US20100175847A1 - Iron-Nickel-Cobalt Alloy - Google Patents
Iron-Nickel-Cobalt Alloy Download PDFInfo
- Publication number
- US20100175847A1 US20100175847A1 US12/223,131 US22313107A US2010175847A1 US 20100175847 A1 US20100175847 A1 US 20100175847A1 US 22313107 A US22313107 A US 22313107A US 2010175847 A1 US2010175847 A1 US 2010175847A1
- Authority
- US
- United States
- Prior art keywords
- max
- alloy
- mold
- accordance
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 229910000531 Co alloy Inorganic materials 0.000 title claims abstract description 8
- KGWWEXORQXHJJQ-UHFFFAOYSA-N [Fe].[Co].[Ni] Chemical compound [Fe].[Co].[Ni] KGWWEXORQXHJJQ-UHFFFAOYSA-N 0.000 title claims abstract description 8
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 34
- 239000000956 alloy Substances 0.000 claims abstract description 34
- 238000000034 method Methods 0.000 claims description 14
- 239000000463 material Substances 0.000 claims description 8
- 229920000049 Carbon (fiber) Polymers 0.000 claims description 4
- 239000004917 carbon fiber Substances 0.000 claims description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 3
- 238000003466 welding Methods 0.000 claims description 2
- 239000012535 impurity Substances 0.000 claims 3
- 239000002131 composite material Substances 0.000 claims 2
- 238000004519 manufacturing process Methods 0.000 abstract description 6
- 229910052799 carbon Inorganic materials 0.000 abstract description 4
- 239000000470 constituent Substances 0.000 abstract description 4
- 229910052748 manganese Inorganic materials 0.000 abstract description 4
- 238000010276 construction Methods 0.000 abstract description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- 239000000203 mixture Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003733 fiber-reinforced composite Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 238000001721 transfer moulding Methods 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/08—Ferrous alloys, e.g. steel alloys containing nickel
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/10—Ferrous alloys, e.g. steel alloys containing cobalt
- C22C38/105—Ferrous alloys, e.g. steel alloys containing cobalt containing Co and Ni
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/10—Ferrous alloys, e.g. steel alloys containing cobalt
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/12—Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
Definitions
- the invention relates to the use of an iron-nickel-cobalt alloy.
- CFC carbon fiber-reinforced composites
- implements for producing such components, implements (molds) are needed in which the viscous resin-carbon fiber layer is cured at a temperature of approx. 180° C.
- RTM resin transfer molding
- carbon fiber textiles are added to the mold, the mold is evacuated, and then the resin is injected into the mold. After curing at approx. 180° C., the component is removed from the implement.
- Materials used for these molds are either C steels or an alloy with a low coefficient of expansion (iron with 36% nickel, Ni36) that typically has a mean thermal expansion coefficient between 1.6 and 2.5 ⁇ 10 ⁇ 6 K ⁇ 1 .
- RTM molds are associated with difficulties and significant complexity because after it is cured the component is difficult to release from the mold and in addition the component must undergo complex subsequent processing so that it can satisfy its functional demands.
- the underlying object of the invention is therefore to provide an alloy for these molds, with which alloy the aforesaid difficulties can be overcome simply.
- the alloy having a mean thermal expansion coefficient of ⁇ 2.0 ⁇ 10 ⁇ 6 /K in the temperature range from 20 to 200° C.
- the Ni content can be adjusted ranging from 32 to 34.5%, where needed even 32.5 to 33.5%.
- One preferred alloy is distinguished by the following composition (in % by weight):
- Another alloy that can be used advantageously is distinguished by the following chemical composition (in % by weight):
- the molds are made as milled parts from heat-formed (forged or rolled) or cast mass material and then annealed.
- the alloy can also be used in the form of wire material, in particular as an added welding substance when producing the mold.
- alloy is found in aircraft manufacture, wherein it is possible to use the alloy as a molded component, in particular for producing CFC fittings using the RTM technology.
- Other aircraft components that are also embodied using the light-weight CFC construction can also be produced with components made of the suggested alloy.
- components can easily be removed from molds of this alloy, because the thermal shrinkage of the mold is lower after the curing process. Given a suitable design for the mold, the component can be removed such that it can perform its function without subsequent processing.
- Table 1 provides examples of chemical compositions for inventive iron-nickel-cobalt alloys (E1, E2, E3, E4, E5, E6) compared to other iron-nickel-cobalt alloys (T1, U1) that were investigated.
- Inventive alloys E1-E3 and E6 attain thermal expansion coefficients ranging from 1.5- ⁇ 2.0 ⁇ 10 ⁇ 6 /K in the 20-200° C. temperature range.
