US20130066024A1 - Polysiloxane-polylactide block copolymer and preparation method thereof - Google Patents

Polysiloxane-polylactide block copolymer and preparation method thereof Download PDF

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US20130066024A1
US20130066024A1 US13/698,610 US201113698610A US2013066024A1 US 20130066024 A1 US20130066024 A1 US 20130066024A1 US 201113698610 A US201113698610 A US 201113698610A US 2013066024 A1 US2013066024 A1 US 2013066024A1
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polysiloxane
carbon atoms
block copolymer
substituted
polylactide block
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Seong-Woo Kim
Seung-Young Park
Sung-Cheol Yoon
In-su Lee
Do-Yong Shim
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LG Chem Ltd
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LG Chem Ltd
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/42—Block-or graft-polymers containing polysiloxane sequences
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/06—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from hydroxycarboxylic acids
    • C08G63/08—Lactones or lactides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/68—Polyesters containing atoms other than carbon, hydrogen and oxygen
    • C08G63/695—Polyesters containing atoms other than carbon, hydrogen and oxygen containing silicon
    • C08G63/6952—Polyesters containing atoms other than carbon, hydrogen and oxygen containing silicon derived from hydroxycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used
    • C08G63/823—Preparation processes characterised by the catalyst used for the preparation of polylactones or polylactides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/42—Block-or graft-polymers containing polysiloxane sequences
    • C08G77/445—Block-or graft-polymers containing polysiloxane sequences containing polyester sequences
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/10—Definition of the polymer structure
    • C08G2261/12—Copolymers
    • C08G2261/126—Copolymers block

Definitions

  • the present invention relates to a polysiloxane-polylactide block copolymer and a preparation method thereof, and more particularly, to a polysiloxane-polylactide block copolymer that exhibits a low tensile modulus to have high flexibility and excellent impact resistance, and a preparation method thereof.
  • Polylactide (or poly lactic acid) resins are a kind of resin containing a repeating unit of the following Formula 1. Unlike the existing petroleum-based products, these polylactide resins are based on biomass, and thus they have environment-friendly features such that they can be used as a renewable resource, and showing low carbon dioxide emissions that contribute to global warming during their production, compared to other resins, and being biodegradable in the presence of moisture and microorganisms, as well as having suitable mechanical strength equivalent to the existing known petroleum-based products.
  • polylactide resins have been mainly used for disposable packaging/containers, coatings, foam products, films/sheets, and fabric. Recently, there have been many trials of use of the polylactide resins as semi-permanent materials for mobile phone bodies or car interior parts, after their physical properties are improved by mixing the polylactide resins with known resins such as ABS, polycarbonate, and polypropylene. However, their application is still limited because the polylactide resins have a weak physical property of biodegradation by factors such as catalysts used in their production or moisture in air.
  • the polylactide resins have an advantage of showing relatively high mechanical strength, they are problematic in that they have a relatively high glass transition temperature of room temperature or higher (Tg, 50 ⁇ 60° C.) and thus become brittle when applied to film or sheet products because of reduced resin flexibility after thermal processing. Furthermore, due to their low impact resistance, their application is still limited. Until now, in order to improve elasticity, there have been many trials in which the resins are compounded with organic materials such as rubber or branches are introduced into the main chain of polylactide, but the effects are still unsatisfactory.
  • the present invention provides a polysiloxane-polylactide block copolymer including repeating units of the following Chemical Formula 1 and 2:
  • the polysiloxane-polylactide block copolymer comprises 1 to 30% by weight of the repeating unit of Chemical Formula 2.
  • the polysiloxane-polylactide block copolymer has a weight average molecular weight of 50,000 to 1,000,000 g/mol.
  • the polysiloxane-polylactide block copolymer has the tensile modulus measured according to ASTM D638 of 2.5 GPa or less.
  • the polysiloxane-polylactide block copolymer has the tensile strength measured according to ASTM D638 of 100 to 700 Kg/cm 2 and the elongation measured according to ASTM D638 of 2 to 20%.
  • the polysiloxane-polylactide block copolymer has notched Charpy impact strength measured according to ASTM D256 of 5 to 50 Kgf ⁇ m/m.
  • the present invention provides a preparation method of the polysiloxane-polylactide block copolymer, including the step of ring-opening polymerization of lactide monomers in the presence of a polysiloxane compound of the following Chemical Formula 3:
  • the polysiloxane compound of Chemical Formula 3 is added in an amount of 1 to 50 parts by weight, based on 100 parts by weight of the lactide monomer.
  • the polysiloxane compound of Chemical Formula 3 has a number average molecular weight of 300 to 30,000 g/mol.
  • the ring-opening polymerization of lactide monomers is performed in the presence of a catalyst including compounds of the following Chemical Formula 5 and 6:
  • R 3 and R 5 are each independently a monovalent phenyl group substituted with an alkyl group having 1 to 10 carbon atoms, or an alkyl or cycloalkyl group having 3 to 10 carbon atoms
  • R 4 is a bivalent phenylene group substituted with an alkyl group having 1 to 10 carbon atoms or an alkylene or cycloalkylene group having 3 to 10 carbon atoms.
  • the compound of Chemical Formula 6 is tin(II) 2-ethylhexanoate(Sn(Oct) 2 ).
  • the organic metal complex catalyst of Chemical Formula 4 is added at a ratio of 0.001 to 0.1 mole, based on 100 moles of the lactide monomer.
  • Each of the compounds of Chemical Formula 5 and 6 is added at a ratio of 0.001 to 0.1 mole, based on 100 moles of the lactide monomer.
  • an initiator including a hydroxyl-containing compound is added at a ratio of 0.001 to 1 mole, based on 100 moles of the lactide monomer, so as to perform the ring-opening polymerization.
  • the ring-opening polymerization is performed by bulk polymerization.
  • the ring-opening polymerization is performed at a temperature of 120 to 200° C. for 0.5 to 8 hours.
  • FIG. 1 shows comparison of tensile modulus values between the polylactide resin according to a comparative example and the polysiloxane-polylactide block copolymers according to examples;
  • FIG. 2 shows comparison in impact strength values between the polylactide resin according to the comparative example and the polysiloxane-polylactide block copolymers according to the examples.
  • lactide monomer may be defined as follows. Typically, lactide may be classified into L-lactide composed of L-lactic acid, D-lactide composed of D-lactic acid, and meso-lactide composed of one L-lactic acid and one D-lactic acid. In addition, a 50:50 mixture of L- and D-lactide is called D,L-lactide or rac-lactide. Among them, when only L-lactide or D-lactide having high optical purity is used to perform polymerization, L- or D-polylactide (PLLA or PDLA) with very high tacticity is known to be obtained.
  • L- or D-polylactide PLLA or PDLA
  • lactide monomer is defined to include all types of lactides, regardless of property differences of each lactide and polylactide prepared therefrom.
  • polysiloxane-polylactide block copolymer refers to a polysiloxane-polylactide block copolymer including the repeating unit of Chemical Formula 1 and the repeating unit of Chemical Formula 2, and the “polysiloxane-polylactide block copolymer” may be prepared by a method including the step of forming the repeating units of Chemical Formula 1 and 2 by ring-opening polymerization of “lactide monomers” in the presence of the polysiloxane of Chemical Formula 3, as described above.
  • the polymer which is prepared after completion of the ring-opening polymerization and the formation process of the following repeating units, may be referred as the “polysiloxane-polylactide block copolymer”.
  • the “lactide monomer” encompasses all types of lactides, as described above.
  • the polymer designated as the “polysiloxane-polylactide block copolymer” encompasses all types of polymers that are prepared after completion of the ring-opening polymerization and the formation process of the repeating units, for example, an unrefined or refined polymer after completion of the ring-opening polymerization, a polymer included in a liquid or solid resin composition before molding of products, a polymer included in a plastic or fabric after molding of products, or the like.
