US5439641A - Undecylenate deodorization of paper mill effluents - Google Patents

Undecylenate deodorization of paper mill effluents Download PDF

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Publication number
US5439641A
US5439641A US08/098,105 US9810593A US5439641A US 5439641 A US5439641 A US 5439641A US 9810593 A US9810593 A US 9810593A US 5439641 A US5439641 A US 5439641A
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US
United States
Prior art keywords
undecylenate
deodorant
ester
paper mill
undecylenic acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
US08/098,105
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English (en)
Inventor
Henri-Jean Caupin
Aim Menassa
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Delta Agro Industries
Arkema France SA
Original Assignee
Delta Agro Industries
Elf Atochem SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Delta Agro Industries, Elf Atochem SA filed Critical Delta Agro Industries
Assigned to ELF ATOCHEM S.A., DELTA AGRO INDUSTRIES reassignment ELF ATOCHEM S.A. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: CAUPIN, HENRI-JEAN, MENASSA, AIME
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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00—Disinfection, sterilisation or deodorisation of air
    • A61L9/01—Deodorant compositions
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S210/00—Liquid purification or separation
    • Y10S210/902—Materials removed
    • Y10S210/916—Odor, e.g. including control or abatement

Definitions

  • the present invention relates to the deodorization of paper mill effluents, and, more especially, to the deodorization of paper mill effluents by treating same with an effective deodorizing amount of an alkyl/polyoxyalkylene ester of undecylenic acid.
  • Paper mills are prime sources of malodorous pollutants, originating in the effluents therefrom.
  • a major object of the present invention is the provision of a unique deodorant for paper mill effluents, said deodorant comprising an alkyl ester of undecylenic acid, or a polyoxyalkylene ester of undecylenic acid containing from 2 to 10 alkylene oxide recurring structural units.
  • FIGS. 1 to 4 are graphs plotting the percentage of undecylate ester in the treated effluent versus the extent of olfactory perception of objectionable smells.
  • especially effective undecylenate deodorants are the C 1 -C 12 alkyl esters and the polyoxyethylene, polyoxypropylene and poly(oxyethylene)/(oxypropylene) esters of undecylenic acid.
  • the undecylenate absorbants/deodorants according to the invention can be used either alone or in admixture, and such undecylenate deodorant(s) can be used as such, or in solution or suspension form, or can even be adsorbed onto a support such as, for example, clay particles.
  • the undecylenic esters are effective at a very low dose, for example on the order of 0.01% to 5% with respect to the weight of the effluent to be treated.
  • fermentation products which may or may not contain sulfur, of cellulose and of starch;
  • the abscissa represents the degree of incorporation of the undecylenic ester (% by weight), the ordinate representing the degree of olfactory perception of the objectionable smell, the values 1 to 6 connoting, respectively: none, very weak, weak, average, strong and very strong.
  • the upper curve corresponds to the smell of the effluent itself
  • the lower curve optionally present, corresponding to the smell of the ester.
  • the curves of FIGS. 1 to 3, in accordance with the invention, indicate that the reduction in the perception of the smell of the effluent is not appreciably replaced by the perception of the smell associated with the ester itself.
  • FIG. 4 indicates that, with a polyoxyethylene ester of undecylenic acid containing 12 ethylene oxide recurring structural units, no reduction in the perception of the objectionable smell of the effluent is observed.
  • Curves 1 to 3 correspond, respectively, to methyl undecylenate, to the polyoxyethylene ester of undecylenic acid containing 8 ethylene oxide recurring structural units and to the ester of this same acid containing 10 ethylene oxide recurring structural units.

