US20180148214A1 - Package, and methods for producing and for using self-adhesive - Google Patents

Package, and methods for producing and for using self-adhesive Download PDF

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Publication number
US20180148214A1
US20180148214A1 US15/574,845 US201615574845A US2018148214A1 US 20180148214 A1 US20180148214 A1 US 20180148214A1 US 201615574845 A US201615574845 A US 201615574845A US 2018148214 A1 US2018148214 A1 US 2018148214A1
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US
United States
Prior art keywords
package
self
adhesive
meth
acrylic acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US15/574,845
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English (en)
Inventor
Mitsunori Abe
Atsushi Sone
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zeon Corp
Original Assignee
Zeon Corp
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Filing date
Publication date
Application filed by Zeon Corp filed Critical Zeon Corp
Assigned to ZEON CORPORATION reassignment ZEON CORPORATION ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: ABE, MITSUNORI, SONE, ATSUSHI
Publication of US20180148214A1 publication Critical patent/US20180148214A1/en
Abandoned legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D5/00—Rigid or semi-rigid containers of polygonal cross-section, e.g. boxes, cartons or trays, formed by folding or erecting one or more blanks made of paper
    • B65D5/02—Rigid or semi-rigid containers of polygonal cross-section, e.g. boxes, cartons or trays, formed by folding or erecting one or more blanks made of paper by folding or erecting a single blank to form a tubular body with or without subsequent folding operations, or the addition of separate elements, to close the ends of the body
    • B65D5/0227—Rigid or semi-rigid containers of polygonal cross-section, e.g. boxes, cartons or trays, formed by folding or erecting one or more blanks made of paper by folding or erecting a single blank to form a tubular body with or without subsequent folding operations, or the addition of separate elements, to close the ends of the body with end closures formed by inward folding of flaps and securing them by heat-sealing, by applying adhesive to the flaps or by staples
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D33/00—Details of, or accessories for, sacks or bags
    • B65D33/16—End- or aperture-closing arrangements or devices
    • B65D33/18—End- or aperture-closing arrangements or devices using adhesive applied to integral parts, e.g. to flaps
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D33/00—Details of, or accessories for, sacks or bags
    • B65D33/16—End- or aperture-closing arrangements or devices
    • B65D33/18—End- or aperture-closing arrangements or devices using adhesive applied to integral parts, e.g. to flaps
    • B65D33/20—End- or aperture-closing arrangements or devices using adhesive applied to integral parts, e.g. to flaps using pressure-sensitive adhesive
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D5/00—Rigid or semi-rigid containers of polygonal cross-section, e.g. boxes, cartons or trays, formed by folding or erecting one or more blanks made of paper
    • B65D5/38—Drawer-and-shell type containers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D5/00—Rigid or semi-rigid containers of polygonal cross-section, e.g. boxes, cartons or trays, formed by folding or erecting one or more blanks made of paper
    • B65D5/42—Details of containers or of foldable or erectable container blanks
    • B65D5/64—Lids
    • B65D5/66—Hinged lids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D5/00—Rigid or semi-rigid containers of polygonal cross-section, e.g. boxes, cartons or trays, formed by folding or erecting one or more blanks made of paper
    • B65D5/42—Details of containers or of foldable or erectable container blanks
    • B65D5/64—Lids
    • B65D5/66—Hinged lids
    • B65D5/6602—Hinged lids formed by folding one or more extensions hinged to the upper edge of a tubular container body
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D85/00—Containers, packaging elements or packages, specially adapted for particular articles or materials
    • B65D85/07—Containers, packaging elements or packages, specially adapted for particular articles or materials for compressible or flexible articles
    • B65D85/08—Containers, packaging elements or packages, specially adapted for particular articles or materials for compressible or flexible articles rod-shaped or tubular
    • B65D85/10—Containers, packaging elements or packages, specially adapted for particular articles or materials for compressible or flexible articles rod-shaped or tubular for cigarettes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D85/00—Containers, packaging elements or packages, specially adapted for particular articles or materials
    • B65D85/07—Containers, packaging elements or packages, specially adapted for particular articles or materials for compressible or flexible articles
    • B65D85/08—Containers, packaging elements or packages, specially adapted for particular articles or materials for compressible or flexible articles rod-shaped or tubular
    • B65D85/10—Containers, packaging elements or packages, specially adapted for particular articles or materials for compressible or flexible articles rod-shaped or tubular for cigarettes
    • B65D85/1036—Containers formed by erecting a rigid or semi-rigid blank
    • B65D85/1045—Containers formed by erecting a rigid or semi-rigid blank having a cap-like lid hinged to an edge
    • B65D85/1056—Containers formed by erecting a rigid or semi-rigid blank having a cap-like lid hinged to an edge characterized by the lid
    • B65D85/10564—Containers formed by erecting a rigid or semi-rigid blank having a cap-like lid hinged to an edge characterized by the lid having means for holding the lid in a closed position
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D85/00—Containers, packaging elements or packages, specially adapted for particular articles or materials
    • B65D85/67—Containers, packaging elements or packages, specially adapted for particular articles or materials for web or tape-like material
    • B65D85/671—Containers, packaging elements or packages, specially adapted for particular articles or materials for web or tape-like material wound in flat spiral form
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1802—C2-(meth)acrylate, e.g. ethyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0014—Use of organic additives
    • C08J9/0028—Use of organic additives containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/30—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof by mixing gases into liquid compositions or plastisols, e.g. frothing with air
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
    • C09J133/04—Homopolymers or copolymers of esters
    • C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09J133/08—Homopolymers or copolymers of acrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2201/00—Foams characterised by the foaming process
    • C08J2201/02—Foams characterised by the foaming process characterised by mechanical pre- or post-treatments
    • C08J2201/026—Crosslinking before of after foaming
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2207/00—Foams characterised by their intended use
    • C08J2207/02—Adhesive
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2333/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
    • C08J2333/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2333/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
    • C08J2333/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
    • C08J2333/06—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters of esters containing only carbon, hydrogen, and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C08J2333/08—Homopolymers or copolymers of acrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2333/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
    • C08J2333/24—Homopolymers or copolymers of amides or imides
    • C08J2333/26—Homopolymers or copolymers of acrylamide or methacrylamide
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2433/00—Presence of (meth)acrylic polymer

Definitions

  • the present invention relates to packages that are repeatedly sealable, and methods for producing and for using self-adhesives that are to be arranged in the packages.
  • Such a box usually has a cup-shaped bottomed container having an opening, and a cup-shaped upper lid that is hinged to an upper edge portion (usually one side of the rectangular opening) of the bottomed container (hereinafter such a lid may be referred to as “hinged lid”).
  • the box is openable and closable by rotating the hinged lid around the upper edge portion.
  • each predetermined number of sweets that came out of a producing machine is packaged and sealed up in a composite film of an aluminized resin film or the like, to be put into a box made of paper.
  • Patent Literature 1 discloses a box defined by a cup-shaped container, a cup-shaped lid, and a collar that protrudes outward from an opening end of the cup-shaped container, wherein the cup-shaped lid has a front wall including an inside strengthened tab, part of the front wall is adhered to part of the collar, and the box is opened by breaking the part of the front wall or the part of the collar.
  • Patent Literature 1 relates to techniques of sealing a package having a hinged lid before opening the package. Opening the package is accompanied with breakage of a member. Thus, the package cannot be sealed again after opened.
  • An object of the present invention is to provide a package that is repeatedly sealable after the package is opened first time, and methods for producing and for using a self-adhesive that is used for the package.
  • a first aspect of the present invention is a package comprising: a space to store contents; and an opening by which the space and an outside communicate, wherein the opening is repeatedly openable and sealable by a self-adhesive (E) that consists of a cross-linking material of a resin composition (C) containing a (meth)acrylic acid ester copolymer resin (A), and a crosslinking agent (B).
  • E self-adhesive
  • (meth)acrylic means “acrylic and/or methacrylic”.
  • a cross-linking material of a resin composition (C) means that an intramolecular or intermolecular crosslinked structure forms at least in (meth)acrylic acid ester copolymer in the resin composition (C).
  • the package according to the first aspect of the present invention may comprise: a package body that has the space to store the contents, the package body being formed with the opening; and a lid with which the opening of the package body can be covered, wherein each of the package body and the lid may have a contact portion where the package body and the lid are in contact with each other in a position of the package being closed, and the self-adhesive (E) may be arranged on at least part of the contact portion.
  • a glass transition temperature of the (meth)acrylic acid ester copolymer resin (A) is no more than ⁇ 10° C.
  • the (meth)acrylic acid ester copolymer resin (A) has a N-methylol group, and gel fraction of no more than 70%.
  • the resin composition (C) is a resin composition foam (D) that is foamed.
  • the resin composition (C) contains 0.1 to 20 parts by mass of a carbodiimide crosslinking agent (B 1 ), to 100 parts by mass of the (meth)acrylic acid ester copolymer resin (A).
