WO1992000680A1 - VERFAHREN ZUM VERGLEICHMÄSSIGEN DES pH-WERTES VON FRISCHFLEISCH - Google Patents

VERFAHREN ZUM VERGLEICHMÄSSIGEN DES pH-WERTES VON FRISCHFLEISCH Download PDF

Info

Publication number
WO1992000680A1
WO1992000680A1 PCT/EP1991/001238 EP9101238W WO9200680A1 WO 1992000680 A1 WO1992000680 A1 WO 1992000680A1 EP 9101238 W EP9101238 W EP 9101238W WO 9200680 A1 WO9200680 A1 WO 9200680A1
Authority
WO
WIPO (PCT)
Prior art keywords
meat
container
pieces
storage
layered
Prior art date
Application number
PCT/EP1991/001238
Other languages
German (de)
English (en)
French (fr)
Inventor
René Aemig
Original Assignee
Vesten Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Vesten Ag filed Critical Vesten Ag
Priority to BR919105814A priority Critical patent/BR9105814A/pt
Publication of WO1992000680A1 publication Critical patent/WO1992000680A1/de

Links

Classifications

    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23BPRESERVATION OF FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES; CHEMICAL RIPENING OF FRUIT OR VEGETABLES
    • A23B4/00Preservation of meat, sausages, fish or fish products
    • A23B4/06Freezing; Subsequent thawing; Cooling
    • A23B4/066Freezing; Subsequent thawing; Cooling the materials not being transported through or in the apparatus with or without shaping, e.g. in the form of powder, granules or flakes
    • A23B4/068Freezing; Subsequent thawing; Cooling the materials not being transported through or in the apparatus with or without shaping, e.g. in the form of powder, granules or flakes with packages or with shaping in the form of blocks or portions
    • AHUMAN NECESSITIES
    • A22BUTCHERING; MEAT TREATMENT; PROCESSING POULTRY OR FISH
    • A22CPROCESSING MEAT, POULTRY, OR FISH
    • A22C7/00Apparatus for pounding, forming, or pressing meat, sausage-meat, or meat products
    • A22C7/0023Pressing means
    • A22C7/003Meat-moulds
    • A22C7/0046Containers in which meat is pressed and moulded
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23BPRESERVATION OF FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES; CHEMICAL RIPENING OF FRUIT OR VEGETABLES
    • A23B2/00Preservation of foods or foodstuffs, in general
    • A23B2/10Preservation of foods or foodstuffs, in general by treatment with pressure variation, shock, acceleration or shear stress
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23BPRESERVATION OF FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES; CHEMICAL RIPENING OF FRUIT OR VEGETABLES
    • A23B4/00Preservation of meat, sausages, fish or fish products
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES, NOT OTHERWISE PROVIDED FOR; PREPARATION OR TREATMENT THEREOF
    • A23L13/00Meat products; Meat meal; Preparation or treatment thereof
    • A23L13/70Tenderised or flavoured meat pieces; Macerating or marinating solutions specially adapted therefor
    • A23L13/76Tenderised or flavoured meat pieces; Macerating or marinating solutions specially adapted therefor by treatment in a gaseous atmosphere, e.g. ageing or ripening; by electrical treatment, irradiation or wave treatment
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES, NOT OTHERWISE PROVIDED FOR; PREPARATION OR TREATMENT THEREOF
    • A23L13/00Meat products; Meat meal; Preparation or treatment thereof
    • A23L13/70Tenderised or flavoured meat pieces; Macerating or marinating solutions specially adapted therefor
    • A23L13/77Tenderised or flavoured meat pieces; Macerating or marinating solutions specially adapted therefor by mechanical treatment, e.g. kneading, rubbing or tumbling

Definitions

  • the present invention relates to a method for equalizing the pH of fresh meat, in particular beef, pork, poultry, lamb and venison.
  • each muscle piece of an animal has a different pH value and that different pH values can even be present within a single muscle piece. So fluctuates e.g. the pH value between 5.3 and 5.8 for normal meat and between 5.8 and 6.2 for pork meat which is still considered tolerable. Since the pH value strongly influences the tenderness, the color, the taste and the water binding capacity and the shelf life of the fresh meat, its non-uniformity in the fresh meat leads to strong fluctuations in the meat quality.
  • the invention has for its object to develop a method by means of which the quality of the fresh meat can be improved with respect to the tenderness of the meat, the color, the taste and the water-binding capacity and the durability of the meat.
  • a method for this purpose is used to even out the pH of fresh meat, in particular beef, pork and poultry meat, freshly slaughtered meat being divided into individual pieces of meat and layered in a container without a gap, and then applied to the layered pieces of meat from the outside pressure is generated such that an anaerobic storage state of the pieces of meat is achieved and osmosis takes place within the layered pieces of meat and between them due to the internal pressure generated, storage for at least seven days at a cooling temperature of between ⁇ 1 ° C. and approx.
  • the invention is thus based on the knowledge that by generating a sufficient internal pressure in the meat while simultaneously creating an anaerobic atmosphere, ie by suppressing and excluding the entry of oxygen, osmotic processes are favored in such a way that a pH value Compensation can occur in the individual pieces of meat or muscle pieces and between the individually stored muscle pieces.
  • the invention achieves an equalization of the pH value, the effect of an additional Increasing the average pH value results in that the overall meat quality is evened out and in particular the tenderness of the meat is improved.
  • a further effect of the method according to the invention is that a high 0 2 partial pressure is generated thereby, which causes oxygen to attach to the divalent iron of myoglobin present in the meat via a secondary valence, thereby forming oxy-myoglobin which cherry-red coloring of the meat causes the appearance of the meat stored according to the invention, in particular beef and pork, to be significantly improved.
  • the method according to the invention creates an anaerobic atmosphere for the storage of meat, the lactic acid bacteria can develop optimally, whereby a taste improvement is achieved. Any risk of acidification of the meat is avoided. Oxidation by atmospheric oxygen, which would cause the formation of aldehydes and ketones, is also excluded, which could result in a rancid aroma. Since such oxidation is prevented, the fatty acids contained in the meat are not adversely affected, so that the freshness taste and the aroma of the meat stored according to the invention are fully retained.
  • the invention includes a method by which the juice holding capacity of the fresh meat is increased. It is particularly advantageous here if the individual pieces of meat are boned. In this case, such pressure is exerted from the outside that the myofibrils of the muscle fiber bundles of the meat, which are composed of thin and thick filaments, swell, so that the distances between them de between the molecules, so that more water binds between the myosin molecules. This water is immobilized, ie it is held firmly and it is no longer freely movable, so that an increase in the water binding and juice holding capacity is achieved.
  • the water-binding and juice-holding capacity is increased in accordance with the invention in that the contraction of the filaments is prevented by exerting pressure on the filaments and a slow drop in temperature.
  • the space available for the water is increased and thus the water-binding and juice-holding capacity is increased.
  • the method according to the invention also binds the water of the sarcoplastic space, which is relatively freely movable, and the extracellular water, which accounts for less than 10% of the total water of the living muscle, in a similar manner.
  • the method according to the invention can be used to store pork used for the production of so-called chorizo - a raw sausage product based on pork.
  • the anaerobic atmosphere which is produced according to the invention promotes an increase in the pH value, so that the meat becomes acidic. This has a particularly favorable effect in the production of chorizo, since a slightly acidic taste which inhibits consumption often occurs here.
  • the storage period is at least 14 days.
  • the method according to the invention can be used to achieve an improvement in the quality of cooked ham, using boned pork that is brined with brine after the method according to the invention has been completed.
  • Evening the pH value also results in a more uniform salt absorption of the meat, so that overall the shelf life, the color, the juiciness and the taste of the cooked ham are improved.
  • an increase in weight of approx. 3% is brought about by the method according to the invention, so that the overall cooking losses are lower.
  • the shelf life, the color, the bacteriological load and the freshness of the meat are improved by the pH balance according to the invention, it also being noted that the texture of the stock according to the invention is also improved Meat improves because it has a short, compact and crumbly structure.
  • a method is also advantageous in which freshly slaughtered poultry meat, divided into individual pieces of meat, is layered without space in a container, and then a pressure is exerted on it from the outside such that an anaerobic storage condition of the pieces of meat is exerted is reached in the container, with storage of at least two weeks at a cooling temperature of a minimum of -1 ° C and a maximum of + 1 ° C, in particular 0 ° C.
  • the number of germs is approximately 50,000 after 24 hours. After two days there is a bacterial count of approx. 150,000 to 200,000 and after four days from approx. 500,000 to 800,000.
  • Poultry meat stored according to the method according to the invention has a germ count of approx. 40,000 to 50,000 at the end of the storage period and this germ count increases only insignificantly even after the method according to the invention has been completed, with a shelf life of an additional one to two weeks being achieved, so that the total durability of the poultry meat is four to six weeks.
  • the method according to the invention offers the particular advantage that this meat, for example from older animals such as, for example, egg chickens, which are no longer productive, can be used, although such meat is tough when freshly slaughtered and optically unattractive because it is a has a yellowish color.
  • Such meat is per se only reduced in price - as cooked meat or processed meat.
  • a storage temperature of 0 ° to -1 ° C.
  • the quality and durability of the meat are now substantially improved, in particular with regard to its tenderness and color, because after a storage period of in particular three weeks, the original yellowish color is paler and thus the meat overall whiter, and in addition the structure of the meat is more compact and crumbly and therefore more tender.
  • poultry meat provided with or without skin can be used.
  • Poultry meat that still contains bone can also be used.
  • the storage temperature for beef and pork is preferably 0 ° C to 1 "C and, as already stated, the storage temperature for poultry meat - l ⁇ C to 0 ⁇ C.
  • the invention relates to a device for performing the method according to the invention, as shown in the accompanying drawings and on the basis of the exemplary embodiments shown therein.
  • FIG. 1 is a perspective view of a container and a lid of the device according to the invention
  • FIG. 2 shows a perspective view of a pressurization device and 3a and 3b cross-sectional views along the line III-III of FIG. 1 of two different
  • the container 1 is formed in the illustrated embodiment with a rectangular cross section with a bottom 2 and four side walls 3, 4, 5 and 6. Furthermore, the container 1 is open at the top.
  • a cover 9 can be inserted from above in the direction of the arrow 11 and can be pressed in by means of a pressure application device 12 (FIG. 2), the function of which will be explained in the following.
  • the lid 9 is slightly smaller than the cross-sectional area of the container interior 7, so that there is always a gap between the lid 9 and at least one of the walls 3 to 6, through which the meat juice exiting the meat when pressurized flows and Air can escape. The pressure is exerted until the lid 9 is covered by the juice and an anaerobic storage state is thus achieved.
  • the container 1 consists of a material which has such elasticity and such a coefficient of thermal expansion that Changes in volume of the meat caused by temperature changes can be compensated for by shrinking or stretching the container 1, ie its base 2 and its walls 3, 4, 5, 6.
  • the material used also has a low thermal conductivity.
  • a plastic material is particularly suitable for this purpose, namely a glass fiber reinforced plastic which, in addition to the required elasticity and low thermal conductivity, also has good mechanical strength, so that even high pressures are possible without problems.
  • the container 1 consists of an outer layer made of polyester resin and glass fiber mats, to which an inner cover layer made of base polyester resin, which may contain admixed color pigments, is applied.
  • a container composition of approximately 60% polyester resin, approximately 30% glass fiber mats and approximately 10% cover layer (in each case percentages by weight) has proven to be advantageous.