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Epidemiology (AREA)
  • Animal Behavior & Ethology (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Veterinary Medicine (AREA)
  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
  • Paper (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Treatment Of Water By Oxidation Or Reduction (AREA)
US08/098,105 1992-07-30 1993-07-28 Undecylenate deodorization of paper mill effluents Expired - Fee Related US5439641A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR929209457A FR2694197B1 (fr) 1992-07-30 1992-07-30 Désodorisant des effluents de papeterie à base d'ester d'acide undécylénique.
FR9209457 1992-07-30

Publications (1)

Publication Number Publication Date
US5439641A true US5439641A (en) 1995-08-08

Family

ID=9432457

Family Applications (1)

Application Number Title Priority Date Filing Date
US08/098,105 Expired - Fee Related US5439641A (en) 1992-07-30 1993-07-28 Undecylenate deodorization of paper mill effluents

Country Status (16)

Country Link
US (1) US5439641A (ko)
JP (1) JPH0741234B2 (ko)
KR (1) KR940005292A (ko)
CN (1) CN1085806A (ko)
BR (1) BR9303003A (ko)
CA (1) CA2101578C (ko)
DE (1) DE4324979A1 (ko)
DK (1) DK88193A (ko)
ES (1) ES2103220B1 (ko)
FI (1) FI933395A (ko)
FR (1) FR2694197B1 (ko)
GB (1) GB2269587A (ko)
IT (1) IT1260947B (ko)
NL (1) NL9301173A (ko)
NO (1) NO301492B1 (ko)
SE (1) SE9302528L (ko)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5976460A (en) * 1995-12-26 1999-11-02 Elf Atochem S.A. Use of a deodorizer based on undecylenic acid or on derivatives of the said acid to deodorize papers, cardboards and nonwovens
US6495097B1 (en) 1999-03-02 2002-12-17 Shaw Mildge & Company Fragrance and flavor compositions containing odor neutralizing agents
US20110124920A1 (en) * 2008-07-15 2011-05-26 Basf Se Process to purify dialkyl sulfides
FR3106980A1 (fr) 2020-02-10 2021-08-13 Jafer Enterprises R&D Sl Composition désodorisante renfermant du 1,8-para-menthènethiol, de l'acétate de 3-mercaptohexyle et de l'acide undécylénique ou ses dérivés

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5681176A (en) * 1994-12-05 1997-10-28 Nec Corporation Hinge connector suitable for use in a hinge portion included in an electronic device
FR2735703B1 (fr) * 1995-06-22 1997-08-01 Atochem Elf Sa Procede de traitement des rejets gazeux issus du procede kraft a l'aide de derives de l'acide undecylenique et/ou undecynoique
JPH09166298A (ja) * 1995-12-15 1997-06-24 Asahi Technos:Kk ガス容器の接続装置
FR2814461B1 (fr) * 2000-09-22 2003-05-23 Ahlstrom Paper Group Res And C Composition semi-solide destinee a etre utilisee comme produit d'epandage et procede de fabrication

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3091511A (en) * 1961-10-09 1963-05-28 Pharmaceutical Food & Drugs As Process of deodorizing
US3953377A (en) * 1970-12-22 1976-04-27 Firmenich S.A. Ethyl-2-trans-4-cis undecadienoate, ethyl-2-trans-4-cis dodecadienoate and ethyl-2-decadienoate perfume compositions
US3989498A (en) * 1975-06-23 1976-11-02 H. Gordon Walker Method of odor control
US4938416A (en) * 1989-05-16 1990-07-03 Consoldiated Ceramic Products, Inc. Method of delivering a water-based room air freshener

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4517919A (en) * 1983-11-01 1985-05-21 The Procter & Gamble Company Animal litter composition
FR2655856A1 (fr) * 1989-12-19 1991-06-21 Delta Agro Ind Desodorisant des boues des stations d'epuration a base d'ester d'acide undecylenique.
FR2655857B1 (fr) * 1989-12-19 1992-03-27 Delta Agro Ind Desodorisant des lisiers au moyen d'ester d'acide undecylenique.
FR2655819B1 (fr) * 1989-12-19 1992-03-27 Delta Agro Ind Desodorisant des aliments pour animaux a base d'ester d'acide undecylenique.

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3091511A (en) * 1961-10-09 1963-05-28 Pharmaceutical Food & Drugs As Process of deodorizing
US3953377A (en) * 1970-12-22 1976-04-27 Firmenich S.A. Ethyl-2-trans-4-cis undecadienoate, ethyl-2-trans-4-cis dodecadienoate and ethyl-2-decadienoate perfume compositions
US3989498A (en) * 1975-06-23 1976-11-02 H. Gordon Walker Method of odor control
US4938416A (en) * 1989-05-16 1990-07-03 Consoldiated Ceramic Products, Inc. Method of delivering a water-based room air freshener

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
Price et al., "Sewage Treatment Plants Combat Odor Pollution Problems" Water & Sewage Works, Oct. 1978, pp. 64-69.
Price et al., Sewage Treatment Plants Combat Odor Pollution Problems Water & Sewage Works, Oct. 1978, pp. 64 69. *

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5976460A (en) * 1995-12-26 1999-11-02 Elf Atochem S.A. Use of a deodorizer based on undecylenic acid or on derivatives of the said acid to deodorize papers, cardboards and nonwovens
US6495097B1 (en) 1999-03-02 2002-12-17 Shaw Mildge & Company Fragrance and flavor compositions containing odor neutralizing agents
US20110124920A1 (en) * 2008-07-15 2011-05-26 Basf Se Process to purify dialkyl sulfides
US8586796B2 (en) 2008-07-15 2013-11-19 Basf Se Process to purify dialkyl sulfides
US9073831B2 (en) 2008-07-15 2015-07-07 Basf Se Process to purify dialkyl sulfides
FR3106980A1 (fr) 2020-02-10 2021-08-13 Jafer Enterprises R&D Sl Composition désodorisante renfermant du 1,8-para-menthènethiol, de l'acétate de 3-mercaptohexyle et de l'acide undécylénique ou ses dérivés
WO2021160613A1 (fr) 2020-02-10 2021-08-19 Jafer Enterprises R&D Sl Composition desodorisante renfermant du 1,8-para-menthenethiol, de l'acetate de 3-mercaptohexyle et de l'acide undecylenique ou ses derives

Also Published As

Publication number Publication date
GB2269587A (en) 1994-02-16
NO932608L (no) 1994-01-31
DK88193A (da) 1994-01-31
GB9315811D0 (en) 1993-09-15
KR940005292A (ko) 1994-03-21
CA2101578A1 (fr) 1994-01-31
FI933395A (fi) 1994-01-31
IT1260947B (it) 1996-04-29
NL9301173A (nl) 1994-02-16
FR2694197A1 (fr) 1994-02-04
ITTO930570A1 (it) 1995-01-29
ES2103220B1 (es) 1998-04-01
ES2103220A1 (es) 1997-09-01
ITTO930570A0 (it) 1993-07-29
FI933395A0 (fi) 1993-07-29
SE9302528D0 (sv) 1993-07-29
DK88193D0 (da) 1993-07-28
DE4324979A1 (de) 1994-02-03
CA2101578C (fr) 1999-01-12
JPH0741234B2 (ja) 1995-05-10
BR9303003A (pt) 1994-03-15
FR2694197B1 (fr) 1994-09-02
SE9302528L (sv) 1994-01-31
CN1085806A (zh) 1994-04-27
NO301492B1 (no) 1997-11-03
NO932608D0 (no) 1993-07-19
JPH06254532A (ja) 1994-09-13

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Owner name: ELF ATOCHEM S.A., FRANCE

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:CAUPIN, HENRI-JEAN;MENASSA, AIME;REEL/FRAME:006731/0404;SIGNING DATES FROM 19930902 TO 19930914

Owner name: DELTA AGRO INDUSTRIES, FRANCE

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:CAUPIN, HENRI-JEAN;MENASSA, AIME;REEL/FRAME:006731/0404;SIGNING DATES FROM 19930902 TO 19930914

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Free format text: PATENT EXPIRED DUE TO NONPAYMENT OF MAINTENANCE FEES UNDER 37 CFR 1.362