WO1988003945A1 - Sulphurised alkaline earth metal hydrocarbyl phenates, their production and use thereof - Google Patents

Sulphurised alkaline earth metal hydrocarbyl phenates, their production and use thereof Download PDF

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Publication number
WO1988003945A1
WO1988003945A1 PCT/GB1987/000848 GB8700848W WO8803945A1 WO 1988003945 A1 WO1988003945 A1 WO 1988003945A1 GB 8700848 W GB8700848 W GB 8700848W WO 8803945 A1 WO8803945 A1 WO 8803945A1
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WIPO (PCT)
Prior art keywords
lubricating oil
additive concentrate
tbn
acid
alkaline earth
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PCT/GB1987/000848
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English (en)
French (fr)
Inventor
Charles Cane
John Crawford
Sean Patrick O'connor
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Bp Chemicals (Additives) Limited
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Application filed by Bp Chemicals (Additives) Limited filed Critical Bp Chemicals (Additives) Limited
Priority to KR1019880700889A priority Critical patent/KR960010991B1/ko
Priority to JP62507103A priority patent/JPH0631384B2/ja
Priority to BR8707551A priority patent/BR8707551A/pt
Publication of WO1988003945A1 publication Critical patent/WO1988003945A1/en
Priority to FI883503A priority patent/FI93654C/fi
Priority to DK198804198A priority patent/DK175287B1/da
Priority to NO883349A priority patent/NO176147C/no
Priority to US08/991,547 priority patent/US6090760A/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M159/00—Lubricating compositions characterised by the additive being of unknown or incompletely defined constitution
    • C10M159/12—Reaction products
    • C10M159/20—Reaction mixtures having an excess of neutralising base, e.g. so-called overbasic or highly basic products
    • C10M159/22—Reaction mixtures having an excess of neutralising base, e.g. so-called overbasic or highly basic products containing phenol radicals

