WO1991012278A1 - Verfahren zur herstellung von polyacrylsäuren - Google Patents
Verfahren zur herstellung von polyacrylsäuren Download PDFInfo
- Publication number
- WO1991012278A1 WO1991012278A1 PCT/EP1991/000298 EP9100298W WO9112278A1 WO 1991012278 A1 WO1991012278 A1 WO 1991012278A1 EP 9100298 W EP9100298 W EP 9100298W WO 9112278 A1 WO9112278 A1 WO 9112278A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- polymerization
- comonomers
- acrylic acid
- calcium
- molecular weight
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
- C08F20/04—Acids, Metal salts or ammonium salts thereof
- C08F20/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/44—Preparation of metal salts or ammonium salts
Definitions
- the invention relates to a process for the preparation of polyacrylic acids and copolymers of acrylic acid with up to 50 mol% of comonomers which have a molecular weight of less than 100,000, measured at a pH of 8, and which comprise 10 to 60 mol% Calcium hydroxide are neutralized and the use of these products as grinding and dispersing aids for calcium carbona.
- polyacrylic acids are diverse. Mention may be made of the use as anti-fouling agent in water circuits and the use of grinding aids and / or dispersing aids for the production of pigment slurries.
- the grinding and dispersion of calcium carbonate is of considerable interest. Finely ground calcium carbonate is used as a filler in the paper industry.
- Polyacrylic acids are produced by polymerizing acrylic acid. Polymerization in a solvent is customary; water or mixtures of water and isopropanol are preferably used.
- EP 0100948 relates to the use of polymers of acrylic acid as dispersants.
- the polyacrylic acid is only partially neutralized for this.
- the polyacrylic acid must be in neutralized form.
- Sodium, ammonium, potassium, calcium, magnesium, amines or combinations thereof are normally used as counterions.
- the proportion of ions which, when used alone, form an insoluble polyacrylate may of course only be so high that the polyacrylic acid has not yet precipitated. For this reason, e.g. the maximum possible amount of calcium ions 60 mol%.
- polyacrylic acids as grinding aids, some of which are neutralized with calcium.
- the polymerization takes place in mixtures of isopropanol and water.
- isopropanol it is not possible in the presence of isopropanol to polymerize the partially neutralized acrylic acid with calcium without precipitating the polymer.
- the neutralization with calcium can only take place when the isopropanol is distilled off from the polyacrylic acid solution, because otherwise the polymer will precipitate.
- the neutralization of the polyacrylic acid with calcium hydroxide after the polymerization has a number of serious disadvantages.
- the time required for the calcium hydroxide to dissolve in the polymer solution is extremely long.
- the polymer solution is very cloudy even after neutralization.
- the object of the present invention is to provide polymers of acrylic acid which are partially neutralized with calcium and do not have the above-mentioned disadvantages of working according to EP 0100947.
- This object was achieved by a process for the preparation of polyacrylic acids or copolymers of acrylic acid with up to 50 mol% of comonomers which, measured at a pH of 8.0, have a molecular weight of less than 100,000 and 10 to 60 mol% are neutralized with calcium hydroxide, which is characterized in that the acrylic acid is partially neutralized with calcium hydroxide before the polymerization and the further neutralization is carried out with monovalent bases after the polymerization.
- the polymers according to the invention preferably have a molecular weight of 500 to 50,000, determined by the method of gel permeation chromatography, in particular a molecular weight of 3,000 to 9,000.
- N-alkyl-substituted acrylamides or Methacrylamides are used which carry a tertiary amino group on the alkyl radical.
- Examples include dimethylaminopropylacrylamide, dimethylaminopropyl ethacrylamide, dimethylamino-2,2-dimethylpropylacrylamide, dimethylamino-2,2-dimethylpropyl methacrylamide and dimethylaminoethylacrylamide.
- the aforementioned monomers can also be in quaternized form, e.g. trimethylacrylamidopropylammonium chloride.
- monomers are acrylamide, methacrylamide, methacrylic acid, 2-acrylamido-2-propanesulfonic acid, methyl acrylate, hydroxypropyl acrylate and acrylonitrile.