  • the package is made of paper.
  • a second aspect of the present invention is a method for producing the self-adhesive (E) to be arranged on the package according to the first aspect of the present invention, the method comprising: making the resin composition (C) that contains the (meth)acrylic acid ester copolymer resin (A), and the crosslinking agent (B); and cross-linking the resin composition (C); or a method for producing the self-adhesive (E) to be arranged on the package according to the first aspect of the present invention, the method comprising: making the resin composition (C) that contains the (meth)acrylic acid ester copolymer resin (A), and the crosslinking agent (B); foaming the resin composition (C), to make the resin composition foam (D); and cross-linking the resin composition foam (D).
  • said cross-linking is carried out on a surface of the package.
  • a third aspect of the present invention is a method for using a self-adhesive (E) for adhesion in a package in order to seal an opening, the package comprising: a space to store contents; and the opening by which the space and an outside communicate, the opening being repeatedly openable and sealable.
  • E self-adhesive
  • the package may comprise: a package body that has the space to store the contents, the package body being formed with the opening; and a lid with which the opening of the package body can be covered, and the adhesion may be at a contact portion of the package body and the lid.
  • the self-adhesive (E) is a foam.
  • a package that is repeatedly sealable after the package is opened first time, and methods for producing and for using a self-adhesive that is used for the package.
  • FIG. 1A is a perspective view showing a position of a package 10 being opened
  • FIG. 1B is a perspective view showing a position of the package 10 being closed.
  • FIGS. 2A, 2C and 2D are perspective views showing positions of packages 20 , 30 and 40 being opened respectively, and FIG. 2B is a perspective view showing a position of the package 20 being closed.
  • FIG. 3A is a perspective view showing a position of a package 50 being closed
  • FIG. 3B is a perspective view showing a position of the package 50 being opened.
  • FIGS. 4A and 4B are perspective views showing positions of packages 60 and 70 being opened respectively.
  • FIG. 5A is a perspective view showing a position of a package 80 being closed
  • FIG. 5B is a perspective view showing a position of the package 80 being opened.
  • FIGS. 6A and 6B are perspective views showing positions of packages 90 and 100 being opened respectively.
  • FIGS. 7A to 7E are perspective views showing positions of packages according to other embodiments of the present invention being opened and closed.
  • FIGS. 8A and 8B are perspective views showing positions of packages according to further other embodiments of the present invention being opened and closed.
  • FIG. 9 is an explanatory flowchart of a method for producing a self-adhesive (E) according to one embodiment of the present invention.
  • a package of the present invention is a package comprising: a space to store contents; and an opening by which the space and an outside communicate, wherein the opening is repeatedly openable and sealable by a self-adhesive (E) that consists of a cross-linking material of a resin composition (C) containing a (meth)acrylic acid ester copolymer resin (A), and a crosslinking agent (B).
  • E self-adhesive
  • FIGS. 1A and 1B a package 10 according to one embodiment of the present invention will be described with reference to FIGS. 1A and 1B .
  • FIG. 1A is a perspective view showing a position of the package 10 being opened
  • FIG. 1B is a perspective view showing a position of the package 10 being closed.
  • the package 10 is a bottom seal bag.
  • the package 10 includes a space 1 to store the contents, and an opening 2 by which the space 1 and the outside communicate.
  • a self-adhesive (E) 3 is arranged over an inside face of at least one of portions 10 a and 10 b of the package 10 which face each other and which form the opening 2 .
  • the following are ways of adhesion of the self-adhesive (E): pasting using adhesion of sheet material itself, and adsorbing to an adherend due to sucking effect using microcavities that are formed in a sheet.
  • the self-adhesive (E) can adhere to an adherend by one or both adhering way(s).
  • the self-adhesive (E) is easy to be restuck without any remaining glue.
  • the package 10 can easily take the closed position shown in FIG. 1B by pressing the portions 10 a and 10 b from the outside of the package in the opened position shown in FIG. 1A .
  • the package 10 is sealed by self-adhesion of the self-adhesive (E) 3 to an inside face of one of the portion 10 a or 10 b of the package which the self-adhesive (E) 3 faces when the self-adhesive (E) 3 is arranged over the inside face of the other of the portions 10 a and 10 b , or by self-adhesion of the self-adhesives (E) 3 to each other when the self-adhesives (E) 3 are arranged over the inside faces of both of the portions 10 a and 10 b of the package.
  • the airtightness can be improved again even after the package is opened.
  • a finger or the like is inserted into the package from the top edge of the package 10 , and expands a space over the opening 2 , thereby the self-adhesive (E) 3 is separated from the portion 10 a or 10 b , or the self-adhesives (E) 3 are separated from each other, and the package can be easily opened.
  • self-adhesion of the self-adhesive (E) 3 is not damaged.
  • the package 10 can be repeatedly sealed and opened.
  • the embodiment of self-adhesion of the self-adhesives (E) 3 to each other can be especially preferably employed when the package 10 is constituted by material to which the self-adhesive (E) 3 is hard to self-adhere.
  • FIG. 2A shows a position of the package 20 being opened viewed from the same point as FIG. 1A .
  • FIG. 2B shows a position of the package 20 being closed viewed from the same point as FIG. 1B .
  • the package 20 is an envelope.
  • the package 20 includes a space 11 to store the contents, a package body 4 that is formed with an opening 12 , and a lid 5 with which the opening 12 of the package body 4 can be covered.
  • the package body 4 and the lid 5 connect along an upper edge 6 of the package body 4 .
  • the lid 5 is a hinged lid.
  • each of the package body 4 and the lid 5 has a contact portion where they are in contact with each other in the position of the package 20 being closed.
  • a self-adhesive (E) 13 is arranged on at least part of the contact portion.
  • the self-adhesive (E) 13 is adhered and fixed to the package body 4 in the package 20 .
  • the self-adhesive (E) 13 self-adheres to the back face of the lid 5 , to seal the package 20 .
  • the package 20 is opened again, for example, a nail or the like is hooked under the lower edge of the lid 5 , thereby the self-adhesive (E) 13 is separated from the lid 5 , and the package can be easily opened.
  • self-adhesion of the self-adhesive (E) 13 is not damaged.
  • the package 20 can be repeatedly sealed and opened.
  • FIG. 2C shows a position of the package 30 being opened viewed from the same point as FIG. 2A .
  • the self-adhesive (E) 13 is arranged over, and adhered and fixed to the back face of the lid 5 in the package 30 .
  • the structure other than this is same as the package 20 .
  • the self-adhesive (E) 13 self-adheres to the surface of the package body 4 , to seal the package 30 .
  • the package 30 can be easily opened by the same way as the package 20 .
  • such an embodiment of the package 30 can be repeatedly sealed and opened as well.
  • FIG. 2D shows a position of the package 40 being opened viewed from the same point as FIG. 2A .
  • the self-adhesive (E) 13 is arranged over, and adhered and fixed to each of the surface of the package body 4 and the back face of the lid 5 in the package 40 .
  • the structure other than this is same as the package 20 .
  • the self-adhesives (E) 13 self-adhere to each other, to seal the package 40 .
  • the package 40 can be easily opened by the same way as the package 20 .
  • the package 40 can be especially preferably employed when the package body 4 and the lid 5 are constituted by material that the self-adhesive (E) 13 is hard to self-adhere to because the self-adhesives (E) 13 self-adhere to each other.
  • a package 50 according to another embodiment of the present invention will be described with reference to FIGS. 3A and 3B .
  • FIG. 3A is a perspective view in a position of the package 50 being closed
  • FIG. 3B is a perspective view in a position of the package 50 being opened.
  • the package 50 includes a box-shaped package body 14 that forms with an opening 22 , and a lid 15 with which the opening 22 of the package body 14 is covered.
  • the package body 14 and the lid 15 connect along an upper edge 16 of the package body 14 .
  • the lid 15 is a hinged lid.
  • the closed ( FIG. 3A ) and opened (at least FIG. 3B ) positions can be taken by the lid 15 rotating around the upper edge 16 .
  • the package body 14 includes a collar 7 that partially adheres to an inner face of the container body 14 , and partially protrudes outward from the opening 22 of the package body 14 .
  • the collar 7 includes: an inner front wall 7 a , and inside walls 7 b , 7 b which adhere to the inner face of the package body 14 ; and an outer front wall 7 c , and outside walls 7 d , 7 d which protrude outward from the opening 22 of the package body 14 .
  • the package body 14 and the lid 15 are in contact with each other over the outside faces of the outer front wall 7 c and outside walls 7 d , 7 d in the position of the package 50 being closed.
  • a self-adhesive (E) 23 is arranged over the outer front wall 7 c among the outer front wall 7 c and the outside walls 7 d , 7 d which are contact portions of the package body 14 and the lid 15 in the package 50 .
  • the self-adhesive (E) 23 is adhered and fixed to the surface of the outer front wall 7 c of the package 50 .
  • the self-adhesive (E) 23 self-adheres to the back face of a front wall 15 a of the lid 15 , to seal the package 50 . Whereby, it is possible to improve the airtightness again even after the package is opened.
  • the package 50 When the package 50 is opened again, a nail or the like is hooked under the lower edge of the front wall 15 a of the lid 15 , or a front wall 14 a of the package body 14 is pressed from the outside, thereby the self-adhesive (E) 23 is separated from the front wall 15 a of the lid 15 , and the package can be easily opened.
  • the package When the package is opened, self-adhesion of the self-adhesive (E) 23 is not damaged.
  • the package 50 can be repeatedly sealed and opened.
  • the self-adhesive (E) 23 is preferably arranged all over the contact portions of the package body 14 and the lid 15 (that is, not only over the outer front wall 7 c but also over the outside walls 7 d , 7 d ).
  • the self-adhesive (E) 23 is preferably arranged only over the outer front wall 7 c .
  • a position where the self-adhesive (E) is arranged among the contact portions of the package body and the lid can be suitably set according to airtightness and easy openability that are demanded from the package.
  • FIG. 4A shows a position of the package 60 being opened viewed from the same point as FIG. 3B .
  • the self-adhesive (E) 23 is arranged over, and adhered and fixed to the back face of the front wall 15 a of the lid 15 in the package 60 .
  • the structure other than this is same as the package 50 .
  • the self-adhesive (E) 23 self-adheres to the surface of the outer front wall 7 c of the package body 14 , to seal the package 60 .
  • the package 60 can be easily opened by the same way as the package 50 .
  • such an embodiment of the package 60 can be repeatedly sealed and opened as well.
  • FIG. 4B shows a position of the package 70 being opened viewed from the same point as FIG. 3B .
  • the self-adhesive (E) 23 is arranged over, and adhered and fixed to each of the surface of the outer front wall 7 c of the package body 14 , and the back face of the front wall 15 a of the lid 15 in the package 70 .
  • the structure other than this is same as the package 50 .
  • the self-adhesives (E) 23 self-adhere to each other, to seal the package 70 . Whereby, it is possible to improve the airtightness again even after the package is opened.
  • the package 70 When opened, the package 70 can be easily opened by the same way as the package 50 . Thus, such an embodiment of the package 70 can be repeatedly sealed and opened as well.
  • the package 70 can be especially preferably employed when the package body 14 and/or the lid 15 are/is constituted by material that the self-adhesive (E) 23 is hard to self-adhere because the self-adhesives (E) 23 self-adhere to each other according to the package 70 .
  • FIG. 5A is a perspective view in a position of the package 80 being closed
  • FIG. 5B is a perspective view in a position of the package 80 being opened.
  • the package 80 includes a package body 24 that forms with an opening 32 , and a lid 25 with which the opening 32 of the package body 24 is covered.
  • the package body 24 and the lid 25 connect along an upper edge 26 of the package body 24 .
  • the lid 25 is a hinged lid.
  • the closed ( FIG. 5A ) and opened (at least FIG. 5B ) positions can be taken by the lid 25 rotating around the upper edge 26 . Wrapping film 18 is stored in the package 80 .
  • the package body 24 and the lid 25 are in contact with each other over the back faces of a front wall 25 a , and side walls 25 b , 25 b of the lid 25 .
  • a self-adhesive (E) 33 is arranged on a portion of the surface of a front wall 24 a of the package body 24 which is to be in contact with the back face of the front wall 25 a of the lid 25 in the package 80 .
  • the self-adhesive (E) 33 is adhered and fixed to the surface of the front wall 24 a of the package 80 .
  • the self-adhesive (E) 33 self-adheres to the back face of the front wall 25 a of the lid 25 , to seal the package 80 . Whereby, it is possible to improve the airtightness again even after the package is opened.
  • the package 80 When the package 80 is opened again, a nail or the like is hooked under the lower edge of the front wall 25 a of the lid 25 , or the front wall 24 a of the package body 24 is pressed from the outside, thereby the self-adhesive (E) 33 is separated from the front wall 25 a of the lid 25 , and the package can be easily opened.
  • the package When the package is opened, self-adhesion of the self-adhesive (E) 33 is not damaged.
  • the package 80 can be repeatedly sealed and opened.
  • the self-adhesive (E) 33 is preferably arranged all over the contact portions of the package body 24 and the lid 25 (that is, not only over the front wall 24 a but also over side walls 24 b , 24 b of the package body 24 ).
  • the self-adhesive (E) 33 is preferably arranged only over the front wall 24 a .
  • a position where the self-adhesive (E) is arranged among the contact portions of the package body and the lid can be suitably set according to airtightness and easy openability that are demanded from the package.
  • FIG. 6A shows a position of the package 90 being opened viewed from the same point as FIG. 5B .
  • the self-adhesive (E) 33 is arranged over, and adhered and fixed to the back face of the front wall 25 a of the lid 25 in the package 90 .
  • the structure other than this is same as the package 80 .
  • the self-adhesive (E) 33 self-adheres to the surface of the front wall 24 a of the package body 24 , to seal the package 90 .
  • the package 90 can be easily opened by the same way as the package 80 .
  • such an embodiment of the package 90 can be repeatedly sealed and opened as well.
  • FIG. 6B shows a position of the package 100 being opened viewed from the same point as FIG. 5B .
  • the self-adhesive (E) 33 is arranged on, and adhered and fixed to each of the surface of the front wall 24 a of the package body 24 , and the back face of the front wall 25 a of the lid 25 in the package 100 .
  • the structure other than this is same as the package 80 .
  • the self-adhesives (E) 33 self-adhere to each other, to seal the package 100 . Whereby, it is possible to improve the airtightness again even after the package is opened.
  • the package 100 When opened, the package 100 can be easily opened by the same way as the package 80 . Thus, such an embodiment of the package 100 can be repeatedly sealed and opened as well.
  • the package 100 can be especially preferably employed when the package body 24 and/or the lid 25 are/is constituted by material that the self-adhesive (E) 33 is hard to self-adhere because the self-adhesives (E) 33 self-adhere to each other according to the package 100 .
  • the structure except the self-adhesive (E) is not restricted as long as including a hinged lid, and as long as there exists a contact portion of the package body and the lid (hinged lid).
  • a known structure can be employed.
  • material for the members other than the self-adhesive (E) is preferably what the self-adhesive (E) is easy to self-adhere to.
  • examples thereof include resin, metal, and paper. Among them, paper is preferable in view of light weight, low costs, and low environmental burdens.
  • a method for applying the self-adhesive (E) to at least part of the contact portion of the package body and the lid is not restricted.
  • the self-adhesive (E) may be adhered and fixed to a planar blank in advance before the blank is assembled to a box, to assemble blank to a box after that.
  • the self-adhesive (E) may be adhered and fixed after the blank is assembled to a box.
  • a method for adhering the self-adhesive (E) to the package body and/or the lid is not restricted.
  • the self-adhesive (E) can be adhered with a known adhesive.
  • FIGS. 7A to 7E show the embodiment that the self-adhesives self-adhere to each other in the closed position.
  • the self-adhesive is arranged on either the package body or the lid (in FIG. 7E , one of two boxes both of which can be the package body and the lid), and that the self-adhesive self-adheres to the package body or the lid in the closed position.
  • the package of this invention may be a sliding-type box (sliding box) as shown in FIGS. 8A and 8B .
  • the upper row shows positions of the packages being opened and the lower row shows positions of the packages being closed.
  • a sliding box consists of an inner box whose top face is open (package body), and an outer box that surrounds the outside of the inner box (lid part).
  • the package shown in FIG. 8A has a rotation piece along an end part of an inner box which is rotatable in a way of a hinge.
  • the package In the closed position, the package is sealed by self-adhesion of the self-adhesive that is arranged over the rotation piece, and the self-adhesive that is arranged over the top face of the outer box to each other.
  • the package shown in FIG. 8B is sealed by self-adhesion of the self-adhesive that is arranged over the top face of an end part of the inner box, and the self-adhesive that is arranged over the surface on the inner box side of the top face of the outer box to each other.
  • FIGS. 8A and 8B show the embodiment that the self-adhesives self-adhere to each other in the closed position.
  • the self-adhesive is arranged either on the package body or on the lid, and the self-adhesive self-adheres to the package body or the lid in the closed position.
  • the self-adhesive (E) will be described.
  • the self-adhesive (E) of the present invention is a cross-linking material of a resin composition (C) containing a (meth)acrylic acid ester copolymer resin (A), and a crosslinking agent (B).
  • the (meth)acrylic acid ester copolymer resin (A) used in the present invention is not restricted.
  • a glass transition temperature thereof is preferably ⁇ 10° C. or less, and more preferably ⁇ 13° C. or less.