Definitions

  • the present invention relates in general to sulphurised alkaline earth metal hydrocarbyl phenates, their production and use thereof as lubricating oil additives.
  • the present invention relates to sulphurised alkaline earth metal hydrocarbyl phenate-containing compositions having a high total base number (TBN) and an acceptable viscosity and to their production from sulphurised alkaline earth metal hydrocarbyl phenates having lower TBNs .
  • TBN total base number
  • One class of compounds generally employed to neutralise the acidic materials and disperse sludge within the lubricating oil are the sulphurised metal alkyl phenates, wherein the metal is an alkaline earth metal such as calcium, magnesium or barium. Both “normal” and “overbased” sulphurised alkaline earth metal alkyl phenates have been employed.
  • the term “overbased” is used to describe those sulphurised alkaline earth metal alkyl phenates in which the ratio of the number of equivalents of the alkaline earth metal moiety to the number of equivalents of the phenol moiety is greater than one, and is usually greater than 1.2 and may be as high as 4.5 or greater.
  • the equivalent ratio of alkaline earth metal moiety to phenol moiety in "normal” alkaline earth metal alkyl phenates is one.
  • the "overbased” material contains greater than 20% in excess of the alkaline earth metal present in the corresponding "normal” material.
  • "overbased” sulphurised alkaline earth metal alkyl phenates have a greater capability for neutralising acidic matter than do the corresponding "normal” alkaline earth metal alkyl phenates.
  • the prior art teaches many methods for preparing both "normal” and “overbased” sulphurised metal alkyl phenates.
  • One such method for preparing "overbased" sulphurised alkyl phenates generally referred to as the “single lime addition” process comprises reacting an alkyl phenol, in the presence of lubricating oil, sulphur, a hydroxylic compound and excess alkaline earth metal hydroxide (above the stoichiometric proportion required to neutralise the alkyl phenol), to form an intermediate product, followed by carbonation, a heading distillation (to remove unreacted hydroxylic compound) and filtration.
  • the production of intermediate product is accompanied by a marked increase in viscosity while the subsequent carbonation reduces the viscosity to a relatively low level.
  • the increase in viscosity accompanying the formation of the intermediate product is undesirable because the reaction mixture becomes difficult to agitate to the detriment of subsequent reactions. Whilst this increase in viscosity may be controlled to an. acceptable level by incorporation of less alkaline earth metal hydroxide in the reaction, the overbased alkyl phenate product necessarily possesses a reduced neutralisation capacity. In order to achieve a high neutralisation capacity product and at the same time control the viscosity of the intermediate product within acceptable limits, the alkaline earth metal hydroxide may be added in two, (generally referred to as the "double lime addition" process) or three separate reaction steps, with sequential carbonation steps. However, this method involves relatively long batch times.
  • TBN total base number
  • Ve have achieved these objectives and thereby achieved compositions having a TBN in excess of 300 and in some cases greater than 350 whilst retaining an acceptable viscosity, that is a viscosity of less than 1000 cSt, and avoiding insolubility by incorporating into a reaction mixture containing a sulphurised alkaline earth metal alkyl phenate at least one carboxylic acid or acid derivative thereof having at least 10 carbon atoms in the molecule.
  • US-A-4049560 describes the production of an overbased magnesium detergent by a process in which carbon dioxide is introduced into a reaction mixture which comprises: (a) 15-40 wt % of a sulphurised phenol or thiophenol containing one or more hydrocarbyl substituents, or a phenol or thiophenol containing one or more hydrocarbyl substituents, or said phenol or thiophenol containing one or more hydrocarbyl substituents together with sulphur,
  • the amount of carboxylic acid (component (e)) is preferably in the range 0.5 to 2.02 by weight.
  • the product prepared by this reaction is said to have a TBN of about 200 to 250, e.g. about 225.
  • EP-A-0094814 discloses an additive concentrate for incorporation in a lubricating oil composition comprising lubricating oil, and from 10 to 90 wt % of an overbased alkaline earth metal hydrocarbyl sulphurised phenate which has been treated, either during or subsequent to the overbasing process, with from 0.1 to 10, preferably 2 to 6, wt % (based on the weight of additive concentrate) of an acid of the formula: (I) R (wherein R is a C 10 to C 24 unbranched alkyl or alkenyl group, and R 1 is hydrogen, a C 1 to C 4 alkyl group or a -CH 2 -COOH group) or an anhydride or a salt thereof.
  • the object of the invention of EP-A-0094814 is to overcome problems encountered with many additive concentrates containing overbased additives, namely lack of stability giving rise to sedimentation, and foaming problems.
  • the problem of EP-A-0094814 is not that of producing phenates having a TBN of greater than 300 and indeed the phenates produced by the process of the invention, although overcoming the problems of stability and foaming, have TBN values of less than 300.
  • the present invention provides an additive concentrate suitable for incorporation into a finished lubricating oil composition, the additive concentrate comprising:
  • a lubricating oil soluble sulphurised alkaline earth metal hydrocarbyl phenate modified by incorporation of from greater than 2 to 35% by weight based on the weight of the composition of either (i) at least one carboxylic acid having the formula:- (I) wherein R is a C 10 to C 24 alkyl or alkenyl group and R 1 is either hydrogen, a C 1 to C 4 alkyl group or a -CH 2 -COOH group, or an anhydride, acid chloride or ester thereof or (ii) a di- or polycarboxylic acid containing from 36 to 100 carbon atoms or an anhydride, acid chloride or ester thereof, the composition having a TBN greater than 300.
  • Component (a) of the composition is a lubricating oil.
  • the lubricating oil may suitably be either an animal oil, a vegetable oil or a mineral oil.
  • the lubricating oil may be a petroleum-derived lubricating oil, such as a naphthenic base, paraffin base or mixed base oil. Solvent neutral oils are particularly suitable.
