UA41895C2 - Каталізатор для одержання вінілацетату, спосіб його одержання, спосіб одержання вінілацетату та спосіб одержання носія для каталізатора синтезу вінілацетату - Google Patents

Каталізатор для одержання вінілацетату, спосіб його одержання, спосіб одержання вінілацетату та спосіб одержання носія для каталізатора синтезу вінілацетату

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Publication number
UA41895C2
UA41895C2 UA95028178A UA95028178A UA41895C2 UA 41895 C2 UA41895 C2 UA 41895C2 UA 95028178 A UA95028178 A UA 95028178A UA 95028178 A UA95028178 A UA 95028178A UA 41895 C2 UA41895 C2 UA 41895C2
Authority
UA
Ukraine
Prior art keywords
vinyl acetate
production
catalyst
carrier
alkali metal
Prior art date
Application number
UA95028178A
Other languages
English (en)
Russian (ru)
Inventor
Патріша Рей Блум
Патриша Рей Блум
Леррі Майкл Чіряк
Лерри Майкл Чиряк
Майкл Френсіс Леманскі
Майкл Френсис Лемански
Крістос Папарізос
Кристос ПАПАРИЗОС
Марк Енсоні Пепера
Марк Энсони Пепера
Original Assignee
Дзе Стендард Ойл Компані
Дзе Стендард Ойл Компани
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Дзе Стендард Ойл Компані, Дзе Стендард Ойл Компани filed Critical Дзе Стендард Ойл Компані
Publication of UA41895C2 publication Critical patent/UA41895C2/uk

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0027Powdering
    • B01J37/0045Drying a slurry, e.g. spray drying
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48Silver or gold
    • B01J23/52Gold
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56Platinum group metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56Platinum group metals
    • B01J23/58Platinum group metals with alkali- or alkaline earth metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56Platinum group metals
    • B01J23/63Platinum group metals with rare earths or actinides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/40Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/50Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/51Spheres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61Surface area
    • B01J35/615100-500 m2/g
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63Pore volume
    • B01J35/633Pore volume less than 0.5 ml/g
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63Pore volume
    • B01J35/6350.5-1.0 ml/g
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00Preparation of carboxylic acid esters
    • C07C67/04Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
    • C07C67/05Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
    • C07C67/055Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation in the presence of platinum group metals or their compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08Silica
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44Palladium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Silicon Compounds (AREA)
  • Glanulating (AREA)

Abstract

Цей винахід стосується способу отримання псевдозрідженого паладій-промотованого каталізатора для використання при отриманні вінілацетату з етилену, оцтової кислоти і кисневмісного газу. Каталізатор для отримання вінілацетату в псевдозрідженому шарі містить паладій і лужний метал на інертному носії. Він є каталізатором, що відповідає формулі Pd-M-A, де М позначає барій, золото, лантан, ніобій, церій, цинк, свинець, кальцій, стронцій, сурму або їх суміші, і А позначає, щонайменше, один лужний метал, що міститься в матеріалі просочення в заздалегідь приготованому практично інертному носії у формі мікросферичних частинок, в якому розміри, щонайменше, 50 % частинок складають менше 10-4 м (100 мкм).
UA95028178A 1994-02-22 1995-02-21 Каталізатор для одержання вінілацетату, спосіб його одержання, спосіб одержання вінілацетату та спосіб одержання носія для каталізатора синтезу вінілацетату UA41895C2 (uk)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/200,130 US5466652A (en) 1994-02-22 1994-02-22 Process for the preparation of vinyl acetate catalyst
US08/376,180 US5591688A (en) 1994-02-22 1995-01-20 Process for the preparation of fluid bed vinyl acetate catalyst

Publications (1)

Publication Number Publication Date
UA41895C2 true UA41895C2 (uk) 2001-10-15

Family

ID=22740461

Family Applications (1)

Application Number Title Priority Date Filing Date
UA95028178A UA41895C2 (uk) 1994-02-22 1995-02-21 Каталізатор для одержання вінілацетату, спосіб його одержання, спосіб одержання вінілацетату та спосіб одержання носія для каталізатора синтезу вінілацетату

Country Status (8)

Country Link
US (2) US5466652A (uk)
EP (1) EP0949000B1 (uk)
KR (1) KR100366976B1 (uk)
MY (1) MY119986A (uk)
RS (1) RS49818B (uk)
UA (1) UA41895C2 (uk)
YU (1) YU49441B (uk)
ZA (1) ZA951441B (uk)

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Also Published As

Publication number Publication date
ZA951441B (en) 1996-08-21
US5591688A (en) 1997-01-07
YU11295A (sh) 1997-09-30
US5466652A (en) 1995-11-14
MY119986A (en) 2005-08-30
KR100366976B1 (ko) 2003-04-23
YU20050479A (sh) 2006-08-17
EP0949000B1 (en) 2007-06-13
RS49818B (sr) 2008-08-07
EP0949000A1 (en) 1999-10-13
KR950031218A (ko) 1995-12-18
YU49441B (sh) 2006-03-03

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