: Fusarium oxysporum, Fusarium solani, Aspergillus niger, Aspergillus candidus, Aspergillus flavus, Aspergillus ustus, Penicillium janthinellum, Penicillium sp., Sclerotium rolfsii, Cylindrocladium sp, Megatherium phosphaticum (and strains thereof), gram-positive bacteria, and members of the genus Pseudomonas.
- a composition such as described in at least Example 4 A may be applied to a soil or plant supporting base (e.g. hydroponics and non-soil based growth techniques) which is rich in insoluble phosphates.
- the liquid composition should be applied such that it can come in to contact with the phosphate material, which will accelerate the rate by which phosphate solubilising organisms affect the phosphate material.
- One method of application for a farmer would be to apply phosphates by normal spreader techniques to pasture, soil etc.
- a liquid composition (such as described in Example 4A) is then applied over the same area. It is generally preferable that the liquid composition is applied secondly so that it has a chance of impregnating the phosphate material.
- the phosphate and liquid compositions may be applied simultaneously. It is possible that the two may be merged prior to spreading though it is noted that typical spreader techniques do not usually successfully operate for wet or damp material. Consequently it is envisaged that one solution is to use a tractor or vehicle equipped with a spray boom or applicators to spray the liquid composition immediately after phosphate spreading and distribution by the same vehicle, or to spray the liquid composition onto the solid material as it leaves the vehicle.
- Example Five Another composition, given by way of example only, illustrates compositions useful for introducing VAMs and PGPRs into the soil.
- composition comprising, by weight up to a total of 100%:
- Percentage by weight Component 0-99.999% solution or composition comprising plant available nutrients, comprising at least a plant available source of at least one of the NPKS elements 0-99.9% liquid fish based fertiliser and/or meat-based fertiliser 0.001-10% at least on fungus micro organism or reproductive material therefor.
- the fungus and micro-organisms may comprise at least one member of a group comprising: Vesicular-arbuscular mycorrhizas, plant growth promoting mycorrhizal bacteria, Pseudomonas (especially fluorescent members), Serratia liquefaciens, Glomus tenuis.
- the above bacteria have generally exhibited tendencies to improve the root growth and establishment of plants. It is envisaged that the compositions of this example will typically be applied to soil and plant supporting bases near the time of planting or seeding, or soon thereafter. However advantages may also be obtained at other points in the growth cycle.
- One possible example illustrating use of the invention is as follows:
- a composition, at least as described in Example 5A is applied to soil, pasture, etc. near the time of planting or seeding.
- the liquid composition is applied to seed rows or troughs, and especially where it is likely to come in to contact by the roots of the developing plants.
- the composition may be sprayed or applied directly to the seeds or roots of plants. However, care should be taken not to burn the roots of the plants and dilution of the composition may be preferable where warranted.
- a thickened composition such as described in Example Six is prepared. Seeds are dispersed within this gel. The seeds may be newly germinated. The gel support is then used to insert the seeds into the soil using known techniques.
- compositions may be based on any of the specific examples given in this specification, or other compositions possible within the scope of the present invention. Generally the viscosity will be increased so that the composition attains a syrupy or gel like consistency. This may be achieved by the use of a thickened fertiliser base such as the seaweed thickened composition available from Moana Fertilisers/Sieber Agriculture Research. This may be used as added thickening agent or may comprise the liquid nutrient portion in its own right. Other accepted thickening agents may also be incorporated to achieve the required consistency.
- a thickened fertiliser base such as the seaweed thickened composition available from Moana Fertilisers/Sieber Agriculture Research. This may be used as added thickening agent or may comprise the liquid nutrient portion in its own right. Other accepted thickening agents may also be incorporated to achieve the required consistency.
Abstract
Description
Claims
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU76677/94A AU715303B2 (en) | 1993-09-24 | 1994-09-23 | Fertilisers comprising nutrient and phosphate solubilising fungus |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NZ248768A NZ248768A (en) | 1993-09-24 | 1993-09-24 | Liquid fertiliser; liquid plant nutrient and at least one introduced fungus, micro-organism and/or reproductive material therefor |
NZ248768 | 1993-09-24 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1995008521A1 true WO1995008521A1 (en) | 1995-03-30 |
Family
ID=19924499
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/NZ1994/000099 WO1995008521A1 (en) | 1993-09-24 | 1994-09-23 | Fertilisers comprising nutrient and phosphate solubilising fungus |
Country Status (5)
Country | Link |
---|---|
CN (1) | CN1135746A (en) |
AU (1) | AU715303B2 (en) |
CA (1) | CA2172528A1 (en) |
NZ (1) | NZ248768A (en) |
WO (1) | WO1995008521A1 (en) |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2004007404A1 (en) * | 2002-07-11 | 2004-01-22 | Norbex Holding, Ltd. | Mineral and bioorganic additive for plant growth and development |
WO2011114280A3 (en) * | 2010-03-18 | 2012-07-05 | Basf Se | Fungicidal compositions comprising comprising a phosphate solubilizing microorganism and a fungicidally active compound |
US8445256B2 (en) * | 2007-07-24 | 2013-05-21 | Novozymes A/S | Liquid mycorrhiza compositions |
US9101088B2 (en) | 2008-10-01 | 2015-08-11 | Novozymes Biologicals Limited | Methods and compositions for increasing the amounts of phosphorus available for plant uptake from soils |
US9365464B2 (en) | 2012-11-16 | 2016-06-14 | Novozymes Bioag A/S | Microbial strains, compositions, and methods for increasing available phosphate for plants |
FR3051466A1 (en) * | 2016-05-19 | 2017-11-24 | Ab7 Innovation | COMPOSITION FOR INDUCING A BIOLOGICAL EFFECT ON A PLANT TARGET |
EP3166911A4 (en) * | 2014-07-07 | 2018-03-14 | The Mosaic Company | Incorporation of biological agents in fertilizers |
US10654759B2 (en) | 2013-08-19 | 2020-05-19 | The Mosaic Company | System and methods for addition of beneficial agricultural, biological, and/or dedusting additives to granular fertilizers |
US11807587B2 (en) | 2015-08-12 | 2023-11-07 | The Mosaic Company, Inc. | Acid treatment for fertilizers to increase zinc solubility and availability |
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CN100393672C (en) * | 2005-06-15 | 2008-06-11 | 湖南大学 | Active additive for promoting agricultural waste material compost decomposition and its application |
CN101805216B (en) * | 2010-03-29 | 2012-06-06 | 浙江师范大学 | Method for locally culturing and producing arbuscular mycorrhiza fungus biological agent fertilizer in farmlands |
CN105309289B (en) * | 2015-10-15 | 2018-04-20 | 青岛农业大学 | A kind of cultural method for improving the anti-root-knot nematode of northern facility tomato |
CN105647817B (en) * | 2016-01-26 | 2019-04-26 | 华中农业大学 | The penicillium janthinellum of one plant of soil slightly solubility aluminum phosphate that reduces sourness and its application |
CN106973749A (en) * | 2017-04-14 | 2017-07-25 | 黄平县华富生态种养殖科技发展有限公司 | The implantation methods of blueberry |
CN107673914A (en) * | 2017-08-24 | 2018-02-09 | 王松堂 | Solve salt bacterium deep sea fish oil preparation technology |
CN109721444B (en) * | 2019-03-07 | 2021-06-25 | 江苏徐淮地区淮阴农业科学研究所 | Soil phosphorus activator and preparation method, application method and application thereof |
CN111718221A (en) * | 2020-05-14 | 2020-09-29 | 南京农业大学 | Composite soil remediation agent and preparation method thereof |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4327181A (en) * | 1980-05-15 | 1982-04-27 | Battelle Development Corporation | Aerobic submerged fermentation of sporulating, ectomycorrhizal fungi |
JPS63173583A (en) * | 1987-01-13 | 1988-07-18 | Akira Yamazaki | Culture of mycelium of basidiomycetes and ascomycetes |
-
1993
- 1993-09-24 NZ NZ248768A patent/NZ248768A/en unknown
-
1994
- 1994-09-23 CA CA002172528A patent/CA2172528A1/en not_active Abandoned
- 1994-09-23 AU AU76677/94A patent/AU715303B2/en not_active Ceased
- 1994-09-23 WO PCT/NZ1994/000099 patent/WO1995008521A1/en active Application Filing
- 1994-09-23 CN CN94194264A patent/CN1135746A/en active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4327181A (en) * | 1980-05-15 | 1982-04-27 | Battelle Development Corporation | Aerobic submerged fermentation of sporulating, ectomycorrhizal fungi |
JPS63173583A (en) * | 1987-01-13 | 1988-07-18 | Akira Yamazaki | Culture of mycelium of basidiomycetes and ascomycetes |
Non-Patent Citations (6)
Title |
---|
APPL. MICROBIOL. BIOTECHNOL., Vol. 24, Published 1986, MARTIN et al., "Studies on the Production of Scytalidium Acidophilum Biomass", pages 84-88. * |
J. AMER. SOC. HORT. SCI., Volume 117, Number 3, Published 1992, WILLIAMS et al., "Low, Controlled Nutrient Availability Provided by Organic Waste Material for Chrysanthemun", pages 422-429. * |
PATENT ABSTRACTS OF JAPAN, C-547, page 24; & JP,A,63 173 583 (YAMAZAKI) 18 July 1988. * |
PESTIC. SCI., Volume 37, Published 15 March 1993, ALABOUVETTE et al., "Recent Advances in the Biological Control of Fusarium Wilts", pages 365-373. * |
PROC. FLA. STATE HORT. SOC., Volume 91, Published 1978, NEMEC S., "Response of Six Citrus Rootstocks to Three Species of Glomus, a Mycorrhizal Fungus", pages 10-14. * |
THE CITRUS INDUSTRY, Volume 60(5), issued May 1979, NEMEC S., "Response of Six Citrus Rootstocks to Three Species of Glomus, a Mycorrhizal Fungus", pages 5-13. * |
Cited By (19)
Publication number | Priority date | Publication date | Assignee | Title |
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WO2004007404A1 (en) * | 2002-07-11 | 2004-01-22 | Norbex Holding, Ltd. | Mineral and bioorganic additive for plant growth and development |
US8883679B2 (en) | 2007-07-24 | 2014-11-11 | Novozymes A/S | Liquid mycorrhiza compositions |
US8445256B2 (en) * | 2007-07-24 | 2013-05-21 | Novozymes A/S | Liquid mycorrhiza compositions |
US9732007B2 (en) | 2008-10-01 | 2017-08-15 | Novozymes Biologicals Limited | Methods and compositions for increasing the amounts of phosphorus available for plant uptake from soils |
US10035735B2 (en) | 2008-10-01 | 2018-07-31 | Novozymes Biologicals Limited | Methods and compositions for increasing the amounts of phosphorus available for plant uptake from soils |
US9101088B2 (en) | 2008-10-01 | 2015-08-11 | Novozymes Biologicals Limited | Methods and compositions for increasing the amounts of phosphorus available for plant uptake from soils |
US11059759B2 (en) | 2008-10-01 | 2021-07-13 | Novozymes Biologicals Limited | Methods and compositions for increasing the amounts of phosphorus available for plant uptake from soils |
US10308561B2 (en) | 2008-10-01 | 2019-06-04 | Novozymes Biologicals Limited | Methods and compositions for increasing the amounts of phosphorus available for plant uptake from soils |
EA022448B1 (en) * | 2010-03-18 | 2016-01-29 | Басф Се | Fungicidal compositions comprising a phosphate solubilizing microorganism and a fungicidally active compound |
US9288996B2 (en) | 2010-03-18 | 2016-03-22 | Basf Se | Fungicidal compositions comprising a phosphate solubilizing microorganism and a fungicidally active compound |
WO2011114280A3 (en) * | 2010-03-18 | 2012-07-05 | Basf Se | Fungicidal compositions comprising comprising a phosphate solubilizing microorganism and a fungicidally active compound |
US9365464B2 (en) | 2012-11-16 | 2016-06-14 | Novozymes Bioag A/S | Microbial strains, compositions, and methods for increasing available phosphate for plants |
US10450237B2 (en) | 2012-11-16 | 2019-10-22 | Novozymes Bioag A/S | Microbial strains, compositions, and methods for increasing available phosphate for plants |
US9758438B2 (en) | 2012-11-16 | 2017-09-12 | Novozymes Bioag A/S | Microbial strains, compositions, and methods for increasing available phosphate for plants |
US10654759B2 (en) | 2013-08-19 | 2020-05-19 | The Mosaic Company | System and methods for addition of beneficial agricultural, biological, and/or dedusting additives to granular fertilizers |
US11084762B2 (en) | 2013-08-19 | 2021-08-10 | The Mosaic Company | System and methods for addition of beneficial agricultural, biological, and/or dedusting additives to granular fertilizers |
EP3166911A4 (en) * | 2014-07-07 | 2018-03-14 | The Mosaic Company | Incorporation of biological agents in fertilizers |
US11807587B2 (en) | 2015-08-12 | 2023-11-07 | The Mosaic Company, Inc. | Acid treatment for fertilizers to increase zinc solubility and availability |
FR3051466A1 (en) * | 2016-05-19 | 2017-11-24 | Ab7 Innovation | COMPOSITION FOR INDUCING A BIOLOGICAL EFFECT ON A PLANT TARGET |
Also Published As
Publication number | Publication date |
---|---|
NZ248768A (en) | 1996-12-20 |
CA2172528A1 (en) | 1995-03-30 |
CN1135746A (en) | 1996-11-13 |
AU7667794A (en) | 1995-04-10 |
AU715303B2 (en) | 2000-01-20 |
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