  • the lubricating oil may be a synthetic lubricating oil.
  • Suitable synthetic lubricating oils include synthetic ester lubricating oils, which oils include diesters such as di-octyl adipate, di-octyl sebacate and tridecyladipate, or polymeric hydrocarbon lubricating oils, for example liquid polyisobutenes and poly-alpha olefins.
  • the lubricating oil may suitably comprise from 10 to 90X, preferably from 10 to 70X, by weight of the composition.
  • Component (b) is a lubricating oil soluble sulphurised alkaline earth metal hydrocarbyl phenate modified by incorporation of from greater than 2 to 35% by weight based on the weight of the composition of either (i) or (ii).
  • the alkaline earth metal may be strontium, calcium, magnesium or barium, preferably calcium, barium or magnesium, more preferably calcium.
  • the hydrocarbyl phenate moiety of the sulphurised alkaline earth metal hydrocarbyl phenate is preferably derived from at least one alkyl phenol.
  • the alkyl groups of the alkyl phenol may be branched or unbranched. Suitable alkyl groups contain from 4 to 50, preferably from 9 to 28 carbon atoms.
  • a particularly suitable alkyl phenol is the C 12 -alkyl phenol obtained by alkylating phenol with propylene tetramer.
  • the sulphurised alkaline earth metal hydrocarbyl phenate is modified by incorporation of either (i) or (ii).
  • this is at least one carboxylic acid having the formula (I) or an acid anhydride, acid chloride or ester thereof.
  • R in the formula (I) is an unbranched alkyl or alkenyl group.
  • Preferred acids of formula (I) are those wherein R is a C 10 to C 24 , more preferably C 18 to C 24 straight chain alkyl groups and R 1 is hydrogen.
  • suitable saturated carboxylic acids of formula (I) include capric acid, lauric acid, myristic acid, palmitic acid, stearic acid, arachidic acid, behenic acid and lignoceric acid.
  • suitable unsaturated acids of formula (I) include lauroleic acid, myristoleic acid, palmitoleic acid, oleic acid, gadoleic acid, erucic acid, ricinoleic acid, linoleic acid and linolenic acid.
  • Mixtures of acids may also be employed, for example rape top fatty acids.
  • Particularly suitable mixtures of acids are those commercial grades containing a range of acids, including both saturated and unsaturated acids.
  • Such mixtures may be obtained synthetically or may be derived from natural products, for example cotton oil, ground nut oil, coconut oil, linseed oil, palm kernel oil, olive oil, corn oil, palm oil, castor oil, soyabean oil, sunflower oil, herring oil, sardine oil and tallow.
  • Sulphurised acids and acid mixtures may also be employed.
  • the carboxylic acid there may be used the acid anhydride, the acid chloride or the ester derivatives of the acid, preferably the acid anhydride. It is preferred however to use a carboxylic acid or a mixture of carboxylic acids.
  • a preferred carboxylic acid of formula (I) is stearic acid.
  • the sulphurised alkaline earth metal hydrocarbyl phenate may be modified by incorporation of (ii), which is a di- or polycarboxylic acid containing from 36 to 100 carbon atoms or an acid anhydride, acid chloride or ester derivative thereof, preferably an acid anhydride thereof.
  • (ii) is a polyisobutene succinic acid or a polyisobutene succinic anhydride.
  • the carboxylic acid(s) having the formula (I), the di- or polycarboxylic acid, or the acid anhydride, acid chloride or ester thereof is incorporated in an amount from greater than 10% to 35%, more preferably from 12 to 20%, for example about 16% by weight based on the weight of the composition.
  • An advantage of incorporating greater than 10% of the carboxylic acid or derivative thereof is generally a relativelylower concentrate viscosity.
  • the alkaline earth metal may be present in the composition in an amount in the range from 10 to 20% by weight based on the weight of the composition.
  • sulphur may be present in the composition in an amount in the range from 1 to 6, preferably from 1.5 to 3% by weight based on the weight of the composition.
  • carbon dioxide may be present in the composition in an amount in the range from 5 to 20, preferably from 9 to 15% by weight based on the weight of the composition.
  • the TBN of the composition is greater than 350, more preferably greater than 400.
  • the composition may have a viscosity measured at 100oC of less than 1000 cSt, preferably less than 750 cSt, more preferably less than 500 cSt.
  • the present invention provides an additive concentrate suitable for incorporation into a finished lubricating oil which concentrate is obtainable by reacting at elevated temperature (A) a sulphurised alkaline earth metal hydrocarbyl phenate having a TBN less than that of the final additive concentrate, (B) an alkaline earth metal base added in either a single addition or in a plurality of additions at intermediate points during the reaction, (C) either a polyhydric alcohol having from 2 to 4 carbon atoms, a di- or tri- (C 2 to C 4 ) glycol, an alkylene glycol alkyl ether or a polyalkylene glycol alkyl ether, (D) a lubricating oil, (E) carbon dioxide added subsequent to the, or each, addition of component (B), and (F) sufficient to provide from greater than 2 to 35% by weight based on the weight of the concentrate of either (i) a carboxylic acid having the formula (I) or an acid anhydride, acid chloride or ester thereof or (i
  • the present invention provides a process for the production of an additive concentrate for incorporation into a finished lubricating oil which process comprises reacting at elevated temperature components (A) to (F) as hereinbefore described, the weight ratios of components (A) to (F) being such as to produce a concentrate having a TBN greater than 300.
  • the process of the invention is advantageous because it affords a method for up-grading low TBN products of the prior art or off-specification products into high TBN products having an acceptable viscosity. Moreover, because hydrogen sulphide is not evolved during operation of the process of the invention, in contrast to processes for producing sulphurised alkaline earth metal alkyl phenates involving the reaction of an alkyl phenol and sulphur, by the more conventional routes, the hydrogen sulphide disposal problem is avoided, thereby allowing manufacture in environmentally sensitive locations and the use of less sophisticated plant.
  • Component (A) of the reaction mixture is a sulphurised alkaline earth metal hydrocarbyl phenate having a TBN lower than that of the final product, i.e. generally less than 300.
  • Any sulphurised alkaline earth metal hydrocarbyl phenate may be employed.
  • the sulphurised alkaline earth metal hydrocarbyl phenate may be carbonated or non-carbonated.
  • the alkaline earth metal moiety and the hydrocarbyl phenate moiety of the sulphurised alkaline earth metal hydrocarbyl phenate may suitably be as hereinbefore described.
  • Methods for preparing sulphurised alkaline earth metal hydrocarbyl phenates are well known in the art.
  • the precursors of a sulphurised alkaline earth metal hydrocarbyl phenate in the form of a non-sulphurised alkaline earth metal hydrocarbyl phenate and sulphur may be employed.
  • the alkaline earth metal base (component B) may suitably be an alkaline earth metal oxide or hydroxide, preferably the hydroxide.
  • Calcium hydroxide may be added for example in the form of slaked lime.
  • Preferred alkaline earth metals are calcium, magnesium and barium and more preferred is calcium.
  • the alkaline earth metal base must be added in an amount relative to component (A) sufficient to produce a product having a TBN in excess of 300, preferably in excess of 350. This amount will depend on a number of factors including the nature of the sulphurised alkaline earth metal hydrocarbyl phenate.
  • the weight ratio of component (B) to component (A) may suitably be in the range from 0.1 to 50, preferably from 0.2 to 5.
  • the alkaline earth metal base (B) may be added in whole to the initial reactants, or in part to the initial reactants and the remainder in one or more portions at a subsequent stage or stages in the process.
  • component (B) is added in a single addition to the initial reactants.
  • Component (C) is either a polyhydric alcohol having from 2 to 4 carbon atoms, a di- or tri- (C 2 to C 4 ) glycol, an alkylene glycol alkyl ther or a polyalkylene glycol alkyl ether.
  • Thepolyhydric alcohol may suitably be either a dihydric alcohol, for example ethylene glycol or propylene glycol, or a trihydric alcohol, for example glycerol.
  • the di- or tri- (C 2 to C 4 ) glycol may suitably be either diethylene glycol or triethylene glycol.
  • the alkylene glycol alkyl ether or polyalkylene glycol alkyl ether may suitably be of the formula:-
  • Suitable solvents having the formula (II) include the monomethyl or dimethyl ethers of ethylene glycol, diethylene glycol, triethylene glycol or tetraethylene glycol.
  • a particularly suitable solvent is methyl digol (CH 3 OCH 2 CH 2 OCH 2 CH 2 OH). Mixtures of glycols and glycol ethers of formula (II) may also be employed.
  • a glycol or glycol ether of formula (II) as solvent it is preferred to use in combination therewith an inorganic halide, for example ammonium chloride, and a lower, i.e. C 1 to C 4 , carboxylic acid, for example acetic acid.
  • an inorganic halide for example ammonium chloride
  • a lower, i.e. C 1 to C 4 , carboxylic acid for example acetic acid.
  • the component (C) is either ethylene glycol or methyl digol, the latter in combination with ammonium chloride and acetic acid.
  • Component (D) is a lubricating oil as hereinbefore described with reference to the concentrate composition.
  • Component (E) is carbon dioxide, which may be added in the form of a gas or a solid, preferably in the form of a gas. In gaseous form it may suitably be blown through the reaction mixture. We have found that generally the amount of carbon dioxide incorporated increases with increasing concentrations of component (F). The carbon dioxide is preferably added subsequent to a single addition of component (B) at the conclusion of the reaction between component (A), (B), (C), (D) and (F).
  • Component (F) is either a carboxylic acid of formula (I), a dior polycarboxylic acid containing from 36 to 100 carbon atoms, or an acid anhydride, an acid chloride or ester thereof as hereinbefore described with reference to the concentrate composition.
  • the amount of the aforesaid required to provide from greater than 2 to 35% by weight based on the weight of the concentrate will be to a first approximation the amount derived in the concentrate. In calculating this amount allowance should be made for loss of water from carboxylic acids, for example.
  • the reaction may be performed in the presence of a diluent.
  • Suitable diluents are liquids having a volatility consistent with operation of the process, i.e. having a volatility such that they are readily strippable from the reaction mixture at the conclusion of the reaction.
  • suitable diluents include 2-ethyl hexanol, iso-octanol, iso-heptanol and tri-decanol.
  • Further sulphur that is sulphur additional to that already present by way of component (A), may be added to the reaction mixture.
  • An advantage of adding further sulphur is that it increases the amount of sulphur in the concentrate, which may be desirable for certain applications.
  • sulphur addition leads to the evolution of hydrogen sulphide, thereby to some extent detracting from the advantage of the invention as hereinbefore mentioned.
  • the reaction is carried out in the presence of a further component which is a catalyst for the reaction.
  • a catalyst for the reaction there may be used an inorganic halide which may suitably be either a hydrogen halide, an ammonium halide or a metal halide.
  • the metal moiety of the metal halide may be zinc, aluminium or an alkaline earth metal, preferably calcium.
  • the chloride is preferred.
  • Suitable catalysts include hydrogen chloride, calcium chloride, ammonium chloride, aluminium chloride and zinc chloride, preferably calcium chloride.
  • the amount of catalyst employed may be up to 2.0% wt/wt.
  • reaction of components (A) - (F) and also the carbonation reaction may be carried out at elevated temperatures in the range from 120 to 200, preferably from about 130 to 165oC, though the actual temperatures chosen for the reaction of components (A) - (F) and the carbonation may differ if desired.
  • the pressure may be atmospheric, subatmospheric or superatmospheric.
  • the concentrate may be recovered by conventional means, for example by distillative stripping of component (C) and diluent (if any).
  • the process of the invention will produce a concentrate having an acceptable viscosity, that is a viscosity of less than 1000 cSt at 100oC, and can produce concentrates having a viscosity less than 750 or 500 cSt at 100oC.
  • the concentrates generally have desirable viscosity index properties. Such viscometric properties are advantageous because they facilitate processing (including filtration) of the concentrate.
  • the concentrate may be diluted with lubricating oil and still retain a TBN in excess of 300, particularly if the TBN of the concentrate as produced is high, for example above 400.
  • the present invention provides a finished lubricating oil composition which composition comprises a lubricating oil and sufficient of the additive concentrate as hereinbefore described to provide a TBN in the range from 0.5 to 120.
  • the finished lubricating oil composition contains sufficient of the concentrate composition to provide a TBN in the range from 0.5 to 100.
  • the amount of concentrate composition present in the finished lubricating oil will depend on the nature of the final use. Thus, for marine lubricating oils the amount of concentrate composition present may suitably be sufficient to provide a TBN in the range from 9 to 100 and for automobile engine lubricating oils the amount may suitably be sufficient to provide a TBN in the range from 4 to 20.
  • the finished lubricating oil may also contain effective amounts of one or more other types of conventional lubricating oil additives, for example viscosity index improvers, anti-wear agents, antioxidants, dispersants, rust inhibitors, pour-point depressants, or the like, which may be incorporated into the finished lubricating oil composition either directly or through the intermediacy of the concentrate composition.
  • the concentrate compositions of the present invention may also find application as fuels additives.
  • TBN is the Total Base Number in mg KOH/g as measured by the method of ASTM D2896.
  • a commercially available sulphurised calcium alkyl phenate derived from a C 12 -alkyl phenol was employed.
  • the phenate is supplied as a solution in lubricating oil, which forms from 36-40% w/w of the composition.
  • the composition has a TBN of 250 and a composition as follows:- calcium (9.25% w/v), sulphur (3.25% w/w) and carbon dioxide (4.6% w/w).
  • the "Charge" for any Example includes lubricating oil, this is additional to that already present in the phenate composition.
  • the product was analysed for calcium, sulphur and carbon dioxide. Its TBN, BPHVI50 and Viscosity at 100oC were determined. The BPHV150 determination is a solubility test. Results of the test are expressed on the scale 1 (highly soluble; pass), 2 (borderline) and 3 (fail). Results
  • Example 2 demonstrates that a low TBN product can be converted to a high TBN product having an acceptable viscosity by the process of the invention.
  • the filtration step (h) was very difficult.
  • Example 6 This Example, as compared with Example 3 demonstrates the desirability of using a catalyst in the process of the invention. In the absence of catalyst, although a lower V 100 was obtained, this was achieved at the expense of reduced incorporation of calcium and carbon dioxide, and moreover filtration was difficult.
  • Example 6 In the absence of catalyst, although a lower V 100 was obtained, this was achieved at the expense of reduced incorporation of calcium and carbon dioxide, and moreover filtration was difficult.
  • TBN concentrate though the viscosity is relatively high, by incorporating 10% w/w stearic acid.
  • Example 6 As for Example 6 except that the phenate was increased from 250 g to 268 g and the stearic acid was increased from 40 g to 51 g. Method:
  • step (h) The filtration rate in step (h) was slow.
  • step (h) The filtration rate in step (h) was slow.
  • Example 10 Charge: Sulphurised calcium alkyl phenate : 230 g
  • step (b) instead of 2-ethyl hexanol (190 g) there was added methyl diglycol (130 g) and in step (d) the addition of ethylene glycol was omitted.
  • step (h) Stearic acid 16 .2% w/w The filtration rate in step (h) was rapid.
  • step (d) the pressure was
  • step (i) The filtration rate in step (i) was rapid.
  • Example 14 demonstrates that a lubricating oil can be replaced by a long carbon chain alpha-olefin (in this case C 18 ) .
  • a lubricating oil can be replaced by a long carbon chain alpha-olefin (in this case C 18 ) .
  • Sulphurised calcium alkyl phenate 250 TBN derived from a mixture of C 12 /C 22 /C 24 alkyl phenols : 233.5 g
  • Example 15 Charge: Sulphurised calcium alkyl phenate : 181 g Lubricating oil (SN 100) : 50 g
  • Example 16 Charge: Sulphurised calcium alkyl phenate 230 g
  • step (a) instead of stearic acid (63 g) there was used Tall Oil Fatty Acid (63 g).
  • PIBSA polyisobutene succinic anhydride
  • Carboxylic acid content 12.1 % w/w ) based on the
  • Example 16 As for Example 16 except that instead of Tall Oil Fatty Acid (63 g) there was used behenic acid (63 g).
  • Vehenic acid 15. 7 % w/w
  • Example 19 Charge: As for Example 15 except that instead of Rape Top Fatty
  • Palmitic acid 18.0 % w/w
  • Carboxylic acid content 18.6 %w/w based on the weight of product.
  • This Test is not an example according to the present invention and is included only for the purpose of demonstrating that lower carboxylic acids, in this case acetic acid, can not be used in the process of the invention.
  • Example 16 As for Example 16 except that instead of the commercially available sulphurised calcium alkyl phenate there was used an uncarbonated commercially available sulphurised calcium C 12 -alkyl phenate (145 TBN).
  • step (c) the amount of lime was increased from 66 g to 83 g and in step (f) the amount of carbon dioxide was increased from 66 g to 83 g.
  • Carboxyl ic acid 15.0% w/w
  • This Example demonstrates that an uncarbonated sulphurised calcium alkyl phenate of low initial TBN can be used in the process of the invention.
  • a carbonated sulphurised calcium alkyl phenate (150 TBN) 253 g
  • Example 23 demonstrates that a low (150) TBN sulphurised calcium alkyl phenate can be upgraded to a high TBN product.
  • Example 14 As for Example 14 except that instead of the sulphurised calcium alkyl phenate derived from a mixture of alkyl phenols there was used the commercially available sulphurised calcium alkyl phenate derived from a C 12 -alkyl phenol (250 TBN).
  • step (b) instead of 2-ethyl hexanol (194 g) there was used iso-heptanol (190 g) and in step (d) the ethylene glycol was added quickly (within 1 minute).
  • the filtration rate was rapid.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Liquid Carbonaceous Fuels (AREA)
  • Catalysts (AREA)
  • Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
PCT/GB1987/000848 1986-11-29 1987-11-26 Sulphurised alkaline earth metal hydrocarbyl phenates, their production and use thereof WO1988003945A1 (en)

Priority Applications (7)

Application Number Priority Date Filing Date Title
KR1019880700889A KR960010991B1 (ko) 1986-11-29 1987-11-26 황화 알칼리 토금속 하이드로카빌 페네이트, 이의 제조방법 및 이를 포함하는 가공 윤활유 조성물
JP62507103A JPH0631384B2 (ja) 1986-11-29 1987-11-26 硫化アルカリ土類金属ヒドロカルビルフェノラートを含有する添加剤コンセントレートの製造方法
BR8707551A BR8707551A (pt) 1986-11-29 1987-11-26 Concentrado de aditivo adequado para incorporacao em um oleo lubrificante acabado,processo para sua producao e composicao de oleo lubrificante acabada
FI883503A FI93654C (fi) 1986-11-29 1988-07-25 Rikitettyjä maa-alkalimetallihydrokarbyylifenaatteja, niiden valmistus ja niiden käyttö
DK198804198A DK175287B1 (da) 1986-11-29 1988-07-27 Sulfurerede jordalkalimetalhydrocarbylphenater, deres fremstilling og anvendelse
NO883349A NO176147C (no) 1986-11-29 1988-07-28 Fremgangsmåte for fremstilling av et additivkonsentrat egnet for inkorporering i smöreolje
US08/991,547 US6090760A (en) 1986-11-29 1997-12-16 Sulphurized alkaline earth metal hydrocarbyl phenates, their production and use thereof

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB8628609 1986-11-29
GB868628609A GB8628609D0 (en) 1986-11-29 1986-11-29 Lubricating oil additives

Publications (1)

Publication Number Publication Date
WO1988003945A1 true WO1988003945A1 (en) 1988-06-02

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PCT/GB1987/000847 WO1988003944A1 (en) 1986-11-29 1987-11-26 Alkaline earth metal hydrocarbyl phenates, their sulphurised derivatives, their production and use thereof

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EP (2) EP0273588B2 (enrdf_load_stackoverflow)
JP (2) JPH0631383B2 (enrdf_load_stackoverflow)
KR (2) KR960010991B1 (enrdf_load_stackoverflow)
CN (2) CN1012074B (enrdf_load_stackoverflow)
AT (2) ATE79396T1 (enrdf_load_stackoverflow)
AU (2) AU609075B2 (enrdf_load_stackoverflow)
BR (2) BR8707551A (enrdf_load_stackoverflow)
CA (2) CA1305696C (enrdf_load_stackoverflow)
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EP0351052A3 (en) * 1988-06-14 1990-05-23 Bp Chemicals (Additives) Limited A process for the production of a lubricating oil additive concentrate
US5433871A (en) * 1988-06-14 1995-07-18 Bp Chemicals (Additives) Limited Process for the production of a lubricating oil additive concentrate
US5437803A (en) * 1988-06-14 1995-08-01 Bp Chemicals (Additives) Limited Process for the production of a lubricating oil additive concentrate
US5942476A (en) * 1998-06-03 1999-08-24 Chevron Chemical Company Low-viscosity highly overbased phenate-carboxylate
EP0989178A4 (en) * 1997-05-07 2000-09-13 Cosmo Sogo Kenkyusho Kk LUBRICANT OIL COMPOSITION MADE FROM OVER-BASED EARTH ALKALINE METAL SULFIDE PHENOLATE CONCENTRATES AND METHOD FOR PRODUCING THESE CONCENTRATES
US6348438B1 (en) 1999-06-03 2002-02-19 Chevron Oronite S.A. Production of high BN alkaline earth metal single-aromatic ring hydrocarbyl salicylate-carboxylate

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GB8814013D0 (en) * 1988-06-14 1988-07-20 Bp Chemicals Additives Chemical process
DK0385616T3 (da) * 1989-02-25 1994-10-10 Bp Chemicals Additives Fremgangsmåde til fremstilling af et smøreolieadditivkoncentrat
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JP2737096B2 (ja) * 1993-08-25 1998-04-08 株式会社コスモ総合研究所 過塩基性硫化アルカリ土類金属フェネートの製造法
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USD551819S1 (en) 2006-05-30 2007-09-25 Kohs Stephen C Fluid reservoir pole with dispensing wash head and squeegee
US20080153723A1 (en) 2006-12-20 2008-06-26 Chevron Oronite Company Llc Diesel cylinder lubricant oil composition
RU2398814C1 (ru) * 2009-01-23 2010-09-10 Ирина Ефимовна Селезнева Способ получения присадки к смазочным маслам
JP5823392B2 (ja) 2009-08-06 2015-11-25 ザ ルブリゾル コーポレイションＴｈｅ Ｌｕｂｒｉｚｏｌ Ｃｏｒｐｏｒａｔｉｏｎ アスファルテン分散剤含有潤滑組成物
BR112012012891A2 (pt) 2009-11-30 2017-06-20 Lubrizol Corp misturas estabilizadas que contêm modificadores de fricção.
BR112012012893A2 (pt) 2009-11-30 2017-06-20 Lubrizol Corp misturas estabilizadoras que contêm modificadores de fricção.
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JP5784756B2 (ja) 2011-02-09 2015-09-24 ザ ルブリゾル コーポレイションＴｈｅ Ｌｕｂｒｉｚｏｌ Ｃｏｒｐｏｒａｔｉｏｎ アスファルテン分散剤含有潤滑組成物
CA2827438A1 (en) 2011-02-17 2012-08-23 The Lubrizol Corporation Lubricants with good tbn retention
DK2607462T3 (da) 2011-12-20 2014-03-31 Infineum Int Ltd Smøring af skibsmotor
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EP2986694B1 (en) 2013-04-17 2020-03-18 The Lubrizol Corporation Method of lubricating a 2-stroke internal combustion engine cylinder liner and piston
NZ725495A (en) 2014-04-02 2020-05-29 Franck Natali Doped rare earth nitride materials and devices comprising same

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EP0095322A2 (en) * 1982-05-22 1983-11-30 Orobis Limited Process for the production of an overbased sulphurised alkaline earth metal alkyl phenate