- comonomers are intended to modify the properties of the copolymers.
- an aqueous monovalent base e.g. Sodium hydroxide solution, ammonia or potassium hydroxide solution completes the neutralization of the polyacrylic acid.
- the polymers according to the invention can be used for many purposes.
- a preferred application is the production of concentrated solid slurries.
- Pigment slurries which are produced using the copolymers according to the invention are distinguished from the products according to EP 0100947 by a significantly improved storage stability.
- the invention therefore also relates to the use of the process products, in particular as grinding and dispersing agents for calcium carbonate.
- the amount used as grinding and dispersing aid is between 0.1 and 1.0 % By weight, in each case based on solid (polymer) on solid (calcium carbonate).
- the polyacrylic acids according to the invention can be obtained by polymerization methods known per se.
- the polymerization is carried out in aqueous solution.
- the polymerization is initiated with the aid of radical polymerization catalysts.
- Redox systems and / or thermally disintegrating radical formers of the azo compound type can be used.
- Azoisobutyronitrile examples are: combinations of hydrogen peroxide, salts of peroxydisulfuric acid or tert-butyl hydroperoxide with sodium sulfite or sodium dithionite as reduction component.
- the polymerization is then conveniently started at low temperatures, e.g. at 20 ° C.
- the final temperature reached by the heat of polymerization released depends on the monomers and concentration ratios used and can be e.g. be up to 180 °.
- the polymerization can also be carried out by introducing a portion of the monomer mixture which Copolymerization starts and then the monomer mixture is metered in continuously.
- the temperature during the copolymerization can vary within a wide range.
- temperatures between 50 ⁇ C and 200 ° C can be optimal. It is also possible to carry out the polymerization at the boiling point of the solvent or under pressure at higher temperatures.
- the monomer solution is partially neutralized with calcium hydroxide. It is expedient to prepare a suspension of calcium hydroxide in water, in which the acrylic acid and possibly comonomers are subsequently introduced. However, a method is also possible in which the calcium hydroxide is added to the submitted monomer solution. According to the invention, 10 to 60 mol% of the acrylic acid is neutralized with calcium. With more than 60 mol% calcium, the insoluble calcium polyacrylate precipitates during the polymerization.
- the turbidity measurement gives a value of 3.5 TE (F) (turbidity units based on the formazin standard).
- F TE
- the polymerization is initiated by stirring in 16 ml of mercaptoethanol, 1 ml of 1% iron (II) sulfate solution and 5 ml of 35% hydrogen peroxide.
- a final temperature of approx. 90 ⁇ C is reached within 2 min.
- 2 ml of 40% hydroxylahydrochloride solution and 4.5 ml of 35% hydrogen peroxide are added.
- the post-reaction time is 1 hour.
- a mixture of 700 g water and 250 g acrylic acid is produced. Analogously to Example 1, the polymerization is initiated at 20 ° C and ⁇ 2 min HACH reached a final temperature of about 90 C ⁇ . The after-reaction takes place analogously to Example 1 within 1 hour. The mixture is then cooled to 60 ° C. and 38 g of calcium hydroxide are added.
- the turbidity of the partially neutralized product is 37 TE (F).
- the end product has a turbidity of 21.2 TE (F).
- the molecular weight (M w ) is 5913 (see Table 2).
- Example 1 The procedure is analogous to Example 1 or Comparative Example 1. 225 g of acrylic acid and 41.7 g of 60% trimethylacryloylamidopropylammonium chloride solution are used as monomers. Neutralization is carried out with 34.7 g calcium hydroxide and 188 g 45% sodium hydroxide solution.
- the neutralization is carried out with 30.8 g of calcium hydroxide and
- Example 1 The procedure is analogous to Example 1 or Comparative Example 1. 150 g of acrylic acid and 100 g of methacrylic acid are used as monomers.
- the neutralization is carried out with 23.1 g calcium hydroxide and 230 g 45% sodium hydroxide solution.
- Example 1 The procedure is analogous to Example 1 or Comparative Example 1. 125 g of acrylic acid and 125 g of 2-acrylamido-2-propanesulfonic acid are used as monomers. Neutralization is carried out with 19.3 g calcium hydroxide and 164 g 45% sodium hydroxide solution. Table 1:
- the polymer from Example 1 is used as a grinding and dispersing aid for calcium carbonate.
- 22.5 g of dry polymer (0.9% by weight of solid (polymer) on solid (calcium carbonate)) are dissolved in about 500 g of water and 1900 g of calcium carbonate are suspended therein.
- the slurry contains approx. 77% solids, the degree of grinding is 80% smaller.
- the polymer from comparative example 1 is used analogously to application example 1.
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Description
Claims
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE59101881T DE59101881D1 (de) | 1990-02-19 | 1991-02-15 | Verfahren zur herstellung von polyacrylsäuren. |
EP91903795A EP0516656B1 (de) | 1990-02-19 | 1991-02-15 | Verfahren zur herstellung von polyacrylsäuren |
FI923675A FI97895C (fi) | 1990-02-19 | 1992-08-17 | Menetelmä polyakryylihappojen valmistamiseksi |
NO19923237A NO179454B1 (no) | 1990-02-19 | 1992-08-18 | Fremgangsmate for fremstilling av polyakrylsyre og anvendelse derav |
GR930300011T GR930300011T1 (en) | 1990-02-19 | 1993-04-28 | Process for producing polyacrylic acids. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEP4004953.1 | 1990-02-19 | ||
DE4004953A DE4004953C3 (de) | 1990-02-19 | 1990-02-19 | Verfahren zur Herstellung von neutralisierten Polyacrylsäuren und ihre Verwendung als Mahl- und Dispergierhilfsmittel |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1991012278A1 true WO1991012278A1 (de) | 1991-08-22 |
Family
ID=6400365
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP1991/000298 WO1991012278A1 (de) | 1990-02-19 | 1991-02-15 | Verfahren zur herstellung von polyacrylsäuren |
Country Status (13)
Country | Link |
---|---|
US (2) | US5241011A (de) |
EP (1) | EP0516656B1 (de) |
JP (1) | JP3013263B2 (de) |
AT (1) | ATE106907T1 (de) |
AU (1) | AU640747B2 (de) |
CA (1) | CA2075925C (de) |
DE (2) | DE4004953C3 (de) |
DK (1) | DK0516656T3 (de) |
ES (1) | ES2052479T3 (de) |
FI (1) | FI97895C (de) |
GR (1) | GR930300011T1 (de) |
NO (1) | NO179454B1 (de) |
WO (1) | WO1991012278A1 (de) |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0548086A1 (de) * | 1990-06-29 | 1993-06-30 | Ecc Int Inc | Verfahren und dispergiermittel für die herstellung von wässrigen kalziumkarbonatsuspensionen mit hohem festkörpergehalt. |
EP0664324A4 (de) * | 1991-02-06 | 1994-12-15 | Yuho Chemicals Inc | Beschichtungsmaterialzusammensetzung. |
WO2001019874A1 (fr) * | 1999-09-16 | 2001-03-22 | Coatex S.A.S. | Procede d'obtention de polymeres hydrosolubles polymeres obtenus et leurs utilisations |
EP1396507A1 (de) * | 2002-09-03 | 2004-03-10 | JSR Corporation | Reaktionsprodukte aus wässrigen Copolymeremulsionen und polyvalenten Metallverbindungen, und diese enthaltende Polierzusammensetzungen |
FR2942477A1 (fr) * | 2009-02-25 | 2010-08-27 | Coatex Sas | Procede de neutralisation d'un polymere acrylique hydrosoluble par au moins un agent monovalent et au moins un agent divalent, polymeres obtenus. |