  • physical properties (weight average molecular weight, etc.) of the “polysiloxane-polylactide block copolymer” may be defined by the physical properties of any polymer that is prepared after completion of the ring-opening polymerization and the formation process of the repeating units.
  • a polysiloxane-polylactide block copolymer including the repeating unit of the following Chemical Formula 1 and the repeating unit of the following Chemical Formula 2 is provided:
  • a block copolymer including the lactide-based repeating unit of Chemical Formula 1 and the polysiloxane repeating unit of Chemical Formula 2 has excellent flexibility and mechanical properties, and the block copolymer can also be prepared by the step of ring-opening polymerization of lactide monomers in the presence of the polysiloxane compound of Chemical Formula 3, as described below.
  • the Si—O bond of the polysiloxane repeating unit of Chemical Formula 2 has low rotation energy in its chemical structure, which reduces the glass transition temperature (Tg) of the polysiloxane-polylactide block copolymer including the same, leading to improvement of flexibility.
  • the aforementioned polysiloxane-polylactide block copolymer can be simply prepared without an additional polymerization initiator:
  • the block copolymer may include the repeating unit of Chemical Formula 2 in an amount of 1 to 30% by weight, and more preferably 5 to 20% by weight.
  • the polysiloxane-polylactide block copolymer has a weight average molecular weight of 50,000 to 1,000,000 g/mol, preferably 100,000 to 1,000,000 g/mol, and most preferably 100,000 to 300,000 g/mol.
  • the polysiloxane-polylactide block copolymer is excellent in terms of mechanical properties as well as flexibility.
  • its tensile modulus measured according to ASTM D638 may be 2.5 GPa or less.
  • the tensile modulus means a force required to stretch a specimen.
  • a lower tensile modulus means that the specimen can be stretched by a smaller force, that is, it has an increase in flexibility of the block copolymer.
  • the conventional biodegradable polylactide resins have attracted much attention owing to relatively excellent mechanical properties, but it is difficult to apply them to various products because of high value of tensile modulus, that is, its brittleness.
  • the polysiloxane-polylactide block copolymer according to one embodiment of the present invention is able to solve the problem of brittleness of the conventional polylactide resins, its application fields are expected to be expanded.
  • the polysiloxane-polylactide block copolymer according to one embodiment of the present invention exhibits excellent flexibility, and also excellent mechanical properties.
  • its tensile strength measured according to ASTM D638 may be 100 to 700 Kg/cm 2
  • its elongation measured according to ASTM D638 may be 2 to 20%
  • its notched Charpy impact strength measured according to D256 may be 5 to 50 Kgf ⁇ m/m.
  • the polysiloxane-polylactide block copolymer exhibits sufficient mechanical strength, and therefore it is applicable to various products.
  • a method of preparing the polysiloxane-polylactide block copolymer including the step of ring-opening polymerization of lactide monomers in the presence of a polysiloxane compound of the following Chemical Formula 3 is provided:
  • polylactide resin polymerization by ring-opening polymerization of lactide monomers is initiated by the compound having a terminal hydroxyl group, and continuous ring opening of lactide monomers occurs with insertion. Therefore, when the terminal hydroxyl group of the polysiloxane compound of Chemical Formula 3 is added to the ring-opening polymerization of lactide monomers, the lactide monomer is inserted at the end of the polysiloxane, and consequently the polysiloxane-polylactide block copolymer is prepared.
  • the polysiloxane compound functions as a polymerization initiator and is also included in the block copolymer as a repeating unit, thereby improving flexibility and mechanical properties such as impact strength of the final block copolymer.
  • the amount of the polysiloxane compound of Chemical Formula 3 used in the ring-opening polymerization may be determined within a proper range, considering the content of the polysiloxane repeating unit included in the final block copolymer and the molar ratio of the hydroxyl group of the initiator required for initiation of the minimal polymerization.
  • the polysiloxane compound of Chemical Formula 3 may be preferably added in an amount of 1 to 50 parts by weight, more preferably 3 to 30 parts by weight, and most preferably 5 to 20 parts by weight, based on 100 parts by weight of the lactide monomer.
  • the polysiloxane compound of Chemical Formula 3 may have a number average molecular weight of 300 to 30,000 g/mol, and another polysiloxane compound having a different number average molecular weight within the above-described range may be mixed therewith for use. More preferably, the polysiloxane compound of Chemical Formula 3 may have a number average molecular weight of 1000 to 20,000 g/mol. If the polysiloxane compound of Chemical Formula 3 having a number average molecular weight within the above-described range is used, a polysiloxane-polylactide block copolymer having excellent physical properties can be obtained without deterioration of polymerization activity.
  • the ring-opening polymerization may be performed in the presence of a catalyst.
  • a catalyst any typical catalyst may be used without limitation in its composition, as long as it is generally used in the preparation of polylactide resins by the ring-opening polymerization of lactide monomers.
  • Preferred examples of the catalyst to be used in the ring-opening polymerization may include an organic metal complex catalyst of the following Chemical Formula 4, or a catalyst including a compound of the following Chemical Formula 5 and a compound of the following Chemical Formula 6:
  • the lactide ring-opening polymerization is performed in the presence of the organic metal complex catalyst or the catalyst including carbodiimide and an organic metal compound, depolymerization or degradation of the final block copolymer may be prevented, and a polysiloxane-polylactide block copolymer having a higher molecular weight and excellent mechanical properties can be obtained at a higher conversion rate.
  • the compounds of Chemical Formula 5 and 6 may be added either simultaneously or sequentially with time intervals therebetween. They may also be added before addition of the lactide monomers or before initiation of the polymerization within a certain time, or added immediately before initiation of polymerization. However, it is preferable for the compounds of Chemical Formula 5 and 6 to be simultaneously added at a predetermined time before initiation of the polymerization, and then to add the monomers to initiate the polymerization, in order to allow a reaction between the compounds of Chemical Formula 5 and 6 to form a complex thereof.
  • R 3 and R 5 are each independently a monovalent phenyl group substituted with an alkyl group having 1 to 10 carbon atoms, or an alkyl or cycloalkyl group having 3 to 10 carbon atoms; and R 4 is a bivalent phenylene group substituted with an alkyl group having 1 to 10 carbon atoms or an alkylene or cycloalkylene group having 3 to 10 carbon atoms.
  • the compound of Chemical Formula 6 is preferably tin(II) 2-ethylhexanoate (Sn(Oct) 2 ) in order to reduce catalytic activity and depolymerization of the final block copolymer.
  • the organic metal complex catalyst of Chemical Formula 4 is added at a ratio of 0.001 to 0.1 mole, based on 100 moles of the lactide monomer, so as to perform the ring-opening polymerization.
  • Each of the compounds of Chemical Formula 5 and 6 is added at a ratio of 0.001 to 0.1 mole, based on 100 moles of the lactide monomer, so as to perform the ring-opening polymerization. If the addition ratio of the catalyst is too low, the polymerization activity is not sufficient.
  • the residual amount of the catalyst in the prepared polysiloxane-polylactide block copolymer may increase to cause copolymer degradation or reduction in the molecular weight due to depolymerization such as trans-esterification.
  • the polysiloxane compound of Chemical Formula 3 functions as an initiator, but an initiator containing a hydroxyl group-containing compound may be separately added to perform the polymerization.
  • the initiator forms an actual active catalyst species by a reaction with the above-described organic metal complex catalyst of Chemical Formula 4 or the catalyst including the compounds of Chemical Formula 5 and 6, together with the polysiloxane compound of Chemical Formula 3, and thus functions to initiate the ring-opening polymerization of lactide monomers.
  • the initiator and the polysiloxane compound of Chemical Formula 3 are used together with the above-described organic metal complex catalyst of Chemical Formula 4 or the catalyst including the compounds of Chemical Formula 5 and 6 so as to improve the activity of the catalyst, resulting in a higher conversion rate of the polysiloxane-polylactide block copolymer.
  • the initiator may be partially involved in depolymerization or degradation of the resin, and thus functions to control the molecular weight of the polylactide resin.
  • the additional initiator may be added independent of the polysiloxane compound of Chemical Formula 3.
  • the polysiloxane compound of Chemical Formula 3 is used alone without the initiator, the ring-opening polymerization of lactide monomers occurs.
  • a compound having a hydroxyl group may be used without limitation as an additional initiator, in addition to the polysiloxane compound of Chemical Formula 3.
  • the compound may be vaporized at the ring-opening polymerization temperature due to its low molecular weight, which makes it difficult for the initiator to be involved in the polymerization. Therefore, it is preferable that a hydroxyl group-containing compound having 8 or more carbon atoms is used as the initiator.
  • the initiator may be added at a ratio of 0.001 to 1 mole, based on 100 moles of the lactide monomer, so as to perform the ring-opening polymerization. If the addition ratio of the initiator is too low, the molecular weight of the resin obtained by the ring-opening polymerization is too high to perform a further process. If the addition ratio of the initiator is too high, the molecular weight of the resin may reduce.
  • ring-opening polymerization of lactide monomers it is preferable for the ring-opening polymerization of lactide monomers to be practically performed by bulk polymerization using no solvent.
  • “practically using no solvent” may encompass use of a small amount of solvent to solubilize the catalyst, for example, a maximum of 1 ml or less per 1 Kg of the lactide monomer used.
  • the ring-opening polymerization is performed by bulk polymerization, a process of removing the solvent can be omitted after polymerization, and thus degradation or loss of the resin attributed to the solvent removal process can be prevented. Owing to the bulk polymerization, the polysiloxane-polylactide block copolymer can be obtained at a high conversion rate and yield.
  • the ring-opening polymerization of lactide monomers may be performed at a temperature of 120 to 200° C. for 0.5 to 8 hours, and preferably 0.5 to 4 hours.
  • the polysiloxane-polylactide block copolymer having excellent flexibility and mechanical properties can be prepared at a high conversion rate.
  • the weight content, weight average molecular weight, tensile modulus, tensile strength, elongation, notched Charpy impact strength value, or the like of the polysiloxane repeating unit included in the polysiloxane-polylactide block copolymer prepared according to the method are the same as in the description of the polysiloxane-polylactide block copolymer according to the above-described embodiments.
  • the present invention provides a polysiloxane-polylactide block copolymer having excellent impact resistance and flexibility and a preparation method thereof, and thus the application fields of the polylactide resins mainly used for disposable products can be expanded to semi-permanent materials such as electronic packaging and car interior parts, in addition to the disposable products such as food packaging film, household products, and sheets.
  • Nuclear magnetic resonance spectra were obtained using a Bruker 600 spectrometer, and 1 H NMR was measured at 600 MHz.
  • the molecular weight and molecular weight distribution of polymers were measured by GPC (gel permeation chromatography) using polystyrene standard samples.
  • An extrusion grade 4032D which is one of polylactides manufactured by
  • the reactor was heated by heating hot oil.
  • the reactor temperature reached 100 ⁇ 130° C.
  • the reactor was stirred. Polymerization was performed within the reactor temperature of 160 ⁇ 190° C. until the reactor viscosity became constant.
  • the stirring was stopped. Then, a bottom drain valve was opened to inject N 2 gas into the reactor, and a polysiloxane-polylactide block copolymer strand was finally obtained.
  • the resin had a conversion rate of 93.1%, and a weight average molecular weight of 141,000 g/mol.
  • the resin had a conversion rate of 93.5%, and a weight average molecular weight of 150,000 g/mol.
  • the resin had a conversion rate of 94.1%, and a weight average molecular weight of 148,000 g/mol.
  • the reactor was heated by heating hot oil.
  • the reactor temperature reached 100 ⁇ 130° C.
  • the reactor was stirred. Polymerization was performed within the reactor temperature of 160 ⁇ 190° C. until the reactor viscosity became constant.
  • the stirring was stopped. Then, a bottom drain valve was opened to inject N 2 gas into the reactor, and a polysiloxane-polylactide block copolymer strand was finally obtained.