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0351052A3 (en) * 1988-06-14 1990-05-23 Bp Chemicals (Additives) Limited A process for the production of a lubricating oil additive concentrate
US5433871A (en) * 1988-06-14 1995-07-18 Bp Chemicals (Additives) Limited Process for the production of a lubricating oil additive concentrate
US5437803A (en) * 1988-06-14 1995-08-01 Bp Chemicals (Additives) Limited Process for the production of a lubricating oil additive concentrate
US5451331A (en) * 1988-06-14 1995-09-19 Bp Chemicals (Additives) Limited Process for the production of a lubricating oil additive concentrate
EP0989178A4 (en) * 1997-05-07 2000-09-13 Cosmo Sogo Kenkyusho Kk LUBRICANT OIL COMPOSITION MADE FROM OVER-BASED EARTH ALKALINE METAL SULFIDE PHENOLATE CONCENTRATES AND METHOD FOR PRODUCING THESE CONCENTRATES
US5942476A (en) * 1998-06-03 1999-08-24 Chevron Chemical Company Low-viscosity highly overbased phenate-carboxylate
SG82602A1 (en) * 1998-06-03 2001-08-21 Chevron Chem Co Low-viscosity highly overbased phenate-carboxylate
US6348438B1 (en) 1999-06-03 2002-02-19 Chevron Oronite S.A. Production of high BN alkaline earth metal single-aromatic ring hydrocarbyl salicylate-carboxylate

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DE3781118D1 (de) 1992-09-17
DE3781126T2 (de) 1993-03-04
IN172581B (enrdf_load_stackoverflow) 1993-10-16
CN1012074B (zh) 1991-03-20
EP0273588B2 (en) 2001-03-28
CA1305696C (en) 1992-07-28
CN1015642B (zh) 1992-02-26
KR960010991B1 (ko) 1996-08-14
NO883348D0 (no) 1988-07-28
MX169105B (es) 1993-06-22
DK419888D0 (da) 1988-07-27
BR8707551A (pt) 1989-03-14
EP0273588B1 (en) 1992-08-12
MX169106B (es) 1993-06-22
ES2051751T3 (es) 1994-07-01
FI883503A0 (fi) 1988-07-25
SG101192G (en) 1992-12-04
FI93653B (fi) 1995-01-31
WO1988003944A1 (en) 1988-06-02
DE3781126D1 (de) 1992-09-17
EP0273588A1 (en) 1988-07-06
DE3781126T3 (de) 2001-08-02
AU8238087A (en) 1988-06-16
NO302763B1 (no) 1998-04-20
DE3781118T3 (de) 2002-08-14
FI93654B (fi) 1995-01-31
NO176147C (no) 1995-02-08
ZA878939B (en) 1989-07-26
GR3006075T3 (enrdf_load_stackoverflow) 1993-06-21
DK419788A (da) 1988-07-27
JPH01501400A (ja) 1989-05-18
GB8628609D0 (en) 1987-01-07
AU609075B2 (en) 1991-04-26
FI883502L (fi) 1988-07-25
FI93653C (fi) 1995-05-10
KR960010992B1 (ko) 1996-08-14
DE3781118T2 (de) 1992-12-17
ATE79396T1 (de) 1992-08-15
NO883348L (no) 1988-09-14
KR890700158A (ko) 1989-03-10
JPH0631383B2 (ja) 1994-04-27
JPH0631384B2 (ja) 1994-04-27
FI883502A0 (fi) 1988-07-25
ES2051752T3 (es) 1994-07-01
NO883349L (no) 1988-09-22
IN169547B (enrdf_load_stackoverflow) 1991-11-09
CN87108239A (zh) 1988-06-15
EP0271262B2 (en) 2002-05-29
NO176147B (no) 1994-10-31
NO883349D0 (no) 1988-07-28
ATE79395T1 (de) 1992-08-15
AU608792B2 (en) 1991-04-18
CN87108344A (zh) 1988-06-22
JPH01501399A (ja) 1989-05-18
DK175287B1 (da) 2004-08-09
CA1305697C (en) 1992-07-28
FI883503L (fi) 1988-07-25
EP0271262B1 (en) 1992-08-12
EP0271262A1 (en) 1988-06-15
DK419788D0 (da) 1988-07-27
FI93654C (fi) 1995-05-10
SG101092G (en) 1992-12-04
AU8237287A (en) 1988-06-16
DK419888A (da) 1988-07-27
GR3006112T3 (enrdf_load_stackoverflow) 1993-06-21
KR890700159A (ko) 1989-03-10
ZA878938B (en) 1989-07-26
BR8707550A (pt) 1989-03-14

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