US8721838B2 (en) | 2010-05-28 | 2014-05-13 | Omya International Ag | Process for manufacturing high solids suspensions of mineral materials |
US9879139B2 (en) | 2008-12-04 | 2018-01-30 | Omya International Ag | Process for manufacturing calcium carbonate materials having a particle surface with improved adsorption properties |
US9969888B2 (en) | 2008-12-19 | 2018-05-15 | Omya International Ag | Process for manufacturing aqueous suspensions of mineral materials or dried mineral materials, the obtained products, as well as uses thereof |
US10119032B2 (en) | 2014-02-21 | 2018-11-06 | Omya International Ag | Process for the preparation of a mineral filler product |
Families Citing this family (15)
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ES2234068T5 (es) | 1992-06-10 | 2011-01-24 | Nippon Shokubai Co., Ltd. | Método de producción de una resina hidrofílica. |
DE19752128A1 (de) * | 1997-11-25 | 1999-07-29 | Stockhausen Chem Fab Gmbh | Verfahren zur Herstellung von wasserlöslichen bzw. wasserquellbaren Polymerisaten mit sehr niedrigem Restmonomergehalt, danach hergestellte Produkte und deren Verwendung |
FR2773070B1 (fr) | 1997-12-31 | 2000-06-30 | Oreal | Compositions pour le traitement des matieres keratiniques contenant l'association d'un polymere zwitterionique et d'une silicone non-volatile et insoluble dans l'eau |
FR2818166B1 (fr) * | 2000-12-20 | 2003-10-31 | Coatex Sas | Agent d'aide au broyage et/ou de dispersion de materiaux mineraux en suspension aqueuse. suspensions aqueuses obtenues et leurs utilisations |
FR2826950B1 (fr) * | 2001-07-04 | 2004-09-10 | Solvay | Procede pour l'obtention de particules de carbonate de calcium precipite structurees a l'echelle nanometrique |
US20040151935A1 (en) * | 2003-02-03 | 2004-08-05 | Robert Dzugan | Co-continuous metal-ceramic article and method for manufacture thereof |
DE10311617A1 (de) * | 2003-03-14 | 2004-09-23 | Basf Ag | Verwendung von Polyacrylsäuren als Mahlhilfsmittel für Calciumcarbonat |
DE102004041127A1 (de) * | 2004-08-24 | 2006-03-02 | Basf Ag | Verfahren zur Herstellung von carboxylatreichen Copolymeren aus monoethylenisch ungesättigten Mono- und Dicarbonsäuren sowie carboxylatreiche Copolymere mit niedrigem Neutralisationsgrad |
CN102458633A (zh) * | 2009-06-11 | 2012-05-16 | 东亚合成株式会社 | 颜料用分散剂及其用途 |
JP2014505753A (ja) | 2010-12-17 | 2014-03-06 | ビーエーエスエフ ソシエタス・ヨーロピア | 安定なポリアクリル酸、その製造およびその使用 |
US9267566B2 (en) | 2012-01-17 | 2016-02-23 | Milliken & Company | Polyester/nylon 6 fibers for rubber reinforcement |
US9278495B2 (en) | 2011-08-03 | 2016-03-08 | Milliken & Company | Rubber reinforced article with high modulus, rectangular cross-section fibers |
EP2712895B1 (de) | 2012-09-26 | 2016-05-18 | Omya International AG | Rheologisch stabile wässrige mineralmaterialsuspensionen mit organischen polymeren mit reduziertem voc-gehalt |
JP6621250B2 (ja) * | 2015-06-02 | 2019-12-18 | 株式会社日本触媒 | ポリカルボン酸系重合体水溶液及びその製造方法 |
WO2018081964A1 (en) | 2016-11-02 | 2018-05-11 | Basf Se | Acrylic acid polymers neutralized with sodium and calcium ions and having a narrow molecular weight distribution |
Citations (2)
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US3705137A (en) * | 1969-12-04 | 1972-12-05 | Mitsui Mining & Smelting Co | Precipitation copolymerization of metal salts of unsaturated carboxylic acids |
EP0100947A1 (de) * | 1982-08-06 | 1984-02-22 | Société COATEX, Société Anonyme | Mahlhilfsmittel auf der Basis von neutralisierten Acrylpolymeren und/oder -copolymeren für grobkörnige mineralische Stoffaufschlämmungen im Hinblick auf eine Anwendung für Pigmentierungszwecke |
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US3058958A (en) * | 1959-01-23 | 1962-10-16 | Rohm & Haas | Continuous polymerization of acrylic salts |
DE1158713B (de) * | 1961-07-20 | 1963-12-05 | Roehm Und Haas G M B H | Verfahren zur Herstellung streufaehiger Salze von Homo- oder Mischpolymerisaten der Methacrylsaeure |
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US4486489A (en) * | 1980-07-08 | 1984-12-04 | The B. F. Goodrich Company | Films of hydrophilic interpolymers of neutralized acrylic acid, hydroxyalkyl methacrylate or dialkylaminoalkyl (meth)acrylate and optionally a cross-linking agent |
FR2488814A1 (fr) * | 1980-08-21 | 1982-02-26 | Coatex Sa | Agent de broyage pour suspension aqueuse de materiaux mineraux en vue d'applications pigmentaires |
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-
1990
- 1990-02-19 DE DE4004953A patent/DE4004953C3/de not_active Expired - Fee Related
-
1991
- 1991-02-15 JP JP3503975A patent/JP3013263B2/ja not_active Expired - Lifetime
- 1991-02-15 AT AT91903795T patent/ATE106907T1/de not_active IP Right Cessation
- 1991-02-15 DE DE59101881T patent/DE59101881D1/de not_active Expired - Fee Related
- 1991-02-15 WO PCT/EP1991/000298 patent/WO1991012278A1/de active IP Right Grant
- 1991-02-15 EP EP91903795A patent/EP0516656B1/de not_active Expired - Lifetime
- 1991-02-15 DK DK91903795.2T patent/DK0516656T3/da active
- 1991-02-15 CA CA002075925A patent/CA2075925C/en not_active Expired - Fee Related
- 1991-02-15 AU AU72369/91A patent/AU640747B2/en not_active Ceased
- 1991-02-15 ES ES91903795T patent/ES2052479T3/es not_active Expired - Lifetime
- 1991-02-15 US US07/917,014 patent/US5241011A/en not_active Expired - Lifetime
-
1992
- 1992-08-17 FI FI923675A patent/FI97895C/fi active
- 1992-08-18 NO NO19923237A patent/NO179454B1/no unknown
-
1993
- 1993-04-28 GR GR930300011T patent/GR930300011T1/el unknown
- 1993-06-17 US US08/078,713 patent/US5297740A/en not_active Expired - Fee Related
Patent Citations (2)
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US3705137A (en) * | 1969-12-04 | 1972-12-05 | Mitsui Mining & Smelting Co | Precipitation copolymerization of metal salts of unsaturated carboxylic acids |
EP0100947A1 (de) * | 1982-08-06 | 1984-02-22 | Société COATEX, Société Anonyme | Mahlhilfsmittel auf der Basis von neutralisierten Acrylpolymeren und/oder -copolymeren für grobkörnige mineralische Stoffaufschlämmungen im Hinblick auf eine Anwendung für Pigmentierungszwecke |
Cited By (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0548086A1 (de) * | 1990-06-29 | 1993-06-30 | Ecc Int Inc | Verfahren und dispergiermittel für die herstellung von wässrigen kalziumkarbonatsuspensionen mit hohem festkörpergehalt. |
EP0548086A4 (de) * | 1990-06-29 | 1994-03-16 | Ecc Internat Inc | Verfahren und dispergiermittel für die herstellung von wässrigen kalziumkarbonatsuspensionen mit hohem festkörpergehalt. |
EP0664324A4 (de) * | 1991-02-06 | 1994-12-15 | Yuho Chemicals Inc | Beschichtungsmaterialzusammensetzung. |
EP0664324A1 (de) * | 1991-02-06 | 1995-07-26 | Yuho Chemicals Inc. | Beschichtungsmaterialzusammensetzung |
WO2001019874A1 (fr) * | 1999-09-16 | 2001-03-22 | Coatex S.A.S. | Procede d'obtention de polymeres hydrosolubles polymeres obtenus et leurs utilisations |
FR2798661A1 (fr) * | 1999-09-16 | 2001-03-23 | Coatex Sa | Procede d'obtention de polymeres hydrosolubles, polymeres obtenus et leurs utilisations |
US6956090B1 (en) | 1999-09-16 | 2005-10-18 | Coatex S.A. | Method for obtaining water-soluble polymers, resulting polymers and uses thereof |
EP1396507A1 (de) * | 2002-09-03 | 2004-03-10 | JSR Corporation | Reaktionsprodukte aus wässrigen Copolymeremulsionen und polyvalenten Metallverbindungen, und diese enthaltende Polierzusammensetzungen |
US9879139B2 (en) | 2008-12-04 | 2018-01-30 | Omya International Ag | Process for manufacturing calcium carbonate materials having a particle surface with improved adsorption properties |
US9896567B2 (en) | 2008-12-04 | 2018-02-20 | Omya International Ag | Process for manufacturing calcium carbonate materials having a particle surface with improved adsorption properties |
US9969888B2 (en) | 2008-12-19 | 2018-05-15 | Omya International Ag | Process for manufacturing aqueous suspensions of mineral materials or dried mineral materials, the obtained products, as well as uses thereof |
US10472522B2 (en) | 2008-12-19 | 2019-11-12 | Omya International Ag | Process for manufacturing aqueous suspensions of mineral materials or dried mineral materials, the obtained products, as well as uses thereof |
WO2010097667A1 (fr) | 2009-02-25 | 2010-09-02 | Coatex S.A.S. | Procede de neutralisation d'un polymere acrylique hydrosoluble par au moins un agent monovalent et au moins un agent divalent, polymeres obtenus |
FR2942477A1 (fr) * | 2009-02-25 | 2010-08-27 | Coatex Sas | Procede de neutralisation d'un polymere acrylique hydrosoluble par au moins un agent monovalent et au moins un agent divalent, polymeres obtenus. |
US8721838B2 (en) | 2010-05-28 | 2014-05-13 | Omya International Ag | Process for manufacturing high solids suspensions of mineral materials |
US9243121B2 (en) | 2010-05-28 | 2016-01-26 | Omya International Ag | Process for manufacturing high solids suspensions of mineral materials |
US10119032B2 (en) | 2014-02-21 | 2018-11-06 | Omya International Ag | Process for the preparation of a mineral filler product |
Also Published As
Publication number | Publication date |
---|---|
NO923237A (no) | 1992-08-18 |
ES2052479T1 (es) | 1994-07-16 |
DE4004953C2 (de) | 1992-10-15 |
DE59101881D1 (de) | 1994-07-14 |
GR930300011T1 (en) | 1993-04-28 |
FI923675A (fi) | 1992-08-17 |
DK0516656T3 (da) | 1994-10-10 |
CA2075925A1 (en) | 1991-08-20 |
AU640747B2 (en) | 1993-09-02 |
NO179454B1 (no) | 1996-10-28 |
JP3013263B2 (ja) | 2000-02-28 |
US5241011A (en) | 1993-08-31 |
AU7236991A (en) | 1991-09-03 |
ATE106907T1 (de) | 1994-06-15 |
FI923675A0 (fi) | 1992-08-17 |
JPH05504586A (ja) | 1993-07-15 |
EP0516656B1 (de) | 1994-06-08 |
FI97895C (fi) | 1997-03-10 |
ES2052479T3 (es) | 1994-08-16 |
CA2075925C (en) | 1996-10-15 |
NO179454B (no) | 1996-07-01 |
EP0516656A1 (de) | 1992-12-09 |
DE4004953C3 (de) | 1998-01-29 |
NO179454C (no) | 1996-10-09 |
FI97895B (fi) | 1996-11-29 |
US5297740A (en) | 1994-03-29 |
NO923237D0 (no) | 1992-08-18 |
DE4004953A1 (de) | 1991-08-22 |
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