US20190136336A1 - High-magnetic-induction low-iron-loss non-oriented silicon steel sheet and manufacturing method therfor - Google Patents

High-magnetic-induction low-iron-loss non-oriented silicon steel sheet and manufacturing method therfor Download PDF

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US20190136336A1
US20190136336A1 US16/304,377 US201716304377A US2019136336A1 US 20190136336 A1 US20190136336 A1 US 20190136336A1 US 201716304377 A US201716304377 A US 201716304377A US 2019136336 A1 US2019136336 A1 US 2019136336A1
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steel sheet
silicon steel
oriented silicon
magnetic
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Feng Zhang
Xianshi Fang
Shishu Xie
Zhenyu Zong
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Baoshan Iron and Steel Co Ltd
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    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/12—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties
    • C21D8/1244—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties the heat treatment(s) being of interest
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/16—Controlling or regulating processes or operations
    • B22D11/22—Controlling or regulating processes or operations for cooling cast stock or mould
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/12—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/12—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties
    • C21D8/1216—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties the working step(s) being of interest
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/12—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties
    • C21D8/1244—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties the heat treatment(s) being of interest
    • C21D8/1272—Final recrystallisation annealing
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/46—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/001—Ferrous alloys, e.g. steel alloys containing N
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/004—Very low carbon steels, i.e. having a carbon content of less than 0,01%
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/12—Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/14—Ferrous alloys, e.g. steel alloys containing titanium or zirconium
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
    • H01F1/00—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties
    • H01F1/01—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials
    • H01F1/03—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity
    • H01F1/12—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials
    • H01F1/14—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials metals or alloys
    • H01F1/16—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials metals or alloys in the form of sheets
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/12—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties
    • C21D8/1205—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties involving a particular fabrication or treatment of ingot or slab
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/12—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties
    • C21D8/1216—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties the working step(s) being of interest
    • C21D8/1222—Hot rolling
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/12—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties
    • C21D8/1216—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties the working step(s) being of interest
    • C21D8/1233—Cold rolling

Definitions

  • the invention relates to a non-oriented silicon steel sheet. Specifically, the invention relates to a high-magnetic-induction low-iron-loss non-oriented silicon steel sheet and a manufacturing method therefor. Particularly, the invention relates to a high-magnetic-induction low-iron-loss non-oriented silicon steel sheet, which is obtained without normalization treatment or intermediate annealing in a bell furnace and has a relatively low manufacturing cost, and a manufacturing method therefor.
  • non-oriented silicon steel sheets for manufacturing of electric motors, compressors and EI iron core materials are required to have excellent electromagnetic properties (i.e. so-called low iron loss and high magnetic induction) under the premise of ensuring a competitive advantage in price, so as to meet the urgent needs of these electric products for high efficiency, energy saving and environmental protection.
  • the addition of high contents of Si and Al to steels can increase the electrical resistivity of the material, thereby reducing the iron loss of the material.
  • the Si content is 2.5% to 4.0%
  • the Al content is 0.5% to 1.5%.
  • the iron loss of the material rapidly decreases as the contents of Si and Al increase, the magnetic induction of the material however rapidly decreases and abnormal situations such as cold-rolled strip breakage are likely to occur.
  • CN 104399749 A discloses a method for preventing edge cracking and brittle fracture of a steel having a Si content of 3.5% or more, which improves the magnetic properties of the silicon steel sheet while preventing the steel sheet from edge cracking during a cold rolling process.
  • the rejection rate of brittle fracture is still 0.15% and the requirement on functional accuracy of the device is high in the above method.
  • 0.20% to 0.45% (Sn+Cu) was added to the steel and the texture morphology of the material was improved by grain-boundary segregation, thereby obtaining a good magnetic induction.
  • Sn and Cu are expensive metals that greatly increase the manufacturing cost, and Cu is likely to cause quality defects on the surface of the strip.
  • the magnetic induction of the material is improved by increasing the ratio of Al/(Si+Al) under the premise that the total amount of Si and Al remains unchanged.
  • the iron loss of the material deteriorates and the mechanical properties of the material decrease.
  • normalization treatment or intermediate annealing in a bell furnace is an effective method to improve the iron loss and magnetic induction of the material and is widely used in the production of high-efficiency, high-grade non-oriented silicon steel sheets, which effectively reduces the iron loss of the material and greatly increases the magnetic induction of the material.
  • it introduces new production equipment, which greatly increases the manufacturing cost and extends the manufacturing and delivery cycle of the material, thereby bringing new troubles to the technical and quality managements in the production field.
  • the object of the invention is to provide a high-magnetic-induction low-iron-loss non-oriented silicon steel sheet and a manufacturing method therefor.
  • the non-oriented silicon steel sheet has high magnetic induction and low iron loss, with no noble metal contained in its chemical composition. Also, the manufacturing process of the non-oriented silicon steel sheet does not require normalization treatment or intermediate annealing in a bell furnace, and has a relatively low manufacturing cost and stable production process.
  • a high-magnetic-induction low-iron-loss non-oriented silicon steel sheet wherein chemical composition thereof by mass percentages is: C ⁇ 0.005%, Si: 0.1% ⁇ 1.6%, Mn: 0.1% ⁇ 0.5%, P ⁇ 0.2%, S ⁇ 0.004%, Al ⁇ 0.003%, N ⁇ 0.005%, Nb ⁇ 0.004%, V ⁇ 0.004% and Ti ⁇ 0.003%, with the balance being Fe and inevitable impurities; and the above elements satisfy the following relationship at the same time: 120 ⁇ [Mn]/[S] ⁇ 160, and [Nb]/93+[V]/51+[Ti]/48+[Al]/27 ⁇ [C]/12+[N]/14.
  • non-oriented silicon steel sheet has the following electromagnetic properties:
  • Si content is 1.2% ⁇ Si ⁇ 1.60%, corresponding to a steel grade of D-grade, magnetic induction B 50 ⁇ 1.70 T, iron loss P 15/50 ⁇ 4.00 W/kg.
  • C strongly hinders the growth of the grains of the finished product and easily forms fine precipitates in combination with Nb, V, Ti, etc., thereby causing an increase in loss and generation of magnetic aging. Therefore, the C content must be strictly controlled to 0.005% or less.
  • Si can increase the electrical resistivity of matrix and effectively reduce the iron loss of the steel.
  • the Si content of the present invention is controlled to 0.1% to 1.6%.
  • Mn combines with S to form MnS, which effectively reduces its adverse effects on magnetic properties while improves the surface state of electrical steel and reduces hot brittleness. Therefore, it is necessary to add a Mn content of 0.1% or more. However, a Mn content of more than 0.5% or more easily breaks the recrystallization texture and greatly increases the manufacturing cost of the steel. Therefore, the Mn content of the present invention is controlled to 0.1% to 0.5%.
  • the P content of the present invention is controlled to 0.2% or less.
  • the S content of the present invention is controlled to 0.004% or less.
  • Al is an element that increases resistance and is used for deep deoxidation of electrical steel.
  • the Al content of the present invention is controlled to 0.003% or less.
  • N when the N content is more than 0.005%, the precipitates formed by N and Nb, V, Ti, Al, and etc. are greatly increased, which strongly inhibits the growth of grains and deteriorates the magnetic properties of the steel. Therefore, the N content of the present invention is controlled to 0.005% or less.
  • Nb when the Nb content is more than 0.004%, C and N inclusions of Nb are greatly increased, which strongly inhibits the growth of grains and deteriorates the magnetic properties of the steel. Therefore, the Nb content of the present invention is controlled to 0.004% or less.
  • V when the V content is more than 0.004%, C and N inclusions of V are greatly increased, which strongly inhibits the growth of grains and deteriorates the magnetic properties of the steel. Therefore, the V content of the present invention is controlled to 0.004% or less.
  • Ti when the Ti content is more than 0.003%, C and N inclusions of Ti are greatly increased, which strongly inhibits the growth of grains and deteriorates the magnetic properties of the steel. Therefore, the Ti content of the present invention is controlled to 0.003% or less.
  • a manufacturing method for the high-magnetic-induction low-iron-loss non-oriented silicon steel sheet according to the present invention comprising the following steps:
  • the charging temperature of the casting slab in step 2) is 300° C. or less.
  • non-oriented silicon steel sheet obtained in the present invention has the following electromagnetic properties:
  • Si content is 1.2% ⁇ Si ⁇ 1.60%, corresponding to a steel grade of D-grade, magnetic induction B 50 ⁇ 1.70 T, iron loss P 15/50 ⁇ 4.00 W/kg.
  • MnS inclusions have great influences on the electromagnetic properties of finished materials due to their small size and large number.
  • strong deoxidizing elements or desulfurizing elements such as rare earth and calcium are added.
  • FIG. 1 shows the relationship between [Mn]/[S] and magnetic induction B 50 . As can be seen from FIG. 1 , as [Mn]/[S] increases, the magnetic induction B 50 first rises and then decreases rapidly.
  • the magnetic induction B 50 is optimal.
  • the invention controls [Mn]/[S] between 120 and 160 to ensure that MnS inclusions are precipitated as early as possible in the initial stage of solidification of liquid steel, which can provide temperature and time conditions for subsequent sufficient growth of MnS inclusions.
  • the influence of MnS inclusions of 0.5 ⁇ m or more on the electromagnetic properties of the finished material is significantly weakened.
  • the present invention also strictly limits the temperature of the slab before charging the casting slab in the heating furnace, specifically, controlling the charging temperature of the casting slab to 600° C. or less, preferably to 300° C. or less, in order to use a lower casting slab temperature to further promote the growth of MnS during the heating process of the casting slab.
  • the magnetic induction B 50 decreases rapidly as the charging temperature of the casting slab increases.
  • the charging temperature is 600° C. or more, the magnetic induction B 50 remains at a low level. Therefore, from the viewpoint of practical production control, the charging temperature of the casting slab is kept at 600° C. or less, or an even lower level is preferable, preferably 300° C. or less.
  • the MnS inclusions formed by Mn and S elements can grow larger under the regulation of the above method, that is, the influence of MnS inclusions can be eliminated or attenuated.
  • Nb, V, Ti, and Al combine with C or N elements to form nanoscale Nb, V, Ti, Al carbon inclusions or nitrogen inclusions, the size of these inclusions is finer and mainly precipitates on the grain boundaries, which seriously impairs the electromagnetic properties of the finished material. Therefore, it is necessary to limit its precipitation as much as possible, that is, the precipitation time should be postponed and the amount of precipitation should be reduced.
  • composition design of the present invention it is necessary to control the Nb, V, Ti, and Al contents within a suitable range and reduce them as much as possible, and control that [Nb]/93+[V]/51+[Ti]/48+[Al]/27 ⁇ [C]/12+[N]/14; on the other hand, in the refining process, controlling C, T, O and OB (oxygen blowing), vacuum degree and other conventional means can be used to achieve ultra-low C and N content.
  • the concentration product of C or N compounds formed by the combination of Nb, V, Ti, or Al element and C or N elements is greatly reduced, being equal to or below the equilibrium concentration product of precipitation, so that the amount of C or N compound formed by the combination of Nb, V, Ti, or Al element and C or N element is greatly reduced.
  • the cooling rate should be limited to 2.5 ⁇ 20° C./min.
  • the cooling rate of the casting slab in the temperature range is increased as much as possible to reduce the residence time in the temperature range.
  • the precipitates are mainly sulfide precipitates, and the precipitates have a large size ( ⁇ 0.5 ⁇ m) and therefore have little influence on the magnetic properties of the finished product.
  • an excessive cooling rate requires high equipment performance, so it is generally difficult to reach a cooling rate of above 20° C./min.
  • a cooling rate exceeding 20° C./min has an adverse effect on the low-magnification quality of the casting slab.
  • the precipitates are mainly nitride precipitates, having a small size ( ⁇ 0.5 ⁇ m) and therefore the magnetic properties of the finished product are affected.
  • the purpose of controlling the [Mn]/[S] between 120 ⁇ 160 and [Nb]/93+[V]/51+[Ti]/48+[Al]/27 ⁇ [C]/12+[N]/14 in the chemical composition of the present invention is to strictly control the sulfides and nitrides which are harmful to magnetic properties.
  • the cooling rate during the cooling process in which the surface temperature of the casting slab is reduced from 1100° C. to 700° C. is controlled to 2.5 ⁇ 20° C./min; and the charging temperature when heating the casting slab is controlled to 600° C. or less, which is based on the metallurgical principle and is optimized by the “formation mechanism” of the precipitate rather than the conventional “control mechanism”.
  • the invention optimizes the chemical composition design and obtains a suitable Mn/S ratio by adjusting the manganese and sulfur contents. After the smelting, the Nb, V, Ti, and Al contents are controlled and meet the design requirements. In the casting process, the cooling rate during the cooling process in which the surface temperature of the casting slab is reduced from 1100° C. to 700° C. is controlled. After the casting of the liquid steel, the charging temperature of the casting slab is adjusted by temperature controlling method. The obtained non-oriented silicon steel sheet has high magnetic induction and low iron loss. The present invention effectively realizes the stable production of high-magnetic-induction low-iron-loss non-oriented silicon steel sheets.
  • the manufacturing process of the present invention does not require normalization treatment or intermediate annealing in a bell furnace, and has the characteristics of low cost, simple operation, easy realization and low production difficulty. At the same time, the manufacturing process is stable, and the produced finished silicon steel sheet has excellent electromagnetic performances.
  • FIG. 1 shows the relationship between [Mn]/[S] and magnetic induction B 50 of the present invention.
  • FIG. 2 shows the relationship between the charging temperature of the casting slab and the magnetic induction B 50 of the present invention.
  • FIG. 3 is a graph showing the type and size of precipitates when the cooling rate during the cooling process in which the surface temperature of the casting slab is reduced from 1100° C. to 700° C. is controlled to 2.5° C./min.
  • FIG. 4 is a graph showing the type and size of precipitates when the cooling rate during the cooling process in which the surface temperature of the casting slab is reduced from 1100° C. to 700° C. is controlled to 25° C./min.
  • Table 1 shows compositions of silicon steel sheets of Examples and Comparative Examples of the present invention.
  • Table 2 shows the process design and electromagnetic properties of Examples and Comparative Examples of the present invention.
  • liquid iron and steel scrap are proportioned according to the chemical composition ratios in Table 1.
  • decarburization, deoxidation and alloying are carried out by RH refining; the Mn content is dynamically adjusted according to the S content in the steel to obtain the optimum ratio of [Mn]/[S], and the C, N, Nb, V, Ti, and Al contents are controlled to meet the design requirements; after the liquid steel is cast by continuous casting, a casting slab of 170 mm to 250 mm thick and 800 mm to 1400 mm wide is obtained; after the casting, the cooling rate during the cooling process in which the surface temperature of the casting slab is reduced from 1100° C. to 700° C.
  • the charging temperature of the casting slab is adjusted to 600° C. or less, preferably 300° C. or less by a temperature controlling method; then, the casting slab is sequentially subjected to hot rolling, pickling, cold rolling, annealing and coating to obtain a final product.
  • the process parameters and electromagnetic properties are shown in Table 2.
  • the Si content is in the range of 0.1% to 1.6%.
  • the steel can be divided into four types according to Si contents: a Si content of 0.11% to 0.30%, a Si content of 0.30% to 0.80% (does not comprise 0.30%), a Si content of 0.80% to 1.20% (does not comprise 0.80%), a Si content of 1.20% to 1.60% (does not comprise 1.20%), marked as A-grade, B-grade, C-grade, and D-grade respectively. Steels of the same grade having different Si content will have magnetic properties of the same type.
  • all A-grade steels (Examples 1-3) satisfy electromagnetic properties of a magnetic induction B 50 ⁇ 1.76 T and an iron loss P 15/50 ⁇ 6.50 W/kg; all B-grade steels (Examples 4-6) satisfy electromagnetic properties of a magnetic induction B 50 ⁇ 1.75 T and an iron loss P 15/50 ⁇ 5.40 W/kg; all C-grade steels (Examples 7-9) satisfy electromagnetic properties of a magnetic induction B 50 ⁇ 1.72 T and an iron loss P 15/50 ⁇ 4.00 W/kg; all D-grade steels (Examples 10-11) satisfy the electromagnetic properties of a magnetic induction B 50 ⁇ 1.70 T and an iron loss P 15/50 ⁇ 3.80 W/kg.
  • the non-oriented silicon steel sheet of the present invention has a higher magnetic induction and a lower iron loss.

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US16/304,377 2016-05-30 2017-05-22 High-magnetic-induction low-iron-loss non-oriented silicon steel sheet and manufacturing method therfor Abandoned US20190136336A1 (en)

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CN201610369192.2A CN105925884B (zh) 2016-05-30 2016-05-30 一种高磁感、低铁损无取向硅钢片及其制造方法
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PCT/CN2017/085324 WO2017206753A1 (zh) 2016-05-30 2017-05-22 一种高磁感、低铁损无取向硅钢片及其制造方法

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CN113755750A (zh) * 2021-08-19 2021-12-07 鞍钢股份有限公司 一种含磷高磁感无取向硅钢的生产方法
US12104215B2 (en) 2018-11-26 2024-10-01 Baoshan Iron & Steel Co., Ltd. High-magnetic-induction low-iron-loss non-oriented silicon steel sheet and manufacturing method therefor

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CN105925884B (zh) * 2016-05-30 2018-03-09 宝山钢铁股份有限公司 一种高磁感、低铁损无取向硅钢片及其制造方法
TWI657150B (zh) * 2017-11-09 2019-04-21 中國鋼鐵股份有限公司 極低碳和鈦的含磷電磁鋼及其製造方法
CN110093486B (zh) * 2018-01-31 2021-08-17 宝山钢铁股份有限公司 一种耐消除应力退火的低铁损取向硅钢的制造方法
CN109082596B (zh) * 2018-09-04 2019-12-13 马鞍山钢铁股份有限公司 一种低铁损高磁极化强度的无取向硅钢及其制备方法
CN110029273A (zh) * 2019-04-23 2019-07-19 洛阳中伟环保科技有限公司 一种磨机用无碳合金隔仓板
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CN112430778A (zh) * 2019-08-26 2021-03-02 宝山钢铁股份有限公司 一种薄规格无取向电工钢板及其制造方法
CN112430780B (zh) * 2019-08-26 2022-03-18 宝山钢铁股份有限公司 一种含Cu高洁净度无取向电工钢板及其制造方法
CN113737089B (zh) * 2020-05-29 2022-07-15 宝山钢铁股份有限公司 一种低成本极低铝的无取向电工钢板及其制造方法
CN111793771A (zh) * 2020-06-10 2020-10-20 宝钢湛江钢铁有限公司 一种低铁损低时效高强度50w800无取向硅钢及其制造方法
CN115198169B (zh) * 2021-04-09 2023-07-07 宝山钢铁股份有限公司 一种无瓦楞状缺陷的高磁感低铁损无取向电工钢板及其制造方法
CN115323283B (zh) * 2022-08-18 2023-08-11 山西太钢不锈钢股份有限公司 一种低合金高强度无取向硅钢及其生产方法
CN115198199A (zh) * 2022-09-14 2022-10-18 张家港扬子江冷轧板有限公司 高强度无取向硅钢生产方法、高强度无取向硅钢及应用

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01139720A (ja) * 1987-11-25 1989-06-01 Kawasaki Steel Corp セミプロセス無方向性電磁鋼板の製造方法
JPH0814015B2 (ja) * 1990-01-16 1996-02-14 日本鋼管株式会社 磁気特性および表面性状の優れた無方向性電磁鋼板およびその製造方法
JP2849279B2 (ja) * 1992-05-29 1999-01-20 川崎製鉄株式会社 被削性の優れたモーター用無方向性電磁鋼板
JPH0790376A (ja) * 1993-06-30 1995-04-04 Nkk Corp 打抜き性に優れた高磁束密度無方向性電磁鋼板の製造方法
JPH07300619A (ja) * 1994-03-07 1995-11-14 Nkk Corp 無方向性電磁鋼板の製造方法
JP3456295B2 (ja) * 1995-03-31 2003-10-14 Ｊｆｅスチール株式会社 無方向性電磁鋼板用鋼の溶製方法
JPH09263909A (ja) * 1996-03-26 1997-10-07 Nkk Corp 鉄損特性の優れた無方向性電磁鋼板
JP2000219917A (ja) * 1999-01-28 2000-08-08 Nippon Steel Corp 磁束密度が高く鉄損の低い無方向性電磁鋼板の製造法
US20040149355A1 (en) * 2001-06-28 2004-08-05 Masaaki Kohno Nonoriented electromagnetic steel sheet
JP4718749B2 (ja) * 2002-08-06 2011-07-06 Ｊｆｅスチール株式会社 回転機用高磁束密度無方向性電磁鋼板及び回転機用部材
RU2398894C1 (ru) * 2006-06-16 2010-09-10 Ниппон Стил Корпорейшн Лист высокопрочной электротехнической стали и способ его производства
CN102373366A (zh) * 2010-08-26 2012-03-14 宝山钢铁股份有限公司 一种改善无取向硅钢表面粗晶的方法
CN102453837B (zh) * 2010-10-25 2013-07-17 宝山钢铁股份有限公司 一种高磁感无取向硅钢的制造方法
JP5668460B2 (ja) * 2010-12-22 2015-02-12 Ｊｆｅスチール株式会社 無方向性電磁鋼板の製造方法
CN103361544B (zh) * 2012-03-26 2015-09-23 宝山钢铁股份有限公司 无取向硅钢及其制造方法
CN104404396B (zh) * 2014-11-24 2017-02-08 武汉钢铁(集团)公司 一种无需常化的高磁感无取向硅钢及用薄板坯生产方法
CN105925884B (zh) * 2016-05-30 2018-03-09 宝山钢铁股份有限公司 一种高磁感、低铁损无取向硅钢片及其制造方法

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US12104215B2 (en) 2018-11-26 2024-10-01 Baoshan Iron & Steel Co., Ltd. High-magnetic-induction low-iron-loss non-oriented silicon steel sheet and manufacturing method therefor
CN113755750A (zh) * 2021-08-19 2021-12-07 鞍钢股份有限公司 一种含磷高磁感无取向硅钢的生产方法

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