UA97127C2 - Способ непрерывной ферментативной обработки композиции, содержащей липид, и система для его осуществления - Google Patents
Способ непрерывной ферментативной обработки композиции, содержащей липид, и система для его осуществления Download PDFInfo
- Publication number
- UA97127C2 UA97127C2 UAA200906940A UAA200906940A UA97127C2 UA 97127 C2 UA97127 C2 UA 97127C2 UA A200906940 A UAA200906940 A UA A200906940A UA A200906940 A UAA200906940 A UA A200906940A UA 97127 C2 UA97127 C2 UA 97127C2
- Authority
- UA
- Ukraine
- Prior art keywords
- oil
- enzyme
- silica
- fixed bed
- lipid
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 153
- 150000002632 lipids Chemical class 0.000 title claims abstract description 69
- 230000002255 enzymatic effect Effects 0.000 title claims abstract description 47
- 102000004190 Enzymes Human genes 0.000 claims abstract description 141
- 108090000790 Enzymes Proteins 0.000 claims abstract description 141
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 133
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 57
- 238000002203 pretreatment Methods 0.000 claims abstract description 20
- 239000003921 oil Substances 0.000 claims description 101
- 235000019198 oils Nutrition 0.000 claims description 101
- 230000008569 process Effects 0.000 claims description 81
- 239000000203 mixture Substances 0.000 claims description 66
- 239000003925 fat Substances 0.000 claims description 53
- 235000019197 fats Nutrition 0.000 claims description 53
- 238000012545 processing Methods 0.000 claims description 49
- 238000006243 chemical reaction Methods 0.000 claims description 39
- 239000000654 additive Substances 0.000 claims description 37
- 230000000996 additive effect Effects 0.000 claims description 36
- 230000000694 effects Effects 0.000 claims description 33
- 239000000463 material Substances 0.000 claims description 27
- 239000007858 starting material Substances 0.000 claims description 22
- 150000004665 fatty acids Chemical class 0.000 claims description 12
- 239000012530 fluid Substances 0.000 claims description 11
- 150000002148 esters Chemical class 0.000 claims description 10
- 239000011148 porous material Substances 0.000 claims description 10
- 238000012423 maintenance Methods 0.000 claims description 9
- 239000000126 substance Substances 0.000 claims description 9
- 108090001060 Lipase Proteins 0.000 claims description 8
- 102000004882 Lipase Human genes 0.000 claims description 8
- 239000004367 Lipase Substances 0.000 claims description 8
- 230000015572 biosynthetic process Effects 0.000 claims description 8
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 8
- 239000000194 fatty acid Substances 0.000 claims description 8
- 229930195729 fatty acid Natural products 0.000 claims description 8
- 235000019421 lipase Nutrition 0.000 claims description 8
- 235000019482 Palm oil Nutrition 0.000 claims description 6
- 239000002540 palm oil Substances 0.000 claims description 6
- 235000012424 soybean oil Nutrition 0.000 claims description 6
- 239000003549 soybean oil Substances 0.000 claims description 6
- 238000005809 transesterification reaction Methods 0.000 claims description 6
- ZIIUUSVHCHPIQD-UHFFFAOYSA-N 2,4,6-trimethyl-N-[3-(trifluoromethyl)phenyl]benzenesulfonamide Chemical compound CC1=CC(C)=CC(C)=C1S(=O)(=O)NC1=CC=CC(C(F)(F)F)=C1 ZIIUUSVHCHPIQD-UHFFFAOYSA-N 0.000 claims description 5
- 108090000371 Esterases Proteins 0.000 claims description 5
- 102000004157 Hydrolases Human genes 0.000 claims description 5
- 108090000604 Hydrolases Proteins 0.000 claims description 5
- 108091005804 Peptidases Proteins 0.000 claims description 5
- 102000015439 Phospholipases Human genes 0.000 claims description 5
- 108010064785 Phospholipases Proteins 0.000 claims description 5
- 239000004365 Protease Substances 0.000 claims description 5
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 claims description 5
- 102000040430 polynucleotide Human genes 0.000 claims description 5
- 108091033319 polynucleotide Proteins 0.000 claims description 5
- 239000002157 polynucleotide Substances 0.000 claims description 5
- 238000003786 synthesis reaction Methods 0.000 claims description 5
- 241000252203 Clupea harengus Species 0.000 claims description 4
- 244000068988 Glycine max Species 0.000 claims description 4
- 235000010469 Glycine max Nutrition 0.000 claims description 4
- 238000004458 analytical method Methods 0.000 claims description 4
- 239000010495 camellia oil Substances 0.000 claims description 4
- 235000019519 canola oil Nutrition 0.000 claims description 4
- 239000000828 canola oil Substances 0.000 claims description 4
- 230000008878 coupling Effects 0.000 claims description 4
- 238000010168 coupling process Methods 0.000 claims description 4
- 238000005859 coupling reaction Methods 0.000 claims description 4
- 235000019514 herring Nutrition 0.000 claims description 4
- 244000005700 microbiome Species 0.000 claims description 4
- 235000015112 vegetable and seed oil Nutrition 0.000 claims description 4
- 238000004891 communication Methods 0.000 claims description 3
- 235000021388 linseed oil Nutrition 0.000 claims description 3
- 239000000944 linseed oil Substances 0.000 claims description 3
- 229920006395 saturated elastomer Polymers 0.000 claims description 3
- 239000008158 vegetable oil Substances 0.000 claims description 3
- 240000001548 Camellia japonica Species 0.000 claims description 2
- 235000019487 Hazelnut oil Nutrition 0.000 claims description 2
- 229910000503 Na-aluminosilicate Inorganic materials 0.000 claims description 2
- 235000019483 Peanut oil Nutrition 0.000 claims description 2
- 235000019484 Rapeseed oil Nutrition 0.000 claims description 2
- 235000019774 Rice Bran oil Nutrition 0.000 claims description 2
- 235000019485 Safflower oil Nutrition 0.000 claims description 2
- 241001125046 Sardina pilchardus Species 0.000 claims description 2
- 235000019486 Sunflower oil Nutrition 0.000 claims description 2
- 238000009395 breeding Methods 0.000 claims description 2
- 230000001488 breeding effect Effects 0.000 claims description 2
- 239000004359 castor oil Substances 0.000 claims description 2
- 235000019438 castor oil Nutrition 0.000 claims description 2
- 235000019864 coconut oil Nutrition 0.000 claims description 2
- 239000003240 coconut oil Substances 0.000 claims description 2
- 239000008119 colloidal silica Substances 0.000 claims description 2
- 239000010636 coriander oil Substances 0.000 claims description 2
- 235000005687 corn oil Nutrition 0.000 claims description 2
- 239000002285 corn oil Substances 0.000 claims description 2
- 235000012343 cottonseed oil Nutrition 0.000 claims description 2
- 239000002385 cottonseed oil Substances 0.000 claims description 2
- 235000021323 fish oil Nutrition 0.000 claims description 2
- 229910021485 fumed silica Inorganic materials 0.000 claims description 2
- 239000005350 fused silica glass Substances 0.000 claims description 2
- 238000012239 gene modification Methods 0.000 claims description 2
- 230000005017 genetic modification Effects 0.000 claims description 2
- 235000013617 genetically modified food Nutrition 0.000 claims description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 2
- 239000010468 hazelnut oil Substances 0.000 claims description 2
- 239000010460 hemp oil Substances 0.000 claims description 2
- 239000000017 hydrogel Substances 0.000 claims description 2
- 235000008390 olive oil Nutrition 0.000 claims description 2
- 239000004006 olive oil Substances 0.000 claims description 2
- 239000000312 peanut oil Substances 0.000 claims description 2
- 239000002994 raw material Substances 0.000 claims description 2
- 239000008165 rice bran oil Substances 0.000 claims description 2
- 235000005713 safflower oil Nutrition 0.000 claims description 2
- 239000003813 safflower oil Substances 0.000 claims description 2
- 235000019512 sardine Nutrition 0.000 claims description 2
- 239000000429 sodium aluminium silicate Substances 0.000 claims description 2
- 235000012217 sodium aluminium silicate Nutrition 0.000 claims description 2
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims description 2
- 239000002600 sunflower oil Substances 0.000 claims description 2
- 235000020238 sunflower seed Nutrition 0.000 claims description 2
- 239000003760 tallow Substances 0.000 claims description 2
- 230000009088 enzymatic function Effects 0.000 claims 3
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid group Chemical group C(CCCCCCC\C=C/CCCCCCCC)(=O)O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims 2
- 239000003039 volatile agent Substances 0.000 claims 2
- 108700023418 Amidases Proteins 0.000 claims 1
- 102000005922 amidase Human genes 0.000 claims 1
- 235000020778 linoleic acid Nutrition 0.000 claims 1
- OYHQOLUKZRVURQ-HZJYTTRNSA-N linoleic acid group Chemical group C(CCCCCCC\C=C/C\C=C/CCCCC)(=O)O OYHQOLUKZRVURQ-HZJYTTRNSA-N 0.000 claims 1
- 239000003346 palm kernel oil Substances 0.000 claims 1
- 235000019865 palm kernel oil Nutrition 0.000 claims 1
- 238000011144 upstream manufacturing Methods 0.000 claims 1
- 239000006057 Non-nutritive feed additive Substances 0.000 abstract 3
- 239000000047 product Substances 0.000 description 56
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 42
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 31
- 238000012360 testing method Methods 0.000 description 24
- 239000003054 catalyst Substances 0.000 description 19
- 238000009886 enzymatic interesterification Methods 0.000 description 18
- 150000002978 peroxides Chemical class 0.000 description 15
- 238000009884 interesterification Methods 0.000 description 13
- 238000004519 manufacturing process Methods 0.000 description 12
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 11
- 239000000741 silica gel Substances 0.000 description 11
- 229910002027 silica gel Inorganic materials 0.000 description 11
- 239000007787 solid Substances 0.000 description 10
- 239000002585 base Substances 0.000 description 9
- 238000004061 bleaching Methods 0.000 description 9
- 239000011521 glass Substances 0.000 description 9
- 229910052751 metal Inorganic materials 0.000 description 8
- 239000002184 metal Substances 0.000 description 8
- 150000002739 metals Chemical class 0.000 description 8
- 239000000344 soap Substances 0.000 description 8
- 108010093096 Immobilized Enzymes Proteins 0.000 description 7
- 239000000758 substrate Substances 0.000 description 7
- 235000014698 Brassica juncea var multisecta Nutrition 0.000 description 6
- WQDUMFSSJAZKTM-UHFFFAOYSA-N Sodium methoxide Chemical compound [Na+].[O-]C WQDUMFSSJAZKTM-UHFFFAOYSA-N 0.000 description 6
- 239000011324 bead Substances 0.000 description 6
- 150000003904 phospholipids Chemical class 0.000 description 6
- 229930003799 tocopherol Natural products 0.000 description 6
- 239000011732 tocopherol Substances 0.000 description 6
- 230000008901 benefit Effects 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- 230000007423 decrease Effects 0.000 description 5
- 238000011156 evaluation Methods 0.000 description 5
- 239000012535 impurity Substances 0.000 description 5
- 238000002844 melting Methods 0.000 description 5
- 230000008018 melting Effects 0.000 description 5
- 238000012544 monitoring process Methods 0.000 description 5
- 239000000523 sample Substances 0.000 description 5
- 235000010692 trans-unsaturated fatty acids Nutrition 0.000 description 5
- 150000003626 triacylglycerols Chemical class 0.000 description 5
- 244000275904 brauner Senf Species 0.000 description 4
- 230000008859 change Effects 0.000 description 4
- 238000009885 chemical interesterification Methods 0.000 description 4
- 235000004977 Brassica sinapistrum Nutrition 0.000 description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 239000004927 clay Substances 0.000 description 3
- 238000005056 compaction Methods 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- GVJHHUAWPYXKBD-UHFFFAOYSA-N d-alpha-tocopherol Natural products OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 description 3
- 230000009849 deactivation Effects 0.000 description 3
- 230000003247 decreasing effect Effects 0.000 description 3
- 238000004332 deodorization Methods 0.000 description 3
- 239000012467 final product Substances 0.000 description 3
- 235000021588 free fatty acids Nutrition 0.000 description 3
- 238000005984 hydrogenation reaction Methods 0.000 description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 235000013310 margarine Nutrition 0.000 description 3
- 238000003825 pressing Methods 0.000 description 3
- 238000000746 purification Methods 0.000 description 3
- 230000008439 repair process Effects 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 239000010703 silicon Substances 0.000 description 3
- 229960001295 tocopherol Drugs 0.000 description 3
- 235000010384 tocopherol Nutrition 0.000 description 3
- 125000002640 tocopherol group Chemical class 0.000 description 3
- 235000019149 tocopherols Nutrition 0.000 description 3
- GVJHHUAWPYXKBD-IEOSBIPESA-N α-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-IEOSBIPESA-N 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 235000006008 Brassica napus var napus Nutrition 0.000 description 2
- 235000006618 Brassica rapa subsp oleifera Nutrition 0.000 description 2
- 244000188595 Brassica sinapistrum Species 0.000 description 2
- 235000001950 Elaeis guineensis Nutrition 0.000 description 2
- 244000127993 Elaeis melanococca Species 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- 241001465754 Metazoa Species 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 238000005119 centrifugation Methods 0.000 description 2
- 239000002738 chelating agent Substances 0.000 description 2
- ATNHDLDRLWWWCB-AENOIHSZSA-M chlorophyll a Chemical compound C1([C@@H](C(=O)OC)C(=O)C2=C3C)=C2N2C3=CC(C(CC)=C3C)=[N+]4C3=CC3=C(C=C)C(C)=C5N3[Mg-2]42[N+]2=C1[C@@H](CCC(=O)OC\C=C(/C)CCC[C@H](C)CCC[C@H](C)CCCC(C)C)[C@H](C)C2=C5 ATNHDLDRLWWWCB-AENOIHSZSA-M 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 238000012790 confirmation Methods 0.000 description 2
- 239000000356 contaminant Substances 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- -1 diglycerides Chemical class 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 238000011049 filling Methods 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- 239000003365 glass fiber Substances 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 239000003264 margarine Substances 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 231100000614 poison Toxicity 0.000 description 2
- 230000008092 positive effect Effects 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000007781 pre-processing Methods 0.000 description 2
- 108090000765 processed proteins & peptides Proteins 0.000 description 2
- 238000007670 refining Methods 0.000 description 2
- 238000005070 sampling Methods 0.000 description 2
- UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 description 2
- DCXXMTOCNZCJGO-UHFFFAOYSA-N tristearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC DCXXMTOCNZCJGO-UHFFFAOYSA-N 0.000 description 2
- 235000013311 vegetables Nutrition 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000010457 zeolite Substances 0.000 description 2
- DYLIWHYUXAJDOJ-OWOJBTEDSA-N (e)-4-(6-aminopurin-9-yl)but-2-en-1-ol Chemical compound NC1=NC=NC2=C1N=CN2C\C=C\CO DYLIWHYUXAJDOJ-OWOJBTEDSA-N 0.000 description 1
- 241000251468 Actinopterygii Species 0.000 description 1
- 240000002791 Brassica napus Species 0.000 description 1
- 241001311578 Calyptraea chinensis Species 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 235000016622 Filipendula ulmaria Nutrition 0.000 description 1
- 244000061544 Filipendula vulgaris Species 0.000 description 1
- 229930186217 Glycolipid Natural products 0.000 description 1
- 244000020551 Helianthus annuus Species 0.000 description 1
- 235000003222 Helianthus annuus Nutrition 0.000 description 1
- 241000189718 Hoplosternum Species 0.000 description 1
- 241001026509 Kata Species 0.000 description 1
- 241000207836 Olea <angiosperm> Species 0.000 description 1
- 241000997494 Oneirodidae Species 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 229930182558 Sterol Natural products 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 238000006136 alcoholysis reaction Methods 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 229960000892 attapulgite Drugs 0.000 description 1
- OGBUMNBNEWYMNJ-UHFFFAOYSA-N batilol Chemical class CCCCCCCCCCCCCCCCCCOCC(O)CO OGBUMNBNEWYMNJ-UHFFFAOYSA-N 0.000 description 1
- 235000015278 beef Nutrition 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 239000003225 biodiesel Substances 0.000 description 1
- 230000002051 biphasic effect Effects 0.000 description 1
- 235000014121 butter Nutrition 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000007809 chemical reaction catalyst Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229930002875 chlorophyll Natural products 0.000 description 1
- 235000019804 chlorophyll Nutrition 0.000 description 1
- 238000005352 clarification Methods 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 238000010411 cooking Methods 0.000 description 1
- 235000014541 cooking fats Nutrition 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000012864 cross contamination Methods 0.000 description 1
- 239000010779 crude oil Substances 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000001877 deodorizing effect Effects 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 239000011152 fibreglass Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 235000019688 fish Nutrition 0.000 description 1
- 125000005456 glyceride group Chemical group 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 230000000415 inactivating effect Effects 0.000 description 1
- 230000002779 inactivation Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000002777 nucleoside Substances 0.000 description 1
- 125000003835 nucleoside group Chemical group 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- BHAAPTBBJKJZER-UHFFFAOYSA-N p-anisidine Chemical compound COC1=CC=C(N)C=C1 BHAAPTBBJKJZER-UHFFFAOYSA-N 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 229910052625 palygorskite Inorganic materials 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 239000006069 physical mixture Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 235000015277 pork Nutrition 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 102000004196 processed proteins & peptides Human genes 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- 229910021647 smectite Inorganic materials 0.000 description 1
- 239000008234 soft water Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000000638 solvent extraction Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000001256 steam distillation Methods 0.000 description 1
- 150000003431 steroids Chemical class 0.000 description 1
- 150000003432 sterols Chemical class 0.000 description 1
- 235000003702 sterols Nutrition 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
- 150000003505 terpenes Chemical class 0.000 description 1
- 235000007586 terpenes Nutrition 0.000 description 1
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 description 1
- 238000012549 training Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 125000003203 triacylglycerol group Chemical group 0.000 description 1
- 238000012795 verification Methods 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 235000019155 vitamin A Nutrition 0.000 description 1
- 239000011719 vitamin A Substances 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
- C11C3/00—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
- C11C3/04—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by esterification of fats or fatty oils
- C11C3/10—Ester interchange
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B3/00—Refining fats or fatty oils
- C11B3/003—Refining fats or fatty oils by enzymes or microorganisms, living or dead
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/0242—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly vertical
- B01J8/025—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly vertical in a cylindrical shaped bed
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
- B01J8/0446—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical
- B01J8/0449—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical in two or more cylindrical beds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
- B01J8/0446—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical
- B01J8/0449—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical in two or more cylindrical beds
- B01J8/0457—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical in two or more cylindrical beds the beds being placed in separate reactors
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
- C11C1/00—Preparation of fatty acids from fats, fatty oils, or waxes; Refining the fatty acids
- C11C1/08—Refining
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12M—APPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
- C12M45/00—Means for pre-treatment of biological substances
- C12M45/09—Means for pre-treatment of biological substances by enzymatic treatment
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
- C12P7/00—Preparation of oxygen-containing organic compounds
- C12P7/64—Fats; Fatty oils; Ester-type waxes; Higher fatty acids, i.e. having at least seven carbon atoms in an unbroken chain bound to a carboxyl group; Oxidised oils or fats
- C12P7/6436—Fatty acid esters
- C12P7/6445—Glycerides
- C12P7/6458—Glycerides by transesterification, e.g. interesterification, ester interchange, alcoholysis or acidolysis
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/10—Biofuels, e.g. bio-diesel
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Zoology (AREA)
- Health & Medical Sciences (AREA)
- Microbiology (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Bioinformatics & Cheminformatics (AREA)
- General Chemical & Material Sciences (AREA)
- Biochemistry (AREA)
- Genetics & Genomics (AREA)
- Biotechnology (AREA)
- General Engineering & Computer Science (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Biomedical Technology (AREA)
- Sustainable Development (AREA)
- Physics & Mathematics (AREA)
- Fluid Mechanics (AREA)
- Preparation Of Compounds By Using Micro-Organisms (AREA)
- Apparatus Associated With Microorganisms And Enzymes (AREA)
- Immobilizing And Processing Of Enzymes And Microorganisms (AREA)
- Enzymes And Modification Thereof (AREA)
Abstract
Способ и система для ферментативной обработки исходного материала, содержащего липиды, который включает осуществление контакта исходного материала с технологической добавкой, содержащей кремнезем, который имеет средний размер пор более чем 150 ангстрем и менее чем 10 % летучих веществ по массе, пропускание исходного материала с, по сути, постоянной скоростью потока через систему обработки, которая включает несколько реакторов, содержащих фермент, с неподвижным слоем, соединенных друг с другом последовательно. Реакторы с неподвижным слоем могут обслуживаться индивидуально, скорость потока исходного материала через систему остается, по сути, постоянной при отключении одного реактора для обслуживания. Технологическая д�
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US11/567,318 US8361763B2 (en) | 2006-12-06 | 2006-12-06 | Continuous process and apparatus for enzymatic treatment of lipids |
PCT/US2006/047018 WO2008069804A1 (en) | 2006-12-06 | 2006-12-08 | A continuous process and apparatus for enzymatic treatment of lipids |
Publications (1)
Publication Number | Publication Date |
---|---|
UA97127C2 true UA97127C2 (ru) | 2012-01-10 |
Family
ID=38267545
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
UAA200906940A UA97127C2 (ru) | 2006-12-06 | 2006-08-12 | Способ непрерывной ферментативной обработки композиции, содержащей липид, и система для его осуществления |
Country Status (15)
Country | Link |
---|---|
US (2) | US8361763B2 (ru) |
EP (1) | EP2094824B1 (ru) |
CN (3) | CN105368586A (ru) |
AR (2) | AR060548A1 (ru) |
BR (1) | BRPI0622189B1 (ru) |
CA (1) | CA2670881C (ru) |
DK (1) | DK2094824T3 (ru) |
ES (1) | ES2427355T3 (ru) |
MX (1) | MX2009005861A (ru) |
MY (1) | MY150772A (ru) |
PL (1) | PL2094824T3 (ru) |
PT (1) | PT2094824E (ru) |
RU (1) | RU2412984C1 (ru) |
UA (1) | UA97127C2 (ru) |
WO (1) | WO2008069804A1 (ru) |
Families Citing this family (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8357503B2 (en) | 2008-08-29 | 2013-01-22 | Bunge Oils, Inc. | Hydrolases, nucleic acids encoding them and methods for making and using them |
US8153391B2 (en) | 2008-08-29 | 2012-04-10 | Bunge Oils, Inc. | Hydrolases, nucleic acids encoding them and methods for making and using them |
US8198062B2 (en) | 2008-08-29 | 2012-06-12 | Dsm Ip Assets B.V. | Hydrolases, nucleic acids encoding them and methods for making and using them |
WO2010036334A1 (en) * | 2008-09-23 | 2010-04-01 | LiveFuels, Inc. | Systems and methods for producing biofuels from algae |
US20100081835A1 (en) * | 2008-09-23 | 2010-04-01 | LiveFuels, Inc. | Systems and methods for producing biofuels from algae |
US20100236137A1 (en) * | 2008-09-23 | 2010-09-23 | LiveFuels, Inc. | Systems and methods for producing eicosapentaenoic acid and docosahexaenoic acid from algae |
WO2010059598A1 (en) * | 2008-11-18 | 2010-05-27 | LiveFuels, Inc. | Methods for producing fish with high lipid content |
WO2010121094A1 (en) | 2009-04-17 | 2010-10-21 | Livefuels. Inc. | Systems and methods for culturing algae with bivalves |
CN102666868A (zh) | 2009-10-21 | 2012-09-12 | 诺维信公司 | 油处理方法 |
CN102687765A (zh) * | 2011-03-21 | 2012-09-26 | 广州市名花香料有限公司 | 一种利用固定酶生物反应器连续制备奶油酸的方法 |
GB2490324B (en) | 2011-04-21 | 2014-06-11 | Desmet Ballestra Engineering S A Nv | Improved enzyme interesterification process |
US9487716B2 (en) | 2011-05-06 | 2016-11-08 | LiveFuels, Inc. | Sourcing phosphorus and other nutrients from the ocean via ocean thermal energy conversion systems |
DK2814470T3 (en) | 2012-02-17 | 2018-07-16 | Alcresta Therapeutics Inc | Methods, compositions and devices for meeting dietary fatty acid requirements |
RU2503249C1 (ru) * | 2012-09-28 | 2014-01-10 | Федеральное государственное унитарное предприятие Тихоокеанский научно-исследовательский рыбохозяйственный центр ФГУП "ТИНРО-Центр" | Способ производства кормовой пасты из рыбного сырья |
CN103642769B (zh) * | 2013-12-05 | 2015-11-25 | 青岛蔚蓝生物集团有限公司 | 一种来源于圆弧青霉的碱性脂肪酶 |
US10258590B2 (en) | 2015-10-14 | 2019-04-16 | Alcresta Therapeutics, Inc. | Enteral feeding device and related methods of use |
WO2017137866A1 (en) | 2016-02-12 | 2017-08-17 | Sabic Global Technologies B.V. | Methods and systems for generating light olefins using a cyclic reactor configuration |
CN106367320B (zh) * | 2016-11-21 | 2023-11-14 | 上海美致臻生物医学科技有限公司 | 一种手动脂肪核心集群细胞、脂肪基质血管组分采集器 |
US11045396B2 (en) | 2017-08-17 | 2021-06-29 | Alcresta Therapeutics, Inc. | Devices and methods for the supplementation of a nutritional formula |
CN108499172B (zh) * | 2018-06-04 | 2024-06-21 | 上海蓝科石化环保科技股份有限公司 | 一种固定床过滤净化系统及流体过滤净化方法 |
CN113684126B (zh) * | 2021-10-26 | 2022-02-15 | 华南理工大学 | 一种多液相体系连续化全酶法合成甘油二酯的装置及方法 |
WO2023229519A1 (en) | 2022-05-27 | 2023-11-30 | Bunge Sa | Batch process for enzymatic modification of lipids |
WO2024041562A1 (en) * | 2022-08-24 | 2024-02-29 | Novozymes A/S | Improved enzymatic splitting of oils and fats to produce free fatty acid |
Family Cites Families (130)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2206168A (en) | 1932-08-22 | 1940-07-02 | Procter & Gamble | Process for manufacturing fatty esters |
US2265837A (en) | 1937-11-13 | 1941-12-09 | Standard Oil Dev Co | Method of and apparatus for carrying out catalytic processes |
GB617078A (en) | 1944-05-27 | 1949-02-01 | Grindstedvaerket As | Method for the production of interface active substances |
US2626852A (en) * | 1949-04-06 | 1953-01-27 | Kaiser Aluminium Chem Corp | Production of sodium sesquicarbonate from a brine containing a substantial sodium carbonate content |
US2626952A (en) | 1949-10-26 | 1953-01-27 | Procter & Gamble | Diglyceride preparation |
US3142545A (en) | 1961-03-24 | 1964-07-28 | Shell Oil Co | System for hydrotreating of hydrocarbons |
US3154481A (en) | 1961-08-31 | 1964-10-27 | Standard Oil Co | Regenerative reforming process |
US3360533A (en) | 1963-06-17 | 1967-12-26 | Procter & Gamble | Process for the improved winterization of oil |
US3392002A (en) | 1964-06-29 | 1968-07-09 | Standard Oil Co | Fixed-bed contacting system |
US3634473A (en) | 1966-11-21 | 1972-01-11 | Scm Corp | Process for manufacture of symmetrical glycerides |
JPS541281B1 (ru) | 1969-01-23 | 1979-01-23 | ||
US3845087A (en) | 1970-11-13 | 1974-10-29 | Lever Brothers Ltd | Isomerization of 1,2-diglycerides to 1,3-diglycerides |
US4032550A (en) | 1975-11-26 | 1977-06-28 | Emery Industries, Inc. | Process for the production of esters |
GB1577933A (en) | 1976-02-11 | 1980-10-29 | Unilever Ltd | Fat process and composition |
US4276322A (en) | 1976-08-02 | 1981-06-30 | Lever Brothers Company | Chocolate having defined hard fat |
US4154749A (en) | 1977-07-08 | 1979-05-15 | Aarjis Poefabrik A/S | Method for catalytic rearrangement of 1,2-diglycerides into 1,3-diglycerides |
NL191022C (nl) | 1978-01-20 | 1994-12-16 | Shell Int Research | Inrichting geschikt voor het katalytisch hydrogenerend behandelen van zware koolwaterstofoliën. |
US4263216A (en) | 1978-10-20 | 1981-04-21 | The Procter & Gamble Company | Diglyceride manufacture |
JPS5571797A (en) | 1978-11-21 | 1980-05-30 | Fuji Oil Co Ltd | Manufacture of cacao butter substitute fat |
JPS561888A (en) * | 1979-06-19 | 1981-01-10 | Nitto Chem Ind Co Ltd | Preparation of concentrated aqueous solution of acrylamide with microorganism |
US4284580A (en) * | 1980-01-02 | 1981-08-18 | The Procter & Gamble Company | Fractionation of triglyceride mixture |
DE3163939D1 (en) | 1980-03-08 | 1984-07-12 | Fuji Oil Co Ltd | Method for enzymatic interesterification of lipid and enzyme used therein |
EP0064855B1 (en) | 1981-05-07 | 1986-09-17 | Unilever Plc | Fat processing |
US4420560A (en) | 1981-11-17 | 1983-12-13 | Fuji Oil Company, Limited | Method for modification of fats and oils |
US4406777A (en) | 1982-01-19 | 1983-09-27 | Mobil Oil Corporation | Fixed bed reactor operation |
IE54838B1 (en) | 1982-04-30 | 1990-02-28 | Unilever Plc | Improvements in and relating to interesterification of triglycerides of fatty acids |
GB2137112B (en) | 1983-03-28 | 1986-12-03 | Shell Int Research | Replacement of particles in vessels |
US5292649A (en) | 1983-03-29 | 1994-03-08 | Agency Of Industrial Science & Technology, Ministy Of International Trade & Industry | Method for reaction of lipase upon fatty acid |
US4789528A (en) | 1983-04-26 | 1988-12-06 | Mobil Oil Corporation | Technique for sequential rotation of reactors in a multi-reactor catalytic conversion system |
DE3468433D1 (en) | 1983-05-19 | 1988-02-11 | Asahi Denka Kogyo Kk | Reaction method for transesterifying fats and oils |
JPS6034189A (ja) | 1983-08-02 | 1985-02-21 | Kanegafuchi Chem Ind Co Ltd | 油脂のエステル交換法 |
DK402583D0 (da) | 1983-09-05 | 1983-09-05 | Novo Industri As | Fremgangsmade til fremstilling af et immobiliseret lipasepraeparat og anvendelse deraf |
US4940845A (en) | 1984-05-30 | 1990-07-10 | Kao Corporation | Esterification process of fats and oils and enzymatic preparation to use therein |
GB8418154D0 (en) | 1984-07-17 | 1984-08-22 | Unilever Plc | Edible fat composition |
US4627192B1 (en) | 1984-11-16 | 1995-10-17 | Sigco Res Inc | Sunflower products and methods for their production |
US4594259A (en) | 1984-12-21 | 1986-06-10 | The Procter & Gamble Company | Temperable confectionery compositions having improved mouth melt suitable for chocolate |
US4735900A (en) | 1984-12-21 | 1988-04-05 | Kao Corporation | Enzyme preparation for interesterification |
US5270188A (en) | 1985-02-06 | 1993-12-14 | Amano Pharmaceutical Co., Ltd. | Preparation of glycerides having a high content of monglycerides with a lipase from Penicillium cyclopium ATCC 34613 |
US5219733A (en) | 1985-03-06 | 1993-06-15 | Yoshikawa Oil & Fat Co., Ltd. | Process for preparing fatty acid esters |
JPH0779621B2 (ja) | 1985-03-25 | 1995-08-30 | 花王株式会社 | カカオバタ−代用組成物 |
JPS61287989A (ja) | 1985-06-14 | 1986-12-18 | 花王株式会社 | 油脂の加水分解方法 |
US4629742A (en) | 1986-01-27 | 1986-12-16 | Akzo America Inc. | Hydrolysis of fats |
GB2188057B (en) | 1986-02-04 | 1990-03-07 | Inst Penyelidikan Minyak Kelap | Transesterification of fats and oils |
SE452166B (sv) | 1986-03-10 | 1987-11-16 | Berol Kemi Ab | Forfarande for transesterifiering av triglycerider |
US5336794A (en) | 1986-05-14 | 1994-08-09 | W. R. Grace & Co.-Conn. | Dual phase adsorption and treatment of glyceride oils |
US4797233A (en) | 1986-08-20 | 1989-01-10 | Uop Inc. | Process for separating mono-, di- and triglycerides |
US5204251A (en) | 1987-05-11 | 1993-04-20 | Kanegafuchi Kagaku Kogyo & Kabushiki Kaisha | Process of enzymatic interesterification maintaining a water content of 30-300 ppm using Rhizopus |
US4781864A (en) * | 1987-05-15 | 1988-11-01 | W. R. Grace & Co.-Conn. | Process for the removal of chlorophyll, color bodies and phospholipids from glyceride oils using acid-treated silica adsorbents |
JPS63296698A (ja) | 1987-05-29 | 1988-12-02 | Lion Corp | 高純度モノグリセリドの連続製造方法 |
US4770819A (en) | 1987-07-06 | 1988-09-13 | Uop Inc. | Process for separating di- and triglycerides |
US5124166A (en) | 1987-08-13 | 1992-06-23 | Nabisco, Inc. | Carboxy/carboxylate disubstituted esters as edible fat mimetics |
US5219744A (en) | 1987-08-26 | 1993-06-15 | Ajinomoto Co., Inc. | Process for modifying fats and oils |
US5190868A (en) | 1987-08-31 | 1993-03-02 | Meito Sangyo Co., Ltd. | Continuous process for the interesterification of fats or oils |
JPH0665311B2 (ja) | 1987-09-09 | 1994-08-24 | 花王株式会社 | ジグリセリドの製造法 |
JPH0198494A (ja) | 1987-10-09 | 1989-04-17 | Agency Of Ind Science & Technol | バイオリアクター |
EP0319126B1 (en) | 1987-10-14 | 1995-11-08 | Kao Corporation | Process for preparation of polyol fatty acid ester and glyceride mixture obtained |
US4880652A (en) | 1987-12-04 | 1989-11-14 | Gycor International Ltd. | Method of filtering edible liquids |
ES2073405T3 (es) | 1987-12-09 | 1995-08-16 | Kao Corp | Enzima inmovilizada y esterificacion e interesterificacion de la misma. |
JP2571587B2 (ja) | 1987-12-22 | 1997-01-16 | 旭電化工業株式会社 | 油脂のエステル交換方法 |
JPH01312995A (ja) | 1988-06-14 | 1989-12-18 | Japanese Res & Dev Assoc Bio Reactor Syst Food Ind | 酵素による油脂の改質方法 |
US4883684A (en) | 1988-07-01 | 1989-11-28 | The Procter & Gamble Company | Functional hardstock fat composition |
US5264597A (en) * | 1988-09-30 | 1993-11-23 | Van Den Bergh Foods, Co., Division Of Conopco, Inc. | Process for refining glyceride oil using precipitated silica |
US5316927A (en) | 1988-10-04 | 1994-05-31 | Opta Food Ingredients, Inc. | Production of monoglycerides by enzymatic transesterification |
JPH0738771B2 (ja) | 1989-01-17 | 1995-05-01 | 花王株式会社 | 液状食用油組成物 |
US5935828A (en) | 1989-05-01 | 1999-08-10 | Opta Food Ingredients, Inc. | Enzymatic production of monoglycerides containing omega-3 unsaturated fatty acids |
US5183750A (en) | 1989-05-26 | 1993-02-02 | Kao Corporation | Processes for the production of phosphatidic acid |
US5108916A (en) | 1989-06-05 | 1992-04-28 | Rhone-Poulenc Rorer, S.A. | Process for stereoselectively hydrolyzing, transesterifying or esterifying with immobilized isozyme of lipase from candida rugosa |
JP2794201B2 (ja) | 1989-07-31 | 1998-09-03 | 味の素株式会社 | 固定化リパーゼ酵素剤 |
US5434278A (en) | 1989-09-20 | 1995-07-18 | Nabisco, Inc. | Synthesis of acetoglyceride fats |
JPH075803B2 (ja) * | 1989-10-16 | 1995-01-25 | チッソ株式会社 | 高立体規則性ポリプロピレン組成物の製造方法 |
GB8925352D0 (en) | 1989-11-09 | 1989-12-28 | Unilever Plc | Fats |
US5288619A (en) | 1989-12-18 | 1994-02-22 | Kraft General Foods, Inc. | Enzymatic method for preparing transesterified oils |
US5142072A (en) | 1989-12-19 | 1992-08-25 | The Procter & Gamble Company | Selective esterification of long chain fatty acid monoglycerides with medium chain fatty acid anhydrides |
US5116745A (en) | 1990-04-19 | 1992-05-26 | The Procter & Gamble Company | Process for preparing 2-acylglycerides or 1,2-diacyl diglycerides or 2,3-diacyl diglycerides |
US5149642A (en) | 1990-04-20 | 1992-09-22 | The Procter & Gamble Company | Process for preparing 2-acylglycerides or 1,2 or 2,3-diacylglycerides |
US5169670A (en) | 1990-05-23 | 1992-12-08 | The Procter & Gamble Company | Low saturate frying oil with fried flavor |
US5225580A (en) * | 1990-08-16 | 1993-07-06 | Uop | Process for separating fatty acids and triglycerides |
US5102582A (en) | 1990-09-17 | 1992-04-07 | Uop | Process for separating fatty acids and triglycerides |
US5137660A (en) | 1991-03-15 | 1992-08-11 | The Procter & Gamble Company | Regioselective synthesis of 1,3-disubstituted glycerides |
US6270828B1 (en) | 1993-11-12 | 2001-08-07 | Cargrill Incorporated | Canola variety producing a seed with reduced glucosinolates and linolenic acid yielding an oil with low sulfur, improved sensory characteristics and increased oxidative stability |
US5445955A (en) | 1992-05-25 | 1995-08-29 | The Nisshin Oil Mills, Ltd. | Immobilization of lipase on a polymer carrier containing epoxy and tertiary amino groups |
US5470741A (en) | 1992-07-22 | 1995-11-28 | Henkel Corporation | Mutant of Geotrichum candidum which produces novel enzyme system to selectively hydrolyze triglycerides |
US5399728A (en) | 1993-04-05 | 1995-03-21 | Arco Chemical Technology, L.P. | Process for the preparation of highly esterified alkoxylated polyol compositions |
ATE154826T1 (de) | 1993-05-13 | 1997-07-15 | Loders Croklaan Bv | Verfahren zur herstellung von muttermilch - fettersatzstoffen |
EP0698090B1 (en) | 1993-05-20 | 1997-11-26 | Loders Croklaan B.V. | Process for preparing immobilized lipases |
JP2668187B2 (ja) | 1993-09-17 | 1997-10-27 | 日清製油株式会社 | リパーゼ粉末を用いたエステル交換法 |
NL9302126A (nl) | 1993-12-07 | 1995-07-03 | Meern Bv Engelhard De | Werkwijze voor het interesterificeren van triglycerides. |
EP0746608B1 (en) * | 1994-02-21 | 2003-08-20 | Novozymes A/S | Method for production of an immobilized enzyme preparation and use of the immobilized enzyme preparation |
GB9404483D0 (en) | 1994-03-08 | 1994-04-20 | Norsk Hydro As | Refining marine oil compositions |
ATE181568T1 (de) | 1994-03-31 | 1999-07-15 | Loders Croklaan Bv | Öle mit niedrigem gehalt an gesättigter fettsäure |
JP3635106B2 (ja) * | 1994-05-25 | 2005-04-06 | 株式会社日本触媒 | 生体触媒による連続反応方法 |
PL324288A1 (en) | 1995-06-27 | 1998-05-11 | Unilever Nv | Immobilised enzyme and application thereof in transformation of triglyceride oils |
US5959128A (en) | 1996-03-13 | 1999-09-28 | Cargill Incorporated | Method for preparation of purified glycerides and products |
US5713965A (en) | 1996-04-12 | 1998-02-03 | The United States Of America As Represented By The Secretary Of Agriculture | Production of biodiesel, lubricants and fuel and lubricant additives |
AR006830A1 (es) | 1996-04-26 | 1999-09-29 | Du Pont | Aceite de soja con alta estabilidad oxidativa |
US5747305A (en) | 1996-07-10 | 1998-05-05 | The United States Of America, As Represented By The Secretary Of Agriculture | Monoglyceride production via enzymatic glycerolysis of oils in supercritical CO2 |
US6004611A (en) | 1996-10-18 | 1999-12-21 | Kao Corporation | General-purpose oils composition |
SK80799A3 (en) | 1996-12-19 | 2000-03-13 | Unilever Nv | Immobilized enzyme and its use for the processing of triglyceride oils |
US6124486A (en) | 1997-01-31 | 2000-09-26 | Eastman Chemical Company | Process for making low calorie triglycerides having long and short fatty acid chains |
US6238926B1 (en) | 1997-09-17 | 2001-05-29 | Cargilll, Incorporated | Partial interesterification of triacylglycerols |
AU8760898A (en) | 1997-09-24 | 1999-04-12 | Enzymotec Ltd. | Surfactant-lipase complex immobilized on insoluble matrix |
US5908655A (en) | 1997-10-21 | 1999-06-01 | Danisco A/S | Shortening system, products therewith, and methods for making and using the same |
FR2772392B1 (fr) | 1997-12-15 | 2000-03-10 | Toulousaine De Rech Et De Dev | Procede et installation de fabrication de monoesters par alcoolyse d'huile vegetale riche en acide oleique |
US5849937A (en) * | 1997-12-19 | 1998-12-15 | Arco Chemical Technology, L.P. | Epoxidation process using serially connected cascade of fixed bed reactors |
TR200002719T2 (tr) | 1998-03-23 | 2000-12-21 | The Procter & Gamble Company | Sindirilmez yağların sentezi ve saflaştırılması ile ilgili gelişmiş yöntemler. |
JP3720194B2 (ja) | 1998-07-09 | 2005-11-24 | 花王株式会社 | 部分グリセリドの製造法 |
JP2002521030A (ja) | 1998-07-22 | 2002-07-16 | セラニーズ ベンチャーズ ゲー・エム・ベー・ハー | 圧縮ガスを使用する同一装置における抽出、反応及びクロマトグラフィーによるバイオマスからの脂肪酸の生産規模製造方法 |
US6258575B1 (en) | 1998-11-26 | 2001-07-10 | Kao Corporation | Hydrolyzing fats and oils using an immobilized enzyme column and substrate-feeding chamber that separates phases |
TR200103523T2 (tr) | 1999-06-04 | 2002-04-22 | Consejo Superior De Investigaciones Cientificas | Yüksek oleik yüksek stearik yağların kullanımı |
US6407269B2 (en) | 1999-06-08 | 2002-06-18 | Kao Corporation | Catalyst for transesterification |
JP3853552B2 (ja) | 1999-12-17 | 2006-12-06 | 花王株式会社 | ジグリセリドの製造方法 |
IL134717A0 (en) | 2000-02-24 | 2001-04-30 | Enzymotec Ltd | Method for increasing the performance of immobilized biocatalysts, and catalysts obtained thereby |
ATE476514T1 (de) | 2000-04-18 | 2010-08-15 | Commw Scient Ind Res Org | Verfahren zur modifizierung des baumwollölgehaltes |
US20030175914A1 (en) | 2000-09-20 | 2003-09-18 | Kai-Uwe Baldenius | Method for producing glycerides of conjugated, polyunsaturated fatty acids on the basis of their alkyl esters |
US20030054509A1 (en) | 2001-04-06 | 2003-03-20 | Archer-Daniels-Midland Company | Method for producing fats or oils |
DE60235303D1 (de) | 2001-07-02 | 2010-03-25 | Suntory Holdings Ltd | Verfahren zur herstellung von fett mit triglyceridhaltiger hochungesättigter fettsäure |
JP4997681B2 (ja) | 2001-09-28 | 2012-08-08 | 住友化学株式会社 | 脂肪酸エステルの製造方法および製造装置 |
CN1585814A (zh) | 2001-10-03 | 2005-02-23 | 阿彻-丹尼尔斯-米德兰公司 | 制备1,3-甘油二酯油的化学方法 |
DK1486569T3 (da) | 2002-03-21 | 2006-09-11 | Fuji Oil Co Ltd | Fremgangsmåde til transesterificering af fedtstof eller en analog dertil |
JP4142887B2 (ja) | 2002-04-26 | 2008-09-03 | 伯東株式会社 | 酵素反応生成物の製造方法 |
DE10220525A1 (de) | 2002-05-08 | 2003-11-20 | Cognis Deutschland Gmbh | Verfahren zur Herstellung von C4-C12-Fettsäuren |
EP1537221B1 (en) | 2002-09-13 | 2016-02-03 | Suntory Holdings Limited | Process for production of transesterified oils/fats or triglycerides |
CA2499813A1 (en) | 2002-10-10 | 2004-04-22 | Ciba Specialty Chemicals Holding Inc. | Process for the preparation of phenolic carboxylic acid derivatives by enzymatic catalysis |
US7267976B2 (en) | 2003-07-02 | 2007-09-11 | E.I. Du Pont De Nemours And Company | Acyltransferases for alteration of polyunsaturated fatty acids and oil content in oleaginous yeasts |
WO2005005586A1 (ja) | 2003-07-09 | 2005-01-20 | The Nisshin Oillio, Ltd | 対称型トリグリセリドの製造方法 |
WO2005010136A2 (en) | 2003-07-16 | 2005-02-03 | Archer-Daniels-Midland Company | Method for producing fats or oils |
DE102004015782A1 (de) | 2004-03-31 | 2005-10-20 | Cognis Ip Man Gmbh | Verfahren zur enzymatischen Synthese von Triglyceriden ungesättigter Fettsäuren |
TW200538464A (en) | 2004-04-08 | 2005-12-01 | Nisshin Oillio Group Ltd | A 1,3-specific lipase powder, methods for producing the same and use thereof |
US7473539B2 (en) | 2004-09-20 | 2009-01-06 | Sunho Biodiesel Corporation | Methods for producing alkyl esters |
US8685680B2 (en) * | 2005-05-13 | 2014-04-01 | Thomas P. Binder | Method for producing fats or oils |
-
2006
- 2006-08-12 UA UAA200906940A patent/UA97127C2/ru unknown
- 2006-12-06 US US11/567,318 patent/US8361763B2/en active Active
- 2006-12-08 BR BRPI0622189A patent/BRPI0622189B1/pt active IP Right Grant
- 2006-12-08 CA CA2670881A patent/CA2670881C/en active Active
- 2006-12-08 DK DK06845100.4T patent/DK2094824T3/da active
- 2006-12-08 EP EP06845100.4A patent/EP2094824B1/en active Active
- 2006-12-08 CN CN201510662667.2A patent/CN105368586A/zh active Pending
- 2006-12-08 MY MYPI20092321 patent/MY150772A/en unknown
- 2006-12-08 MX MX2009005861A patent/MX2009005861A/es active IP Right Grant
- 2006-12-08 PT PT68451004T patent/PT2094824E/pt unknown
- 2006-12-08 WO PCT/US2006/047018 patent/WO2008069804A1/en active Application Filing
- 2006-12-08 CN CN201510662648.XA patent/CN105331444A/zh active Pending
- 2006-12-08 ES ES06845100T patent/ES2427355T3/es active Active
- 2006-12-08 PL PL06845100T patent/PL2094824T3/pl unknown
- 2006-12-08 RU RU2009125540/13A patent/RU2412984C1/ru not_active IP Right Cessation
- 2006-12-08 CN CNA2006800568954A patent/CN101595206A/zh active Pending
-
2007
- 2007-04-19 AR ARP070101687A patent/AR060548A1/es active IP Right Grant
-
2009
- 2009-07-07 US US12/499,052 patent/US8409853B2/en active Active
-
2016
- 2016-03-28 AR ARP160100815A patent/AR104111A2/es active IP Right Grant
Also Published As
Publication number | Publication date |
---|---|
RU2412984C1 (ru) | 2011-02-27 |
CA2670881A1 (en) | 2008-06-12 |
BRPI0622189B1 (pt) | 2017-04-11 |
WO2008069804A1 (en) | 2008-06-12 |
CN101595206A (zh) | 2009-12-02 |
CA2670881C (en) | 2014-07-08 |
CN105368586A (zh) | 2016-03-02 |
AR104111A2 (es) | 2017-06-28 |
US8409853B2 (en) | 2013-04-02 |
PL2094824T3 (pl) | 2013-12-31 |
US8361763B2 (en) | 2013-01-29 |
PT2094824E (pt) | 2013-09-25 |
MX2009005861A (es) | 2009-06-12 |
ES2427355T3 (es) | 2013-10-30 |
MY150772A (en) | 2014-02-28 |
AR060548A1 (es) | 2008-06-25 |
BRPI0622189A2 (pt) | 2011-12-27 |
DK2094824T3 (da) | 2013-08-19 |
US20090317902A1 (en) | 2009-12-24 |
RU2009125540A (ru) | 2011-01-20 |
EP2094824A1 (en) | 2009-09-02 |
US20080138867A1 (en) | 2008-06-12 |
EP2094824B1 (en) | 2013-07-03 |
CN105331444A (zh) | 2016-02-17 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
UA97127C2 (ru) | Способ непрерывной ферментативной обработки композиции, содержащей липид, и система для его осуществления | |
US8685680B2 (en) | Method for producing fats or oils | |
MX2008007794A (es) | Proceso para mejorar la calidad del aceite y productos producidos del mismo. | |
US20080057552A1 (en) | Processes for Producing Fats or Oils and Compositions Comprising the Fats or Oils | |
JP5868967B2 (ja) | 植物油の処理 | |
RU2341557C2 (ru) | Способ переэтерификации жира с высоким содержанием глицеридов | |
GB2490324A (en) | Improved enzyme interesterification process | |
CN116406233A (zh) | 脂肪组合物 | |
JPS62287A (ja) | 酵素による油脂の精製法 | |
O'Brien | Soybean oil purification | |
Belur et al. | Refining technologies for edible oils | |
JP6990076B2 (ja) | 脂肪酸類の製造方法 | |
Matthäus | Oil technology | |
Zhang et al. | Enzymes in oil and lipid based industries | |
De | Comparison of bio-and autocatalytic esterification of oils using mono-and diglycerides | |
BRPI0710065B1 (pt) | Processo para modificação de um substrato | |
JP2018172517A (ja) | 油脂の製造方法 | |
US9657319B2 (en) | Process for production of low saturate oils | |
Belur et al. | 5 Refining Technologies |