US20140065007A1 - Hot press-formed product, process for producing same, and thin steel sheet for hot press forming - Google Patents

Hot press-formed product, process for producing same, and thin steel sheet for hot press forming Download PDF

Info

Publication number
US20140065007A1
US20140065007A1 US14/114,715 US201214114715A US2014065007A1 US 20140065007 A1 US20140065007 A1 US 20140065007A1 US 201214114715 A US201214114715 A US 201214114715A US 2014065007 A1 US2014065007 A1 US 2014065007A1
Authority
US
United States
Prior art keywords
hot press
forming
formed product
steel sheet
thin steel
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US14/114,715
Other languages
English (en)
Inventor
Junya Naitou
Toshio Murakami
Shushi Ikeda
Keisuke Okita
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kobe Steel Ltd
Original Assignee
Kobe Steel Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kobe Steel Ltd filed Critical Kobe Steel Ltd
Assigned to KABUSHIKI KAISHA KOBE SEIKO SHO (KOBE STEEL, LTD.) reassignment KABUSHIKI KAISHA KOBE SEIKO SHO (KOBE STEEL, LTD.) ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: IKEDA, SHUSHI, MURAKAMI, TOSHIO, NAITOU, JUNYA, OKITA, KEISUKE
Publication of US20140065007A1 publication Critical patent/US20140065007A1/en
Abandoned legal-status Critical Current

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/58—Ferrous alloys, e.g. steel alloys containing chromium with nickel with more than 1.5% by weight of manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21D—WORKING OR PROCESSING OF SHEET METAL OR METAL TUBES, RODS OR PROFILES WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21D22/00—Shaping without cutting, by stamping, spinning, or deep-drawing
    • B21D22/02—Stamping using rigid devices or tools
    • B21D22/022—Stamping using rigid devices or tools by heating the blank or stamping associated with heat treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21D—WORKING OR PROCESSING OF SHEET METAL OR METAL TUBES, RODS OR PROFILES WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21D22/00—Shaping without cutting, by stamping, spinning, or deep-drawing
    • B21D22/20—Deep-drawing
    • B21D22/208—Deep-drawing by heating the blank or deep-drawing associated with heat treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21D—WORKING OR PROCESSING OF SHEET METAL OR METAL TUBES, RODS OR PROFILES WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21D22/00—Shaping without cutting, by stamping, spinning, or deep-drawing
    • B21D22/20—Deep-drawing
    • B21D22/22—Deep-drawing with devices for holding the edge of the blanks
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21D—WORKING OR PROCESSING OF SHEET METAL OR METAL TUBES, RODS OR PROFILES WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21D37/00—Tools as parts of machines covered by this subclass
    • B21D37/16—Heating or cooling
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/18—Hardening; Quenching with or without subsequent tempering
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/62—Quenching devices
    • C21D1/673—Quenching devices for die quenching
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/001—Ferrous alloys, e.g. steel alloys containing N
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/14—Ferrous alloys, e.g. steel alloys containing titanium or zirconium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/20—Ferrous alloys, e.g. steel alloys containing chromium with copper
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/22—Ferrous alloys, e.g. steel alloys containing chromium with molybdenum or tungsten
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/24—Ferrous alloys, e.g. steel alloys containing chromium with vanadium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/26—Ferrous alloys, e.g. steel alloys containing chromium with niobium or tantalum
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/28—Ferrous alloys, e.g. steel alloys containing chromium with titanium or zirconium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/32—Ferrous alloys, e.g. steel alloys containing chromium with boron
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/50—Ferrous alloys, e.g. steel alloys containing chromium with nickel with titanium or zirconium
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/54—Ferrous alloys, e.g. steel alloys containing chromium with nickel with boron
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/60—Ferrous alloys, e.g. steel alloys containing lead, selenium, tellurium, or antimony, or more than 0.04% by weight of sulfur
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00—Microstructure comprising significant phases
    • C21D2211/008—Martensite

Definitions

  • the present invention relates to a hot press-formed product required to have high strength, such as used for structural members of automobile parts, a process for producing the same, and a thin steel sheet for hot press forming.
  • the present invention relates to a hot press-formed product that can be provided with a prescribed shape and at the same time heat treated to have prescribed strength when a preheated steel sheet (blank) is formed into the prescribed shape, a process for producing such a hot press-formed product, and a thin steel sheet for hot press forming.
  • a hot press-forming method for production of parts, in which method a steel sheet is heated to a prescribed temperature (e.g., a temperature for change in austenite phase) to lower its strength (i.e., make it easily formable) and then formed with a press tool at a temperature (e.g., room temperature) lower than that of the thin steel sheet, whereby the steel sheet is provided with a shape and at the same time heat treated by rapid cooling (quenching), which makes use of a temperature difference between both, to secure its strength after forming.
  • a prescribed temperature e.g., a temperature for change in austenite phase
  • a press tool at a temperature (e.g., room temperature) lower than that of the thin steel sheet
  • a steel sheet is formed in a state of low strength, and therefore, the steel sheet has decreased springback (favorable shape fixability).
  • Such a hot press-forming method has been called with various names, in addition to a hot press method, such as a hot forming method, a hot stamping method, a hot stamp method, and a die quench method.
  • FIG. 1 is a schematic explanatory view showing the structure of a press tool for carrying out hot press forming as described above (hereinafter represented sometimes by “hot stamp”).
  • reference numerals 1 , 2 , 3 , and 4 represent a punch, a die, a blank holder, and a steel sheet (blank), respectively
  • abbreviations BHF, rp, rd, and CL represent a blank holding force, a punch shoulder radius, a die shoulder radius, and a clearance between the punch and the die, respectively.
  • punch 1 and die 2 have passage 1 a and passage 2 a , respectively, formed in the inside thereof, through which passages a cooling medium (e.g., water) can be allowed to pass, and the press tool is made to have a structure so that these members can be cooled by allowing the cooling medium to pass through these passages.
  • a cooling medium e.g., water
  • the forming is started in a state where steel sheet (blank) 4 is softened by heating to a temperature within single-phase region, which is not lower than Acs transformation point. More specifically, steel sheet 4 is pushed into a cavity of die 2 (between the parts indicated by reference numerals 2 and 2 in FIG. 1 ) by punch 1 with steel sheet 4 in high-temperature state being sandwiched between die 2 and blank holder 3 , thereby forming steel sheet 4 into a shape corresponding to the outer shape of punch 1 while reducing the outer diameter of steel sheet 4 .
  • hot stamp e.g., hot deep drawing
  • steel sheets for hot stamp which have widely been used at present, there are known steel sheets based on 22MnB5 steel. These steel sheets have tensile strengths of 1500 MPa and elongations of about 6% to 8%, and have been applied to impact-resistant members (members neither deformed nor fractured as much as possible at the time of impact). In addition, some developments have also proceeded for C content increase and further highly strengthening (in 1500 to 1800 MPa class) based on 22MnB5 steel.
  • both functions as an impact-resistant portion and an energy-absorbing portion may sometimes be provided in parts such as B pillars or rear side members.
  • To produce such members there has mainly been used so far, for example, a method in which ultra-high tensile strength steel sheets having high strength of 980 MPa class and high tensile strength steel sheets having elongation of 440 MPa class are laser welded (to prepare a tailor welded blank, abbreviated as TWB) and then cold press formed.
  • TWB tailor welded blank
  • Non-patent Document 1 has proposed a method of laser welding 22MnB5 steel for hot stamp and a material that does not have high strength even if quenched with a press tool (to prepare a tailor welded blank, abbreviated as TWB), followed by hot stamp, in which method different strengths are provided so that tensile strength at a high strength side (i.e., impact-resistant portion side) becomes 1500 MPa (and elongation becomes 6% to 8%) and tensile strength at a low strength side (i.e., energy-absorbing portion side) becomes 440 MPa (and elongation becomes 12%).
  • some techniques have also been proposed, such as disclosed in Non-patent Documents 2 to 4.
  • Non-patent Documents 1 and 2 provide a tensile strength of not higher than 600 MPa and an elongation of about 12% to 18% at an energy-absorbing portion side, in which techniques, however, laser welding (to prepare a tailor welded blank, abbreviated as TWB) is needed previously, thereby increasing the number of steps and resulting in high cost. In addition, it results in the heating of energy-absorbing portions, which need not to be hardened originally. Therefore, these techniques are not preferred from the viewpoint of energy consumption.
  • Non-patent Document 3 is based on 22MnB5 steel, in which boron addition, however, adversely affects the robustness of strength after quenching against heating to a temperature within two-phase region, making difficult the control of strength at an energy-absorbing portion side, and further making it possible to obtain only an elongation as low as 15%.
  • Non-patent Document 4 is based on 22MnB5 steel, and therefore, this technique is not economic in that control is made in such a manner that 22MnB5, which originally has excellent hardenability, is not hardened (control of press tool cooling).
  • the present invention has been made in view of the above-described circumstances, and its object is to provide a hot press-formed product in which balance between strength and elongation can be controlled in a proper range and high ductility can be achieved, a process useful for producing such a hot press-formed product, and a thin steel sheet for hot press forming.
  • the hot press-formed product of the present invention which can achieve the above object, is a hot press-formed product, characterized by comprising a thin steel sheet formed by a hot press-forming method, and having a metallic structure that contains martensite at 80% to 97% by area and retained austenite at 3% to 20% by area, the remainder structure of which is at 5% by area or lower.
  • the chemical element composition thereof is not particularly limited, typical examples of which may include the following chemical element composition: C at 0.15% to 0.35% (where “%” means “% by mass”, and the same applies to the below with respect to the chemical element composition); Si at 0.5% to 3%; Mn at 0.5% to 2%; P at 0.05% or lower (not including 0%); S at 0.05% or lower (not including 0%); Al at 0.01% to 0.1%; Cr at 0.01% to 1%; B at 0.0002% to 0.01%; Ti at (N content) ⁇ 4% to 0.1%; and N at 0.001% to 0.01%, and the remainder consisting of iron and unavoidable impurities.
  • the hot press-formed product of the present invention it is also useful to allow additional elements to be contained, when needed; for example, (a) one or more selected from the group consisting of Cu, Ni, and Mo at 1% or lower (not including 0%) in total; and (b) V and/or Nb at 0.1% or lower (not including 0%) in total.
  • the hot press-formed product may have further improved characteristics.
  • the following steps may be used, i.e., heating a thin steel sheet to a temperature not lower than Acs transformation point and not higher than 1000° C.; and then starting the forming of the thin steel sheet with a press tool to produce the hot press-formed product, during which forming an average cooling rate of 20° C./sec or higher is kept in the press tool, and which forming is finished at a temperature not higher than (martensite transformation starting temperature Ms point ⁇ 50° C.).
  • the present invention further includes a thin steel sheet for hot press forming, which is intended for producing a hot press-formed product as described above, and this thin steel sheet is characterized by having a chemical element composition as described above.
  • the present invention makes it possible that: retained austenite can be allowed to exist at a proper fraction to adjust the metallic structure of a hot press-formed product by properly controlling the conditions of a hot press-forming method; a hot press-formed product having more enhanced ductility (retained ductility) inherent to the formed product as compared with the case where conventional 22MnB5 steel is used; and strength and elongation can be controlled by a combination of heat treatment conditions and pre-forming steel sheet structure (initial structure).
  • FIG. 1 is a schematic explanatory view showing the structure of a press tool for carrying out hot press forming.
  • the present inventors have studied from various angles to realize a hot press-formed product having high strength and further exhibiting excellent ductility (elongation) after forming when a thin steel sheet is heated to a prescribed temperature and then hot press formed to produce the formed product.
  • a hot press-formed product having excellent balance between strength and ductility can be achieved when heating temperature and forming conditions are properly controlled so that its structure is adjusted to contain retained austenite at 3% to 20% by area in the press forming of a thin steel sheet with a press tool to produce the hot press-formed product, thereby completing the present invention.
  • Strength of a hot press-formed product can be secured by making its structure composed mainly of high-strength martensite.
  • the area fraction of martensite should be controlled to 80% by area or higher. However, when this fraction is higher than 97% by area, the faction of retained austenite becomes insufficient, resulting in the lowering of ductility (retained ductility).
  • the fraction of martensite may preferably be not lower than 83% by area as the preferred lower limit (more preferably not lower than 85% by area) and not higher than 95% by area as the preferred upper limit (more preferably not higher than 93% by area).
  • Retained austenite is transformed into martensite during plastic deformation, thereby having the effect of increasing work hardening rate (transformation-inducing plasticity) to improve the ductility of a formed product.
  • the fraction of retained austenite should be controlled to 3% by area or higher. When the fraction of retained austenite is higher, ductility becomes more excellent. In a composition to be used for automobile steel sheets, retained austenite that can be secured is limited, of which upper limit becomes about 20% by area.
  • the fraction of retained austenite may preferably be not lower than 5% by area as the preferred lower limit (more preferably not lower than 7% by area) and not higher than 17% by area as the preferred upper limit (more preferably not higher than 15% by area or not higher than 10% by area).
  • the metallic structure of a hot press-formed product may contain ferrite, pearlite, and/or bainite as the remainder structure, but may preferably contain the remainder structure as low as possible, because these structures are softer than martensite and have lower contributions to strength as compared with the other structures.
  • the fraction of the remainder structure up to 5% by area may be acceptable.
  • the fraction of the remainder structure may more preferably be not higher than 3% by area, still more preferably 0% by area.
  • a thin steel sheet may be used (which has the same chemical element composition as that of the hot press-formed product), and when the thin steel sheet is press formed with a press tool, the thin steel sheet may be heated to a temperature not lower than Ac 3 transformation point and not higher than 1000° C., and then the forming of the thin steel sheet may be started, during which forming an average cooling rate of 20° C./sec or higher may be kept in the press tool, and which forming may be finished at a temperature not higher than (martensite transformation starting temperature Ms point ⁇ 50° C.).
  • the reasons for defining the respective requirements in this process are as follows:
  • the heating temperature should be controlled in a prescribed range.
  • the proper control of the heating temperature makes it possible to cause transformation into a structure composed mainly of martensite while securing a prescribed fraction of retained austenite in the subsequent cooling step to provide the final hot press-formed product with a desired structure.
  • the heating temperature of the thin steel sheet is lower than Acs transformation point, a sufficient fraction of austenite cannot be obtained during heating, and therefore, a prescribed fraction of retained austenite cannot be secured in the final structure (the structure of a formed product).
  • the average cooling rate during forming and the forming finishing temperature should properly be controlled.
  • the average cooling rate during forming should be controlled to 20° C./sec or higher, and the forming finishing temperature should be controlled to a temperature not higher than (martensite transformation starting temperature Ms point ⁇ 50° C., sometimes abbreviated as “Ms point ⁇ 50° C.”).
  • Ms point ⁇ 50° C. martensite transformation starting temperature Ms point ⁇ 50° C.
  • the average cooling rate during forming may preferably be 30° C./sec or higher (more preferably 40° C./sec or higher).
  • the forming may be finished while cooling to room temperature at an average cooling rate as described above.
  • cooling may be carried out to (Ms point ⁇ 50° C.) or lower (preferably to a temperature of Ms point ⁇ 50° C.), and then cooling may further be carried out to 200° C. or lower at an average cooling rate of lower than 20° C./sec (two-step cooling).
  • the addition of such cooling steps makes it possible that carbon in martensite is concentrated in untransformed austenite, thereby increasing the fraction of retained austenite.
  • the average cooling rate during cooling as the second step when such two-step cooling is carried out may preferably be 10° C./sec or lower (more preferably 5° C./sec or lower).
  • the control of the average cooling temperature during forming can be achieved by a means of, for example, (a) controlling the temperature of a press tool (using a cooling medium shown in FIG. 1 above) or (b) controlling the thermal conductivity of a press tool.
  • the hot press-forming method of the present invention can be applied, not only to the case where a hot press-formed product having a simple shape as shown in FIG. 1 above is produced (i.e., direct method), but also to the case where a formed product having a relatively complicated shape is produced.
  • direct method a method of cold press forming in a step prior to hot press forming
  • This method includes previously forming a difficult-to-form portion into an approximate shape by cold processing and then hot press forming the other portions.
  • the present invention is intended for a hot press-formed product made of a high-strength steel sheet, the steel grade of which is acceptable, if it has an ordinary chemical element composition as a high-strength steel sheet, in which, however, C, Si, Mn, P, S, Al, Cr, B, Ti, and N contents may preferably be controlled in their respective proper ranges.
  • C, Si, Mn, P, S, Al, Cr, B, Ti, and N contents may preferably be controlled in their respective proper ranges.
  • the preferred ranges of these chemical elements and the grounds for limiting their ranges are as follows:
  • C is an important element for controlling the strength of martensite structure.
  • C content When C content is decreased, the strength becomes insufficient even if the structure is full of martensite.
  • C content When C content is less than 0.15%, the strength of martensite becomes insufficient, and therefore, high strength of a hot press-formed product cannot be secured.
  • C content When C content becomes higher than 0.35%, it results in that strength becomes too high, thereby making it impossible to obtain excellent ductility.
  • C content may more preferably be not lower than 0.18% as the more preferred lower limit (still more preferably not lower than 0.20%) and not higher than 0.30% as the more preferred upper limit (still more preferably not higher than 0.27%, and further still more preferably not higher than 0.25%).
  • Si exhibits the action of forming retained austenite during quenching. It further exhibits the action of enhancing strength by solid solution enhancement without deteriorating ductility too much.
  • Si content is less than 0.5%, retained austenite cannot be secured at a prescribed fraction, making it impossible to obtain excellent ductility.
  • Si content becomes more than 3%, the degree of solid solution enhancement becomes too high, resulting in the drastic deterioration of ductility.
  • Si content may more preferably be not lower than 1.15% as the more preferred lower limit (still more preferably not lower than 1.20%) and not higher than 2.7% as the more preferred upper limit (still more preferably not higher than 2.5%).
  • Mn is an element to stabilize austenite, and it contributes to an increase of retained austenite. It enhances hardenability, and therefore, it is an element to prevent the formation of ferrite, pearlite, and bainite, during cooling after heating, thereby contributing to the securement of retained austenite.
  • Mn may preferably be contained at 0.5% or higher. Mn content may be preferred when it is higher, in the case where only characteristics are taken into consideration, but Mn content may preferably be controlled to 2% or lower, because of a cost increase by alloy element addition.
  • Mn is contained at higher than 2%.
  • Mn content may more preferably be not lower than 0.7% as the more preferred lower limit (still more preferably not lower than 0.9%) and not higher than 1.8% as the more preferred higher limit (still more preferably not higher than 1.6%).
  • P is an element unavoidably contained in steel and deteriorates ductility. Therefore, P content may preferably be reduced as low as possible. However, extreme reduction causes an increase of steel production cost, and reduction to 0% is difficult in the actual production. Therefore, P content may more preferably be controlled to 0.05% or lower (not including 0%). P content may more preferably be not higher than 0.045% as the more preferred upper limit (still more preferably not higher than 0.040%).
  • S is also an element unavoidably contained in steel and deteriorates ductility, similarly to P. Therefore, S content may preferably be reduced as low as possible. However, extreme reduction causes an increase of steel production cost, and reduction to 0% is difficult in the actual production. Therefore, S content may preferably be controlled to 0.05% or lower (not including 0%). S content may more preferably be not higher than 0.045% as the more preferred upper limit (still more preferably not higher than 0.040%).
  • Al is useful as a deoxidizing element and further useful for fixation of dissolved N in steel as AlN to improve ductility.
  • Al content may preferably be controlled to 0.01% or higher. However, when Al content becomes higher than 0.1%, it results in the excessive formation of Al 2 O 3 to deteriorate ductility.
  • Al content may more preferably be not lower than 0.013% as the more preferred lower limit (still more preferably not lower than 0.015%) and not higher than 0.08% as the more preferred upper limit (still more preferably not higher than 0.06%).
  • Cr has the action of suppressing ferrite transformation, pearlite transformation, and bainite transformation, and therefore, it is an element to prevent the formation of ferrite, pearlite, and bainite, during cooling after heating, thereby contributing to the securement of retained austenite.
  • Cr may preferably be contained at 0.01% or higher. Even if Cr is contained at higher than 1%, it results in a cost increase.
  • Cr content may more preferably be not lower than 0.02% as the more preferred lower limit (still more preferably not lower than 0.05%) and not higher than 0.8% as the more preferred higher limit (still more preferably not higher than 0.5%).
  • B has the action of enhancing hardenability and suppressing ferrite transformation, pearlite transformation, and bainite transformation, and therefore, it is an element to prevent the formation of ferrite, pearlite, and bainite, during cooling after heating, thereby contributing to the securement of retained austenite.
  • B may preferably be contained at 0.0002% or higher, but even if B is contained beyond 0.01%, the effect is saturated.
  • B content may more preferably be not lower than 0.0003% as the more preferred lower limit (still more preferably not lower than 0.0005%) and not higher than 0.008% as the more preferred upper limit (still more preferably not higher than 0.005%).
  • Ti fixes N and maintains B in solid solution state, thereby exhibiting the effect of improving hardenability.
  • Ti may preferably be contained at least 4 times higher than N content.
  • Ti content may more preferably be not lower than 0.05% as the more preferred lower limit (still more preferably not lower than 0.06%) and not higher than 0.09% as the more preferred higher limit (still more preferably not higher than 0.08%).
  • N is an element to fix B as BN, thereby lowering the effect of hardenability improvement, and a reduction of N content as low as possible may be preferred, which has, however, a limitation in actual process. Therefore, the lower limit of N content was set to 0.001%. When N content becomes excessive, it results in the formation of coarse TiN, which becomes the origin of fracture, thereby deteriorating ductility. Therefore, the upper limit of N content was set to 0.01%. N content may more preferably be not higher than 0.008% as the more preferred upper limit (still more preferably not higher than 0.006%).
  • the basic chemical components in the press-formed product of the present invention are as described above, and the remainder consists essentially of iron.
  • the wording “consists essentially of iron” means that the press-formed product of the present invention can contain, in addition to iron, minor components (e.g., besides Mg, Ca, Sr, and Ba, REM such as La, and carbide-forming elements such as Zr, Hf, Ta, W, and Mo) in such a level that these minor components do not inhibit the characteristics of the steel sheet of the present invention, and can further contain unavoidable impurities (e.g., O, H) other than P and S.
  • minor components e.g., besides Mg, Ca, Sr, and Ba, REM such as La
  • carbide-forming elements such as Zr, Hf, Ta, W, and Mo
  • the press-formed product of the present invention may contain additional elements, when needed; for example, (a) one or more selected from the group consisting of Cu, Ni, and Mo at 1% or lower (not including 0%) in total; and (b) V and/or Nb at 0.1% or lower (not including 0%) in total.
  • the hot press-formed product may have further improved characteristics depending on the kinds of elements contained. When these elements are contained, their preferred ranges and grounds for limitation of their ranges are as follows:
  • these elements may preferably be contained at 0.01% or higher in total. Taking only characteristics into consideration, their content may be preferable when it is higher, but may preferably be controlled to 1% or lower in total because of a cost increase by alloy element addition. In addition, these elements have the action of considerably enhancing the strength of austenite, thereby increasing a hot rolling load so that the production of steel sheets becomes difficult. Therefore, even from the viewpoint of productivity, their content may preferably be controlled to 1% or lower. These elements' content may more preferably be not lower than 0.05% as the more preferred lower limit (still more preferably not lower than 0.06%) in total and not higher than 0.9% as the more preferred upper limit (still more preferably not higher than 0.8%) in total.
  • V and Nb have the effect of forming fine carbide and make structure fine by pinning effect.
  • these elements may preferably be contained at 0.001% or higher in total.
  • these elements' content may preferably be controlled to 0.1% or lower in total.
  • These elements' content may more preferably be not lower than 0.005% as the more preferred lower limit (still more preferably not lower than 0.008%) in total and not higher than 0.08% as the more preferred upper limit (still more preferably not higher than 0.06%) in total.
  • the thin steel sheet for hot press forming of the present invention may be either a non-plated steel sheet or a plated steel sheet.
  • the type of plating may be either ordinary galvanization or aluminium coating.
  • the method of plating may be either hot-dip plating or electroplating. After the plating, alloying heat treatment may be carried out, or additional plating may be carried out as multilayer plating.
  • the characteristics of formed products can be controlled by properly adjusting press forming conditions (heating temperature and cooling rate), and in addition, hot press-formed products having high ductility (retained ductility) can be obtained, so that they can be applied even to parts (e.g., energy-absorbing members), to which conventional hot press-formed products have hardly been applied; therefore, the present invention is extremely useful for extending the application range of hot press-formed products.
  • the formed products, which can be obtained in the present invention have further enhanced residual ductility as compared with formed products, of which structure was adjusted by ordinary annealing after cold press forming.
  • the steel sheets thus obtained were heated under the respective conditions shown in Table 2 below, and then subjected to cooling treatment using a high speed heat treatment testing system for steel sheets (CAS series, available from ULVAC-RIKO, Inc.), which can control an average cooling rate.
  • the steel sheets to be subjected to forming and cooling treatment had a size of 190 mm ⁇ 70 mm (and a sheet thickness of 1.4 mm).
  • Cooling rates 1 and 2 shown in Table 2 indicate an average cooling rate from heating temperature to (Ms point ⁇ 50° C.) or lower (forming finishing temperature), and an average cooling rate from the forming finishing temperature to 200° C. or lower, respectively.
  • the steel sheet is subjected to hot-dip galvanization to obtain a hot-dip galvanized steel sheet (Test No. 21).
  • JIS No. 5 specimens were used for tensile tests to measure tensile strength (TS) and elongation (EL). At that time, strain rate in the tensile tests was set to 10 mm/sec. In the present invention, the specimens were evaluated as “passing” when fulfilling the condition (a): tensile strength (TS) is 1470 MPa and elongation (EL) is 9% or higher.
  • the steel sheets were each measured by an X-ray diffraction method, after grinding to one-quarter thicknesses of the steel sheets and subsequent chemical polishing (see, e.g., ISJJ Int. Vol. 33 (1933), No. 7, p. 776).
  • Test Nos. 1, 2, 6, 11, 12, and 14 to 21 are Examples fulfilling the requirements defined in the present invention, thereby indicating that parts having satisfactory balance between strength and ductility were obtained.
  • Test No. 6 indicates that parts having extremely high strength and further exhibiting excellent ductility were obtained.
  • Test Nos. 3 to 5, 7 to 10, and 13 are Comparative Examples not fulfilling any of the requirements defined in the present invention, thereby deteriorating any of the characteristics. More specifically, Test No. 3 was the case where cooling rate after heating was low, so that the fraction of martensite was not secured (ferrite and bainitic ferrite were formed), thereby failing to secure strength. Test No. 4 was the case where heating temperature was lower than Acs transformation point, so that the fraction of martensite was not secured, thereby failing to secure strength.
  • Test No. 5 was the case in which forming was finished at Ms point or higher, so that the fraction of martensite was not secured (bainitic ferrite was formed), thereby failing to secure strength.
  • Test Nos. 7 and 8 were intended for conventional 22MnB5 equivalent steel (steel grade C shown in Table 1), so that retained austenite was not secured, thereby obtaining only low elongation (EL), although high strength was obtained.
  • Test No. 9 was the case where steel free of Ti and B (steel grade shown in Table 1) was used, so that the fraction of martensite was not secured, thereby failing to secure strength.
  • Test No. 10 was the case where steel short of C content (steel grade E shown in Table 1) was used, so that retained austenite was not secured, thereby obtaining low elongation (EL).
  • Test No. 13 was the case where steel free of Cr (steel grade H shown in Table 1) was used, so that the fraction of martensite and strength was not secured, thereby failing to secure strength.
  • the present invention makes it possible to provide a hot press-formed product, including a thin steel sheet formed by a hot press-forming method, and having a metallic structure that contains martensite at 80% to 97% by area and retained austenite at 3% to 20% by area, the remainder structure of which is at 5% by area or lower, whereby balance between strength and elongation can be controlled in a proper range and high ductility can be achieved.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Shaping Metal By Deep-Drawing, Or The Like (AREA)
  • Heat Treatment Of Articles (AREA)
  • Heat Treatment Of Sheet Steel (AREA)
US14/114,715 2011-06-10 2012-06-08 Hot press-formed product, process for producing same, and thin steel sheet for hot press forming Abandoned US20140065007A1 (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
JP2011130635 2011-06-10
JP2011-130635 2011-06-10
JP2011-208032 2011-09-22
JP2011208032 2011-09-22
PCT/JP2012/064851 WO2012169640A1 (ja) 2011-06-10 2012-06-08 熱間プレス成形品、その製造方法および熱間プレス成形用薄鋼板

Publications (1)

Publication Number Publication Date
US20140065007A1 true US20140065007A1 (en) 2014-03-06

Family

ID=47296192

Family Applications (1)

Application Number Title Priority Date Filing Date
US14/114,715 Abandoned US20140065007A1 (en) 2011-06-10 2012-06-08 Hot press-formed product, process for producing same, and thin steel sheet for hot press forming

Country Status (7)

Country Link
US (1) US20140065007A1 (de)
EP (1) EP2719788B1 (de)
JP (1) JP5873393B2 (de)
KR (1) KR20140027451A (de)
CN (1) CN103620075B (de)
ES (1) ES2603590T3 (de)
WO (1) WO2012169640A1 (de)

Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3020845A1 (de) * 2013-09-18 2016-05-18 Nippon Steel & Sumitomo Metal Corporation Heissgestanzter formkörper und verfahren zur herstellung davon
JP2016125099A (ja) * 2015-01-05 2016-07-11 セイコーエプソン株式会社 粉末冶金用金属粉末、コンパウンド、造粒粉末および焼結体
US9761846B2 (en) 2013-01-11 2017-09-12 Futaba Industrial Co., Ltd. Battery case
EP3199257A4 (de) * 2014-09-25 2017-12-06 JFE Steel Corporation Verfahren zur herstellung eines heisspressgeformten teils und heisspressgeformtes teil
EP3282030A4 (de) * 2015-04-08 2018-09-12 Nippon Steel & Sumitomo Metal Corporation Wärmebehandeltes stahlblechelement und herstellungsverfahren dafür
US10385415B2 (en) 2016-04-28 2019-08-20 GM Global Technology Operations LLC Zinc-coated hot formed high strength steel part with through-thickness gradient microstructure
US10392677B2 (en) 2014-10-24 2019-08-27 Jfe Steel Corporation High-strength hot-pressed part and method for manufacturing the same
EP3366797B1 (de) * 2015-10-19 2019-12-18 JFE Steel Corporation Verfahren zur herstellung eines heisspresselement
US10619223B2 (en) 2016-04-28 2020-04-14 GM Global Technology Operations LLC Zinc-coated hot formed steel component with tailored property
CN111332367A (zh) * 2018-12-18 2020-06-26 通用汽车环球科技运作有限责任公司 加压硬化焊接钢合金部件
US10822680B2 (en) 2015-04-08 2020-11-03 Nippon Steel Corporation Steel sheet for heat treatment
US10858718B2 (en) 2016-03-29 2020-12-08 Jfe Steel Corporation Steel sheet for hot press and method of manufacturing same, and hot-press forming part and method of manufacturing same
EP3760755A4 (de) * 2018-03-27 2021-10-27 Kabushiki Kaisha Kobe Seiko Sho (Kobe Steel, Ltd.) Stahlplatte für heissprägen
US11203796B2 (en) 2015-12-23 2021-12-21 Posco Ultra high strength hot-rolled steel sheet having excellent ductility and method for manufacturing same
US11293075B2 (en) 2016-03-29 2022-04-05 Jfe Steel Corporation Hot-press forming part and method of manufacturing same
US11530469B2 (en) 2019-07-02 2022-12-20 GM Global Technology Operations LLC Press hardened steel with surface layered homogenous oxide after hot forming
US11613789B2 (en) 2018-05-24 2023-03-28 GM Global Technology Operations LLC Method for improving both strength and ductility of a press-hardening steel
US11612926B2 (en) 2018-06-19 2023-03-28 GM Global Technology Operations LLC Low density press-hardening steel having enhanced mechanical properties