  • the resin had a conversion rate of 95.5%, and a weight average molecular weight of 266,000 g/mol.
  • the resin had a conversion rate of 94.0%, and a weight average molecular weight of 142,000 g/mol.
  • the resin had a conversion rate of 94.2%, and a weight average molecular weight of 154,000 g/mol.
  • the reactor was heated by heating hot oil.
  • the reactor temperature reached 100 ⁇ 130° C.
  • the reactor was stirred. Polymerization was performed within the reactor temperature of 160 ⁇ 190° C. until the reactor viscosity became constant.
  • the stirring was stopped. Then, a bottom drain valve was opened to inject N 2 gas into the reactor, and a polysiloxane-polylactide block copolymer strand was finally obtained.
  • the resin had a conversion rate of 94.3%, and a weight average molecular weight of 187,000 g/mol.
  • the basic physical properties (weight average molecular weight) of the polylactide according to the comparative example, preparation conditions (injection ratio of polysiloxane, content of polysiloxane included in block copolymer, and conversion rate) of the polysiloxane-polylactide block copolymers according to the examples, and the basic physical properties (content of polysiloxane included in block copolymer and weight average molecular weight) of the polysiloxane-polylactide block copolymers according to the examples are the same as in the following Table 1.
  • polysiloxane repeating unit in the polysiloxane-polylactide block copolymers according to Examples 1 to 7 were measured using Varian 500 1H NMR, and the results are shown in Tables 1 and 2.
  • the content of polysiloxane included in the polysiloxane-polylactide block copolymer can be calculated from the content of polysiloxane injected. Meanwhile, 1H NMR was measured after completely dissolving 5 mg of each polymer resin in 2 ml of CDCl 3 without additional pretreatment.
  • the tensile modulus of the resins was gradually reduced and therefore their tensile strength was also reduced, while there was no great change in their elongation.
  • the tensile modulus of Example 7 was 50% of that of Comparative Example 1, and its tensile strength was greatly reduced to 43%.
  • the low tensile modulus means that the specimen can be stretched by a small force, indicating increased flexibility of the resin.
  • the polysiloxane-polylactide block copolymer is prepared by the addition of polysiloxane during the polymerization of lactide monomers, flexibility of the polylactide resin can be highly improved. As shown in the examples of the present invention, it can be seen that the polysiloxane content is controlled to prepare the polylactide resins having various ranges of flexibility.
  • the polysiloxane-polylactide block copolymer resins of the examples of the present invention were found to have greatly improved flexibility, compared to the conventional pure polylactide resins.
  • the increase in the resin flexibility is expected to greatly reduce brittleness, which is the one major drawback found in the production of film or sheet products.
  • Brittleness of resin can be represented by impact strength, in which high impact strength means low brittleness.
  • the polysiloxane-polylactide block copolymers showed higher impact strength than the pure polylactide resin, and the value of impact strength linearly increased depending on the content of polysiloxane injected to the ring-opening polymerization.
  • the polysiloxane-polylactide block copolymer of Example 7 that was prepared by injection of 20% by weight of polysiloxane based on the weight of lactide monomer had impact strength of 26.8 Kgf ⁇ m/m, which is 11 times higher than that of the pure polylactide resin of Comparative Example 1.
  • the polysiloxane-polylactide block copolymers prepared by the examples exhibit excellent flexibility and improved mechanical properties, and therefore the problems of the polylactide resins of the prior art can be improved. Expectedly, their application field can be expanded.

