Classifications

• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
  • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
  • C09D139/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Coating compositions based on derivatives of such polymers
  • C09D139/04—Homopolymers or copolymers of monomers containing heterocyclic rings having nitrogen as ring member
  • C09D139/06—Homopolymers or copolymers of N-vinyl-pyrrolidones
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
  • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
  • C08J7/04—Coating
  • C08J7/0427—Coating with only one layer of a composition containing a polymer binder
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
  • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
  • C08J7/04—Coating
  • C08J7/043—Improving the adhesiveness of the coatings per se, e.g. forming primers
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
  • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
  • C08J7/04—Coating
  • C08J7/054—Forming anti-misting or drip-proofing coatings
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
  • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
  • C08J7/04—Coating
  • C08J7/056—Forming hydrophilic coatings
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
  • C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
  • C08J2439/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Derivatives of such polymers
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
  • C08K5/00—Use of organic ingredients
  • C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
  • C08K5/41—Compounds containing sulfur bound to oxygen
  • C08K5/42—Sulfonic acids; Derivatives thereof
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
  • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
  • Y10T428/00—Stock material or miscellaneous articles
  • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
  • Y10T428/24942—Structurally defined web or sheet [e.g., overall dimension, etc.] including components having same physical characteristic in differing degree
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
  • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
  • Y10T428/00—Stock material or miscellaneous articles
  • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
  • Y10T428/24942—Structurally defined web or sheet [e.g., overall dimension, etc.] including components having same physical characteristic in differing degree
  • Y10T428/2495—Thickness [relative or absolute]
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
  • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
  • Y10T428/00—Stock material or miscellaneous articles
  • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
  • Y10T428/24942—Structurally defined web or sheet [e.g., overall dimension, etc.] including components having same physical characteristic in differing degree
  • Y10T428/2495—Thickness [relative or absolute]
  • Y10T428/24967—Absolute thicknesses specified
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
  • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
  • Y10T428/00—Stock material or miscellaneous articles
  • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
  • Y10T428/24942—Structurally defined web or sheet [e.g., overall dimension, etc.] including components having same physical characteristic in differing degree
  • Y10T428/2495—Thickness [relative or absolute]
  • Y10T428/24967—Absolute thicknesses specified
  • Y10T428/24975—No layer or component greater than 5 mils thick
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
  • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
  • Y10T428/00—Stock material or miscellaneous articles
  • Y10T428/26—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
  • Y10T428/263—Coating layer not in excess of 5 mils thick or equivalent
  • Y10T428/264—Up to 3 mils
  • Y10T428/265—1 mil or less
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
  • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
  • Y10T428/00—Stock material or miscellaneous articles
  • Y10T428/31504—Composite [nonstructural laminate]
  • Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
  • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
  • Y10T428/00—Stock material or miscellaneous articles
  • Y10T428/31504—Composite [nonstructural laminate]
  • Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
  • Y10T428/31565—Next to polyester [polyethylene terephthalate, etc.]
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
  • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
  • Y10T428/00—Stock material or miscellaneous articles
  • Y10T428/31504—Composite [nonstructural laminate]
  • Y10T428/31786—Of polyester [e.g., alkyd, etc.]
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
  • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
  • Y10T428/00—Stock material or miscellaneous articles
  • Y10T428/31504—Composite [nonstructural laminate]
  • Y10T428/31786—Of polyester [e.g., alkyd, etc.]
  • Y10T428/31797—Next to addition polymer from unsaturated monomers
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
  • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
  • Y10T428/00—Stock material or miscellaneous articles
  • Y10T428/31504—Composite [nonstructural laminate]
  • Y10T428/31855—Of addition polymer from unsaturated monomers
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
  • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
  • Y10T428/00—Stock material or miscellaneous articles
  • Y10T428/31504—Composite [nonstructural laminate]
  • Y10T428/31855—Of addition polymer from unsaturated monomers
  • Y10T428/31935—Ester, halide or nitrile of addition polymer

Definitions

• the invention relates to an aqueous coating composition which comprises polyvinylpyrrolidone, a surfactant and optionally an adhesion-promoting polymer.
• This composition is suitable for inline coating of biaxially oriented polyester films.
• the thus obtained coated films feature a characteristic hydrophilic surface which prevents the fogging of the film with water droplets (known as antifog coating).
• the packaging industry has a high demand for transparent biaxially oriented polyester films.
• the result can be, particularly in the case of chilled products, undesired fogging of the film and thus deterioration of the transparency when moisture condenses out of the packaged products onto the film in the form of drops, usually of different size.
• the transparency of the film is distinctly worsened by the condensate.
• the reduction of the transparency of the film can be prevented by a hydrophilic coating, also known as an antifog coating.
• hydrophilization of the film is required is that of medical applications.
• the applied liquid for example blood
• the applied liquid has to be distributed rapidly and uniformly over the surface. This can be achieved with a hydrophilic coating.
• Antifog properties of plastics surfaces can be realized by means of two different technologies. Firstly, the addition of an additive into the polymer is conceivable; secondly, an antifog coating can be applied to the film.
• the addition of an additive into the polymer is possible in the case of polyolefin articles, in particular films (for example WO2002/074535).
• the antifog action on the film surface is based on the migration of the additive, usually an amphiphilic molecule, to the surface, so that the polar ends of the molecules form the actual antifog layer. A transfer of this principle to a polyester film is not possible, owing to the high polarity of the polyester.
• coatings based on hydrophilic water-soluble polymers are also known.
• a problem in this context is the ease with which the coating is washed out, which can be prevented by additives which lead to crosslinking of the polymer.
• Surfactants are also used for antifog coatings, since they lower the surface tension of the water.
• these known coatings are applied to an existing film surface, i.e. the production of the substrate and the coating are effected in two steps. It would be desirable to apply such coatings to the polyester films actually within the production process thereof (in what is known as the inline process); however, such coatings are to date not known.
• U.S. Pat. No. 4,467,073 discloses a transparent antifog coating.
• the composition comprises a) polyvinylpyrrolidone, polydimethylacrylamide or a polyvinylpyrrolidone copolymer with an ⁇ -olefin, b) a polyisocyanate prepolymer, c) a surfactant and d) an organic solvent.
• the disadvantage of this invention is the use of an organic solvent, especially when the coating step is to be incorporated into the film production (inline).
• the use of an isocyanate in foodstuff packaging is controversial, since carcinogenic primary amines can form.
• U.S. Pat. No. 5,262,475 describes a hydrophilic composition which comprises polyvinylpyrrolidone, polyvinyl alcohol and, as a crosslinker, melamine, a mineral acid or a strong organic acid.
• the coating solution may comprise additives such as chain extenders, foam regulators or surfactants.
• the solids content of the coating is from 5 to 50%.
• the crosslinking to hard clear layers requires temperatures of at least 75° C.; in the examples, temperatures between 130 and 150° C. are used. This makes these coatings unsuitable for inline application to polyester films, since the components crosslink as early as in the course of drying or in the course of stretching, and the coating thus starts to tear and therefore can lead to tears in the film.
• the fact that the crosslinked coatings are described as hard also suggests that they are unsuitable for use on flexible substrates.
• the thus obtained coated polyester films should have good antifog effect, high washout resistance and high hydrophilicity.
• an aqueous coating composition which, in addition to water, comprises the following components:
• the total concentration of all components a) to c) in water is preferably in the range from 1 to 8% by weight. Unless stated otherwise, all amounts specified are percentages by weight.
• the polyvinylpyrrolidone is used preferably with a molecular weight (Mw) between 20 and 2500 kdaltons, more preferably between 40 and 1500 kdaltons.
• Mw molecular weight
• the proportion of the polyvinylpyrrolidone in the coating solution is from 0.3 to 4.0% by weight, preferably from 0.5 to 3.5% by weight.
• Surfactants refer to molecules which consist of a hydrophobic and a hydrophilic part; they are referred to as amphiphilic.
• the surfactant mentioned in the above-described coating composition is used in a concentration of from 0.1 to 2.5% by weight, preferably from 0.3 to 2.0% by weight, and is preferably an ionic, more preferably an anionic surfactant, and is more preferably selected from the group of the alkylsulfates, alkylbenzenesulfates, alkyl ether sulfates or sulfosuccinic esters.
• the polymers which improve the binding of the polyvinylpyrrolidone to the polyester surface are used preferably in the form of an aqueous solution or dispersion.
• concentration in the finished coating solution is from 0.3 to 4.0% by weight, preferably from 0.5 to 3.5% by weight.
• Suitable polymers of this type are acrylates, as described, for example, in WO94/13476, hydrophilic polyesters (5-Na-sulfoisophthalic acid-containing PET/IPA polyester, as described, for example, in EP-A-0144878, U.S. Pat. No.
• the acrylates preferably comprise an ester of methacrylic zacid, in particular an alkyl ester whose alkyl group contains up to ten carbon atoms, for example the methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, tertiary butyl, hexyl, 2-ethyhexyl, heptyl and n-octyl group.
• Acrylic copolymers which are derived from a lower alkyl acrylate (C1 to C4), in particular ethyl acrylate, together with a lower alkyl methacrylate give rise to particularly good adhesion to the polyester film.
• suitable comonomers for example N-methylolacrylamide, N-methylolmethacrylamide and the corresponding ethers; carboxyl-containing monomers, for example crotonic acid, itaconic acid, maleic acid or acrylic acid; anhydrides, for example maleic anhydride or itaconic anhydride; hydroxyl-containing monomers, for example allyl alcohol and hydroxyethyl or hydroxypropyl acrylate or methacrylate, and amides, for example acrylamide, methacrylamide or maleamide.
• Such acrylate copolymers give rise to particularly good adhesion between the polyester film and the polyvinylpyrrolidone.
• the coating may comprise antiblocking agents.
• Customary antiblocking agents are inorganic and/or organic particles, for example calcium carbonate, amorphous silica, talc, magnesium carbonate, barium carbonate, calcium sulfate, barium sulfate, lithium phosphate, calcium phosphate, magnesium phosphate, alumina, lithium fluoride, titanium dioxide, kaolin or crosslinked polystyrene or acrylate particles.
• porous SiO 2 such as amorphous silica, since this promotes the distribution of water over the surface of the film.
• the coating composition thus contains preferably only water and components a) and b), or a), b) and c), and also optionally antiblocking agents.
• “Contains” means here that the composition comprises to an extent of at least 90% by weight, preferably at least 95% by weight and more preferably at least 99% by weight, of the aforementioned substances.
• the coating comprises of the dried residue (drying product) of the coating composition, which then likewise preferably contains only of the drying product of components a) and b), or a), b) and c), and also optionally antiblocking agents.
• the inventive coating may be used in order to coat biaxially oriented polyester film inline, i.e. the coating is applied during the film production process before the longitudinal and/or transverse stretching.
• the surface is preferably initially corona-treated.
• the coating can be applied with a common suitable process, such as with a slot coater or a spray process. Particular preference is given to applying the coating by means of the reverse gravure-roll coating process, in which the coating can be applied extremely homogeneously with application weights between 1.0 and 3.0 g/m 2 . Preference is likewise given to application by the Meyer Rod process, with which larger coating thicknesses can be achieved.
• the coating on the finished film has a thickness of from 5 to 500 nm, preferably from 30 to 200 nm.
• the coating components can react with one another during the drying and orientation of the polyester film and particularly in the subsequent heat treatment, which can extend up to 240° C.
• the reaction product affords, especially on a biaxially oriented polyester film, good antifog effect, high washout resistance and high hydrophilicity.
• the polyester film to which the coating is applied can have a single-layer structure, a two-layer structure comprised of a base layer (B) and an outer layer (A), or a three-layer structure comprised of a base layer (B) and two outer layers (A) and (A′ or C).
• the total thickness of the polyester film is typically in the range from 5 to 500 ⁇ m, preferably from 10 to 350 ⁇ m.
• the polyester film may be transparent, white, opaque, glossy or matt. These different optical properties are achieved, for example, by the addition of different amounts of additives such as calcium carbonate, amorphous silica or titanium dioxide. These additives may be present both in the base layer and in any outer layers present.
• additives such as calcium carbonate, amorphous silica or titanium dioxide. These additives may be present both in the base layer and in any outer layers present.
• the polyester film may be sealable and peelable. This is commonly achieved by use of polyesters with low glass transition temperature or of other sealable polymers in at least one outer layer.
• the polyester film is comprised mainly of thermoplastic polyester.
• polyesters are specified in the “Handbook of Thermoplastic Polyesters, Ed. S. Fakirov, Wiley-VCH, 2002”.
• polyester films The production process for polyester films is described, for example, in the “Handbook of Thermoplastic Polyesters, Ed. S. Fakirov, Wiley-VCH, 2002” or in the chapter “Polyesters, Films” in the “Encyclopedia of Polymer Science and Engineering, Vol. 12, John Wiley & Sons, 1988”.
• the molten polymer material is extruded, optionally with the additives, through a slot die and quenched on a chill roll as a substantially amorphous prefilm.
• This film is subsequently reheated and oriented in at least one direction, either in machine direction (MD) or in transverse direction (TD), but preferably in longitudinal and transverse direction or in transverse and longitudinal direction, or in longitudinal, in transverse and once again in longitudinal direction and/or transverse direction.
• the film temperatures in the stretching process are generally from 10 to 60° C. above the glass transition temperature Tg of the polyester used; the stretching ratio of the longitudinal stretching is typically from 2.0 to 6.0, in particular from 3.0 to 4.5, that of the transverse stretching is from 2.0 to 5.0, in particular from 3.0 to 4.5, and that of the optionally performed second longitudinal and transverse stretching from 1.1 to 5.0.
• the longitudinal stretching may also be carried out simultaneously with the transverse stretching (simultaneous stretching) or in any conceivable sequence. This is followed by heat-setting of the film at oven temperatures of from 180 to 260° C., in particular from 220 to 250° C. Subsequently, the film is cooled and wound up.
• Inventive Coating components range Preferred Unit Polyvinylpyrrolidone, 0.3 to 4.0 0.5 to 3.5 % by wt. proportion Polyvinylpyrrolidone, M w 20 to 2500 40 to 1500 kdaltons Surfactant, proportion 0.1 to 2.5 0.3 to 2.0 % by wt. Optional polymer, 0.3 to 4.0 0.5 to 3.5 % by wt. proportion Thickness of the 5 to 500 30 to 200 nm coating
• polyester films were coated and these were characterized by the following test methods.
• the surface tension of the films is so high (>70 mN/m) that it cannot be measured by the contact angle method, since the water drop is very flat.
• the antifog properties of the polyester films were determined as follows:
• the trays were stored in a refrigerator controlled at 4° C. and were taken out for assessment after 10 min, 30 min, 4 h, 8 h and 24 h.
• the condensate formation on cooling of the air at 23° C. to refrigerator temperature was tested.
• a film equipped with an effective antifog composition is transparent even after condensate formation, since the condensate, for example, forms a coherent, transparent film. Without effective antifog composition, the formation of a fine droplet mist on the film surface leads to reduced transparency of the film; in the most unfavorable case, the contents of the tray are no longer visible.
• a further investigation method is what is known as the hot fog test.
• a 250 ml beaker which contains 50 ml of water and over which is stretched the film to be tested is placed in a water bath heated to 70° C. (ambient temperature 23° C.).
• the assessment is the same as described above.
• this test can be used to test the long-term antifog action and the washout stability of the film, since the vapor condenses constantly on the film and runs off or drips off again. Readily soluble substances are thus washed out and the antifog action declines.
• the measurement on the coated polyester films is effected on the Hazegard Hazemeter XL-211 from BYK Gardner based on ASTM-D 1033-77 for transparency and on ASTM-D 1003-61 for opacity.
• This coating solution was applied to polyester film by the following process:
• a melt was produced from polyethylene terephthalate and was extruded through a slot die onto a casting roll kept at about 20° C., where it solidified to give an unoriented film.
• the unoriented film was stretched longitudinally in a stretching ratio of 3.8:1, in the course of which it was kept at a temperature of 115° C.
• the longitudinally stretched film was corona-treated in a corona discharge unit and then coated by reverse gravure coating with the above-described solution of polyvinylpyrrolidone and diethylhexyl sulfosuccinate sodium salt.
• the longitudinally stretched, corona-treated film was dried at a temperature of 100° C.
• the film was then stretched transversely in a stretching ratio of 3.8:1, so as to obtain a biaxially stretched film.
• the biaxially stretched film was heat-set at 230° C.
• the end film thickness was 25 ⁇ m.
• the dry weight of the coating was approx. 0.04 g/m 2 .
• the film exhibited very good antifog properties, i.e. the formation of fine droplets was not observed; at the same time, the washout resistance of the coating was good.
• the transparency and the opacity of the film remained unchanged in the antifog test.
• the dry weight of the coating was approx. 0.04 g/m 2 at a thickness of the carrier film of approx. 50 ⁇ m.
• this film also exhibited very good antifog properties; at the same time, the washout resistance of the coating was improved, i.e. the antifog properties were retained even after several hours of treatment with steam. The transparency and the opacity of the film remained unchanged in the antifog test.
• the dry weight of the coating was approx. 0.06 g/m 2 at a thickness of the carrier film of approx. 12 ⁇ m.
• the film exhibited very good antifog properties; at the same time, the washout resistance of the coating was very good. The transparency and the opacity of the film remained unchanged in the antifog test.
• the film exhibited a high degree of droplet formation, i.e. the film did not have an antifog effect.

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• 2004
  • 2004-10-12 DE DE200410049609 patent/DE102004049609A1/de not_active Withdrawn
• 2005
  • 2005-10-04 US US11/243,373 patent/US7384684B2/en not_active Expired - Fee Related
  • 2005-10-05 DE DE200550006519 patent/DE502005006519D1/de active Active
  • 2005-10-05 EP EP20050021685 patent/EP1647568B1/de active Active
  • 2005-10-11 JP JP2005296100A patent/JP2006131901A/ja active Pending
  • 2005-10-12 KR KR1020050096086A patent/KR20060052231A/ko not_active Application Discontinuation

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