  • the above described upper limit or less of the glass transition temperature of the (meth)acrylic acid ester copolymer resin (A) makes it easy to have the gel fraction of the (meth)acrylic acid ester copolymer resin (A) described below of a predetermined upper limit or less. As a result, it becomes easy to make the self-adhesive (E) having proper self adhesion strength and excellent smoothness.
  • the lower limit is preferably ⁇ 40° C. or more.
  • the (meth)acrylic acid ester copolymer resin (A) consists of no less than 50% by mass of monomeric units derived from (meth)acrylic acid ester monomer and no more than 50% by mass of monomeric units derived from monomer copolymerizable with the (meth)acrylic acid ester monomer; preferably, no less than 70% by mass of monomeric units derived from (meth)acrylic acid ester monomer and no more than 30% by mass of monomeric units derived from monomer copolymerizable with the (meth)acrylic acid ester monomer; more preferably, no less than 80% by mass of monomeric units derived from (meth)acrylic acid ester monomer and no more than 20% by mass of monomeric units derived from monomer copolymerizable with the (meth)acrylic acid ester monomer; and further preferably, no less than 80% by mass of monomeric units derived from (meth)acrylic acid ester monomer and no more than 20% by mass of monomeric units derived from mono
  • the (meth)acrylic acid ester copolymer resin (A) preferably has a N-methylol group.
  • Using the (meth)acrylic acid ester copolymer resin (A) having a N-methylol group makes it easy to have the gel fraction described below of a predetermined upper limit or less. As a result, it becomes easy to make the self-adhesive (E) having proper self adhesion strength and excellent smoothness.
  • a N-methylol group is usually included in a monomeric unit copolymerizable with (meth)acrylic acid ester monomer, and may be included in a monomeric unit of (meth)acrylic acid ester as well.
  • (Meth)acrylic acid ester monomer applicable to the present invention is not limited, and preferably, units of (meth)acrylic acid ester monomer composing homopolymer of ⁇ 20° C. or below in glass transition temperature are contained in view of easily making the glass transition temperature of the (meth)acrylic acid ester copolymer resin (A) ⁇ 10° C. or below, which is a preferred embodiment.
  • Non-limiting examples of the above described (meth)acrylic acid ester monomer composing homopolymer of ⁇ 20° C. or below in glass transition temperature include: (meth)acrylic acid alkyl esters composing homopolymer of ⁇ 20° C. or below in glass transition temperature such as ethyl acrylate (homopolymer therefrom is ⁇ 24° C. in glass transition temperature.
  • n-propyl acrylate ( ⁇ 37° C.), n-butyl acrylate ( ⁇ 54° C.), sec-butyl acrylate ( ⁇ 22° C.), n-heptyl acrylate ( ⁇ 60° C.), n-hexyl acrylate ( ⁇ 61° C.), n-octyl acrylate ( ⁇ 65° C.), 2-ethylhexyl acrylate ( ⁇ 50° C.), n-octyl methacrylate ( ⁇ 25° C.), and n-decyl methacrylate ( ⁇ 49° C.); and (meth)acrylic acid alkoxyalkyl esters composing homopolymer of ⁇ 20° C.
  • (meth)acrylic acid alkyl esters composing homopolymer of ⁇ 20° C. or below in glass transition temperature such as: 2-methoxyethyl acrylate ( ⁇ 50° C.), 3-methoxypropyl acrylate ( ⁇ 75° C.), 3-methoxybutyl acrylate ( ⁇ 56° C.), and ethoxymethyl acrylate ( ⁇ 50° C.).
  • (meth)acrylic acid alkyl esters composing homopolymer of ⁇ 20° C. or below in glass transition temperature and (meth)acrylic acid alkoxyalkyl esters composing homopolymer of ⁇ 20° C. or below in glass transition temperature are preferable, and (meth)acrylic acid alkyl esters composing homopolymer of ⁇ 20° C. or below in glass transition temperature are more preferable.
  • methyl acrylate (homopolymer is 10° C. in glass transition temperature.
  • methyl methacrylate (105° C.), ethyl methacrylate (63° C.), n-propyl methacrylate (25° C.), n-butyl methacrylate (20° C.) or the like may be used.
  • Only one kind of the above described (meth)acrylic acid ester monomer may be used. Alternatively, two or more kinds thereof may be used together.
  • monomer including a N-methylol group such as N-methylolacrylamide and N-methylolmethacrylamide
  • monomer copolymerizable with (meth)acrylic acid ester monomer hereinafter referred to as “monomer for copolymerization”.
  • monomer including a N-methylol group easily leads to the (meth)acrylic acid ester copolymer resin (A) including a N-methylol group.
  • A the self-adhesive (E) having proper self adhesion strength, and excellent smoothness.
  • monomeric units derived from monomer including a N-methylol group are preferably 0.1 to 10% by mass, and more preferably 0.5 to 5% by mass when the (meth)acrylic acid ester copolymer resin (A) is 100% by mass.
  • another kind of monomer may be used together as monomer for copolymerization.
  • Such another kind of monomer is not limited. Specific examples thereof include ⁇ , ⁇ -ethylenically unsaturated polyvalent carboxylic acid complete esters, alkenyl aromatic monomer, vinyl cyanide monomer, esters of carboxylic acids and unsaturated alcohols, olefinic monomer, and another monomer including a functional group. Only one kind of the above monomer may be used, or two or more kinds thereof may be used together.
  • ⁇ , ⁇ -ethylenically unsaturated polyvalent carboxylic acid complete esters include dimethyl fumarate, diethyl fumarate, dimethyl maleate, diethyl maleate, and dimethyl itaconate.
  • alkenyl aromatic monomer examples include styrene, ⁇ -methylstyrene, methyl ⁇ -methylstyrene, and vinyltoluene.
  • vinyl cyanide monomer examples include acrylonitrile, methacrylonitrile, ⁇ -chloroacrylonitrile, and ⁇ -ethylacrylonitrile.
  • esters of carboxylic acids and unsaturated alcohols include vinyl acetate.
  • olefinic monomer examples include ethylene, propylene, butene, and pentene.
  • Monomer including a functional group may be used as monomer for copolymerization for the purpose of efficient crosslinking inside or between copolymer.
  • Examples of functional groups mentioned here include organic acid groups, hydroxyl group, amino group, amide group, mercapto group, and epoxy groups.
  • Monomer including organic acid groups is not limited, and the representative thereof include monomer having an organic acid group such as a carboxyl group, an acid anhydride group, and a sulfonic acid group. Other than them, monomer containing a sulfenic acid group, a sulfinic acid group, and a phosphoric acid group can be used as well.
  • monomer having a carboxyl group examples include: ⁇ , ⁇ -ethylenically unsaturated monocarboxylic acids such as acrylic acid, methacrylic acid, and crotonic acid; ⁇ , ⁇ -ethylenically unsaturated polyvalent carboxylic acids such as itaconic acid, maleic acid, and fumaric acid; and in addition, ⁇ , ⁇ -ethylenically unsaturated polyvalent carboxylic acid partial esters such as monomethyl itaconate, monobutyl maleate, and monopropyl fumarate.
  • Monomer including a group from which a carboxyl group can be derived by hydrolysis etc., such as maleic anhydride, and itaconic anhydride, can be used as well.
  • monomer having a sulfonic acid group examples include ⁇ , ⁇ -unsaturated sulfonic acids such as allylsulfonic acid, methallylsulfonic acid, vinylsulfonic acid, styrenesulfonic acid, and acrylamido-2-methylpropane sulfonic acid; and salts thereof.
  • monomeric units derived therefrom are preferably 0.1 to 20% by mass, and more preferably 0.5 to 15% by mass when the (meth)acrylic acid ester copolymer resin (A) is 100% by mass.
  • the usage of monomer including an organic acid group within the above described range makes it easy to keep the viscosity of the polymerization system in polymerization within a proper range, and to prevent self-adhesion of the self-adhesive (E) from being lost due to excessive progress of crosslinking of copolymer.
  • a monomeric unit including an organic acid group is easy and preferable to be introduced into the (meth)acrylic acid ester copolymer resin (A) according to polymerization of monomer including an organic acid group.
  • An organic acid group may be introduced according to a known polymer reaction after the (meth)acrylic acid ester copolymer resin (A) forms.
  • Examples of monomer having a hydroxyl group include hydroxy alkyl(meth)acrylic acid esters such as 2-hydroxyethyl (meth)acrylate, and 3-hydroxypropyl(meth)acrylate.
  • Examples of monomer having an amino group include N,N-dimethylaminomethyl (meth)acrylate, N,N-dimethylaminoethyl (meth)acrylate, and aminostyrene.
  • Examples of monomer having an amide group include ⁇ , ⁇ -ethylenically unsaturated carboxylic acid amide monomer such as acrylamide, methacrylamide, and N,N-dimethylacrylamide.
  • Examples of monomer having an epoxy group include glycidyl(meth)acrylate, and allyl glycidyl ether.
  • such an amount of this monomer is preferably used for polymerization that monomeric units derived therefrom is no more than 10% by mass when the (meth)acrylic acid ester copolymer resin is 100% by mass. If the usage of monomer having a functional group other than organic acid groups is no more than 10% by mass, the viscosity of the polymerization system in polymerization can be easily kept within a proper range, and self-adhesion of the self-adhesive (E) can be easily prevented from being lost due to excessive progress of crosslinking of copolymer.
  • Polyfunctional monomer having a plurality of polymerizable unsaturated bonds may be used together as monomer for copolymerization. Unsaturated bond-terminated polyfunctional monomer is preferable. Using such polyfunctional monomer makes it possible to introduce intramolecular and/or intermolecular crosslinking into the (meth)acrylic acid ester copolymer resin (A), to improve cohesive force.
  • polyfunctional monomer examples include: polyfunctional (meth)acrylates such as 1,6-hexanediol di(meth)acrylate, 1,2-ethylene glycol di(meth)acrylate, 1,12-dodecanediol di(meth)acrylate, polyethylene glycol di(meth)acrylate, polypropyleneglycol di(meth)acrylate, neopentylglycol di(meth)acrylate, pentaerythritol di(meth)acrylate, trimethylolpropane tri(meth)acrylate, pentaerythritol tri(meth)acrylate, ditrimethylolpropane tri(meth)acrylate, pentaerythritol tetra(meth)acrylate, and dipentaerythritol hexa(meth)acrylate; substituted triazines such as 2,4-bis(trichloromethyl)-6-p-methoxysty
  • Polyfunctional (meth)acrylates are preferable, and pentaerythritol di(meth)acrylate, pentaerythritol tri(meth)acrylate, and pentaerythritol tetra(meth)acrylate are more preferable. Only one kind of polyfunctional monomer may be used, or two or more kinds thereof may be used together.
  • the (meth)acrylic acid ester copolymer resin (A) can be obtained by copolymerization of (meth)acrylic acid ester monomer and monomer for copolymerization. Any of polymerization methods such as solution polymerization, emulsion polymerization, suspension polymerization, bulk polymerization, and any other methods may be used when the (meth)acrylic acid ester copolymer resin (A) is obtained. Types and amounts of a polymerization initiator, an emulsifying agent, a dispersing agent, and the like that are used for polymerization are not limited as well.
  • Methods for adding monomer, a polymerization initiator, an emulsifying agent, a dispersing agent, and the like upon polymerization are not limited as well. Also, there is no limitation on polymerization temperature, polymerization pressure, stirring conditions, and the like.
  • the (meth)acrylic acid ester copolymer resin (A) may be either solid or a dispersion. If an emulsion or dispersion obtained from emulsion polymerization or dispersion polymerization is used as it is, operation is easy in mixing with a crosslinking agent and a conductive compound, and it is convenient to foam the obtained emulsion or dispersion.
  • the gel fraction of the (meth)acrylic acid ester copolymer resin (A) is preferably 70% or less, and more preferably 65% or less.
  • the gel fraction within the above range makes it easy to make the self-adhesive (E) of proper self adhesion strength, and excellent smoothness.
  • the gel fraction in the present invention is a value obtained from the following formula after: in 100 ml of ethyl acetate, 500 mg of a sample of an acrylic acid ester copolymer resin is immersed at normal temperature for 3 days; after that, insoluble matters are filtered through woven metal of 200 mesh, and air-dried at normal temperature for 15 hours; after that, the resulting matters are dried at 100° C. for 2 hours, and a dry mass of the resulting insoluble content is weighed.
  • the crosslinking agent (B) used in this invention is not restricted.
  • a melamine crosslinking agent that is preferably used for foam material conventionally in view of improving strength, etc. can be used.
  • Any non-limiting conventionally known melamine crosslinking agent can be used in this invention.
  • examples thereof include melamine, methylol melamine obtained by condensation of melamine and formaldehyde, partially or completely etherified compounds obtained by reaction of a lower alcohol with methylol melamine, and mixtures thereof.
  • a melamine crosslinking agent used therein may be monomer, a condensation product consisting of polymer that is at least dimer, or mixture thereof.
  • methylol melamine examples include monomethylol melamine, dimethylol melamine, trimethylol melamine, tetramethylol melamine, pentamethylol melamine, and hexamethylol melamine.
  • Examples of the above described lower alcohol used for etherifying methylol melamine include methyl alcohol, ethyl alcohol, isopropyl alcohol, n-butanol, and isobutanol.
  • a compound contained in the melamine crosslinking agent includes imino group, methylol group, or alkoxymethyl group such as methoxymethyl group, and butoxymethyl group in a molecule as a functional group, for example.
  • Examples of such a compound include imino group-type methylated melamine, methylol group-type melamine, methylol group-type methylated melamine, and complete alkyl-type methylated melamine.
  • the melamine crosslinking agent forms an intramolecular or intermolecular crosslinked structure in (meth)acrylic acid ester copolymer according to reaction of the above functional group thereof with a N-methylol group in the (meth)acrylic acid ester copolymer resin (A).
  • the melamine crosslinking agent is excellent in crosslinking effect at high temperature equal to or over 120° C.
  • the melamine crosslinking agent is preferable because the self-adhesive (E) excellent in strength and self-adhesion can form.
  • the usage of the melamine crosslinking agent is preferably 1 to 20 parts by mass, and more preferably 3 to 15 parts by mass as a solid, to 100 parts by mass of the (meth)acrylic acid ester copolymer resin (A).
  • the usage of the melamine crosslinking agent within the above described range makes it possible to have a proper self adhesion strength, and to improve strength of the resin after crosslinking.
  • a carbodiimide crosslinking agent (B 1 ) may be used as the crosslinking agent (B) used in the present invention instead of, or in addition to the melamine crosslinking agent.
  • Using the carbodiimide crosslinking agent (B 1 ) makes it possible to reduce the emission of formaldehyde that forms in a crosslinking reaction of the (meth)acrylic acid ester copolymer resin (A) having a N-methylol group.
  • the self-adhesive (E) from which a reduced amount of formaldehyde is emitted can be made.
  • the carbodiimide crosslinking agent (B 1 ) used in the present invention is not restricted.
  • a compound where two or more carbodiimide groups are included in a molecule is preferably used.
  • a known carbodiimide compound can be used as such a compound.
  • Either synthesized or commercially available carbodiimide compound may be used as a known carbodiimide compound described above.
  • Examples of a commercially available carbodiimide compound include “DICNAL HX” manufactured by DIC Corporation, and “CARBODILITE” manufactured by Nisshinbo Chemical Inc.
  • a carbodiimide compound is synthesized, for example, a polycarbodiimide compound that is carbodiimidized polyisocyanate by decarboxylative condensation reaction in the presence of a carbodiimidization catalyst can be used.
  • Examples of a polyisocyanate of raw material include hexamethylene diisocyanate (HDI), hydrogenated xylylene diisocyanate (H6XDI), xylylene diisocyanate (XDI), 2,2,4-trimethylhexamethylene diisocyanate (TMHDI), 1,12-diisocyanatedecane (DDI), norbornane diisocyanate (NBDI), 2,4-bis-(8-isocyanateoctyl)-1,3-dioctylcyclobutane (OCDI), 4,4′-dicyclohexylmethane diisocyanate (HMDI), tetramethylxylylene diisocyanate (TMXDI), isophorone diisocyanate (IPDI), 2,4,6-triisopropylphenyldiisocyanate (TIDI), 4,4′-diphenylmethane diisocyanate (MDI), toly
  • a carbodiimide compound can be synthesized by: stirring and mixing a polyisocyanate within the temperature range of 0 to 200° C. for any length of time in the presence of an air flow or bubbling of an inert gas; after that, adding the resultant along with a carbodiimidization catalyst, and stirring and mixing them.
  • a carbodiimidization catalyst described above is an organophosphorus compound.
  • a phospholene oxide is preferable in view of activity. Specific examples thereof include 3-methyl-1-phenyl-2-phospholene-1-oxide, 3-methyl-1-ethyl-2-phospholene-1-oxide, 1,3-dimethyl-2-phospholene-1-oxide, 1-ethyl-2-phospholene-1-oxide, 1-methyl-2-phospholene-1-oxide, and double bond isomer thereof.
  • the carbodiimide crosslinking agent (B 1 ) forms an intramolecular or intermolecular crosslinked structure in the (meth)acrylic acid ester copolymer according to reaction of a carbodiimide group thereof with a N-methylol group in the (meth)acrylic acid ester copolymer resin (A).
  • the carbodiimide crosslinking agent (B 1 ) is excellent especially in crosslinking effect at low temperature.
  • the carbodiimide crosslinking agent (B 1 ) is preferable because the self-adhesive (E) excellent in strength and self-adhesion can form.
  • the usage of the carbodiimide crosslinking agent (B 1 ) is preferably 0.1 to 20 parts by mass, and more preferably 0.5 to 15 parts by mass as a solid, to 100 parts by mass of the (meth)acrylic acid ester copolymer resin (A).
  • the usage of the carbodiimide crosslinking agent (B 1 ) within the above described range makes it possible to have a proper self adhesion strength, and to improve strength of the resin after crosslinking.
  • crosslinking agents may be used as well such as: epoxy resins such as polyethylene glycol diglycidyl ether, glycerin polyglycidyl ether, sorbitol polyglycidyl ether, and bisphenol A polyglycidyl ether; aziridines such as ethylenimine derivatives including aldehyde and acrolein; multifunctional isocyanate crosslinking agents such as tolylene diisocyanate, trimethylolpropane tolylene diisocyanate, and diphenylmethane triisocyanate; oxazoline crosslinking agents; metal salt-based crosslinking agents; metal chelate-based crosslinking agents; peroxide-based crosslinking agents; aldehyde resins such as urea-formaldehyde resins, and phenolformaldehyde resin
  • the resin composition (C) may contain a formaldehyde scavenger.
  • Formaldehyde scavengers that can be used for the present invention are not limited as long as being compounds that physically adhere to formaldehyde or that can chemically react with formaldehyde.
  • Formaldehyde scavengers may be either inorganic compounds or organic compounds that include even polymer.
  • formaldehyde scavengers include: nitrogen-containing compounds such as hydroxylamine sulfate, hydroxylamine hydrochloride, ammonium acetate, urea, ethyleneurea, dicyandiamide, polyamide resins, triazine compounds, and hydrazide compounds; halogen oxides such as stabilized chlorine dioxide; and metallic salts such as disodium hydrogen phosphate, zinc sulfate, calcium chloride, and magnesium sulfate.
  • nitrogen-containing compounds are preferable and hydroxylamine sulfate is especially preferable in view of easy availability, operability and formaldehyde scavenging performance.
  • One of these formaldehyde scavengers may be used individually, or two or more of them may be used together.
  • the resin composition (C) can contain various additives if necessary in order to improve processability in processes of producing the self-adhesive (E), and to improve performance of the self-adhesive (E) to be obtained.
  • additives include foam stabilizers, auxiliary blowing agents, thickeners, fillers, antiseptics, fungicides, gelatinizers, flame retardants, anti-aging agents, antioxidants, pigments, dyes, tackifiers, photosensitizers, and conductive compounds.
  • ammonium salts of fatty acids such as ammonium stearate, sulfonic acid-type anionic surfactants such as alkyl sulfosuccinates, quaternary alkylammonium chlorides, amphoteric compounds of alkyl betaines, and alkanolamine salts of fatty acids.
  • auxiliary blowing agents the following can be used: sodium lauryl sulfate, sodium alkyl diphenyl ether disulphonate, and sodium polyoxyethylene alkylphenol ether sulfate.
  • acrylic polymer particles acrylic polymer particles, inorganic compounds particulates such as fine silica particles, and reactive inorganic compounds such as magnesium oxide.
  • fillers the following can be used: calcium carbonate, magnesium carbonate, aluminum hydroxide, magnesium hydroxide, barium hydroxide, clay, kaolin, and glass powder.
  • antiseptics and fungicides examples include dihydroxy dichlorophenylmethane, sodium pentachlorophenate, 2,3,4,6-tetrachloro-4-(methylsulfonyl)pyridine, 2,3,5,6-tetrachloro-4-(methylsulfonyl)pyridine, bis(tributyltin) oxide, hexahydro-1,3,5-triethyl-s-triazine, silver complexes, and zinc complexes.
  • gelatinizers the following can be used: ammonium salts such as ammonium acetate, ammonium chloride, and ammonium carbonate; alkylphenol alkylene oxide addition products; polyvinylmethyl ether; polypropylene glycol; polyether polyformal; methylcellulose; hydroxyethyl cellulose; and silicone heat sensitizers.
  • flame retardants the following can be used: phosphoric acid ester compounds, halogen phosphoric acid ester compounds, ammonium polyphosphate, antimony trioxide, zinc borate, barium metaborate, ammonium hydroxide, magnesium hydroxide, tin compounds, organophosphorous compounds, red phosphorus compounds, and silicone flame retardants.
  • Antioxidants based on polyphenol, hydroquinone, hindered amine, and the like can be used here.
  • pigments and dyes examples include titan oxide, carbon black, iron oxide red, and quinacridone.
  • any compounds selected from the following can be used: rosin resins such as gum rosins, tall oil rosins, wood rosins, hydrogenated rosins, disproportionated rosins, polymerized rosins, maleated rosins, rosin glycerol esters, and hydrogenated rosin glycerol esters; terpene based resins such as terpene resins, terpene phenol resins, and aromatic modified terpene resins; petroleum resins such as aliphatic petroleum resins, alicyclic petroleum resins, and aromatic petroleum resins; coumarone-indene resins; terpene phenol-based resins; phenol resins; hydrogenated rosin esters; disproportionated rosin esters; and xylene resins.
  • rosin resins such as gum rosins, tall oil rosins, wood rosins, hydrogenated rosins, disproportionated rosins, polymerized ros
  • photosensitizers examples include: amines such as n-butylamine, trimethylamine, N-methyldiethanolamine, piperidine, N,N-dimethylaniline, triethylenetetramine, and diethylaminoethyl (meth)acrylate; urea compounds such as O-tolylthiourea; sulfur compounds such as s-benzyl-isothiuronium-p-toluenesulfinate; nitriles such as N,N-dimethyl-p-aminobenzonitrile; and phosphorus compounds such as sodium diethyl thiophosphate.
  • amines such as n-butylamine, trimethylamine, N-methyldiethanolamine, piperidine, N,N-dimethylaniline, triethylenetetramine, and diethylaminoethyl (meth)acrylate
  • urea compounds such as O-tolylthiourea
  • sulfur compounds such as s-benz
  • a photosensitizer is an additive that, although not activated by irradiation with ultraviolet rays or the like when used individually, has a function of promoting progress of radical polymerization when used with a photopolymerization initiator, compared to the case of using the photopolymerization initiator individually.
  • the self-adhesive (E) may be laminated to a base material. Laminating the self-adhesive (E) to a base material leads to adhesion of the face on the base material side to the package body and/or the lid of the package when the self-adhesive (E) is adhered and fixed to the package body and/or the lid. Whereby, adhesive compositions bleed over the surface (face on the self-adhesive (E) side), which makes it possible to prevent self-adhesion from being lost.
  • base material examples include paper bases, and plastic sheets.
  • examples of paper bases include woodfree paper, art paper, coated paper, kraft paper, cartonboard, and laminated paper obtained by laminating a thermoplastic resin such as polyethylene to any paper base described above.
  • plastic sheets include: polyester resins such as polyethylene terephthalate, and polyethylene naphthalate; polystyrene resins; polyvinyl chloride resins; acrylic resins; polycarbonate resins; polyamide resins; fluorocarbon polymers such as polytetrafluoroethylene; polyolefine resins such as polyethylene, and polypropylene; polycycloolefin resins; polyvinyl alcohol resins; poly(ethylene-vinylalcohol copolymer) resins; and sheets composed of mixtures or laminates thereof.
  • Thickness of a supporting layer consisting of the base material is not limited. Normally, thickness thereof is 10 ⁇ m to 200 ⁇ m.
  • the resin composition (C) is preferably a resin composition foam (D) that is foamed.
  • the resin composition (C) of the foamed resin composition foam (D) makes it possible for a cross-linking material of the resin composition (C) to have a foaming structure, and for the self-adhesive (E) consisting of the cross-linking material to show adsorption due to sucking effect using microcavities.
  • a method for foaming the resin composition (C) will be described in detail in a foaming step S 12 of the producing method described later.
  • the self-adhesive (E) that adheres by adsorption is more excellent in releasability than the self-adhesive (E) that adheres only by pasting, and glue is difficult to remain.
  • foaming cells communicate, air bubbles come out well, and everyone can stick the self-adhesive (E) neatly.
  • FIG. 9 is an exemplary flowchart of a method for producing the self-adhesive (E) of the present invention S 10 (hereinafter may be abbreviated as “this producing method S 10 ”).
  • this producing method S 10 includes a resin composition making step S 1 , and a cross-linking step S 2 in this order.
  • This producing method S 10 preferably includes a foaming step S 12 between the resin composition making step S 1 , and the cross-linking step S 2 .
  • each step will be described.
  • the resin composition making step S 1 is a step of making the resin composition (C) containing the (meth)acrylic acid ester copolymer resin (A), and the crosslinking agent (B).
  • the resin composition (C) can be made by mixing the (meth)acrylic acid ester copolymer resin (A), and the crosslinking agent (B), which are essential components, and other components used if desired, according to some method.
  • the proportion of the use thereof, etc. are as described above, and thus the description thereof is omitted here.
  • the (meth)acrylic acid ester copolymer resin (A) can be easily mixed with the crosslinking agent, and the other components just by adding them in a state of an aqueous dispersion, a water solution, or the like, to the resin (A) during stirring.
  • the (meth)acrylic acid ester copolymer resin (A) is a solid
  • a way of mixing is not restricted as well.
  • mixing may be carried out with a roll, a Henschel mixer, or a kneader. Either batch mixing or continuous mixing may be carried out.
  • Examples of a batch mixer include kneaders and stirrers for high viscosity raw material such as: a mortar machine, a kneader, an internal mixer, and a planetary mixer.
  • Examples of a continuous mixer include a Farrel continuous mixer that is combination of a rotor and a screw, and a kneader of screw-type special structure.
  • a single-screw extruder and a twin-screw extruder that are used for extruding are also included. At least two of these extruders and kneaders may be used in combination, or a plurality of machines of the same type may be coupled to be used.
  • the embodiment of the resin composition (C) of the present invention is not limited.
  • the embodiment of either emulsion or dispersion makes it convenient to obtain the self-adhesive (E).
  • the viscosity of this emulsion or dispersion is preferably 2000 to 10000 mPa ⁇ s, and more preferably 3500 to 5500 mPa ⁇ s.
  • the cross-linking step S 2 is a step of cross-linking the resin component (C).
  • the cross-linking step S 2 is a step of cross-linking the resin composition foam (D).
  • the self-adhesive (E) that is made by solidification of the resin composition (C) can be obtained by a crosslinking reaction of the (meth)acrylic acid ester copolymer resin (A) in the resin composition (C).
  • the self-adhesive (E) obtained in the cross-linking step S 2 is processed to be a desired shape by cutting or blanking, so as to match the shape of a portion where the self-adhesion (E) is to be arranged (at least part of the contact portion of the package body and the lid of the package).
  • the resin composition (C) is preferably shaped into a sheet. Shaping the resin composition (C) into a sheet makes it possible to make the self-adhesive (E) having a sheet shape after the cross-linking step S 2 .
  • the self-adhesive (E) having a sheet shape has a uniform thickness, and is easy to be processed to be a desired shape, so as to match the shape of a portion where the self-adhesion (E) is to be arranged.
  • a method for shaping the resin composition (C) into a sheet is not restricted.
  • Preferred examples of such a method include a method of coating process paper such as a polyester film on which a releasing process is carried out, with the resin composition (C), to be shaped into a sheet.
  • the following coating devices which are generally known, can be used for a method of coating process paper with the resin composition (C): a roll coater, a reverse roll coater, a screen coater, a doctor knife coater, a comma knife coater, a gravure coater, etc. Specifically, a uniform coating thickness can be obtained using a doctor knife coater.
  • the self-adhesive (E) that is made by solidification of the resin composition (C) of a sheet can be formed over process paper by a crosslinking reaction of the (meth)acrylic acid ester copolymer resin (A) after the resin composition (C) is shaped into a sheet over process paper as described above. At this time, if process paper having releasability is used, the self-adhesive (E) can be easily separated from this process paper.
  • the self-adhesive (E) When the self-adhesive (E) that is laminated to a base material is produced, the self-adhesive (E) can be formed over a base material in the cross-linking step S 2 by using the above described base material as process paper, and a laminated sheet consisting of the self-adhesive (E), and the base material can be produced.
  • heating and drying is carried out when the (meth)acrylic acid ester copolymer resin (A) is subjected to crosslinking reaction.
  • a method for heating and drying is not restricted as long as a foamed emulsion with which process paper is coated can be dried and crosslinked according to the method.
  • An ordinary oven with hot air circulation, a hot air chamber with a hot oil circulator, a far infrared ray heater chamber, etc. can be used for this method. Drying temperature is properly 60° C. to 180° C. Drying conditions can be properly selected according to the properties of the emulsion, the coating amount, the coating thickness, etc.
  • drying is not carried out at fixed temperature but multi-stage drying is carried out such that: drying is carried out from the inside at lower temperature at the early stage, and through at higher temperature at the later stage.
  • photo-curing can be achieved by light such as UV.
  • a resin composition containing a photo-curable resin and a photoinitiator is irradiated with a predetermined amount of light by a lump such as a high pressure mercury lamp (main wavelength: 365 nm), to obtain a cured product.
  • a lump such as a high pressure mercury lamp (main wavelength: 365 nm
  • the thickness of the self-adhesive (E) is preferably 0.03 to 3 mm, more preferably 0.05 to 1 mm, and especially preferably 0.05 to 0.5 mm.
  • the density of the self-adhesive (E) is not restricted, and is preferably 0.1 to 1.0 g/cm 3 in view of impact absorbency.
  • the foaming step S 12 is preferably included between the resin composition making step S 1 and the cross-linking step S 2 . Including the foaming step S 12 makes it possible to produce a self-adhesive sheet having a foaming structure, and showing adsorption due to sucking effect using microcavities.
  • the foaming step S 12 is a step of foaming the resin composition (C), to make the resin composition foam (D).
  • the resin composition (C), which is made in the resin composition making step S 1 is foamed, which makes it possible to obtain the resin composition foam (D) in an unsolidified state.
  • the resin composition (C) is in the embodiment of an emulsion or dispersion, a foamed emulsion or foamed dispersion is obtained.
  • Foaming magnification may be properly adjusted, is usually 1.2 to 5 times, and is preferably 1.5 to 4 times.
  • a method for mechanical foaming is not restricted. Mechanical foaming can be carried out by mixing a certain amount of air with the emulsion of the resin composition, and stirring the mixture with a continuous or batch type Oakes mixer, whipper, or the like. The foamed emulsion obtained according to this way is creamy.
  • the resin composition foam (D) can be also prepared with, for example, a method of using a proper synthetic resin such as vinylidene chloride copolymer as a shell wall, and adding thermally expandable microcapsules that encompass a hydrocarbon compound of low boiling point to an acrylic resin emulsion or butadiene synthetic rubber emulsion.
  • a proper synthetic resin such as vinylidene chloride copolymer as a shell wall
  • the method for using the self-adhesive (E) of the present invention is a method for uses for adhesion in a package in order to seal an opening, the package comprising: a space to store contents; and the opening by which the space and an outside communicate, the opening being repeatedly openable and sealable.
  • the package comprises: a package body that has the space to store the contents, the package body being formed with the opening; and a lid with which the opening of the package body can be covered, and the adhesion is at a contact portion of the package body and the lid.
  • the method for using the self-adhesive (E) of the present invention is as described above concerning the above description about the package, using FIGS. 1A to 8B .
  • the self-adhesive (E) may be used for adhesion of a contact portion between flaps of a regular slotted container, a contact portion of a package body (body) and a lid (sleeve) of a sleeve box, a contact portion of a package body (inner body) and a lid (outer body) of a telescopic box (inner and outer trays), and a contact portion between the members that constitute handles of a cake box. Because particles of food, luxuries, etc.
  • the self-adhesive (E) can be preferably used especially for tentative fixing after such a package is opened that particles therein are easy to scatter over the outside. Further, the self-adhesive (E) can increase airtightness of the package such as a box and a bag, can keep the contents fresh, and can prevent the contents from spoiling due to oxygen, moisture, and the like.
  • the self-adhesive (E) can be used for packages of, for example, sweets, coffee, tea, cigarettes, and detergents as the use when packages may be repeatedly opened and closed, and the use when the contents have to be kept fresh, as described above.
  • the glass transition temperature (Tg) of the acrylic acid ester copolymer resin that was used for material for a self-adhesive described below was measured with the following method: 50 ⁇ m of a polyethylene terephthalate film in thickness was coated with the acrylic acid ester copolymer resin with a 250 ⁇ m applicator, and was dried at normal temperature for 24 hours, to obtain a resin film; and using this film as a sample, the glass transition temperature (° C.) was measured at ⁇ 50° C. to 160° C. in measurement temperature at 10° C./min in heating rate with a differential scanning calorimeter (DSC6220 manufactured by SII NanoTechnology Inc.), conforming to JIS (Japanese Industrial Standards) K 7121. The results are shown in Table 1.
  • the gel fraction of the acrylic acid ester copolymer resin used for a self-adhesive described later was measured with the following method: 50 ⁇ m of a polyethylene terephthalate film in thickness was coated with the acrylic acid ester copolymer resin with a 250 ⁇ m applicator, and dried at normal temperature for 24 hours, to obtain a resin film; a certain amount (X) (approximately 500 mg) of this film as a sample was precisely weighed, and was immersed in 100 ml of ethyl acetate at normal temperature for 3 days; after that, insoluble was filtered through a woven metal of 200 mesh, and air-dried at normal temperature for 15 hours; after that, the resultant was dried at 100° C. for 2 hours, and cooled at normal temperature; and after that, the mass of the sample (Y) was measured.
  • the gel fraction was calculated by substitution of the values of X and Y into the following formula. The results are shown in Table 1.
  • self-adhesive laminated sheet After a sheet obtained by laminating a self-adhesive layer consisting of a self-adhesive to a base material (hereinafter will be referred to as “self-adhesive laminated sheet”) was made as described later, a test piece that was cut out into a size of 125 mm ⁇ 25 mm was prepared. A self-adhesive layer side face of the test piece was stuck onto milk carton (KM-3 manufactured by KP PLATECH Co., Ltd.) of a smooth surface, and the test piece was contact-bonded with a 2 kgf loading roller from the top thereof, and allowed to stand at 23° C. at 50% RH for 1 hour.
  • milk carton KM-3 manufactured by KP PLATECH Co., Ltd.
  • test strength at this time was defined as a self adhesion strength (N/cm).
  • N/cm self adhesion strength
  • test pieces that were cut out into a size of 125 mm ⁇ 25 mm were prepared.
  • a base material side face of one of the test pieces was stuck onto a SUS plate, self-adhesive layers were stuck onto each other, and the test pieces were contact-bonded with a 2 kgf loading roller from the top thereof, and allowed to stand at 23° C. at 50% RH for 1 hour.
  • cohering object of the self-adhesive layer was confirmed on the base material face, or cohering object of the base material was confirmed on the self-adhesive layer.
  • test piece that was cut out into a size of 200 mm ⁇ 200 mm was prepared.
  • the test piece was put into a tedlar bag of 5 L in volume, and the bag was hermetically sealed. Air of 2 L was encapsulated in the bag, and the bag was allowed to stand for 6 hours in a constant temperature oven at 23° C. at 50% RH, and after that, the concentration of formaldehyde in the bag was measured with a detector tube (No. 91L manufactured by Gastec Corporation). The results are shown in Table 1, where the case where the concentration of formaldehyde was 0.2 ppm or below is indicated by “good”, and the case where the concentration of formaldehyde was beyond 0.2 ppm is indicated by “bad”.
  • composition of (I) was a copolymer resin of: 46.9 of ethyl acrylate/45.8 of butyl acrylate/5.9 of acrylonitrile/1.4 of N-methylolacrylamide; ⁇ 25.9° C.
  • a thickener carboxylic acid-modified acrylic acid ester polymer. ARON B-300K manufactured by Toagosei Co., Ltd.
  • a foam stabilizer [a 1/1 mixture of: a mixture of an amphoteric compound of alkyl betaine, and fatty acid alkanolamide (DICNAL M-20 manufactured by DIC Corporation)/a sulfonic acid-type anionic surfactant (DICNAL M-40 from DIC Corporation)] in terms of the solid content were added in this order, and the resultant was filtered through 150 mesh.
  • ammonia was added, to adjust the viscosity to 4500 mPa ⁇ s, and a resin composition was obtained.
  • This resin composition was stirred with a beater, to be whipped so that the foaming magnification was twice. Further, stirring was continued for 5 minutes at a lower stirring speed.
  • the obtained foamed mixture was applied onto a base material (a polyethylene terephthalate film of 50 ⁇ m in thickness) using a 0.3 mm applicator.
  • the resultant was put into a drying oven, and kept at 80° C. for 1.33 minutes; at 120° C. for 1.33 minutes; and at 140° C. for 1.33 minutes, to dry-crosslinked.
  • a self-adhesive layer (a self-adhesive) was laminated to the base material, and a self-adhesive laminated sheet according to Example 1 was obtained.
  • a sheet according to Example 2 was made in the same manner as in Example 1 except using a carbodiimide crosslinking agent (CARBODILITE (registered trademark) E-02 manufactured by Nisshinbo Chemical Inc.) instead of the carbodiimide crosslinking agent (DICNALHX manufactured by DIC Corporation) used in Example 1.
  • CARBODILITE registered trademark
  • E-02 manufactured by Nisshinbo Chemical Inc.
  • DINVALHX manufactured by DIC Corporation
  • a sheet according to Example 3 was made in the same manner as in Example 1 except using a N-methylol group containing acrylic acid ester copolymer resin (II) whose composition was modified from that of the N-methylol group containing acrylic acid ester copolymer resin (I) used in Example 1, so as to have glass transition temperature of ⁇ 17.6° C. and gel fraction of 28.0%.
  • a N-methylol group containing acrylic acid ester copolymer resin (II) whose composition was modified from that of the N-methylol group containing acrylic acid ester copolymer resin (I) used in Example 1, so as to have glass transition temperature of ⁇ 17.6° C. and gel fraction of 28.0%.
  • a sheet according to Example 4 was made in the same manner as in Example 1 except using a N-methylol group containing acrylic acid ester copolymer resin (III) whose composition was modified from that of the N-methylol group containing acrylic acid ester copolymer resin (I) used in Example 1, so as to have glass transition temperature of ⁇ 10.1° C. and gel fraction of 42.2%.
  • a sheet according to Example 5 was made in the same manner as in Example 1 except using a N-methylol group containing acrylic acid ester copolymer resin (IV) whose composition was modified from that of the N-methylol group containing acrylic acid ester copolymer resin (I) used in Example 1, so as to have glass transition temperature of ⁇ 15.3° C. and gel fraction of 41.5%.
  • a sheet according to Example 6 was made in the same manner as in Example 1 except using a N-methylol group containing acrylic acid ester copolymer resin (V) whose composition was modified from that of the N-methylol group containing acrylic acid ester copolymer resin (I) used in Example 1, so as to have glass transition temperature of ⁇ 22.8° C. and gel fraction of 60.5%.
  • a sheet according to Example 7 was made in the same manner as in Example 5 except using 2.2 parts of a carbodiimide crosslinking agent (CARBODILITE (registered trademark) E-02 manufactured by Nisshinbo Chemical Inc.) instead of 3.6 parts of the carbodiimide crosslinking agent (DICNALHX manufactured by DIC Corporation) used in Example 5.
  • CARBODILITE registered trademark
  • E-02 manufactured by Nisshinbo Chemical Inc.
  • a sheet according to Example 8 was made in the same manner as in Example 5 except that the resin composition was not foamed but applied to the base material as it was in Example 5.
  • Example 7 Two sheets according to Example 7 were prepared. Self adhesion strength of the self-adhesive layers adhering to each other, and the concentration of formaldehyde when the sheets were put in the tedlar bag were measured.
  • a sheet according to Example 10 was made in the same manner as in Example 1 except using a melamine crosslinking agent (BECKAMINE M3 manufactured by DIC Corporation) and a crosslinking promoter (CATALYST ACX manufactured by DIC Corporation) instead of the carbodiimide crosslinking agent (DICNAL HX manufactured by DIC Corporation) used in Example 1.
  • a melamine crosslinking agent BECKAMINE M3 manufactured by DIC Corporation
  • CALYST ACX manufactured by DIC Corporation
  • a sheet according to Example 11 was made in the same manner as in Example 1 except using carboxylic group containing acrylic acid ester copolymer resin (I′) (composition: a copolymer resin of 49.0 of ethyl acrylate/42.1 of butyl acrylate/6.9 of acrylonitrile/2.0 of acrylic acid; glass transition temperature: ⁇ 20.9° C., and gel fraction: 89.6%) instead of the N-methylol group containing acrylic acid ester copolymer resin (I) used in Example 1.
  • carboxylic group containing acrylic acid ester copolymer resin (I′) composition: a copolymer resin of 49.0 of ethyl acrylate/42.1 of butyl acrylate/6.9 of acrylonitrile/2.0 of acrylic acid; glass transition temperature: ⁇ 20.9° C., and gel fraction: 89.6%

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WO2023230378A1 (en) * 2022-05-27 2023-11-30 3D Architech, Inc. Additive manufacturing and post-treatment of inorganic materials

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TW201707586A (zh) * 2015-08-28 2017-03-01 菲利浦莫里斯製品股份有限公司 具有改良的關閉機構之容器
CN109072024B (zh) * 2016-04-28 2021-05-11 日本瑞翁株式会社 自粘性层
KR20190003486A (ko) * 2016-04-28 2019-01-09 니폰 제온 가부시키가이샤 자기점착성 층
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PT3305675T (pt) 2021-05-06
US11066206B2 (en) 2021-07-20
WO2016199523A1 (ja) 2016-12-15
JPWO2016199523A1 (ja) 2018-03-22
EP3305675A1 (de) 2018-04-11
CN107531358A (zh) 2018-01-02
EP3305675A4 (de) 2019-01-23
EP3305675B1 (de) 2021-03-10

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