- the inventive alloys E4 and E5 attain an even lower expansion coefficient of about 1.3 ⁇ 10 ⁇ 6 /K in the 20 to 200° C. temperature range so that with the alloys E4 and E5 a combination of increased strength with simultaneously lower thermal expansion is attained.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Moulds For Moulding Plastics Or The Like (AREA)
- Heat Treatment Of Steel (AREA)
- Heat Treatment Of Sheet Steel (AREA)
- Sealing Battery Cases Or Jackets (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102006005252.8 | 2006-02-02 | ||
DE102006005252A DE102006005252B4 (de) | 2006-02-02 | 2006-02-02 | Formbauteil aus einer Eisen-Nickel-Kobalt-Legierung |
PCT/DE2007/000142 WO2007087786A1 (de) | 2006-02-02 | 2007-01-26 | Eisen-nickel-kobalt-legierung |
Publications (1)
Publication Number | Publication Date |
---|---|
US20100175847A1 true US20100175847A1 (en) | 2010-07-15 |
Family
ID=38001632
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US12/223,131 Abandoned US20100175847A1 (en) | 2006-02-02 | 2007-01-26 | Iron-Nickel-Cobalt Alloy |
Country Status (10)
Country | Link |
---|---|
US (1) | US20100175847A1 (ja) |
EP (1) | EP1979502B1 (ja) |
JP (1) | JP2009525400A (ja) |
CN (1) | CN101379210B (ja) |
AT (1) | AT508430B1 (ja) |
CA (1) | CA2637499C (ja) |
DE (1) | DE102006005252B4 (ja) |
ES (1) | ES2330186B2 (ja) |
GB (1) | GB2447856B (ja) |
WO (1) | WO2007087786A1 (ja) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US10435780B2 (en) | 2009-06-11 | 2019-10-08 | Genius Solutions Engineering Company | Low CTE slush molds with textured surface, and method of making and using the same |
WO2023227929A1 (fr) * | 2022-05-27 | 2023-11-30 | Aperam | Alliage pour la fabrication d'outillages destinés à la fabrication de pièces aéronautiques réalisées en matériau composite |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101474839A (zh) * | 2008-12-24 | 2009-07-08 | 西安飞机工业(集团)有限责任公司 | 一种用于复合材料成型的模具结构 |
CN103924153B (zh) * | 2014-04-22 | 2016-04-27 | 钢铁研究总院 | 一种低膨胀磁屏蔽合金及其制备方法 |
JP6188643B2 (ja) * | 2014-06-30 | 2017-08-30 | 新報国製鉄株式会社 | 極低熱膨張合金及びその製造方法 |
US10351459B2 (en) * | 2015-08-14 | 2019-07-16 | Corning Incorporated | Molds and methods to control mold surface quality |
KR20240098517A (ko) * | 2022-12-21 | 2024-06-28 | 주식회사 포스코 | 알칼리 환경에서 내식성이 향상된 무코팅 오스테나이트 강판 및 그 제조방법 |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1929909A (en) * | 1930-10-04 | 1933-10-10 | Lebanon Steel Foundry | Manufacture of die blocks and the like |
US4853298A (en) * | 1986-04-08 | 1989-08-01 | Carpenter Technology Corporation | Thermally stable super invar and its named article |
US20020144401A1 (en) * | 2001-02-13 | 2002-10-10 | Airbus Espana, S.L. | Method for manufacturing elements of composite materials by the co-bonding technique |
US6510601B1 (en) * | 2000-03-20 | 2003-01-28 | The Boeing Company | Invar forming method for making tooling |
US6528012B2 (en) * | 1998-10-02 | 2003-03-04 | Sumitomo Metal Industries, Ltd. | Welded structure made of low thermal expansion coefficient alloy and welding material therefore |
US6605163B2 (en) * | 2001-01-24 | 2003-08-12 | Imphy Ugine Precision | Process for manufacturing a strip made of an Fe-Ni alloy |
US20060186580A1 (en) * | 2005-02-24 | 2006-08-24 | Vidina Otten | Device, arrangement and method for manufacturing a component |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB912826A (en) * | 1960-03-23 | 1962-12-12 | British Petroleum Co | Improvements in or relating to the production of isoprene-containing material |
JPH01306540A (ja) * | 1988-05-31 | 1989-12-11 | Shinichi Enomoto | 低熱膨張合金鉄 |
JPH02298236A (ja) * | 1989-05-12 | 1990-12-10 | Shinichi Enomoto | 鋳造用低熱膨脹合金 |
JP2001049395A (ja) * | 1999-08-11 | 2001-02-20 | Hitachi Metals Ltd | エッチング性および低熱膨張特性に優れたFe−Ni−Co系合金およびエッチング孔内郭形状の円滑性に優れたシャドウマスク |
JP2001181796A (ja) * | 1999-12-28 | 2001-07-03 | Hitachi Metals Ltd | エッチング性および低熱膨張特性に優れたFe−Ni−Co系合金およびエッチング孔形状性に優れたシャドウマスク |
JP3542024B2 (ja) * | 2000-03-17 | 2004-07-14 | 日立金属株式会社 | 高強度低熱膨張Fe−Ni系合金およびシャドウマスク、リードフレーム |
JP2004183000A (ja) * | 2002-11-29 | 2004-07-02 | Jfe Steel Kk | 成形性と耐衝撃性に優れた低熱膨張合金薄板及びその製造方法さらに前記低熱膨張合金薄板を用いたシャドウマスク |
DE10258356B3 (de) * | 2002-12-12 | 2004-05-27 | Thyssenkrupp Vdm Gmbh | Verwendung einer Eisen-Nickel-Cobalt-Legierung |
-
2006
- 2006-02-02 DE DE102006005252A patent/DE102006005252B4/de not_active Expired - Fee Related
-
2007
- 2007-01-26 JP JP2008552672A patent/JP2009525400A/ja active Pending
- 2007-01-26 CN CN2007800041283A patent/CN101379210B/zh active Active
- 2007-01-26 ES ES200850067A patent/ES2330186B2/es not_active Expired - Fee Related
- 2007-01-26 CA CA2637499A patent/CA2637499C/en active Active
- 2007-01-26 US US12/223,131 patent/US20100175847A1/en not_active Abandoned
- 2007-01-26 AT AT0900107A patent/AT508430B1/de active
- 2007-01-26 EP EP07721865.9A patent/EP1979502B1/de active Active
- 2007-01-26 GB GB0813844A patent/GB2447856B/en active Active
- 2007-01-26 WO PCT/DE2007/000142 patent/WO2007087786A1/de active IP Right Grant
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1929909A (en) * | 1930-10-04 | 1933-10-10 | Lebanon Steel Foundry | Manufacture of die blocks and the like |
US4853298A (en) * | 1986-04-08 | 1989-08-01 | Carpenter Technology Corporation | Thermally stable super invar and its named article |
US6528012B2 (en) * | 1998-10-02 | 2003-03-04 | Sumitomo Metal Industries, Ltd. | Welded structure made of low thermal expansion coefficient alloy and welding material therefore |
US6510601B1 (en) * | 2000-03-20 | 2003-01-28 | The Boeing Company | Invar forming method for making tooling |
US6605163B2 (en) * | 2001-01-24 | 2003-08-12 | Imphy Ugine Precision | Process for manufacturing a strip made of an Fe-Ni alloy |
US20020144401A1 (en) * | 2001-02-13 | 2002-10-10 | Airbus Espana, S.L. | Method for manufacturing elements of composite materials by the co-bonding technique |
US20060186580A1 (en) * | 2005-02-24 | 2006-08-24 | Vidina Otten | Device, arrangement and method for manufacturing a component |
Non-Patent Citations (1)
Title |
---|
A Word About "Invar", Special Metals Corporation 2001, p. 2-11 * |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US10435780B2 (en) | 2009-06-11 | 2019-10-08 | Genius Solutions Engineering Company | Low CTE slush molds with textured surface, and method of making and using the same |
WO2023227929A1 (fr) * | 2022-05-27 | 2023-11-30 | Aperam | Alliage pour la fabrication d'outillages destinés à la fabrication de pièces aéronautiques réalisées en matériau composite |
Also Published As
Publication number | Publication date |
---|---|
GB0813844D0 (en) | 2008-09-03 |
WO2007087786A8 (de) | 2007-10-11 |
EP1979502B1 (de) | 2014-01-22 |
CN101379210A (zh) | 2009-03-04 |
CA2637499A1 (en) | 2007-08-09 |
AT508430A5 (de) | 2011-01-15 |
GB2447856B (en) | 2011-09-07 |
CN101379210B (zh) | 2012-07-04 |
ES2330186A1 (es) | 2009-12-04 |
DE102006005252B4 (de) | 2010-10-28 |
JP2009525400A (ja) | 2009-07-09 |
GB2447856A (en) | 2008-10-01 |
ES2330186B2 (es) | 2010-04-19 |
AT508430B1 (de) | 2011-01-15 |
DE102006005252A1 (de) | 2007-08-16 |
WO2007087786A1 (de) | 2007-08-09 |
CA2637499C (en) | 2012-04-17 |
EP1979502A1 (de) | 2008-10-15 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
AS | Assignment |
Owner name: THYSSENKRUPP VDM GMBH, GERMANY Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:GEHRMANN, BODO;BOER, BERND;SIGNING DATES FROM 20080814 TO 20080818;REEL/FRAME:021537/0769 |
|
AS | Assignment |
Owner name: OUTOKUMPU VDM GMBH, GERMANY Free format text: CHANGE OF NAME;ASSIGNOR:THYSSENKRUPP VDM GMBH;REEL/FRAME:029838/0865 Effective date: 20130118 |
|
STCB | Information on status: application discontinuation |
Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION |