US20030006025A1 - Evacuated jacket for thermal insulation and process for manufacturing the same - Google Patents

Evacuated jacket for thermal insulation and process for manufacturing the same Download PDF

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Publication number
US20030006025A1
US20030006025A1 US10/223,140 US22314002A US2003006025A1 US 20030006025 A1 US20030006025 A1 US 20030006025A1 US 22314002 A US22314002 A US 22314002A US 2003006025 A1 US2003006025 A1 US 2003006025A1
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US
United States
Prior art keywords
layer
envelope
barrier sheet
upper layer
lower layer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US10/223,140
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English (en)
Inventor
Paolo Manini
Bruno Ferrario
Enea Rizzi
Massimo Palladino
Pierattilio Di Gregorio
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SAES Getters SpA
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SAES Getters SpA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SAES Getters SpA filed Critical SAES Getters SpA
Assigned to SAES GETTERS S.P.A. reassignment SAES GETTERS S.P.A. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: DE GREGORIO, PIERATTILIO, FERRARIO, BRUNO, MANINI, PAOLO, PALLADINO, MASSIMO, RIZZI, ENEA
Publication of US20030006025A1 publication Critical patent/US20030006025A1/en
Abandoned legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • B32B27/20—Layered products comprising a layer of synthetic resin characterised by the use of special additives using fillers, pigments, thixotroping agents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
    • B32B3/02—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by features of form at particular places, e.g. in edge regions
    • B32B3/04—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by features of form at particular places, e.g. in edge regions characterised by at least one layer folded at the edge, e.g. over another layer ; characterised by at least one layer enveloping or enclosing a material

