Classifications

• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
  • C08G18/00—Polymeric products of isocyanates or isothiocyanates
  • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
  • C08G18/83—Chemically modified polymers
• • C—CHEMISTRY; METALLURGY
  • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
  • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
  • C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
  • C09J175/04—Polyurethanes
  • C09J175/06—Polyurethanes from polyesters
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
  • C08G18/00—Polymeric products of isocyanates or isothiocyanates
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
  • C08G18/00—Polymeric products of isocyanates or isothiocyanates
  • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
  • C08G18/08—Processes
  • C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
  • C08G18/00—Polymeric products of isocyanates or isothiocyanates
  • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
  • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
  • C08G18/30—Low-molecular-weight compounds
  • C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
  • C08G18/3819—Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen
  • C08G18/3821—Carboxylic acids; Esters thereof with monohydroxyl compounds
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
  • C08G18/00—Polymeric products of isocyanates or isothiocyanates
  • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
  • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
  • C08G18/40—High-molecular-weight compounds
  • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
  • C08G18/00—Polymeric products of isocyanates or isothiocyanates
  • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
  • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
  • C08G18/40—High-molecular-weight compounds
  • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
  • C08G18/4236—Polycondensates having carboxylic or carbonic ester groups in the main chain containing only aliphatic groups
  • C08G18/4238—Polycondensates having carboxylic or carbonic ester groups in the main chain containing only aliphatic groups derived from dicarboxylic acids and dialcohols
  • C08G18/4241—Polycondensates having carboxylic or carbonic ester groups in the main chain containing only aliphatic groups derived from dicarboxylic acids and dialcohols from dicarboxylic acids and dialcohols in combination with polycarboxylic acids and/or polyhydroxy compounds which are at least trifunctional
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
  • C08G18/00—Polymeric products of isocyanates or isothiocyanates
  • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
  • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
  • C08G18/40—High-molecular-weight compounds
  • C08G18/61—Polysiloxanes
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
  • C08G18/00—Polymeric products of isocyanates or isothiocyanates
  • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
  • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
  • C08G18/71—Monoisocyanates or monoisothiocyanates
  • C08G18/718—Monoisocyanates or monoisothiocyanates containing silicon

Definitions

• the present invention relates to prepolymers containing alkoxysilane groups based on special, low-viscosity polyester polyols, which exhibit particularly high strength, a process for the production thereof and their application as a binder for adhesives, primers or coatings.
• Alkoxysilane-functional polyurethanes which cure via silane polycondensation have long been known.
• a review article on this topic can be found e.g. in “Adhesives Age” April 1995, pages 30 ff. (authors: Ta-Min Feng, B. A. Waldmann).
• Single-component polyurethanes of this type which contain terminal alkoxysilane groups and which cure under the effect of moisture, are increasingly being used as flexible coating, sealing and adhesive compositions in the building trade and in the automotive industry.
• alkoxysilane-functional polyurethanes can be produced in accordance with U.S. Pat. No. 3,627,722 or U.S. Pat. No. 3,632,557 by reacting, for example, polyether polyols with an excess of polyisocyanate to form an NCO-containing prepolymer, which is then further reacted with an amino-functional alkoxysilane.
• Another way of producing alkoxysilane-functional polyurethanes consists, according to the teaching of EP-A 0 070 475, in capping hydroxy-functional polyurethane prepolymers with isocyanate-functional alkoxysilanes.
• Polyester-based alkoxysilane-functional polyurethanes have also been described already for example, EP-A 0 354 472 or WO2004/005420 describe silane-curing hot-melt adhesives which, although they can achieve considerable tensile strength, are by nature solids at ambient temperature. While it is true that EP-A 0 480 363 also describes a special polyester-based system in which acrylate components are also modified, however, a solvent is obviously needed in this case in order to be able to achieve the desired viscosity. A modern adhesive system should not contain any solvent, however.
• polyester polyol-based, silane-curing polyurethane described in U.S. Pat. No. 6,756,456 is referred to as being at least “flowable”.
• the isocyanate used is TMXDI, which is accessible only with difficulty and is therefore expensive.
• the possibly low viscosity is obviously achieved by a polyether-polyester block structure.
• the patent specification provides no information on the tensile strength of such a system.
• silane-curing polyurethanes containing polyether are rather flexible and exhibit a lower tensile strength
• the object of the present invention was now to provide polyester-based, silane-curing polyurethanes which exhibit a sufficiently low viscosity, can be processed at ambient temperature and, when cured, achieve high cohesive strength with, at the same time, sufficiently high extensibility, which permits structural bonding.
• prepolymers of this type can be produced either by reacting a polyester polyol produced on the basis of the raw materials adipic acid, hexanediol and neopentyl glycol directly with an isocyanate-functional silane or by first producing an NCO prepolymer with a diisocyanate, which is then modified with an amino-functional silane in a second step.
• the present invention therefore provides alkoxysilane group-modified polyurethanes of the general formula (I),
• PIC is a residue of a diisocyanate reduced by the isocyanate groups
• Q is a difunctional, linear or branched, aliphatic residue
• the invention also provides a process for the production of polyurethanes modified with alkoxysilane groups, in which either
• a polyester polyol which is substantially the reaction product of adipic acid as the acid component with a diol component which is a mixture of neopentyl glycol and hexanediol and/or butanediol.
• This diol component must contain at least 20 wt. %, preferably at least 30 wt. %, neopentyl glycol and at least 20 wt. %, preferably at least 30 wt. %, hexanediol and/or butanediol.
• the polyester polyol can also contain up to 10 wt. %, preferably up to 5 wt. %, of other components, such as triols, to modify the functionality.
• other components such as triols
• all polyhydric, preferably dihydric or trihydric alcohols can be incorporated, such as e.g.
• ethylene glycol triethylene glycol, tetraethylene glycol, 1,2- and 1,3-propanediol, 1,4- and 1,3-butanediol, 1,6-hexanediol, 1,8-octanediol, neopentyl glycol, 1,4-bis(hydroxymethyl)cyclohexane, bis(hydroxymethyl)tricyclo[5.2.1.0 2.6 ]decane or 1,4-bis(2-hydroxyethoxy)benzene, 2-methyl-1,3-propanediol, 2,2,4-trimethylpentanediol, 2-ethyl-1,3-hexanediol, dipropylene glycol, polypropylene glycols, dibutylene glycol, polybutylene glycols, 1,4-phenoldimethanol, bisphenol A, tetrabromobisphenol A, glycerol, trimethylolpropane, 1,2,6-hexanetriol
• polycarboxylic acids may optionally also be incorporated.
• the corresponding polycarboxylic anhydrides or corresponding polycarboxylic acid esters of lower alcohols or mixtures thereof can also be used for the production of the polyester
• the polycarboxylic acids can be aliphatic, cycloaliphatic, aromatic and/or heterocyclic in nature and optionally substituted, e.g. by halogen atoms, and/or unsaturated.
• phthalic acid isophthalic acid, succinic acid, suberic acid, azelaic acid, sebacic acid, trimellitic acid, phthalic anhydride, tetrahydrophthalic anhydride, glutaric anhydride, tetrachlorophthalic anhydride, endomethylene tetrahydrophthalic anhydride, maleic anhydride, maleic acid, fumaric acid, dimer and trimer fatty acids such as oleic acid, optionally mixed with monomer fatty acids, terephthalic acid dimethyl ester or terephthalic acid bisglycol ester.
• polyester polyols to be used according to the invention have number-average molecular weights of 500 g/mol to 2500 g/mol, preferably 800 g/mol to 2000 g/mol.
• polyester polyol or an OH-functional prepolymer produced by reacting the polyester polyol with a deficiency of diisocyanates, with an alkoxysilyl group which also carries an isocyanate group as additional functionality.
• isocyanatomethyltrimethoxysilane isocyanatomethyltriethoxysilane, (isocyanatomethyl)methyldimethoxysilane, (iso-cyanatomethyl)methyldiethoxysilane, 3-isocyanatopropyltrimethoxysilane, 3-isocyanatopropylmethyldimethoxysilane, 3-isocyanatopropyltriethoxysilane and 3-isocyanatopropylmethyldiethoxysilane can be mentioned as examples.
• the use of 3-isocyanatopropyltrimethoxysilane is preferred here.
• an OH-functional prepolymer which was reacted by the reaction of the polyester polyol described with a deficiency of diisocyanate.
• Aromatic, aliphatic and cycloaliphatic diisocyanates are suitable for use as diisocyanates.
• Suitable diisocyanates are compounds of the formula PIC(NCO) 2 with an average molecular weight of less than 400, wherein PIC signifies an aromatic C 6 -C 15 hydrocarbon residue, an aliphatic C 4 -C 12 hydrocarbon residue or a cycloaliphatic C 6 -C 15 hydrocarbon residue, e.g.
• IPDI, HDI or TDI and/or MDI derivatives are preferably used here.
• 1-Isocyanato-3,3,5-trimethyl-5-isocyanatomethylcyclohexane (IPDI) or hexamethylene diisocyanate (HDI) are particularly preferably employed as the diisocyanate.
• urethanisation catalysts which are known per se to the person skilled in the art, such as organotin compounds or amine catalysts, are suitable.
• organotin compounds dibutyltin diacetate, dibutyltin dilaurate, dibutyltin bisacetoacetonate and tin carboxyates, such as e.g. tin octoate.
• tin catalysts can optionally be used in combination with amine catalysts, such as aminosilanes or 1,4-diazabicyclo[2.2.2]octane.
• dibutyltin dilaurate is used as the urethanisation catalyst.
• This catalyst component where incorporated, is employed in the process according to the invention in quantities of 0.001 to 5.0 wt. %, preferably 0.001 to 0.1 wt. % and particularly preferably 0.005 to 0.05 wt. %, based on the solids content of the process product.
• the urethanisation of the polyester polyols according to the invention with diisocyanates or isocyanate-functional alkoxysilanes is carried out at temperatures of 20 to 200° C., preferably 40 to 120° C. and particularly preferably 60 to 100° C.
• the reaction is continued until complete conversion of the NCO groups of the isocyanate-containing compound is achieved.
• the progress of the reaction can be monitored by means of suitable measuring instruments installed in the reaction vessel and/or by means of analyses on samples taken. Appropriate methods are known to the person skilled in the art. Examples include viscosity measurements, measurements of the NCO content, the refractive index and the OH content, gas chromatography (GC), nuclear magnetic resonance (NMR) spectroscopy, infrared (IR) spectroscopy and near-infrared (NIR) spectroscopy.
• the NCO content of the mixture is preferably determined by a titrimetric method.
• the process according to the invention is preferably carried out in a stirred reactor.
• the second process for the production of the polyurethanes according to the invention is based on a reaction of the polyester polyols first with an excess of diisocyanate to form an isocyanate-functional prepolymer, and on the further reaction of these isocyanate groups with a compound carrying alkoxysilyl groups, which also carries a functionality that is reactive with isocyanate groups as an additional functionality.
• an excess of diisocyanate is used for the synthesis of an NCO prepolymer, preferably with the selection of an NCO:OH ratio of 1.3:1.0 to 2:1, particularly preferably 1.5:1.0 to 2:1.
• the aromatic, aliphatic and cycloaliphatic diisocyanates already mentioned are suitable for use as diisocyanates.
• IPDI 1-isocyanato-3,3,5-trimethyl-5-isocyanatomethylcyclohexane
• HDI hexamethylene diisocyanate
• this urethanisation can also be accelerated by catalysis; the temperature ranges of the reaction are also analogous.
• the reaction is continued until complete conversion of the OH groups of the polyester polyols is achieved.
• the progress of the reaction is usefully monitored by checking the NCO content and it is complete when the appropriate theoretical NCO content is reached. This can be followed by suitable measuring instruments installed in the reaction vessel and/or by means of analyses on samples taken. Appropriate methods are known to the person skilled in the art. Examples include viscosity measurements, measurements of the NCO content, the refractive index and the OH content, gas chromatography (GC), nuclear magnetic resonance (NMR) spectroscopy, infrared (IR) spectroscopy and near-infrared (NIR) spectroscopy.
• the NCO content of the mixture is preferably determined by a titrimetric method.
• NCO prepolymers are reacted with isocyanate-reactive alkoxysilane compounds.
• Suitable isocyanate-reactive alkoxysilane compounds are adequately known to the person skilled in the art, the following being mentioned as examples: aminopropyltrimethoxysilane, mercaptopropyltrimethoxysilane, aminopropylmethyldimethoxysilane, mercaptopropylmethyldimethoxysilane, aminopropyltriethoxysilane, mercaptopropyltriethoxysilane, aminopropylmethyldiethoxy-silane, mercaptopropylmethyldiethoxysilane, aminomethyltrimethoxysilane, aminomethyltriethoxysilane, (aminomethyl)methyldimethoxysilane, (aminomethyl)-methyldiethoxysilane, N-butylaminopropyltrimethoxysilane, N-ethylaminopropyltrime
• X signifies the same or different alkoxy or alkyl residues, which may also be bridged, but at least one alkoxy residue must be present on each Si atom here
• Q is a difunctional, linear or branched aliphatic residue
• Z denotes an alkoxy residue with 1 to 10 carbon atoms. The use of these aspartic acid esters is preferred for this embodiment of the invention.
• Examples of particularly preferred aspartic acid esters are N-(3-triethoxysilylpropyl)aspartic acid diethyl ester, N-(3-trimethoxysilyl-propyl)aspartic acid diethyl ester and N-(3-dimethoxymethylsilylpropyl)aspartic acid diethyl ester.
• the use of N-(3-trimethoxysilylpropyl)aspartic acid diethyl ester is especially preferred.
• This reaction with isocyanate-reactive alkoxysilanes takes place within a temperature range of 0° C. to 150° C., preferably 20° C. to 80° C., the quantitative ratios generally being selected such that 0.95 to 1.1 moles of the isocyanate-reactive alkoxysilane compound are used per mole of NCO groups used.
• This cyclocondensation can be brought about by simply stirring the polyester-based polyurethane prepolymer capped with an isocyanate-reactive alkoxysilane of formula II at temperatures of 70° C. to 180° C., preferably of 80° C. to 150° C.
• the reaction can be carried out without further catalysis or, preferably, accelerated by catalysis.
• Both basic and acidic organic compounds are suitable as catalysts, for example N,N,N,N-benzyltrimethylammonium hydroxide, other hydroxides which are soluble in organic media, DBN, DBU, other amidines, tin octoate, dibutyltin dilaurate, other organic tin compounds, zinc octoate, acetic acid, other alkanoic acids, benzoic acid, benzoyl chloride, other acid chlorides or dibutyl phosphate, or other derivatives of phosphoric acid.
• the catalyst is added in quantities of 0.005 wt. % to 5 wt. %, preferably 0.05 wt. % to 1 wt. %.
• the compounds according to the invention are highly suitable as binders for the production of isocyanate-free polyurethane adhesives. These adhesives cure under the action of atmospheric humidity by means of a silanol polycondensation.
• the present invention therefore also provides adhesives, primers and coatings based on the polyurethane prepolymers according to the invention.
• the polyurethane prepolymers containing alkoxysilane end groups according to the invention can be formulated together with conventional plasticisers, fillers, pigments, drying agents, additives, light stabilisers, antioxidants, thixotropic agents, catalysts, adhesion promoters and optionally other auxiliary substances and additives by known sealant manufacturing processes.
• Suitable fillers include, by way of example, carbon black, precipitated silicas, pyrogenic silicas, mineral chalks and precipitated chalks.
• Suitable plasticisers include, by way of example, phthalates, adipates, alkylsulfonates of phenol or phosphoric acid esters.
• thixotropic agents examples include pyrogenic silicas, polyamides, reaction products of hydrogenated castor oil or else polyvinyl chloride.
• organometallic compounds and amine catalysts that are known to promote silane polycondensation.
• organometallic compounds are, in particular, compounds of tin and of titanium.
• Preferred tin compounds are, for example: dibutyltin diacetate, dibutyltin dilaurate, dioctyltin maleate and tin carboxylates, such as e.g. tin(II) octoate or dibutyltin bisacetoacetonate.
• the tin catalysts mentioned may optionally be used in combination with amine catalysts, such as aminosilanes or 1,4-diazabicyclo[2.2.2]octane.
• Preferred titanium compounds are, for example, alkyl titanates, such as diisobutylbisethylacetoacetate titanate.
• amine catalysts are used alone, those which exhibit a particularly high basicity are particularly suitable, such as amines with an amidine structure.
• Preferred amine catalysts are therefore 1,8-diazabicyclo[5.4.0]undec-7-ene or 1,5-diazabicyclo[4.3.0]non-5-ene, for example.
• alkoxysilyl compounds such as vinyltrimethoxysilane, methyltrimethoxysilane, i-butyltrimethoxysilane and hexadecyltrinethoxysilane, may be mentioned as drying agents.
• the known functional silanes such as e.g. aminosilanes of the type mentioned above but also N-aminoethyl-3-aminopropyltrimethoxy and/or N-aminoethyl-3-amino-propylmethyldimethoxysilane, epoxysilanes and/or mercaptosilanes, are used as adhesion promoters.
• the viscosity measurements were performed at 23° C., with a shear rate of 47.94/s using a plate-plate rotational viscometer, Roto Visko 1 from Haake, Del., in accordance with ISO/DIS 3219:1990.
• RT The ambient temperature prevailing at the time of conducting the tests
• Polyester diol A polyester consisting of 1,6-hexanediol (25.8%), neopentyl glycol (29.6%) and adipic acid (59.2%), minus water (14.6%), OH value: 94 mg KOH/g.
• Polyester diol B polyester consisting of 1,6-hexanediol (24.2%), neopentyl glycol (27.8%) and adipic acid (63.8%), minus water (15.8%), OH value: 31 mg KOH/g.
• dibutyltin dilaurate (Desmorapid Z®, Bayer MaterialScience AG, Leverkusen, Del.) were added to 2197.92 g of the polyester diol A and the mixture was heated to 60° C.
• 814.3 g isocyanatopropyltrimethoxysilane (Geniosil® GF40, Wacker AG, Burghausen) were then added dropwise over three hours and stirring was continued until an NCO content could no longer be detected by titration.
• the alkoxysilyl end group-containing polyurethane prepolymer obtained had a viscosity of 6,450 mPas (23° C.).
• dibutyltin dilaurate (Desmorapid Z®, Bayer MaterialScience AG, Leverkusen, Del.) were added to 4470.2 g of the polyester diol B and the mixture was heated to 60° C. 529.3 g isocyanatopropyltrimethoxysilane (Geniosil® GF40, Wacker AG, Burghausen) were then added dropwise over half an hour and stirring was continued until an NCO content could no longer be detected by titration.
• the alkoxysilyl end group-containing polyurethane prepolymer obtained had a viscosity of 90,500 mPas (23° C.).
• dibutyltin dilaurate (Desmorapid® Z, Bayer MaterialScience AG, Leverkusen, Del.) were added to 2387.2 g of the polyester diol A and the mixture was heated to 60° C.
• hexamethylene diisocyanate (Desmodur H®, Bayer MaterialScience AG, Leverkusen, Del.) were added first over half an hour and 557.1 g isocyanatopropyltrimethoxysilane (Geniosil® GF40, Wacker AG, Burghausen) were then added dropwise over an hour and stirring was continued until an NCO content could no longer be detected by titration.
• the alkoxysilyl end group-containing polyurethane prepolymer obtained had a viscosity of 25,100 mPas (23° C.).
• polyester diol A 566.2 g of the polyester diol A were prepolymerised with 205.3 g isophorone diisocyanate (Bayer MaterialScience AG, Leverkusen) at 60° C. with the addition of 200 ppm dibutyltin dilaurate (Desmorapid® Z, Bayer MaterialScience AG, Leverkusen, Del.) until the theoretical NCO content of 4.62% was reached.
• polyester diol A 596.8 g of the polyester diol A were prepolymerised with 155.4 g hexamethylene diisocyanate (Desmodur H®, Bayer MaterialScience AG, Leverkusen, Del.) at 60° C. with the addition of 50 ppm dibutyltin dilaurate (Desmorapid® Z, Bayer MaterialScience AG, Leverkusen, Del.) until the theoretical NCO content of 4.75% was reached.
• the reaction was cooled to 50° C. and 0.32 g of methanol were mixed in. Stirring was continued for about 90 minutes at 50° C. until no NCO content could be detected any longer.
• the alkoxysilyl end group-containing polyurethane prepolymer obtained had a viscosity of 48,000 mPas (23° C.).
• filler Socal® U1S2 from Solvay GmbH
• drying agent Densilicate® VTMO from Degussa
• the adhesion promoter (Dynasylan® 1146 from Degussa) is then added and stirred in at 1000 rpm within 5 min.
• the catalyst (Tegokat® 233 from Goldschmidt) is mixed in at 1000 rpm and the finished mixture is finally degassed in vacuo.
• both membranes 2 mm thick and samples to determine the longitudinal shear strength are produced. From the membranes, S2 specimens are stamped, and to measure the longitudinal shear strength, specimens of oak are used. The membranes are stored for 14 days at 23° C./50% relative humidity to cure and the specimens for the tensile shear tests are stored for 28 days, also at 23° C./50% relative humidity.
• the hardness of the films is measured in accordance with DIN 53505, the mechanical properties of the S2 bars on the basis of DIN 53504 and the longitudinal shear strength according to DIN 281.
• Examples 1-5 show the clear gain in strength that can be achieved by using polyester-based, silane-curing polyurethanes.
• the tensile strengths of the pure adhesive film are 87 to 242% higher than that of the comparative example, which is based on a polyether.
• the measurements on adhesive joints (oak/oak) also show significant increases in strength, in this case ranging from 39 to 57%.
• polyester-based, silane-curing polyurethanes permits a large gain in cohesive strength.
• the viscosity of the polymers can be kept sufficiently low that they can be handled without any problems.

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• Chemical & Material Sciences (AREA)
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• Health & Medical Sciences (AREA)
• Chemical Kinetics & Catalysis (AREA)
• Medicinal Chemistry (AREA)
• Polymers & Plastics (AREA)
• General Chemical & Material Sciences (AREA)
• Polyurethanes Or Polyureas (AREA)
• Adhesives Or Adhesive Processes (AREA)
• Reinforced Plastic Materials (AREA)
• Polyesters Or Polycarbonates (AREA)
• Paints Or Removers (AREA)

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