  • the container 1 according to the invention is easy to clean, hygienic and food-neutral and, moreover, also has sufficient mechanical strength to ensure the necessary pressures without cracks or other damage occurring.
  • Polyester resin based on orthophthalic acid polyester resin with 35% monostyrene with a viscosity of 1000 mp can be used as the base material, the 0.8 to 1% cobalt accelerator, consisting of a solution of styrene with 1% cobalt naphtenal and as a hardener 2% methyl ethyl ketone peroxide, consisting of a normally active solution of approx. 9% active oxygen, dissolved in phlegmatizing agent phthalate ester and a glycoderivative.
  • the base material the 0.8 to 1% cobalt accelerator, consisting of a solution of styrene with 1% cobalt naphtenal and as a hardener 2% methyl ethyl ketone peroxide, consisting of a normally active solution of approx. 9% active oxygen, dissolved in phlegmatizing agent phthalate ester and a glycoderivative.
  • the 0.8 to 1% cobalt accelerator consisting of
  • the top layer consists of isophthalic acid polyester resin with standard glycol and dispersed silica plus monostyrene and color pigments made of titanium oxide, as well as the o. a. Amounts of cobalt accelerators and hardeners.
  • the container 1 made from this material has a very good and long-lasting, ie non-tiring ability to expand or shrink when the temperature changes.
  • an 80 kg meat container is 620 mm high, 470 mm wide and 580 mm long at a temperature of 18 ° C.
  • At this temperature of i8 Q C in the empty container 25 at height above the ground has a measured Um ⁇ fang of 163.5 cm.
  • the filled, pressurized container then has a circumference of 164 cm at 15 ° C. and 163.5 cm at 3 ° C., so that sufficient pressure is guaranteed in any case even after cooling.
  • the container 1 according to the invention can be produced in any size and shape. In particular, four different standard sizes are provided, ie for 45 kg, 80 kg, 150 kg and 300 kg meat.
  • the interior 7 of the container 1 extends upwards from its bottom 2.
  • the cover 9 is preferably approximately congruent with the surface of the bottom 2. This training ensures very good ventilation of the meat. Even with small amounts of meat, the lid 9 is spaced from the container walls 3 to 6, so that the F leis chsaft and Air can escape. Furthermore, the widening shape of the interior 7 is also advantageous for the production of the container 1, since this makes it easy to remove from the mold.
  • the lid 9 on its underside 15 facing the bottom 2 of the container 1 has a preferably centrally located elevation 16 (FIG. 3a) or 17 (FIG. 3b) ) having.
  • the elevation 16 has a trapezoidal cross section tapering away from the underside 15 of the cover 9, while in the alternative embodiment according to FIG. 3b the elevation 17 is convex.
  • the lid 9 shown in the drawing has on its top 18 facing away from the bottom 2 of the container 1 an eccentrically arranged handle 19, which facilitates removal of the lid 9, which can adhere to the meat due to adhesive forces . Furthermore, it is advantageous if the cover 9 is chamfered at its edges 21 in such a way that the underside 15 has a smaller area than the top side 18. This also contributes to the fact that air can escape well between the cover 9 and the walls 3 to 6.
  • the container 1 In the region of its upper opening, the container 1 has an opening which surrounds the opening and extending edge 23, which is reinforced at least at two diametrically opposite points for engagement by the pressure application device 12. These reinforced points are expediently in the central region of the edges 23 of two opposite walls 3, 5 and 4, respectively.
  • the pressurization device 12 shown in FIG. 2 has a U-shaped bracket 25 with a web 26 and two parallel legs 27, 28.
  • the two legs 27, 28 carry at their ends 29 mutually facing grippers 31 for gripping around the container edge 23.
  • a jack 32 is fastened to the web 26, which has a lifting rod 33 which can be moved vertically in the direction of the arrow 30.
  • the lifting rod 33 preferably carries a pressure plate 34 for resting on the cover 9.
  • the jack 32 is a mechanical embodiment, the stroke being pivoted back and forth in the direction of arrow 36 by an actuating lever 35 ⁇ rod 33 can be moved vertically downwards, whereby the cover 9 is pressed into the container interior 7 via the pressure plate 34.
  • the lifting rod 33 of the jack 32 is guided through a central bore in the bracket web 26 in order to apply the compressive force in the center of the cover.
  • the grippers fastened to the bracket legs 27, 28 are formed by angle rails, the mutually facing legs of which grip around the container edge 23.
  • guide rollers 37 are arranged on the legs 27, 28 with a height distance from the angle rails, which come to rest on the top of the container rim 23.
  • the pressurization direction 12 can be pushed laterally onto the container edge 23.
  • the design of the container 1 according to the invention offers the following advantages:

Landscapes

  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Food Science & Technology (AREA)
  • Chemical & Material Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Health & Medical Sciences (AREA)
  • Nutrition Science (AREA)
  • Mechanical Engineering (AREA)
  • Meat, Egg Or Seafood Products (AREA)
PCT/EP1991/001238 1990-07-11 1991-07-03 VERFAHREN ZUM VERGLEICHMÄSSIGEN DES pH-WERTES VON FRISCHFLEISCH WO1992000680A1 (de)

Priority Applications (1)

Application Number Priority Date Filing Date Title
BR919105814A BR9105814A (pt) 1990-07-11 1991-07-03 Processo para comparar o valor do ph de carne fresca

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DEP4022007.9 1990-07-11
DE4022007A DE4022007C1 (enrdf_load_stackoverflow) 1990-07-11 1990-07-11

Publications (1)

Publication Number Publication Date
WO1992000680A1 true WO1992000680A1 (de) 1992-01-23

Family

ID=6410044

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP1991/001238 WO1992000680A1 (de) 1990-07-11 1991-07-03 VERFAHREN ZUM VERGLEICHMÄSSIGEN DES pH-WERTES VON FRISCHFLEISCH

Country Status (7)

Country Link
EP (1) EP0491896A1 (enrdf_load_stackoverflow)
KR (1) KR930012204B1 (enrdf_load_stackoverflow)
AU (1) AU8008991A (enrdf_load_stackoverflow)
BR (1) BR9105814A (enrdf_load_stackoverflow)
CA (1) CA2065725A1 (enrdf_load_stackoverflow)
DE (1) DE4022007C1 (enrdf_load_stackoverflow)
WO (1) WO1992000680A1 (enrdf_load_stackoverflow)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2283403B (en) * 1992-06-11 1996-03-20 Tenderland Ltd Improvements in and relating to treatment of meat
US10179104B2 (en) 2011-09-29 2019-01-15 Plx Opco Inc. PH dependent carriers for targeted release of pharmaceuticals along the gastrointestinal tract, compositions therefrom, and making and using same

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1448449A (fr) * 1964-11-02 1966-08-05 Whirlpool Co Procédé pour rendre la viande plus tendre
EP0250911A1 (de) * 1986-07-03 1988-01-07 Vesten Ag Vorrichtung zum Aufbewahren von Frischfleisch

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3106265C2 (de) * 1981-02-20 1984-12-06 Jürgen 7801 Umkirch Schlegel Verfahren zum Aufbewahren von Frischfleisch

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1448449A (fr) * 1964-11-02 1966-08-05 Whirlpool Co Procédé pour rendre la viande plus tendre
EP0250911A1 (de) * 1986-07-03 1988-01-07 Vesten Ag Vorrichtung zum Aufbewahren von Frischfleisch

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2283403B (en) * 1992-06-11 1996-03-20 Tenderland Ltd Improvements in and relating to treatment of meat
US10179104B2 (en) 2011-09-29 2019-01-15 Plx Opco Inc. PH dependent carriers for targeted release of pharmaceuticals along the gastrointestinal tract, compositions therefrom, and making and using same

Also Published As

Publication number Publication date
EP0491896A1 (de) 1992-07-01
KR920002034A (ko) 1992-02-28
DE4022007C1 (enrdf_load_stackoverflow) 1992-02-20
CA2065725A1 (en) 1992-01-12
AU8008991A (en) 1992-02-04
KR930012204B1 (ko) 1993-12-24
BR9105814A (pt) 1992-09-22

Similar Documents

Publication Publication Date Title
EP2986129B1 (de) Verfahren zum reifen von wild- oder rindfleisch und verwendung eines elements hierzu
DE3879203T2 (de) Verfahren zur herstellung geformter fischprodukte.
DE19826978C5 (de) Verfahren zur Herstellung oder Vervollkommnung von Fleischwaren oder Fleischerzeugnissen und danach hergestelltes Produkt
DE3912071C2 (enrdf_load_stackoverflow)
WO1992000680A1 (de) VERFAHREN ZUM VERGLEICHMÄSSIGEN DES pH-WERTES VON FRISCHFLEISCH
DE3008650A1 (de) Verfahren zur herstellung trockener oder halbtrockener wuerste und mittel zur herbeifuehrung einer fermentation einer (zur wurstbereitung dienenden) fleischemulsion
EP2424389B1 (de) Verfahren zur veredelung von frischfleisch
DE69307395T2 (de) Verbessertes Verfahren zur Herstellung von getrockneten Würsten
EP2701538B1 (de) Verfahren zur veredelung von frischfleisch
DE2437366A1 (de) Herstellungsverfahren fuer fleischprodukte, wie z.b. fleisch- und gefluegelbraten und fuer wurstwaren, wie z.b. schinken, pasteten, und damit erhaltene erzeugnisse
EP0250911B1 (de) Vorrichtung zum Aufbewahren von Frischfleisch
AT517280B1 (de) Verfahren zur Herstellung eines Fleischproduktes, welches eine Füllung aufweist
DE2552354A1 (de) Verfahren zur kaeltebehandlung von rohem fisch und fleisch
DE69205150T2 (de) Verfahren zur Behandlung von frischem Fleisch zur Erhöhung seiner Haltbarkeit.
DE69601169T2 (de) Vorrichtung zur durchführung eines verfahrens zur verarbeitung von fisch, insbesondere lachs
DE4410332C1 (de) Verfahren zur Reifung von Rohwürsten, Dauerwürsten und ähnlichen Produkten unter Zusatz feuchtigkeitsaufnehmender Stoffe
DE19546345A1 (de) Verfahren und Vorrichtung zur Herstellung von Käse, in dessen Innerem sich Schimmel entwickelt
EP1151674B1 (de) Hunde-Kauknochen und Verfahren zu seiner Herstellung
DE3211817C2 (de) Verfahren zum Herstellen von naturgepökelten, rohen Fleischwaren
EP1457117A1 (de) Verfahren zum Herstellen von Rohpökelwaren
EP2701539B1 (de) Verfahren zur veredelung von schweinefleisch
DE10017294A1 (de) Schinken und Verfahren zu seiner Herstellung
AT69631B (de) Verfahren zum Haltbarmachen von gekochten Schinken.
DE3413293A1 (de) Verfahren zur herstellung von geraeucherten oder luftgetrockneten fleischwaren
DE202018100341U1 (de) Schinken, erhältlich mittels eines Pökelverfahrens

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A1

Designated state(s): AU BR CA CS FI HU NO PL SU US

AL Designated countries for regional patents

Kind code of ref document: A1

Designated state(s): AT BE CH DE DK ES FR GB GR IT LU NL SE

WWE Wipo information: entry into national phase

Ref document number: 1991911742

Country of ref document: EP

WWE Wipo information: entry into national phase

Ref document number: 2065725

Country of ref document: CA

WWP Wipo information: published in national office

Ref document number: 1991911742

Country of ref document: EP

WWW Wipo information: withdrawn in national office

Ref document number: 1991911742

Country of ref document: EP