WO1987002698A1 - Produit de nettoyage - Google Patents

Produit de nettoyage Download PDF

Info

Publication number
WO1987002698A1
WO1987002698A1 PCT/GB1986/000652 GB8600652W WO8702698A1 WO 1987002698 A1 WO1987002698 A1 WO 1987002698A1 GB 8600652 W GB8600652 W GB 8600652W WO 8702698 A1 WO8702698 A1 WO 8702698A1
Authority
WO
WIPO (PCT)
Prior art keywords
composition according
composition
water
terpenes
weight
Prior art date
Application number
PCT/GB1986/000652
Other languages
English (en)
Inventor
George Edward Taylor
Original Assignee
Thomas Christy Limited
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Thomas Christy Limited filed Critical Thomas Christy Limited
Publication of WO1987002698A1 publication Critical patent/WO1987002698A1/fr
Priority to KR870700530A priority Critical patent/KR880700053A/ko

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
    • A61K8/494—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with more than one nitrogen as the only hetero atom
    • A61K8/4946—Imidazoles or their condensed derivatives, e.g. benzimidazoles
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0208—Tissues; Wipes; Patches
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37—Esters of carboxylic acids
    • A61K8/375—Esters of carboxylic acids the alcohol moiety containing more than one hydroxy group
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
    • A61K8/4993—Derivatives containing from 2 to 10 oxyalkylene groups
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • A61K8/925—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of animal origin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/10—Washing or bathing preparations
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/18—Hydrocarbons

Definitions

  • CLEANING PRODUCT This invention relates to products for use in cleaning, and especially for stain removal.
  • Citrus oil is useful as a stain remover.
  • Citrus 5 oil e.g. orange terpenes, the residue of extraction of perfumery products from citrus fruits, dissolves and thus removes ink or other stains from the skin or from clothing.
  • aqueous compositions comprising an antiseptic and a small concentration of a perfume, 25 absorbed in a serrated roll of non-woven paper material, are available in a dispenser for tearing and application as individual "wipes" .
  • a composition according to the present invention comprises orange or other citrus fruit terpenes and a 30 solubilising agent which has a HLB-value of at least 10. It has been found that orange terpenes, in such a
  • an aqueous composition of the invention can be absorbed in a suitable carrier, e.g. a non-woven paper or other fabric, as in conventional "wipes".
  • a suitable carrier e.g. a non-woven paper or other fabric
  • the products of the invention provide the effective properties of, say, orange terpenes at an economical level, i.e. at less than 20% w/w, more preferably less than 10% w/w, of the aqueous composition.
  • the minimum level of terpenes in the aqueous composition is usually 0.5% w/w, and preferably at least 1% w/w.
  • non-aqueous compositions of the invention are storage-stable concentrates well adapted to mere dilution with water, for further use.
  • the solubilising agent used in the present invention is an essential component.
  • the HLB value of this agent is preferably from 12 to 18, e.g. 13 to 17.
  • polyoxyalkylene ester copolymers e.g. polyoxyethylene fatty acid copolymers such as Polysorbate 20 (HLB 16.7) and a polyethylene glycol mono-ester having a molecular weight of about 600, which is a wax-like non-ionic surfactant, e.g. as sold under the trade name Cithrol 6 S (HLB 14) .
  • the weight ratio of this component to the terpenes may be, for example, 0.01:10, 0.05:5 or 0.1:1.
  • a mixture of HLB>10 surfactants may sometimes be preferred.
  • a HLB ⁇ 10 (e.g. 2 to 8) material may be used, e.g. a polyol ester such as glyceryl monostearate.
  • Another desirable additive is an amphoteric surfactant such as a low viscosity coconut imadazoline betaine, e.g.
  • compositions of the invention may comprise various other ingredients, depending on the desired end use. It will often be desirable to ensure that the composition is topically-acceptable, e.g. for use as a hand cleanser.
  • the composition may comprise components such as propylene glycol and a water-soluble lanolin, e.g. an ethoxylated lanolin, for example the hydrophilic wax sold as Solan.
  • compositions of the invention It will also often be desirable to include a preservative in compositions of the invention.
  • Conventional preservatives may be used; one which has been found to act satisfactorily is a mixture of methyl isothiazolinone and methyl chloroisothiazolinone sold under the trade name Kathon.
  • the predominant component of aqueous compositions of the invention is water.
  • the amount of water is usually at least 70% w/w and often at least 75% w/w.
  • the terpenes often provide the next greatest amount o.f the composition.
  • the total amount of solubilising agents and other components may be, for example, 2 to 20% w/w of the composition.
  • Aqueous compositions of the invention may be prepared by mixing the terpenes and the solubilising agent together with, if desired, a small proportion of water, to prepare a thick mass. This mass is then mixed with the, or the remaining proportion of the, water, suitably while warming the components of the mixture, to obtain the desired composition.
  • An aqueous composition of the invention may be used to impregnate a "log" of absorbent . non-woven material in conventional manner.
  • the roll of material can then be dispensed through a conventional "wipe" dispenser, to give one-use tissues or "wipes" which are effective to remove stains from hands or material by virtue of the effective concentration of orange terpenes.
  • the following Examples illustrate the invention. All percentages are by weight. Example 1
  • Example 1 The procedure of Example 1 was successfully repeated, using grapefruit terpenes rather than orange terpenes.

Landscapes

  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Chemical & Material Sciences (AREA)
  • Epidemiology (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Biomedical Technology (AREA)
  • Dermatology (AREA)
  • Emergency Medicine (AREA)
  • Zoology (AREA)
  • Detergent Compositions (AREA)

Abstract

Une composition qui comporte de l'essence de citrus et un agent solubilisant présentant une valeur HLB supérieure à 10 peut être mélangée de manière homogène à de l'eau pour donner un produit détachant efficace, sous forme d'un liquide ou imprégnée dans un véhicule, contenant seulement une faible proportion de l'ingrédient efficace, par exemple des terpènes d'orange.
PCT/GB1986/000652 1985-10-22 1986-10-22 Produit de nettoyage WO1987002698A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
KR870700530A KR880700053A (ko) 1985-10-22 1987-06-22 세제 조성물

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB858526051A GB8526051D0 (en) 1985-10-22 1985-10-22 Cleaning product
GB8526051 1985-10-22

Publications (1)

Publication Number Publication Date
WO1987002698A1 true WO1987002698A1 (fr) 1987-05-07

Family

ID=10587079

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/GB1986/000652 WO1987002698A1 (fr) 1985-10-22 1986-10-22 Produit de nettoyage

Country Status (5)

Country Link
EP (1) EP0248822A1 (fr)
JP (1) JPS63501363A (fr)
KR (1) KR880700053A (fr)
GB (1) GB8526051D0 (fr)
WO (1) WO1987002698A1 (fr)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5025069A (en) * 1988-12-19 1991-06-18 Kao Corporation Mild alkyl glycoside-based detergent compositions, further comprising terpene and isothiazolone derivatives
EP0512328A1 (fr) * 1991-05-06 1992-11-11 Miles Inc. Composition nettoyante inoffensive vis à vis des produits alimentaires
DE19724106A1 (de) * 1997-06-07 1999-04-01 Sandner Herbert Dipl Ing Verfahren zur Vorbehandlung von durch Schweiß verunreinigten Bereichen von Textilien vor einer allgemeinen Reinigung sowie Eiweißlösemittel insbesondere hierfür
FR2853325A1 (fr) * 2003-04-04 2004-10-08 Teinturerie Leschaeve Composition aqueuse pour nettoyage a sec naturel, procede et appareil de nettoyage a sec
GB2405639A (en) * 2003-09-08 2005-03-09 R Mc Power Recovery Ltd Metal cleaning compositions
EP1757261A2 (fr) * 2001-07-13 2007-02-28 JOHNSON & JOHNSON GmbH Produits comprenant un film et une phase aqueuse lipidique

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SE526170C2 (sv) * 2003-05-07 2005-07-19 Akzo Nobel Nv Vattenhaltig komposition innehållande en alkylenoxid addukt, en hexylglukosid och en aktiv nonionisk alkylenoxid addukt som vätmedel

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2262692A1 (fr) * 1974-02-28 1975-09-26 Raffinage Cie Francaise
US4330422A (en) * 1977-02-01 1982-05-18 Minnesota Mining And Manufacturing Company Treating composition containing white oil
EP0072488A1 (fr) * 1981-08-14 1983-02-23 S.C. Johnson & Son, Inc. Composition de pré-détachage du linge à faible teneur de solvant
DE3144168A1 (de) * 1981-11-06 1983-05-19 Robert Cornelius 32750 Longwood Fla. Ghegan Wasserloses, terpen aus zitrusoel enthaltendes handreinigungsmittel
US4414128A (en) * 1981-06-08 1983-11-08 The Procter & Gamble Company Liquid detergent compositions
US4511488A (en) * 1983-12-05 1985-04-16 Penetone Corporation D-Limonene based aqueous cleaning compositions
EP0137474A2 (fr) * 1983-10-12 1985-04-17 S.C. Johnson & Son, Inc. Composition métastable pour enlever des tâches

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2262692A1 (fr) * 1974-02-28 1975-09-26 Raffinage Cie Francaise
US4330422A (en) * 1977-02-01 1982-05-18 Minnesota Mining And Manufacturing Company Treating composition containing white oil
US4414128A (en) * 1981-06-08 1983-11-08 The Procter & Gamble Company Liquid detergent compositions
EP0072488A1 (fr) * 1981-08-14 1983-02-23 S.C. Johnson & Son, Inc. Composition de pré-détachage du linge à faible teneur de solvant
DE3144168A1 (de) * 1981-11-06 1983-05-19 Robert Cornelius 32750 Longwood Fla. Ghegan Wasserloses, terpen aus zitrusoel enthaltendes handreinigungsmittel
EP0137474A2 (fr) * 1983-10-12 1985-04-17 S.C. Johnson & Son, Inc. Composition métastable pour enlever des tâches
US4511488A (en) * 1983-12-05 1985-04-16 Penetone Corporation D-Limonene based aqueous cleaning compositions
US4511488B1 (fr) * 1983-12-05 1990-09-11 Penetone Corp

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5025069A (en) * 1988-12-19 1991-06-18 Kao Corporation Mild alkyl glycoside-based detergent compositions, further comprising terpene and isothiazolone derivatives
EP0512328A1 (fr) * 1991-05-06 1992-11-11 Miles Inc. Composition nettoyante inoffensive vis à vis des produits alimentaires
DE19724106A1 (de) * 1997-06-07 1999-04-01 Sandner Herbert Dipl Ing Verfahren zur Vorbehandlung von durch Schweiß verunreinigten Bereichen von Textilien vor einer allgemeinen Reinigung sowie Eiweißlösemittel insbesondere hierfür
EP1757261A2 (fr) * 2001-07-13 2007-02-28 JOHNSON & JOHNSON GmbH Produits comprenant un film et une phase aqueuse lipidique
EP1757261A3 (fr) * 2001-07-13 2008-06-11 JOHNSON & JOHNSON GmbH Produits comprenant un film et une phase aqueuse lipidique
FR2853325A1 (fr) * 2003-04-04 2004-10-08 Teinturerie Leschaeve Composition aqueuse pour nettoyage a sec naturel, procede et appareil de nettoyage a sec
WO2004090219A2 (fr) * 2003-04-04 2004-10-21 Teinturerie Leschaeve Composition aqueuse naturelle et machine pour nettoyage a sec des textiles et peausseries
WO2004090219A3 (fr) * 2003-04-04 2005-06-09 Teinturerie Leschaeve Composition aqueuse naturelle et machine pour nettoyage a sec des textiles et peausseries
GB2405639A (en) * 2003-09-08 2005-03-09 R Mc Power Recovery Ltd Metal cleaning compositions

Also Published As

Publication number Publication date
GB8526051D0 (en) 1985-11-27
JPS63501363A (ja) 1988-05-26
EP0248822A1 (fr) 1987-12-16
KR880700053A (ko) 1988-02-15

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