US20050175564A1 - Tickener, cosmetic preparation containing the same, and process for producing the same - Google Patents

Tickener, cosmetic preparation containing the same, and process for producing the same Download PDF

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Publication number
US20050175564A1
US20050175564A1 US10/513,824 US51382404A US2005175564A1 US 20050175564 A1 US20050175564 A1 US 20050175564A1 US 51382404 A US51382404 A US 51382404A US 2005175564 A1 US2005175564 A1 US 2005175564A1
Authority
US
United States
Prior art keywords
water
microgel
thickener
phase
denotes
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US10/513,824
Other languages
English (en)
Inventor
Isamu Kaneda
Toshio Yanaki
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shiseido Co Ltd
Original Assignee
Shiseido Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=29422413&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=US20050175564(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Priority claimed from JP2002209587A external-priority patent/JP3850347B2/ja
Application filed by Shiseido Co Ltd filed Critical Shiseido Co Ltd
Assigned to SHISEIDO COMPANY, LTD. reassignment SHISEIDO COMPANY, LTD. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: KANEDA, ISAMU, YANAKI, TOSHIO
Publication of US20050175564A1 publication Critical patent/US20050175564A1/en
Priority to US12/576,438 priority Critical patent/US7927615B2/en
Abandoned legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/32—Polymerisation in water-in-oil emulsions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/042—Gels
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8158—Homopolymers or copolymers of amides or imides, e.g. (meth) acrylamide; Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00—Materials not provided for elsewhere
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02—Preparations containing skin colorants, e.g. pigments
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q15/00—Anti-perspirants or body deodorants
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
    • A61Q17/005—Antimicrobial preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/002—Aftershave preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/04—Preparations for care of the skin for chemically tanning the skin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
    • A61Q5/065—Preparations for temporary colouring the hair, e.g. direct dyes
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/08—Preparations for bleaching the hair

Definitions

  • the present invention provides a thickener consisting of said microgel wherein the apparent viscosity of the microgel ethanol dispersion having 0.5% (mass percentage) of it at 25° C. is 5,000 mPa ⁇ s or higher at a shear rate of 1.0 s ⁇ 1 .
  • the thickener of the present invention is manufactured with the reverse phase emulsion polymerization method. That is, this thickener is manufactured by radical polymerization of water soluble ethylene-type unsaturated monomers dissolved in the dispersion phase in a composition having an organic solvent or an oil component as the dispersion medium and water as the dispersion phase. The polymerized microgel is rinsed and dried, but there is no need for crushing.
  • a single phase microemulsion is a state wherein the oil phase and water phase coexist in a thermodynamically stable manner and the surface tension between the oil and water is at a minimum.
  • a fine W/O emulsion is a state wherein the oil and water exist as a fine W/O emulsion in a thermodynamically unstable but kinetically stable fashion.
  • the particle size of the inner water phase of a fine W/O emulsion is several tens to 100 nm.
  • the weight average molecular weight of the microgel used in the present invention is 100,000-5,000,000 (PEG equivalent, measured with the GPC); it is adjusted according to the desired viscosity of the thickener.
  • the microgel to be used in the present invention can be isolated in a powder form after a precipitation/purification process.
  • the microgel thus isolated in a powder form is easily dispersed in water, ethanol, or a water/ethanol mixed solvent and quickly swells and functions as a thickener.
  • FIG. 6 shows an example of a pseudo three component polymerization system of hexane/polyoxyethylene (6) oleyl ether/water soluble ethylene type unsaturated monomer aqueous solution.
  • a 80:20 molar ratio mixture of dimethylacrylamide and 2-acrylamido-2-methylpropanesulfonic acid dissolved in ion-exchanged water (20 mass %) is used for the water soluble ethylene type unsaturated monomer aqueous solution.
  • acetone is added to the microgel suspension to precipitate the microgel, followed by rinsing with acetone three times to remove the remaining monomers and the surfactant.
  • the precipitate is filtered and then dried under a reduced pressure to obtain the dried microgel in a white powder form.
  • Table 14 shows Examples of an O/W type liquid foundation containing the thickeners prepared in Synthesis examples 1-7.
  • the O/W type liquid foundations containing the thickeners of Synthesis examples 1-7 provided stable emulsified compositions.

Landscapes

  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Organic Chemistry (AREA)
  • Dermatology (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dispersion Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Cosmetics (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
US10/513,824 2002-05-14 2003-05-12 Tickener, cosmetic preparation containing the same, and process for producing the same Abandoned US20050175564A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US12/576,438 US7927615B2 (en) 2002-05-14 2009-10-09 Thickener, cosmetic preparation containing the same, and process for producing the same

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
JP2002-138533 2002-05-12
JP2002138533 2002-05-14
JP2002209587A JP3850347B2 (ja) 2002-07-18 2002-07-18 水膨潤性高分子の製造方法
JP2002-209587 2002-07-18
PCT/JP2003/005863 WO2003095583A1 (fr) 2002-05-14 2003-05-12 Agent epaississant, preparation cosmetique en contenant, et son procede de production

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US12/576,438 Division US7927615B2 (en) 2002-05-14 2009-10-09 Thickener, cosmetic preparation containing the same, and process for producing the same

Publications (1)

Publication Number Publication Date
US20050175564A1 true US20050175564A1 (en) 2005-08-11

Family

ID=29422413

Family Applications (2)

Application Number Title Priority Date Filing Date
US10/513,824 Abandoned US20050175564A1 (en) 2002-05-14 2003-05-12 Tickener, cosmetic preparation containing the same, and process for producing the same
US12/576,438 Expired - Lifetime US7927615B2 (en) 2002-05-14 2009-10-09 Thickener, cosmetic preparation containing the same, and process for producing the same

Family Applications After (1)

Application Number Title Priority Date Filing Date
US12/576,438 Expired - Lifetime US7927615B2 (en) 2002-05-14 2009-10-09 Thickener, cosmetic preparation containing the same, and process for producing the same

Country Status (6)

Country Link
US (2) US20050175564A1 (fr)
EP (1) EP1505139B2 (fr)
KR (1) KR100970123B1 (fr)
CN (1) CN100579507C (fr)
TW (1) TWI287571B (fr)
WO (1) WO2003095583A1 (fr)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070231354A1 (en) * 2005-04-21 2007-10-04 Atsushi Sogabe Water-Soluble Thickener and Cosmetic Preparation Containing Same
US20070238896A1 (en) * 2006-03-17 2007-10-11 Croda, Inc. Amine/amide-functionalized lipophiles
WO2010026052A1 (fr) * 2008-09-03 2010-03-11 Unilever Plc Produit ménager ou de soins personnels
US8323629B2 (en) 2009-06-29 2012-12-04 Shiseido Company, Ltd. External preparation for the skin
US9763869B2 (en) 2013-06-28 2017-09-19 Sumitomo Seika Chemicals Co., Ltd. Hydrophilic thickener and cosmetic composition
CN108348443A (zh) * 2015-09-30 2018-07-31 株式会社资生堂 水包油包粉体型组合物

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4541277B2 (ja) * 2005-11-01 2010-09-08 株式会社資生堂 燃料電池用液体燃料及び燃料電池
CN102452964A (zh) * 2010-10-20 2012-05-16 中国石油化工股份有限公司 两亲性可聚合单体和两亲性增粘共聚物及其制备方法和应用
WO2013080717A1 (fr) 2011-12-01 2013-06-06 株式会社資生堂 Préparation cosmétique aqueuse destinée à la peau
CN104693351B (zh) * 2013-12-09 2016-08-17 中国石油化工股份有限公司 一种具表面活性功能聚合物及其制备方法和应用
DE102013226946A1 (de) * 2013-12-20 2015-06-25 Henkel Ag & Co. Kgaa Konditioniermittel für keratinische Fasern mit PCA-Derivat
CN104892835B (zh) * 2015-05-06 2017-05-24 同济大学 一种酶促聚合制备微凝胶的方法
JP6334646B2 (ja) * 2016-10-31 2018-05-30 株式会社 資生堂 液状皮膚外用組成物
CN115304707B (zh) * 2021-05-08 2023-08-04 中国石油化工股份有限公司 粒径可调的聚丙烯酰胺类微球乳液及其制备方法和应用

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4540740A (en) * 1983-04-04 1985-09-10 Ppg Industries, Inc. Cross-linked polymeric microgel prepared from polymerizing epoxy-containing monomer in the presence of an acid
US4547299A (en) * 1984-03-15 1985-10-15 Milchem Incorporated Drilling fluid containing a copolymer filtration control agent
US4749506A (en) * 1984-09-29 1988-06-07 Ricoh Co., Ltd. Fine particle substance-containing microgel dispersions
US6197287B1 (en) * 1998-01-16 2001-03-06 Societe D'exploitation De Produits Pour Les Industries Chimiques Seppic Thickening latex, manufacturing process and cosmetic applications

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS54154437A (en) * 1978-05-26 1979-12-05 Sanyo Chem Ind Ltd Liquid composition containing water-soluble vinyl polymer and its production
FR2524895A1 (fr) † 1982-04-09 1983-10-14 Inst Francais Du Petrole Procede de preparation de microlatex en phase huileuse continue par polymerisation en micro-emulsion du type eau dans l'huile d'un monomere hydrosoluble, microlatex obtenus et leur utilisation en recuperation assistee du petrole
US4554018A (en) 1984-02-01 1985-11-19 Allied Colloids Limited Production of polymeric thickeners and their use in printing
FR2617172B1 (fr) † 1987-06-25 1993-07-02 Charbonnages Ste Chimique Preparation de microlatex inverses utilisables comme adjuvants de flottation et de drainage ainsi que pour l'absorption et la retention de fluides aqueux
CA1331251C (fr) † 1988-05-20 1994-08-02 Peter Flesher Polymeres de matieres particulaires, leur production et leurs utilisations
JP2676483B2 (ja) † 1994-03-03 1997-11-17 三洋化成工業株式会社 水溶性ビニル重合体の油中水型マイクロエマルション
JPH0912613A (ja) 1995-06-28 1997-01-14 Mitsubishi Chem Corp 吸水性樹脂の製造方法
US6069216A (en) † 1997-06-11 2000-05-30 Kao Corporation Cationic group-containing copolymer and thickener
CA2301141A1 (fr) * 1998-06-15 1999-12-23 The Lubrizol Corporation Procede d'utilisation d'une composition aqueuse contenant un polymere synthetique hydrosoluble ou dispersable dans l'eau
US6414080B1 (en) † 1999-06-09 2002-07-02 Calgon Corporation Inverse emulsion polymer and production thereof
JP3681154B2 (ja) † 1999-10-14 2005-08-10 株式会社資生堂 水溶性増粘剤及びこれを配合した化粧料
JP3695254B2 (ja) * 1999-10-14 2005-09-14 株式会社資生堂 水溶性増粘剤及びこれを配合した化粧料
FR2802936B1 (fr) † 1999-12-28 2006-03-31 Seppic Sa Nouveaux polymeres, le procede pour leur preparation et les microlatex inverses les contenant

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4540740A (en) * 1983-04-04 1985-09-10 Ppg Industries, Inc. Cross-linked polymeric microgel prepared from polymerizing epoxy-containing monomer in the presence of an acid
US4547299A (en) * 1984-03-15 1985-10-15 Milchem Incorporated Drilling fluid containing a copolymer filtration control agent
US4749506A (en) * 1984-09-29 1988-06-07 Ricoh Co., Ltd. Fine particle substance-containing microgel dispersions
US6197287B1 (en) * 1998-01-16 2001-03-06 Societe D'exploitation De Produits Pour Les Industries Chimiques Seppic Thickening latex, manufacturing process and cosmetic applications

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070231354A1 (en) * 2005-04-21 2007-10-04 Atsushi Sogabe Water-Soluble Thickener and Cosmetic Preparation Containing Same
US20070238896A1 (en) * 2006-03-17 2007-10-11 Croda, Inc. Amine/amide-functionalized lipophiles
US7781391B2 (en) * 2006-03-17 2010-08-24 Croda, Inc. Amine/amide-functionalized lipophiles
WO2010026052A1 (fr) * 2008-09-03 2010-03-11 Unilever Plc Produit ménager ou de soins personnels
US8323629B2 (en) 2009-06-29 2012-12-04 Shiseido Company, Ltd. External preparation for the skin
US9763869B2 (en) 2013-06-28 2017-09-19 Sumitomo Seika Chemicals Co., Ltd. Hydrophilic thickener and cosmetic composition
CN108348443A (zh) * 2015-09-30 2018-07-31 株式会社资生堂 水包油包粉体型组合物

Also Published As

Publication number Publication date
WO2003095583A1 (fr) 2003-11-20
EP1505139B2 (fr) 2014-06-18
CN1653152A (zh) 2005-08-10
CN100579507C (zh) 2010-01-13
US7927615B2 (en) 2011-04-19
EP1505139B1 (fr) 2011-07-13
EP1505139A4 (fr) 2005-08-03
KR20040111358A (ko) 2004-12-31
TWI287571B (en) 2007-10-01
US20100029787A1 (en) 2010-02-04
KR100970123B1 (ko) 2010-07-13
TW200403328A (en) 2004-03-01
EP1505139A1 (fr) 2005-02-09

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Legal Events

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AS Assignment

Owner name: SHISEIDO COMPANY, LTD., JAPAN

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:KANEDA, ISAMU;YANAKI, TOSHIO;REEL/FRAME:016503/0459

Effective date: 20041010

STCB Information on status: application discontinuation

Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION