US1776052A - Process for treating cellulosic fibers with alkali - Google Patents
Process for treating cellulosic fibers with alkali Download PDFInfo
- Publication number
- US1776052A US1776052A US218109A US21810927A US1776052A US 1776052 A US1776052 A US 1776052A US 218109 A US218109 A US 218109A US 21810927 A US21810927 A US 21810927A US 1776052 A US1776052 A US 1776052A
- Authority
- US
- United States
- Prior art keywords
- alkali
- cellulosic fibers
- lye
- mixture
- mercerizing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- 238000000034 method Methods 0.000 title description 11
- 239000000835 fiber Substances 0.000 title description 10
- 239000003513 alkali Substances 0.000 title description 8
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 25
- 239000000203 mixture Substances 0.000 description 15
- 235000011121 sodium hydroxide Nutrition 0.000 description 12
- 239000000126 substance Substances 0.000 description 12
- 239000004744 fabric Substances 0.000 description 8
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 8
- 125000003118 aryl group Chemical group 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 229920000742 Cotton Polymers 0.000 description 4
- 150000002989 phenols Chemical class 0.000 description 4
- 229920000297 Rayon Polymers 0.000 description 3
- 238000005517 mercerization Methods 0.000 description 3
- 238000009736 wetting Methods 0.000 description 3
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- 229930003836 cresol Natural products 0.000 description 2
- 150000001896 cresols Chemical class 0.000 description 2
- NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 description 2
- 150000004780 naphthols Chemical class 0.000 description 2
- MTQKMPGBALVEDL-ZPCKWCKBSA-N (z,12r)-12-hydroxy-2-sulfooctadec-9-enoic acid Chemical class CCCCCC[C@@H](O)C\C=C/CCCCCCC(C(O)=O)S(O)(=O)=O MTQKMPGBALVEDL-ZPCKWCKBSA-N 0.000 description 1
- MQWCXKGKQLNYQG-UHFFFAOYSA-N 4-methylcyclohexan-1-ol Chemical compound CC1CCC(O)CC1 MQWCXKGKQLNYQG-UHFFFAOYSA-N 0.000 description 1
- 229920003043 Cellulose fiber Polymers 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 101150004141 Vcan gene Proteins 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 150000004707 phenolate Chemical class 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
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- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/325—Amines
- D06M13/335—Amines having an amino group bound to a carbon atom of a six-membered aromatic ring
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- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/38—Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic Table
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- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with hydrogen peroxide or peroxides of metals; with persulfuric, permanganic, pernitric, percarbonic acids or their salts
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- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/02—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with hydrocarbons
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- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
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- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/12—Aldehydes; Ketones
- D06M13/127—Mono-aldehydes, e.g. formaldehyde; Monoketones
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- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/137—Acetals, e.g. formals, or ketals
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- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/144—Alcohols; Metal alcoholates
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- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/152—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen having a hydroxy group bound to a carbon atom of a six-membered aromatic ring
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- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/165—Ethers
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- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
- D06M13/256—Sulfonated compounds esters thereof, e.g. sultones
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- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/325—Amines
- D06M13/332—Di- or polyamines
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- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/325—Amines
- D06M13/338—Organic hydrazines; Hydrazinium compounds
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- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/35—Heterocyclic compounds
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- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/402—Amides imides, sulfamic acids
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- D—TEXTILES; PAPER
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- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/402—Amides imides, sulfamic acids
- D06M13/405—Acylated polyalkylene polyamines
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- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
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- D—TEXTILES; PAPER
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- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
- D06M13/463—Compounds containing quaternary nitrogen atoms derived from monoamines
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- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/17—Natural resins, resinous alcohols, resinous acids, or derivatives thereof
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- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S162/00—Paper making and fiber liberation
- Y10S162/03—Wetting agent
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S516/00—Colloid systems and wetting agents; subcombinations thereof; processes of
- Y10S516/01—Wetting, emulsifying, dispersing, or stabilizing agents
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S516/00—Colloid systems and wetting agents; subcombinations thereof; processes of
- Y10S516/01—Wetting, emulsifying, dispersing, or stabilizing agents
- Y10S516/03—Organic sulfoxy compound containing
- Y10S516/05—Organic amine, amide, or n-base containing
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S516/00—Colloid systems and wetting agents; subcombinations thereof; processes of
- Y10S516/01—Wetting, emulsifying, dispersing, or stabilizing agents
- Y10S516/06—Protein or carboxylic compound containing
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S516/00—Colloid systems and wetting agents; subcombinations thereof; processes of
- Y10S516/01—Wetting, emulsifying, dispersing, or stabilizing agents
- Y10S516/07—Organic amine, amide, or n-base containing
Definitions
- the following hydrogenated aromatic substances come into consideration for the present process:
- the products of hydrogenation of naphthalene, naphthols and phenols as for instance tetrahydroand decahydronaphthalene, hydrogenated naphthols, cyclohexanol, methylcylohexanols and mixtures of these substances.
- phenolic substances ordinary phenol, then especially the cresols and mixtures of them, further the higher phenol homologues may be used.
- a raw and unbowked cotton fabric is mercerized with a caustic soda lye'of 34 B. to which 1 of a mixture of 91% of a cresol mixture 'and 9% of a methylcycloincreased elasticity together with a deeper mercerization than that mercerized according to the old mercerizing process. Further the operation is carried out in a shorter time than is the ca e Without the mixt re.
- Emample 2 fil of a mixture of 95% of cresols and 5% of tetrahydronaphthalene is added a to a mercerizing lye of 36 B. the same efl'ect 5 as described in Example 1 is observed.
- Example 3 A viscose fabric containing fibers which have been produced in different manufacturing operations is passed through a mercerizing lye of 20 B. to which 1 (calculated on the weight of the lye) of a mixture oiE 90% of a cresolimixtu're and 10% of methylcyclohexanolmixture are added. The fabric is then squeezed out. The fabric thus treated vcan be dyed in more even shades than without this treatment. 7 What I claim is:
- An improved process for thetreatment of natural and artificial cellulose fibers with alkali consisting in adding a mixture of a phenol and hydrogenated aromatic substances to the alkaline medium.
- An improved process for the treatment of natural and artificial cellulosic fibers with alkali consisting in adding. a mixture of a 1 cresol mixture and a methylcyclohexanol mixture to the alkaline medium.
- An improvedprocess for the treatment of natural and artificial cellulosic fibers with alkali consisting in adding a mixture of 212% of hydrogenated aromatic substances and of 98-88% of phenolic substances to the ⁇ 35 alkaline lye, said mixture being added in quantities of 12% reckoned on .the weight of the lye.
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Coloring (AREA)
- Treatment Of Fiber Materials (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (11)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEC38909D DE591923C (de) | 1926-10-29 | 1926-10-29 | Verfahren zur Erhoehung der Netzfaehigkeit von Mercerisierlaugen |
DEC43256D DE669426C (de) | 1926-10-29 | 1929-06-17 | Verfahren zum Mercerisieren |
DE1930C0000330 DE593048C (de) | 1926-10-29 | 1930-01-15 | Verfahren zur Erhoehung der Netzfaehigkeit von Mercerisierlaugen |
DE1930C0000630 DE661428C (de) | 1926-10-29 | 1930-01-16 | Mercerisieren |
DE374214X | 1930-04-23 | ||
DE1930C0005330 DE614913C (de) | 1926-10-29 | 1930-05-27 | Verfahren zur Erhoehung der Netzfaehigkeit von Mercerisierlaugen |
DE360472X | 1930-06-14 | ||
DE361865X | 1930-06-16 | ||
DE1930C0007930 DE674894C (de) | 1926-10-29 | 1930-07-31 | Verfahren zum Verbessern der Mercerisierlaugen |
DE1930C0009130 DE679766C (de) | 1926-10-29 | 1930-08-21 | Verfahren zum Mercerisieren |
DE382373X | 1930-09-16 |
Publications (1)
Publication Number | Publication Date |
---|---|
US1776052A true US1776052A (en) | 1930-09-16 |
Family
ID=31950999
Family Applications (8)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US218109A Expired - Lifetime US1776052A (en) | 1926-10-29 | 1927-09-07 | Process for treating cellulosic fibers with alkali |
US459122A Expired - Lifetime US1851914A (en) | 1926-10-29 | 1930-06-03 | Manufacture and use of new wetting preparations |
US473773A Expired - Lifetime US1851393A (en) | 1926-10-29 | 1930-08-07 | Preparation of wetting agents for use in mercerizing lyes |
US475373A Expired - Lifetime US1851394A (en) | 1926-10-29 | 1930-08-14 | Preparation of wetting agents |
US506507A Expired - Lifetime US2008459A (en) | 1926-10-29 | 1931-01-03 | Process for increasing the wettingout power of alkaline lyes |
US506506A Expired - Lifetime US2008458A (en) | 1926-10-29 | 1931-01-03 | Process for increasing the wettingout power of alkaline lyes |
US537225A Expired - Lifetime US1976886A (en) | 1926-10-29 | 1931-05-13 | Preparation of wetting agents for use in alkalizing lyes |
US552547A Expired - Lifetime US1998550A (en) | 1926-10-29 | 1931-07-22 | Preparation of wetting agents for use in mercerizing lyes |
Family Applications After (7)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US459122A Expired - Lifetime US1851914A (en) | 1926-10-29 | 1930-06-03 | Manufacture and use of new wetting preparations |
US473773A Expired - Lifetime US1851393A (en) | 1926-10-29 | 1930-08-07 | Preparation of wetting agents for use in mercerizing lyes |
US475373A Expired - Lifetime US1851394A (en) | 1926-10-29 | 1930-08-14 | Preparation of wetting agents |
US506507A Expired - Lifetime US2008459A (en) | 1926-10-29 | 1931-01-03 | Process for increasing the wettingout power of alkaline lyes |
US506506A Expired - Lifetime US2008458A (en) | 1926-10-29 | 1931-01-03 | Process for increasing the wettingout power of alkaline lyes |
US537225A Expired - Lifetime US1976886A (en) | 1926-10-29 | 1931-05-13 | Preparation of wetting agents for use in alkalizing lyes |
US552547A Expired - Lifetime US1998550A (en) | 1926-10-29 | 1931-07-22 | Preparation of wetting agents for use in mercerizing lyes |
Country Status (5)
Country | Link |
---|---|
US (8) | US1776052A (fr) |
DE (2) | DE669426C (fr) |
FR (7) | FR38872E (fr) |
GB (11) | GB279784A (fr) |
NL (6) | NL28346C (fr) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE751172C (de) * | 1932-04-27 | 1954-01-04 | Boehme Fettchemie Ges M B H | Netzmittel fuer Mercerisierlaugen |
DE753403C (de) * | 1935-11-20 | 1952-11-24 | Ig Farbenindustrie Ag | Wasch-, Netz-, Reinigungs-, Schaum- und Dispergiermittel |
US2497519A (en) * | 1946-12-04 | 1950-02-14 | Alrose Chemical Company | Art of stabilizing rayon type fabric |
US2971918A (en) * | 1957-01-07 | 1961-02-14 | Solventol Chemical Products In | Paint stripper composition |
US3027223A (en) * | 1957-12-11 | 1962-03-27 | Dow Chemical Co | Caustic mercerizing solutions |
US3279901A (en) * | 1963-08-30 | 1966-10-18 | Exxon Research Engineering Co | Distillate fuels |
US4384113A (en) * | 1982-03-23 | 1983-05-17 | The Dow Chemical Company | Stabilization of alkali polysaccharides |
US5379807A (en) * | 1993-11-22 | 1995-01-10 | Kelley; Jerry | Shuttle weft yarn control |
-
0
- NL NL30506D patent/NL30506C/xx active
- NL NL30262D patent/NL30262C/xx active
- NL NL30555D patent/NL30555C/xx active
-
1927
- 1927-06-10 GB GB15544/27A patent/GB279784A/en not_active Expired
- 1927-09-07 US US218109A patent/US1776052A/en not_active Expired - Lifetime
-
1929
- 1929-06-17 DE DEC43256D patent/DE669426C/de not_active Expired
-
1930
- 1930-06-03 US US459122A patent/US1851914A/en not_active Expired - Lifetime
- 1930-06-11 FR FR38872D patent/FR38872E/fr not_active Expired
- 1930-06-16 GB GB18408/30A patent/GB359399A/en not_active Expired
- 1930-06-16 NL NL52154A patent/NL28346C/xx active
- 1930-08-04 FR FR38915D patent/FR38915E/fr not_active Expired
- 1930-08-06 GB GB23562/30A patent/GB360472A/en not_active Expired
- 1930-08-07 US US473773A patent/US1851393A/en not_active Expired - Lifetime
- 1930-08-12 FR FR39219D patent/FR39219E/fr not_active Expired
- 1930-08-14 US US475373A patent/US1851394A/en not_active Expired - Lifetime
- 1930-08-21 DE DE1930C0009130 patent/DE679766C/de not_active Expired
- 1930-08-25 GB GB25356/30A patent/GB361865A/en not_active Expired
-
1931
- 1931-01-03 US US506507A patent/US2008459A/en not_active Expired - Lifetime
- 1931-01-03 US US506506A patent/US2008458A/en not_active Expired - Lifetime
- 1931-01-09 NL NL55095A patent/NL28668C/xx active
- 1931-01-09 GB GB831/31A patent/GB364844A/en not_active Expired
- 1931-01-12 FR FR39681D patent/FR39681E/fr not_active Expired
- 1931-01-16 GB GB1521/31A patent/GB365323A/en not_active Expired
- 1931-04-20 FR FR40131D patent/FR40131E/fr not_active Expired
- 1931-04-23 GB GB12102/31A patent/GB374214A/en not_active Expired
- 1931-05-13 US US537225A patent/US1976886A/en not_active Expired - Lifetime
- 1931-05-21 NL NL56978A patent/NL30340C/xx active
- 1931-05-21 FR FR40318D patent/FR40318E/fr not_active Expired
- 1931-05-22 GB GB15194/31A patent/GB368606A/en not_active Expired
- 1931-07-22 US US552547A patent/US1998550A/en not_active Expired - Lifetime
- 1931-07-24 FR FR40615D patent/FR40615E/fr not_active Expired
- 1931-07-29 GB GB21692/31A patent/GB378194A/en not_active Expired
- 1931-08-12 GB GB22803/31A patent/GB382345A/en not_active Expired
- 1931-09-11 GB GB25545/31A patent/GB382373A/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
GB382345A (en) | 1932-10-27 |
GB378194A (en) | 1932-08-11 |
US2008459A (en) | 1935-07-16 |
NL30555C (fr) | |
GB361865A (en) | 1931-11-25 |
GB360472A (en) | 1931-11-06 |
FR39681E (fr) | 1932-02-17 |
FR40615E (fr) | 1932-07-27 |
NL30340C (nl) | 1933-07-15 |
GB359399A (fr) | 1931-10-16 |
GB364844A (en) | 1932-01-14 |
US1851914A (en) | 1932-03-29 |
FR38915E (fr) | 1931-08-07 |
US1851394A (en) | 1932-03-29 |
GB368606A (en) | 1932-03-10 |
NL28346C (nl) | 1932-11-15 |
FR38872E (fr) | 1931-08-07 |
US1976886A (en) | 1934-10-16 |
GB365323A (en) | 1932-01-21 |
GB374214A (en) | 1932-06-09 |
GB279784A (en) | 1927-12-22 |
DE679766C (de) | 1939-08-12 |
NL28668C (nl) | 1932-12-15 |
DE669426C (de) | 1938-12-24 |
US1998550A (en) | 1935-04-23 |
US2008458A (en) | 1935-07-16 |
GB382373A (en) | 1932-10-27 |
FR40131E (fr) | 1932-04-20 |
NL30506C (fr) | |
NL30262C (fr) | |
US1851393A (en) | 1932-03-29 |
FR40318E (fr) | 1932-06-09 |
FR39219E (fr) | 1931-10-21 |
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