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112940264A (zh) * 2021-03-02 2021-06-11 苏州市和好塑业有限公司 一种改性聚乳酸材料、其制法与应用
US11485852B2 (en) * 2020-02-18 2022-11-01 Northern Technologies International Corporation High impact resistant poly(lactic acid) blends

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20160312041A1 (en) * 2013-12-05 2016-10-27 Ppg Coatings Europe B.V. A Coating Composition
KR102255307B1 (ko) 2014-11-05 2021-05-24 삼성전자주식회사 열가소성 수지 조성물 및 이로 이루어진 성형품
CN107840949A (zh) * 2017-10-27 2018-03-27 杭州师范大学 一种基于有机硅改性聚乙交酯的制备方法
CN107828058A (zh) * 2017-10-27 2018-03-23 杭州师范大学 一种聚乳酸‑聚有机硅氧烷共聚物的制备方法
KR102241367B1 (ko) 2018-01-05 2021-04-15 주식회사 엘지화학 블록 공중합체
CN111655831A (zh) 2018-01-29 2020-09-11 宝洁公司 颗粒衣物软化洗涤添加剂
EP3746533A1 (en) 2018-01-29 2020-12-09 The Procter & Gamble Company Liquid fabric enhancers comprising branched polyester molecules
CA3031768C (en) 2018-01-29 2022-02-15 The Procter & Gamble Company Dryer sheets comprising branched polyester polymers
CN108559084B (zh) * 2018-04-13 2020-12-04 华东理工大学 一种聚乳酸基疏水薄膜的制备方法
CA3044750C (en) 2018-05-30 2023-02-28 The Procter & Gamble Company Dryer sheets comprising branched polyester polymers
US11046917B2 (en) 2018-05-30 2021-06-29 The Procter & Gamble Company Liquid fabric enhancers comprising branched polyester molecules
WO2019232107A1 (en) * 2018-05-30 2019-12-05 The Procter & Gamble Company Particulate laundry softening wash additive
US20210261819A1 (en) * 2018-06-21 2021-08-26 Albert Ludwigs Universtät Freiburg Use of Phase Segregated Block Copolymers with Tunable Properties for the Coating of Surfaces and Coated Substrates
KR20200115166A (ko) 2019-03-26 2020-10-07 주식회사 엘지화학 트리블록 공중합체 및 이의 제조 방법
CN110511412B (zh) * 2019-09-11 2021-05-25 内蒙古农业大学 一种高透气性PLDxL共聚物薄膜及其制备方法和在果蔬保鲜中的应用
CN111961348B (zh) * 2020-08-27 2022-03-15 内蒙古农业大学 具有硅氧烷侧链的聚乳酸共聚物薄膜及其制备方法和在果蔬保鲜中的应用
CN117069943B (zh) * 2023-08-30 2024-02-09 阳春市墨儿谷新材料有限公司 一种3d打印pla共聚物增韧改性材料及其制备方法

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5202413A (en) * 1993-02-16 1993-04-13 E. I. Du Pont De Nemours And Company Alternating (ABA)N polylactide block copolymers
KR100289074B1 (ko) 1998-02-04 2001-07-12 김윤 난용성약물함유시스템
DE102005036602A1 (de) * 2005-08-01 2007-02-08 Ge Bayer Silicones Gmbh & Co. Kg Polyammonium-Polysiloxancopolymere
US20100120991A1 (en) * 2007-03-29 2010-05-13 Teijin Limited Polylactic acid composition
JP5123547B2 (ja) * 2007-03-30 2013-01-23 帝人株式会社 ステレオコンプレックスポリ乳酸フィルム
FR2924938B1 (fr) 2007-12-13 2009-12-25 Oreal Procede de traitement des fibres capillaires au moyen de polysiloxane polyuree
KR101183225B1 (ko) * 2009-05-08 2012-09-14 주식회사 엘지화학 폴리락타이드 수지, 이의 제조 방법 및 이를 포함하는 폴리락타이드 수지 조성물

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11485852B2 (en) * 2020-02-18 2022-11-01 Northern Technologies International Corporation High impact resistant poly(lactic acid) blends
CN112940264A (zh) * 2021-03-02 2021-06-11 苏州市和好塑业有限公司 一种改性聚乳酸材料、其制法与应用

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EP2603546B1 (en) 2017-06-14
CN103052672B (zh) 2015-03-11
WO2012020992A2 (en) 2012-02-16
CN103052672A (zh) 2013-04-17
KR20120021611A (ko) 2012-03-09
US20130317181A1 (en) 2013-11-28
WO2012020992A3 (en) 2012-05-24
KR101160980B1 (ko) 2012-06-29

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