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9315876B2 (en) * 2010-09-30 2016-04-19 Kobe Steel, Ltd. Press-formed product and method for producing same
KR101108838B1 (ko) * 2011-06-30 2012-01-31 현대하이스코 주식회사 충돌성능이 우수한 열처리 경화강 및 이를 이용한 열처리 경화형 부품 제조 방법
JP6001883B2 (ja) 2012-03-09 2016-10-05 株式会社神戸製鋼所 プレス成形品の製造方法およびプレス成形品
JP6001884B2 (ja) * 2012-03-09 2016-10-05 株式会社神戸製鋼所 プレス成形品の製造方法およびプレス成形品
JP5890711B2 (ja) 2012-03-15 2016-03-22 株式会社神戸製鋼所 熱間プレス成形品およびその製造方法
JP5890710B2 (ja) 2012-03-15 2016-03-22 株式会社神戸製鋼所 熱間プレス成形品およびその製造方法
JP5942841B2 (ja) * 2012-12-21 2016-06-29 新日鐵住金株式会社 強度と耐水素脆性に優れたホットスタンプ成形体及びホットスタンプ成形体の製造方法
JP6073154B2 (ja) * 2013-02-21 2017-02-01 株式会社神戸製鋼所 熱間プレス成形品の製造方法
CA2923583A1 (en) * 2013-09-10 2015-03-19 Kabushiki Kaisha Kobe Seiko Sho (Kobe Steel, Ltd.) Hot-pressing steel plate, press-molded article, and method for manufacturing press-molded article
EP3045550A4 (de) * 2013-09-10 2017-05-31 Kabushiki Kaisha Kobe Seiko Sho (Kobe Steel, Ltd.) Verfahren zur herstellung pressgeformter artikel und pressgeformter artikel
CN105518171B (zh) * 2013-09-10 2017-04-05 株式会社神户制钢所 热压用钢板和冲压成形品、以及冲压成形品的制造方法
KR101677351B1 (ko) * 2014-12-26 2016-11-18 주식회사 포스코 재질 편차가 적고, 조관성 및 내식성이 우수한 열간 프레스 성형용 열연강판, 이를 이용한 열간 프레스 성형품 및 이들의 제조방법
JP6168118B2 (ja) 2015-10-19 2017-07-26 Ｊｆｅスチール株式会社 ホットプレス部材およびその製造方法
JP2019534381A (ja) * 2016-10-03 2019-11-28 エーケー スティール プロパティ−ズ、インク． 高伸長プレス硬化鋼及びその製造
US20180216205A1 (en) * 2017-01-27 2018-08-02 GM Global Technology Operations LLC Two-step hot forming of steels
KR20230128107A (ko) * 2021-02-10 2023-09-01 닛폰세이테츠 가부시키가이샤 핫 스탬프 성형체
WO2023171492A1 (ja) * 2022-03-11 2023-09-14 日本製鉄株式会社 ホットスタンプ成形体

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2855392B2 (ja) * 1993-02-22 1999-02-10 新日本製鐵株式会社 冷間圧延板
EP2267176A1 (de) * 2008-02-08 2010-12-29 JFE Steel Corporation Hochfestes heissverzinktes stahlblech mit hervorragender verarbeitbarkeit und herstellungsverfahren dafür
WO2011013845A1 (ja) * 2009-07-30 2011-02-03 Ｊｆｅスチール株式会社 高強度鋼板およびその製造方法

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2847270B1 (fr) * 2002-11-19 2004-12-24 Usinor Procede pour fabriquer une tole en acier resistant a l'abrasion et tole obtenue
JP4325277B2 (ja) * 2003-05-28 2009-09-02 住友金属工業株式会社 熱間成形法と熱間成形部材
JP4673558B2 (ja) * 2004-01-26 2011-04-20 新日本製鐵株式会社 生産性に優れた熱間プレス成形方法及び自動車用部材
JP5177119B2 (ja) * 2004-10-29 2013-04-03 新日鐵住金株式会社 熱間プレス用鋼板
JP4513608B2 (ja) * 2004-10-29 2010-07-28 住友金属工業株式会社 熱間プレス鋼板部材、その製造方法
JP4575799B2 (ja) * 2005-02-02 2010-11-04 新日本製鐵株式会社 成形性に優れたホットプレス高強度鋼製部材の製造方法
JP4630188B2 (ja) * 2005-12-19 2011-02-09 株式会社神戸製鋼所 スポット溶接部の接合強度および熱間成形性に優れた熱間成形用鋼板並びに熱間成形品
KR101504370B1 (ko) * 2007-02-23 2015-03-19 타타 스틸 이즈무이덴 베.뷔. 초고강도를 갖는 최종 제품을 열가공 정형하는 방법 및 이에 의해 제조된 제품
JP5277658B2 (ja) * 2008-02-19 2013-08-28 新日鐵住金株式会社 熱間プレス部材の製造方法
KR101010971B1 (ko) * 2008-03-24 2011-01-26 주식회사 포스코 저온 열처리 특성을 가지는 성형용 강판, 그 제조방법,이를 이용한 부품의 제조방법 및 제조된 부품
JP5257062B2 (ja) * 2008-12-25 2013-08-07 新日鐵住金株式会社 靭性及び耐水素脆化特性に優れた高強度ホットスタンピング成形品及びその製造方法
EP2374910A1 (de) * 2010-04-01 2011-10-12 ThyssenKrupp Steel Europe AG Stahl, Stahlflachprodukt, Stahlbauteil und Verfahren zur Herstellung eines Stahlbauteils
JP5598157B2 (ja) * 2010-08-20 2014-10-01 新日鐵住金株式会社 耐遅れ破壊特性及び衝突安全性に優れたホットプレス用鋼板及びその製造方法
KR101253885B1 (ko) * 2010-12-27 2013-04-16 주식회사 포스코 연성이 우수한 성형 부재용 강판, 성형 부재 및 그 제조방법

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2855392B2 (ja) * 1993-02-22 1999-02-10 新日本製鐵株式会社 冷間圧延板
EP2267176A1 (de) * 2008-02-08 2010-12-29 JFE Steel Corporation Hochfestes heissverzinktes stahlblech mit hervorragender verarbeitbarkeit und herstellungsverfahren dafür
WO2011013845A1 (ja) * 2009-07-30 2011-02-03 Ｊｆｅスチール株式会社 高強度鋼板およびその製造方法
US20120175028A1 (en) * 2009-07-30 2012-07-12 Jfe Steel Corporation High strength steel sheet and method for manufacturing the same

