Classifications

• • D—TEXTILES; PAPER
  • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
  • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
  • D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
  • D04H3/08—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating
  • D04H3/12—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating with filaments or yarns secured together by chemical or thermo-activatable bonding agents, e.g. adhesives, applied or incorporated in liquid or solid form
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
  • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
  • Y10T428/00—Stock material or miscellaneous articles
  • Y10T428/26—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
  • Y10T428/269—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension including synthetic resin or polymer layer or component
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
  • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
  • Y10T428/00—Stock material or miscellaneous articles
  • Y10T428/27—Web or sheet containing structurally defined element or component, the element or component having a specified weight per unit area [e.g., gms/sq cm, lbs/sq ft, etc.]
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
  • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
  • Y10T428/00—Stock material or miscellaneous articles
  • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
  • Y10T428/2913—Rod, strand, filament or fiber
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
  • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
  • Y10T428/00—Stock material or miscellaneous articles
  • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
  • Y10T428/2913—Rod, strand, filament or fiber
  • Y10T428/2922—Nonlinear [e.g., crimped, coiled, etc.]
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
  • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
  • Y10T428/00—Stock material or miscellaneous articles
  • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
  • Y10T428/2913—Rod, strand, filament or fiber
  • Y10T428/298—Physical dimension

Definitions

• the present invention relates to a fiber sheet excellent in heat resistance, chemical resistance, flame retardancy, electrical insulation, strength and the like. More specifically, the present invention relates to a fiber sheet made of polyolefin renewable sulfide (hereinafter referred to as "s") long fiber and a method for producing the same.
• s polyolefin renewable sulfide
• PPS is 5, 912, 095, etc.] It is known as a thermoplastic polymer with excellent chemical resistance and heat resistance.
• melt spinning can be performed is also described in JP-B-52-122, JP-B-52-309, and the like.
• PPS-based polymers having a viscosity suitable for melt spinning tend to form dalized products, and gelled products are mixed in particles, and frequently break during spinning and drawing. . In particular, those with fine fineness are remarkable.
• a material whose viscosity has been reduced to avoid gelation lacks spinnability and is excessively brittle. Thread breakage due to friction with the thread can be avoided.
• Iron fibers produced by force are also rigid, easily electrified, and have a flat surface.3 They lack convergence, and crimping is not possible. Even yarn Difficulty is that spinning and weaving are not easy to achieve through a card to make a uniform sheet. Furthermore, it is hardly dispersed in water due to its strong hydrophobicity, and is suitable for the papermaking process. Therefore, it was easy to obtain a fibrous sheet consisting of PPs-based polymers with high strength and homogeneity.
• the present invention has the following configuration.
• PPS-based long fiber with a single fiber fineness of 0.1 to 1.5 denier is randomly dispersed and laminated in a random manner.
• a method of extruding through a fine hole into a pressurized air chamber and ejecting it at a high speed together with a pressurized fluid from a nozzle opposite the fine hole is adopted.
• a fiber with a dry heat shrinkage of 140 to 5% on gZd l3 ⁇ 4 can be 5 to 40%, and the spinning temperature must be higher than the melting point by 1 to 20 ° C or more, and 30 to 0 '. c Higher is preferred.
• the pore size of the pores is 0. "! ⁇ 1. 0 mm, the number of holes is 1 0 or more is commonly employed.
• the distance between the pores and the air jet is usually from 200 to 200 mm. If the distance is too short, thread breakage will occur.] If it is too long, the spinning speed will decrease. Strength decreases. In general, the appropriate distance shifts to the longer one when the single-filament iron is larger, and to the shorter one when the iron-yarn is smaller.
• the method of charging the running spun yarn may simply require contact with the wall surface of the air jet or a reflector.
• fibers generate high-speed airflow.
• Light contact with or near the wall surface of the object can be avoided, but the curvature of the contact surface can be increased and the angle of contact can be easily reduced. Therefore, fiber damage can be avoided.
• the spinning speed can be increased.
• a single yarn strength close to that of a PPS drawn yarn by a conventional method can be realized.
• C There is no occurrence of necking like a normal undrawn yarn. . However, it is composed of long fibers, which is the case with short-fiber nonwoven fabrics.]
• High strength can be achieved. This effect is extremely prominent when the number of bonding and entanglement points is reduced to increase flexibility.
• Used in the present invention As a PPS-based polymer, one having a melting degree of 300 to 100,000 voids at a temperature of 300 ° and a shear rate of 200 seconds: good .
• a plurality of types of PPS-based polymers can be extruded from different pores and mixed in an air stream.
• the single fiber size is 0.1 to 15 denier, preferably 0.5 to 5 d, and the basis weight of the long fiber web is 10 to 10 ⁇ ⁇ 8 ⁇ 2 ⁇ preferably 20 ⁇ 300 gZ is adopted. Of course, it is easy to stack them.
• the long fiber web is 5 ⁇ 803 ⁇ 4 ⁇ , preferably 1C! It has an area shrinkage rate of up to 0%, more preferably 15 to 40% (according to the method for measuring the area shrinkage rate of paper of JIS c—2 11 1), Very convenient in molding. If it exceeds 80%, problems will occur in the dimensional stability and quality of the product.
• the constituent fibers will exhibit crimp and become bulky and flexible.
• a confounding treatment with a dollar or a water jet can provide various properties, such as bulkiness, strength, and flexibility. Effective after needle punch 3 ⁇ 4 To expect crimping, the punch density should be 30 to 300, preferably 5C! ⁇ 200 lines ⁇ 2 . If the basis weight is 200 gm 2 or more, damage to the fiber is small and high strength is easily maintained.
• the confounding by the water jet is very convenient for the confounding of the PPS-based web with little damage to the fiber.
• the method disclosed in Japanese Patent Publication No. 48-137349 can be applied. For example, the web is placed on a porous support,
• the PPS-based polymer of the present invention means a homo- or copolymer having a p-ferrenal sulfide unit as a main constituent unit. These are obtained by condensing P-dichlorobenzen with sodium sulfide. When a plurality of polymers having different melting points or different shrinkages are used, it is preferable to use one having a different degree of copolymerization.
• the copolymerization components include m-dichlorobenzen, 1,2,41-trichlorosolbenzen, or diphenylenolenyl, a diphenylenolenyl group, A base with a base or a naphthalene core is used. Trichlorbenzen impairs the spinnability, so it is not preferable to copolymerize it. Even if a plurality of polymers are used, it is desirable that the main polymer component has a copolymerization component of 10% or less. In such a case, I 0 basic properties such Re loss Wa large active kinds regardless PP s copolymerization component
• a high-gravity metal carbonate such as lithium severe acid, is added to obtain a high-gravity polymer.
• a moderately linear PPS is particularly suitable for the present invention.
• the degree of polymer cross-linking or branching can be defined by the non-Newton's constant n
• r is the shear rate
• ⁇ is the shear force
• ⁇ is the apparent viscosity.
• ⁇ is a value approximately determined from the plot of r and increases as the number of crosslinked or branched structures increases.
• a polymer of 0.9> n> 5.0 is suitable, and a polymer of 0.9> n> -2.0 is particularly suitable.
• Such a polymer has excellent spinnability and does not easily gel during melt spinning. What is remarkable is that the spinning speed is dramatically improved when air is taken. Often from less than 200 m / min
• Various heat resistant binders before or after the thermal dressing for example, Polyimide, Polyamide, Aromatic Polyamide, Polybenzimidazo It can be applied by impregnation, coating, spraying, spraying, etc., with a single-layer or poly-relene salfide. The amount applied is fine
• the nonwoven fabric of the present invention can be converted to a substantially insoluble nonwoven fabric by treating it with an oxidizing agent such as sodium hypochlorite.
• an oxidizing agent such as sodium hypochlorite.
• it can be used as an industrial filter exposed to a high-temperature atmosphere and a nonwoven fabric useful for firefighting suits and the like.
• the value of the polyester felt is a cutting strength of 5 to 8 kg and an elongation of 8 C! ⁇ 100%, subtraction f O PI Cracks 2 to 43 mm.
• the graded fiber used in this example was cut into a step shape and a force-ding method was used to make a 3 web. ]. Web formation was not possible. From this, the effectiveness of long-fiber non-woven fabric was proved in the heat- and chemical-resistant felt made of the union.
• Example 2 In Example 1, the number of -1 dollar punches obtained in the obtained chip was changed to 100, 50, 200 , 300, and 400, and ⁇ 2. The mechanical properties of the similarly processed felt are shown as exponential values, where the numerical value obtained in Example 1 is 100.
• Example 3 Using the web made of the ⁇ 1 fiber obtained in Example 1, a entanglement treatment using a water jet was performed.
• a water stream was sprayed from the nozzle at a pressure of 7033 ⁇ 4 / on s to intermittently move the gold ash to form a nonwoven fabric.
• the resulting felt had an apparent specific gravity of 0-39 gZcc, and the mechanical properties in terms of 100 gZm 2 basis weight were as follows.
• the 200-voise polymer was melted under 320 ° C, and the 0.7 thigh diameter pores were extruded from a mouthpiece with 20 pores to a single hole per minute]? 0.3 g ⁇ ⁇ ⁇ In the position of [7] and led to the air aspirator.
• a pressure air of 1] 3 ⁇ 4 ⁇ 2 ⁇ & was supplied to the assulator (as a result, the filament of the PPS was operated at a speed of 17 Q0 m / min.
• the filaments obtained had a fineness of 1. ⁇ -d-el, a cutting strength of 1.7 g Z-d-el, and a cutting elongation of 120 0 ⁇ and 160 0. It had a shrinkage ratio of 45 during the 10-minute free-shrink heat treatment.
• the corona discharge device sets the needle electrode and the earth electrode with a diameter of 20 thighs at an interval of 8 rows, and sets the negative electrode between both electrodes.
• the filament When the filament is unwound from the collected sheet, the filament spreads up to 0 cm away from the position vertically below the assulator. Coordinated until: ⁇ 'I understand.
• the web was run and collected continuously to obtain a web with a width of 40 cm and a basis weight of 55 gZm 2 . After removing static electricity from the web on the wire mesh, the web was separated to obtain a nonwoven fabric. This nonwoven fabric had a planar surface yield of 36 when a 10 cm square sample was ripened in a 160 ° C oven.
• This nonwoven fabric is applied to a calendar roller with a surface temperature of 1 ° O'G and a load of 500 °] 3 ⁇ 4.
• a 0.2-mm-thick, dense, smooth-surfaced paper-like sheet was created.
• ⁇ This sheet had the shape and metastability to withstand various wet treatments.
• paper impregnated with a solution of Polyimide 30 in N-methylvinylidone was applied, attached to the fiber weight 25 ⁇ , dried, and cured at 180 for 1 hour. It had the following characteristics.
• the air pressure of the aspirator is reduced.
• the PP s type long fiber sheet of the present invention is excellent in heat resistance, chemical resistance, flame retardancy, electric insulation, strength, and the like. For example! It has long-term heat resistance equivalent to one kind of film.
• These include industrial filters, gaskets, fillings, safety clothing for disaster prevention, base materials for reinforcement, insulation materials, etc., and dense electrical insulation materials, speaker cores, etc. It can be applied to a wide variety of applications such as components, wiring boards, battery separators, etc.

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• Chemical & Material Sciences (AREA)
• Chemical Kinetics & Catalysis (AREA)
• General Chemical & Material Sciences (AREA)
• Engineering & Computer Science (AREA)
• Textile Engineering (AREA)
• Nonwoven Fabrics (AREA)
• Artificial Filaments (AREA)
• Treatment Of Fiber Materials (AREA)
• Filtering Materials (AREA)

Priority Applications (2)

Applications Claiming Priority (2)

Publications (1)

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Family Applications (1)

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Cited By (1)

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Citations (3)

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• 1980
  • 1980-06-27 JP JP8656880A patent/JPS5716954A/ja active Granted
• 1981
  • 1981-06-24 WO PCT/JP1981/000145 patent/WO1982000163A1/ja not_active Ceased
  • 1981-06-24 EP EP81901788A patent/EP0056418B2/en not_active Expired - Lifetime
  • 1981-06-24 DE DE8181901788T patent/DE3165555D1/de not_active Expired
  • 1981-06-24 US US06/348,007 patent/US4454189A/en not_active Expired - Lifetime

Patent Citations (3)

Non-Patent Citations (1)

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