Definitions

  • an evacuated jacket is formed of an envelope inside which a filling material is provided.
  • the envelope has the purpose of preventing (or reducing as much as possible) the entrance of atmospheric gases into the jacket, so as to maintain a vacuum level compatible with the degree of thermal insulation required by the application.
  • the filling material has mainly the function of spacing apart the two opposite sides of the envelope when the jacket is evacuated, and must have a porous or discontinuous internal structure, so that its porosities or interstices can be evacuated in order to perform the thermally insulating function.
  • the envelope is generally formed of two barrier sheets having rectangular shape, reciprocally joined along the margins thereof by means of perimetrical weldings.
  • the so joined margins of the barrier sheets form four flanges arranged at the sides of the resulting envelope.
  • the main drawback of the envelopes of this kind consists exactly in the presence of these flanges, which are very fragile and their possible fracturing can easily propagate beyond the perimetrical weldings, causing the permeation of atmospheric gases into the jacket and thus compromising the thermal insulating features thereof.
  • an envelope is formed having two opened ends whose sealing, transversely to flange F, is carried out by inserting the edges thereof between welding bars. In the two areas wherein these weldings intersect the flange, the envelope takes on the conformation shown in FIG. 5 c (which has an enlarged scale with respect to FIGS. 5 a and 5 b ).
  • Object of the present invention is therefore providing an evacuated jacket free from said drawbacks and a process for manufacturing the same. Said object is achieved by means of an evacuated jacket whose main features are specified in the first claim and other features are specified in the subsequent claims. The features of the process are specified in claim 7.
  • a first advantage of the evacuated jacket according to the present invention consists in that its envelope has a very good gas tightness also at the end seals, although it is made starting from a single barrier sheet.
  • said support layer and said protecting layer being formed of mutually heat-sealable materials having a similar melting temperature, it is possible that the opposite layers which are joined together by means of said longitudinal welding belong to opposite sides of the sheet, so that the resulting envelope is flat in the welding area and does not comprise a longitudinal flange.
  • said support layer and said protection layer are made of the same material.
  • FIG. 1 shows an enlarged cross-sectional view of a barrier sheet that can be used for manufacturing an evacuated jacket according to said embodiment
  • FIG. 2 shows a step of the manufacturing of the evacuated jacket according to said embodiment
  • FIG. 3 shows a complete evacuated jacket according to said embodiment
  • FIG. 4 shows an enlarged cross-sectional view of a lateral flange of the jacket of FIG. 3 taken along line IV-IV of the same figure;
  • FIGS. 5 a, 5 b and 5 c the last being an enlarged partial sectional view, schematically show three steps of the manufacturing of a known jacket.
  • barrier sheet 1 which forms the envelope of the evacuated jacket according to the present embodiment of the invention is a multi-layer comprising a central layer 2 provided with barrier properties towards atmospheric gases and consisting for example of a metal sheet, e.g. aluminum, having a thickness between 4 and 10 ⁇ m.
  • a metal sheet e.g. aluminum
  • said multi-layer comprises a lower layer 3 and an upper layer 4 suitable for providing support and protection for the central layer 2 , and to enable the heat-sealing of the sheet.
  • the materials which form said layers are mutually heat-sealable.
  • Said materials can be selected in the group consisting of polyacrylonitrile (PAN), polyolefines, such as polyethylene, and polyvinylchloride, as well as mixtures and copolymers thereof.
  • PAN polyacrylonitrile
  • the lower layer 3 and the upper layer 4 suitably have a thickness between 20 and 100 ⁇ m, preferably of about 50 ⁇ m.
  • the lower layer 3 and the upper layer 4 are made of the same material.
  • Particularly suitable for this purpose is high density polyethylene (known as HDPE).
  • the envelope of the evacuated jacket according to the present invention is made rolling up said barrier sheet 1 so as to superimpose two opposite margins 5 and 6 thereof.
  • the superimposition is carried out so as to contact the lower layer 3 at margin 5 with the upper layer 4 at the other margin 6 .
  • a porous or discontinuous, organic or inorganic filling material of any known kind and optionally a getter material or device are inserted inside the envelope.
  • getter materials or devices suitable for chemically sorbing moisture or other atmospheric gases, are known in the field and therefore do not need a detailed description.
  • FIG. 4 shows an enlarged partial view in cross-section of one of said lateral flanges 8 .
  • it shows the portion of said flange which comprises the linear zone 7 of the longitudinal welding.
  • the thickness of each lateral flange 8 is uniform all over its length, in spite of the threefold superimposition of the barrier sheet 1 , in the linear zone 7 of the longitudinal welding. This can be explained considering that in said linear zone 7 the lower layer 3 and upper layer 4 of the barrier sheet have become thinner.
  • the heat of the welding bars causes said layers to be melted and to become soft, so that some of the polymeric material of which they are formed is discharged form the sides because of the pressure of said bars and can be removed.
  • the edges of the envelope ends are perfectly sealed on themselves and no slot is present.
  • the seals in this area are not perfect, so that the entrance of air inside the jacket is allowed which compromises the thermal insulation properties thereof.

Landscapes

  • Thermal Insulation (AREA)
  • Laminated Bodies (AREA)
  • Muffle Furnaces And Rotary Kilns (AREA)
  • Building Environments (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
US10/223,140 2000-02-18 2002-08-19 Evacuated jacket for thermal insulation and process for manufacturing the same Abandoned US20030006025A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
ITMI2000A000287 2000-02-18
IT2000MI000287A IT1316769B1 (it) 2000-02-18 2000-02-18 Pannello evacuato per isolamento termico con ridotta conduzione dicalore ai bordi
PCT/IT2001/000053 WO2001060598A2 (en) 2000-02-18 2001-02-07 Evacuated jacket for thermal insulation and process for manufacturing the same

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
PCT/IT2001/000053 Continuation WO2001060598A2 (en) 2000-02-18 2001-02-07 Evacuated jacket for thermal insulation and process for manufacturing the same

Publications (1)

Publication Number Publication Date
US20030006025A1 true US20030006025A1 (en) 2003-01-09

Family

ID=11444077

Family Applications (1)

Application Number Title Priority Date Filing Date
US10/223,140 Abandoned US20030006025A1 (en) 2000-02-18 2002-08-19 Evacuated jacket for thermal insulation and process for manufacturing the same

Country Status (17)

Country Link
US (1) US20030006025A1 (it)
EP (1) EP1265746B1 (it)
JP (1) JP2003522918A (it)
KR (1) KR100548674B1 (it)
AT (1) ATE252452T1 (it)
AU (1) AU2001234076A1 (it)
BR (1) BR0108392A (it)
CA (1) CA2398890A1 (it)
DE (2) DE60101050T2 (it)
DK (1) DK1265746T3 (it)
ES (1) ES2208559T3 (it)
HK (1) HK1052482A1 (it)
IT (1) IT1316769B1 (it)
MX (1) MXPA02007904A (it)
RU (1) RU2253792C2 (it)
TR (1) TR200301897T4 (it)
WO (1) WO2001060598A2 (it)

Cited By (13)

* Cited by examiner, † Cited by third party
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US20040128808A1 (en) * 2000-07-25 2004-07-08 Bridgeman William M. Carbon-based weld blanket, methods of making and methods of use
US20060084602A1 (en) * 2004-10-14 2006-04-20 Lynch Samuel E Platelet-derived growth factor compositions and methods of use thereof
US20070129807A1 (en) * 2004-10-14 2007-06-07 Lynch Samuel E Maxillofacial bone augmentation using rhPDGF-BB and a biocompatible matrix
US20070207185A1 (en) * 2004-10-14 2007-09-06 Hart Charles E Compositions and methods for treating bone
US20090232890A1 (en) * 2008-02-07 2009-09-17 Lynch Samuel E Compositions and methods for distraction osteogenesis
US20100174368A1 (en) * 2008-09-09 2010-07-08 Lynch Samuel E Platelet-derived growth factor compositions and methods for the treatment of tendon and ligament injuries
US20100183515A1 (en) * 2006-06-30 2010-07-22 Hart Charles E Compositions and methods for treating the vertebral column
US20100247651A1 (en) * 2009-03-05 2010-09-30 Biomimetic Therapeutics, Inc. Platelet-derived growth factor compositions and methods for the treatment of osteochondral defects
US8106008B2 (en) 2006-11-03 2012-01-31 Biomimetic Therapeutics, Inc. Compositions and methods for arthrodetic procedures
US8492335B2 (en) 2010-02-22 2013-07-23 Biomimetic Therapeutics, Llc Platelet-derived growth factor compositions and methods for the treatment of tendinopathies
US8899068B2 (en) 2010-10-28 2014-12-02 Lg Electronics Inc. Refrigerator comprising vacuum space
US9642891B2 (en) 2006-06-30 2017-05-09 Biomimetic Therapeutics, Llc Compositions and methods for treating rotator cuff injuries
US20170184340A1 (en) * 2015-12-29 2017-06-29 Whirlpool Corporation Injection molded gas barrier parts for vacuum insulated structure

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ITMI20020320A1 (it) * 2002-02-18 2003-08-18 Getters Spa Metodo e sensore per misurare il vuoto nonche' pannello evacuato comprendente detto sensore
AU2003262373A1 (en) 2002-04-19 2003-11-03 Salviac Limited A medical device
AU2003262374A1 (en) 2002-04-19 2003-11-03 Salviac Limited A medical device
FR2963291B1 (fr) 2010-07-27 2012-08-31 Jean Chereau Sas Module de carrosserie pour vehicule frigorifique comprenant un panneau d'isolation sous vide, et procede de fabrication associe.
RU2489636C1 (ru) * 2012-03-15 2013-08-10 Алексей Леонидович Чепайкин Мобильный теплозвукоизоляционный модуль для объектов сложной геометрической формы
US8944541B2 (en) 2012-04-02 2015-02-03 Whirlpool Corporation Vacuum panel cabinet structure for a refrigerator
US9221210B2 (en) 2012-04-11 2015-12-29 Whirlpool Corporation Method to create vacuum insulated cabinets for refrigerators
FR2991250B1 (fr) 2012-06-05 2014-06-13 Jean Chereau Sas Module de carrosserie pour vehicule frigorifique comprenant un panneau d'isolation sous vide, et procede de fabrication associe.
RU2553629C1 (ru) * 2013-12-03 2015-06-20 Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Самарский государственный университет путей сообщения" (СамГУПС) Способ изготовления вакуумного теплоизоляционного изделия
US9689604B2 (en) 2014-02-24 2017-06-27 Whirlpool Corporation Multi-section core vacuum insulation panels with hybrid barrier film envelope
US10052819B2 (en) 2014-02-24 2018-08-21 Whirlpool Corporation Vacuum packaged 3D vacuum insulated door structure and method therefor using a tooling fixture
US9476633B2 (en) 2015-03-02 2016-10-25 Whirlpool Corporation 3D vacuum panel and a folding approach to create the 3D vacuum panel from a 2D vacuum panel of non-uniform thickness
US10161669B2 (en) 2015-03-05 2018-12-25 Whirlpool Corporation Attachment arrangement for vacuum insulated door
US9897370B2 (en) 2015-03-11 2018-02-20 Whirlpool Corporation Self-contained pantry box system for insertion into an appliance
US9441779B1 (en) 2015-07-01 2016-09-13 Whirlpool Corporation Split hybrid insulation structure for an appliance
US10041724B2 (en) 2015-12-08 2018-08-07 Whirlpool Corporation Methods for dispensing and compacting insulation materials into a vacuum sealed structure
US10422573B2 (en) 2015-12-08 2019-09-24 Whirlpool Corporation Insulation structure for an appliance having a uniformly mixed multi-component insulation material, and a method for even distribution of material combinations therein
US10222116B2 (en) 2015-12-08 2019-03-05 Whirlpool Corporation Method and apparatus for forming a vacuum insulated structure for an appliance having a pressing mechanism incorporated within an insulation delivery system
US11052579B2 (en) 2015-12-08 2021-07-06 Whirlpool Corporation Method for preparing a densified insulation material for use in appliance insulated structure
US10429125B2 (en) 2015-12-08 2019-10-01 Whirlpool Corporation Insulation structure for an appliance having a uniformly mixed multi-component insulation material, and a method for even distribution of material combinations therein
US11994336B2 (en) 2015-12-09 2024-05-28 Whirlpool Corporation Vacuum insulated structure with thermal bridge breaker with heat loop
US10808987B2 (en) 2015-12-09 2020-10-20 Whirlpool Corporation Vacuum insulation structures with multiple insulators
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US9752818B2 (en) 2015-12-22 2017-09-05 Whirlpool Corporation Umbilical for pass through in vacuum insulated refrigerator structures
US9840042B2 (en) 2015-12-22 2017-12-12 Whirlpool Corporation Adhesively secured vacuum insulated panels for refrigerators
US10610985B2 (en) 2015-12-28 2020-04-07 Whirlpool Corporation Multilayer barrier materials with PVD or plasma coating for vacuum insulated structure
US10018406B2 (en) 2015-12-28 2018-07-10 Whirlpool Corporation Multi-layer gas barrier materials for vacuum insulated structure
US10807298B2 (en) 2015-12-29 2020-10-20 Whirlpool Corporation Molded gas barrier parts for vacuum insulated structure
US11247369B2 (en) 2015-12-30 2022-02-15 Whirlpool Corporation Method of fabricating 3D vacuum insulated refrigerator structure having core material
US10712080B2 (en) 2016-04-15 2020-07-14 Whirlpool Corporation Vacuum insulated refrigerator cabinet
EP3443284B1 (en) 2016-04-15 2020-11-18 Whirlpool Corporation Vacuum insulated refrigerator structure with three dimensional characteristics
US10767919B2 (en) 2016-07-26 2020-09-08 Whirlpool Corporation Method for ensuring reliable core material fill around the pass throughs in a vacuum insulated structure
WO2018022007A1 (en) 2016-07-26 2018-02-01 Whirlpool Corporation Vacuum insulated structure trim breaker
US11391506B2 (en) 2016-08-18 2022-07-19 Whirlpool Corporation Machine compartment for a vacuum insulated structure
EP3519746B1 (en) * 2016-10-03 2022-10-26 Whirlpool Corporation Encapsulation system for a thermal bridge breaker-to-metal liner
RU174567U1 (ru) * 2016-11-16 2017-10-20 Общество с ограниченной ответственностью "К-ФЛЕКС" Чехол для теплоизоляции объектов сложной геометрической формы
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US10352613B2 (en) 2016-12-05 2019-07-16 Whirlpool Corporation Pigmented monolayer liner for appliances and methods of making the same
US10907888B2 (en) 2018-06-25 2021-02-02 Whirlpool Corporation Hybrid pigmented hot stitched color liner system
US10907891B2 (en) 2019-02-18 2021-02-02 Whirlpool Corporation Trim breaker for a structural cabinet that incorporates a structural glass contact surface
FR3100218A1 (fr) 2019-09-02 2021-03-05 Jean Chereau Sas Module de carrosserie pour véhicule frigorifique comprenant un panneau d’isolation sous vide, et procédé de fabrication associé
FR3113628B1 (fr) 2020-08-31 2023-04-14 Jean Chereau Sas Module de carrosserie pour véhicule frigorifique comprenant un panneau d’isolation sous vide, et procédé de fabrication associé

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Cited By (37)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040128808A1 (en) * 2000-07-25 2004-07-08 Bridgeman William M. Carbon-based weld blanket, methods of making and methods of use
US6959855B2 (en) * 2000-07-25 2005-11-01 Tex Tech Industries Inc. Carbon-based weld blanket, methods of making and methods of use
US7473678B2 (en) 2004-10-14 2009-01-06 Biomimetic Therapeutics, Inc. Platelet-derived growth factor compositions and methods of use thereof
US20070207185A1 (en) * 2004-10-14 2007-09-06 Hart Charles E Compositions and methods for treating bone
US20110117018A1 (en) * 2004-10-14 2011-05-19 Biomimetic Therapeutics, Inc. Compositions and methods for treating bone
US20070259814A1 (en) * 2004-10-14 2007-11-08 Lynch Samuel E Platelet Derived Growth Factor and Methods of Use Thereof
US10258566B2 (en) 2004-10-14 2019-04-16 Biomimetic Therapeutics, Llc Compositions and methods for treating bone
US9545377B2 (en) 2004-10-14 2017-01-17 Biomimetic Therapeutics, Llc Platelet-derived growth factor compositions and methods of use thereof
US11571497B2 (en) 2004-10-14 2023-02-07 Biomimetic Therapeutics, Llc Platelet-derived growth factor compositions and methods of use thereof
US20060084602A1 (en) * 2004-10-14 2006-04-20 Lynch Samuel E Platelet-derived growth factor compositions and methods of use thereof
US11318230B2 (en) 2004-10-14 2022-05-03 Biomimetic Therapeutics, Llc Platelet-derived growth factor compositions and methods of use thereof
US11364325B2 (en) 2004-10-14 2022-06-21 Biomimetic Therapeutics, Llc Platelet-derived growth factor compositions and methods of use thereof
US8114841B2 (en) 2004-10-14 2012-02-14 Biomimetic Therapeutics, Inc. Maxillofacial bone augmentation using rhPDGF-BB and a biocompatible matrix
US20070129807A1 (en) * 2004-10-14 2007-06-07 Lynch Samuel E Maxillofacial bone augmentation using rhPDGF-BB and a biocompatible matrix
US7799754B2 (en) 2004-10-14 2010-09-21 Biomimetic Therapeutics, Inc. Compositions and methods for treating bone
US10456450B2 (en) 2006-06-30 2019-10-29 Biomimetic Therapeutics, Llc Compositions and methods for treating rotator cuff injuries
US20100183515A1 (en) * 2006-06-30 2010-07-22 Hart Charles E Compositions and methods for treating the vertebral column
US11058801B2 (en) 2006-06-30 2021-07-13 Biomimetic Therapeutics, Llc Compositions and methods for treating the vertebral column
US9161967B2 (en) 2006-06-30 2015-10-20 Biomimetic Therapeutics, Llc Compositions and methods for treating the vertebral column
US9642891B2 (en) 2006-06-30 2017-05-09 Biomimetic Therapeutics, Llc Compositions and methods for treating rotator cuff injuries
US8106008B2 (en) 2006-11-03 2012-01-31 Biomimetic Therapeutics, Inc. Compositions and methods for arthrodetic procedures
US8349796B2 (en) 2008-02-07 2013-01-08 Biomimetic Therapeutics Inc. Methods for treatment of distraction osteogenesis using PDGF
US20090232890A1 (en) * 2008-02-07 2009-09-17 Lynch Samuel E Compositions and methods for distraction osteogenesis
US7943573B2 (en) 2008-02-07 2011-05-17 Biomimetic Therapeutics, Inc. Methods for treatment of distraction osteogenesis using PDGF
US8870954B2 (en) 2008-09-09 2014-10-28 Biomimetic Therapeutics, Llc Platelet-derived growth factor compositions and methods for the treatment of tendon and ligament injuries
US11135341B2 (en) 2008-09-09 2021-10-05 Biomimetic Therapeutics, Llc Platelet-derived growth factor composition and methods for the treatment of tendon and ligament injuries
US20100174368A1 (en) * 2008-09-09 2010-07-08 Lynch Samuel E Platelet-derived growth factor compositions and methods for the treatment of tendon and ligament injuries
US20100247651A1 (en) * 2009-03-05 2010-09-30 Biomimetic Therapeutics, Inc. Platelet-derived growth factor compositions and methods for the treatment of osteochondral defects
US11235030B2 (en) 2010-02-22 2022-02-01 Biomimetic Therapeutics, Llc Platelet-derived growth factor compositions and methods for the treatment of tendinopathies
US8492335B2 (en) 2010-02-22 2013-07-23 Biomimetic Therapeutics, Llc Platelet-derived growth factor compositions and methods for the treatment of tendinopathies
US10337788B2 (en) 2010-10-28 2019-07-02 Lg Electronics Inc. Refrigerator comprising vacuum space
US9651292B2 (en) 2010-10-28 2017-05-16 Lg Electronics Inc. Refrigerator comprising vacuum space
US8899068B2 (en) 2010-10-28 2014-12-02 Lg Electronics Inc. Refrigerator comprising vacuum space
US11384977B2 (en) 2010-10-28 2022-07-12 Lg Electronics Inc. Refrigerator comprising vacuum space
US11821678B2 (en) 2010-10-28 2023-11-21 Lg Electronics Inc. Refrigerator comprising vacuum space
US10030905B2 (en) * 2015-12-29 2018-07-24 Whirlpool Corporation Method of fabricating a vacuum insulated appliance structure
US20170184340A1 (en) * 2015-12-29 2017-06-29 Whirlpool Corporation Injection molded gas barrier parts for vacuum insulated structure

Also Published As

Publication number Publication date
MX223141B (it) 2004-09-29
TR200301897T4 (tr) 2004-01-21
KR20020084138A (ko) 2002-11-04
ITMI20000287A1 (it) 2001-08-18
CA2398890A1 (en) 2001-08-23
JP2003522918A (ja) 2003-07-29
ATE252452T1 (de) 2003-11-15
DE60101050T2 (de) 2004-08-19
KR100548674B1 (ko) 2006-02-02
DE20121944U1 (de) 2003-07-24
BR0108392A (pt) 2003-03-11
EP1265746B1 (en) 2003-10-22
HK1052482A1 (zh) 2003-09-19
AU2001234076A1 (en) 2001-08-27
ES2208559T3 (es) 2004-06-16
MXPA02007904A (es) 2002-11-29
DE60101050D1 (de) 2003-11-27
WO2001060598A3 (en) 2002-02-07
RU2253792C2 (ru) 2005-06-10
ITMI20000287A0 (it) 2000-02-18
DK1265746T3 (da) 2004-03-01
EP1265746A2 (en) 2002-12-18
WO2001060598A2 (en) 2001-08-23
IT1316769B1 (it) 2003-05-12

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