Cited By (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9761846B2 (en) 2013-01-11 2017-09-12 Futaba Industrial Co., Ltd. Battery case
US10301699B2 (en) 2013-09-18 2019-05-28 Nippon Steel & Sumitomo Metal Corporation Hot-stamped part and method of manufacturing the same
EP3020845A4 (de) * 2013-09-18 2017-04-05 Nippon Steel & Sumitomo Metal Corporation Heissgestanzter formkörper und verfahren zur herstellung davon
EP3020845A1 (de) * 2013-09-18 2016-05-18 Nippon Steel & Sumitomo Metal Corporation Heissgestanzter formkörper und verfahren zur herstellung davon
EP3199257A4 (de) * 2014-09-25 2017-12-06 JFE Steel Corporation Verfahren zur herstellung eines heisspressgeformten teils und heisspressgeformtes teil
US10392677B2 (en) 2014-10-24 2019-08-27 Jfe Steel Corporation High-strength hot-pressed part and method for manufacturing the same
JP2016125099A (ja) * 2015-01-05 2016-07-11 セイコーエプソン株式会社 粉末冶金用金属粉末、コンパウンド、造粒粉末および焼結体
EP3282030A4 (de) * 2015-04-08 2018-09-12 Nippon Steel & Sumitomo Metal Corporation Wärmebehandeltes stahlblechelement und herstellungsverfahren dafür
US11041225B2 (en) * 2015-04-08 2021-06-22 Nippon Steel Corporation Heat-treated steel sheet member and method for producing the same
US10822680B2 (en) 2015-04-08 2020-11-03 Nippon Steel Corporation Steel sheet for heat treatment
EP3366797B1 (de) * 2015-10-19 2019-12-18 JFE Steel Corporation Verfahren zur herstellung eines heisspresselement
US11203796B2 (en) 2015-12-23 2021-12-21 Posco Ultra high strength hot-rolled steel sheet having excellent ductility and method for manufacturing same
US11293075B2 (en) 2016-03-29 2022-04-05 Jfe Steel Corporation Hot-press forming part and method of manufacturing same
US10858718B2 (en) 2016-03-29 2020-12-08 Jfe Steel Corporation Steel sheet for hot press and method of manufacturing same, and hot-press forming part and method of manufacturing same
US10619223B2 (en) 2016-04-28 2020-04-14 GM Global Technology Operations LLC Zinc-coated hot formed steel component with tailored property
US10385415B2 (en) 2016-04-28 2019-08-20 GM Global Technology Operations LLC Zinc-coated hot formed high strength steel part with through-thickness gradient microstructure
EP3760755A4 (de) * 2018-03-27 2021-10-27 Kabushiki Kaisha Kobe Seiko Sho (Kobe Steel, Ltd.) Stahlplatte für heissprägen
US11613789B2 (en) 2018-05-24 2023-03-28 GM Global Technology Operations LLC Method for improving both strength and ductility of a press-hardening steel
US11612926B2 (en) 2018-06-19 2023-03-28 GM Global Technology Operations LLC Low density press-hardening steel having enhanced mechanical properties
US11951522B2 (en) 2018-06-19 2024-04-09 GM Global Technology Operations LLC Low density press-hardening steel having enhanced mechanical properties
CN111332367A (zh) * 2018-12-18 2020-06-26 通用汽车环球科技运作有限责任公司 加压硬化焊接钢合金部件
US11530469B2 (en) 2019-07-02 2022-12-20 GM Global Technology Operations LLC Press hardened steel with surface layered homogenous oxide after hot forming

Also Published As

Publication number Publication date
EP2719788B1 (de) 2016-11-02
EP2719788A1 (de) 2014-04-16
WO2012169640A1 (ja) 2012-12-13
CN103620075B (zh) 2016-02-17
CN103620075A (zh) 2014-03-05
ES2603590T3 (es) 2017-02-28
EP2719788A4 (de) 2015-10-21
JP5873393B2 (ja) 2016-03-01
KR20140027451A (ko) 2014-03-06
JP2013079441A (ja) 2013-05-02

Similar Documents

Publication Publication Date Title
US9475113B2 (en) Process for producing hot press-formed product
EP2719788B1 (de) Heissgepresster formartikel, herstellungsverfahren dafür und dünnes stahlblech zum heisspressen
US9475112B2 (en) Hot press-formed product and process for producing same
EP2719787B1 (de) Heissgepresster formartikel, herstellungsverfahren dafür und dünnes stahlblech zum heisspressen
US9850554B2 (en) Hot-press formed product and method for manufacturing same
US9611518B2 (en) Hot-press formed product and method for manufacturing same
KR101609967B1 (ko) 열간 프레스용 강판 및 프레스 성형품, 및 프레스 성형품의 제조 방법
US20190241988A1 (en) Hot-pressing steel plate, press-molded article, and method for manufacturing press-molded article
KR101609968B1 (ko) 열간 프레스용 강판 및 프레스 성형품, 및 프레스 성형품의 제조 방법
KR101716624B1 (ko) 프레스 성형품의 제조 방법 및 프레스 성형품
KR20140119811A (ko) 프레스 성형품의 제조 방법 및 프레스 성형품
JP2004124123A (ja) 加工性と形状凍結性に優れた低降伏比型高強度冷延鋼板及びその製造方法

Legal Events

Date Code Title Description
AS Assignment

Owner name: KABUSHIKI KAISHA KOBE SEIKO SHO (KOBE STEEL, LTD.)

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:NAITOU, JUNYA;MURAKAMI, TOSHIO;IKEDA, SHUSHI;AND OTHERS;REEL/FRAME:031504/0055

Effective date: 20121001

STCB Information on status: application discontinuation

Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION