ATE169520T1 - Katalysatoren und verfahren für die herstellung von vinylacetat - Google Patents
Katalysatoren und verfahren für die herstellung von vinylacetatInfo
- Publication number
- ATE169520T1 ATE169520T1 AT92302781T AT92302781T ATE169520T1 AT E169520 T1 ATE169520 T1 AT E169520T1 AT 92302781 T AT92302781 T AT 92302781T AT 92302781 T AT92302781 T AT 92302781T AT E169520 T1 ATE169520 T1 AT E169520T1
- Authority
- AT
- Austria
- Prior art keywords
- catalyst
- vinyl acetate
- production
- palladium
- catalysts
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title abstract 7
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 title abstract 3
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 abstract 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 abstract 3
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 abstract 2
- 239000010931 gold Substances 0.000 abstract 2
- 229910052737 gold Inorganic materials 0.000 abstract 2
- 229910052763 palladium Inorganic materials 0.000 abstract 2
- 239000002245 particle Substances 0.000 abstract 2
- SCVFZCLFOSHCOH-UHFFFAOYSA-M potassium acetate Chemical compound [K+].CC([O-])=O SCVFZCLFOSHCOH-UHFFFAOYSA-M 0.000 abstract 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 1
- 239000005977 Ethylene Substances 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 239000007789 gas Substances 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000011148 porous material Substances 0.000 abstract 1
- 235000011056 potassium acetate Nutrition 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/58—Platinum group metals with alkali- or alkaline earth metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/44—Palladium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/48—Silver or gold
- B01J23/52—Gold
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
- C07C67/05—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
- C07C67/055—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation in the presence of platinum group metals or their compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/396—Distribution of the active metal ingredient
- B01J35/397—Egg shell like
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/06—Washing
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Applications Claiming Priority (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US07/696,215 US5185308A (en) | 1991-05-06 | 1991-05-06 | Catalysts and processes for the manufacture of vinyl acetate |
| US07/793,131 US5179056A (en) | 1991-05-06 | 1991-11-18 | Production of alkenyl alkanoate catalysts |
| JP07415592A JP3369209B2 (ja) | 1991-05-06 | 1992-03-30 | 酢酸ビニルを製造するための触媒および方法 |
| CA002064444A CA2064444C (en) | 1991-05-06 | 1992-03-30 | Catalysts and processes for the manufacture of vinyl acetate |
| CA002081942A CA2081942C (en) | 1991-11-18 | 1992-11-02 | Production of alkenyl alkanoate catalysts |
| CA002081937A CA2081937C (en) | 1991-05-06 | 1992-11-02 | Catalysts for alkenyl alkanoate production |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE169520T1 true ATE169520T1 (de) | 1998-08-15 |
Family
ID=27543439
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT92302781T ATE169520T1 (de) | 1991-05-06 | 1992-03-30 | Katalysatoren und verfahren für die herstellung von vinylacetat |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US5179056A (de) |
| EP (1) | EP0569624B1 (de) |
| CN (1) | CN1058480C (de) |
| AT (1) | ATE169520T1 (de) |
| DE (1) | DE69226626T2 (de) |
| ES (1) | ES2118788T3 (de) |
Families Citing this family (77)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5194417A (en) * | 1991-12-05 | 1993-03-16 | Quantum Chemical Corporation | Pretreatment of palladium-gold catalysts useful in vinyl acetate synthesis |
| DE4323981C1 (de) * | 1993-07-16 | 1995-03-09 | Hoechst Ag | Palladium und Kalium sowie Cadmium, Barium oder Gold enthaltender Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung zur Herstellung von Vinylacetat |
| DE4323978C1 (de) * | 1993-07-16 | 1995-02-16 | Hoechst Ag | Palladium und Kalium sowie Cadmium, Barium oder Gold enthaltender Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung zur Herstellung von Vinylacetat |
| DE4323980C1 (de) * | 1993-07-16 | 1995-03-30 | Hoechst Ag | Palladium und Kalium sowie Cadmium, Barium oder Gold enthaltender Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung zur Herstellung von Vinylacetat |
| CA2135021A1 (en) * | 1993-11-19 | 1995-05-20 | David J. Gulliver | Process for the preparation of catalysts for use in the production of vinyl acetate |
| ES2287994T3 (es) * | 1994-02-22 | 2007-12-16 | The Standard Oil Company | Procedimiento para la preparacion de soporte de catalizador de acetato de vinilo de lecho fluidizado. |
| US6395676B2 (en) | 1994-02-22 | 2002-05-28 | The Standard Oil Company | Process for the preparation of fluid bed vinyl acetate catalyst |
| US5466652A (en) * | 1994-02-22 | 1995-11-14 | The Standard Oil Co. | Process for the preparation of vinyl acetate catalyst |
| US5665667A (en) * | 1994-06-02 | 1997-09-09 | The Standard Oil Company | Process for the preparation of vinyl acetate catalyst |
| SG46156A1 (en) * | 1994-06-02 | 1998-02-20 | Standard Oil Co Ohio | Fluid bed process for the acetoxylation of ethylene in the production of vinyl acetate |
| US5550281A (en) * | 1994-06-02 | 1996-08-27 | Cirjak; Larry M. | Fluid bed process for the acetoxylation of ethylene in the production of vinyl acetate |
| US5536693A (en) * | 1994-06-02 | 1996-07-16 | The Standard Oil Company | Process for the preparation of vinyl acetate catalyst |
| US5693586A (en) * | 1996-06-28 | 1997-12-02 | Hoechst Celanese Corporation | Palladium-gold catalyst for vinyl acetate production |
| US6407283B2 (en) | 1996-11-04 | 2002-06-18 | Bp Chemicals Limited | Process for the production of vinyl acetate |
| GB9622911D0 (en) | 1996-11-04 | 1997-01-08 | Bp Chem Int Ltd | Process |
| US5952523A (en) * | 1997-07-24 | 1999-09-14 | Praxair Technology, Inc. | Method for producing vinyl acetate |
| GB9810928D0 (en) * | 1998-05-22 | 1998-07-22 | Bp Chem Int Ltd | Catalyst and process |
| TW471982B (en) | 1998-06-02 | 2002-01-11 | Dairen Chemical Corp | Catalyst manufacture method and its use for preparing vinyl acetate |
| DE19827844A1 (de) * | 1998-06-23 | 1999-12-30 | Aventis Res & Tech Gmbh & Co | Verfahren zur Herstellung von Schalenkatalysatoren durch CVD-Beschichtung |
| GB9817363D0 (en) * | 1998-08-11 | 1998-10-07 | Bp Chem Int Ltd | Process for the production of vinyl acetate |
| DE19840372A1 (de) | 1998-09-04 | 2000-03-09 | Basf Ag | Katalysator und Verfahren zur Reinigung von Stoffströmen |
| CN1089638C (zh) * | 1998-10-12 | 2002-08-28 | 大连化学工业股份有限公司 | 催化剂的制法及其在制备乙酸烯酯中的用途 |
| DE19914066A1 (de) * | 1999-03-27 | 2000-10-05 | Celanese Chem Europe Gmbh | Katalysatoren für die Gasphasenoxidation von Ethylen und Essigsäure zu Vinylacetat, Verfahren zu ihrer Herstellung und ihre Verwendung |
| US6420308B1 (en) | 2000-07-07 | 2002-07-16 | Saudi Basic Industries Corp | Highly selective shell impregnated catalyst of improved space time yield for production of vinyl acetate |
| US6794332B2 (en) | 2000-07-07 | 2004-09-21 | Saudi Basic Industries Corporation | Highly selective shell impregnated catalyst of improved space time yield for production of vinyl acetate |
| US6534438B1 (en) | 2000-07-26 | 2003-03-18 | Bp Chemicals Limited | Catalyst composition |
| US7425647B2 (en) * | 2001-03-30 | 2008-09-16 | Shell Oil Company | Process for preparing a group V111-metal containing catalyst, use thereof for preparing an alkenyl carboxylate |
| GB0201378D0 (en) * | 2002-01-22 | 2002-03-13 | Bp Chem Int Ltd | Process |
| JP4421201B2 (ja) * | 2002-03-27 | 2010-02-24 | シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー | 触媒を調製する方法、触媒、および触媒の使用 |
| GB0214383D0 (en) | 2002-06-21 | 2002-07-31 | Isis Innovation | Catalyst |
| TW200539941A (en) | 2003-12-19 | 2005-12-16 | Celanese Int Corp | Methods of making alkenyl alkanoates |
| CN1302849C (zh) * | 2004-12-02 | 2007-03-07 | 黄德欢 | 制备载纳米金粉体的方法 |
| CN1302850C (zh) * | 2004-12-02 | 2007-03-07 | 黄德欢 | 热分解制备载纳米金粉体的方法及装置 |
| CN101124043B (zh) | 2004-12-20 | 2012-10-10 | 国际人造丝公司 | 改进的负载型催化材料 |
| CN1299864C (zh) * | 2005-04-26 | 2007-02-14 | 黄德欢 | 纳米铜粉的制备方法 |
| CN1299865C (zh) * | 2005-04-26 | 2007-02-14 | 黄德欢 | 核-壳结构纳米金铜粉的制备方法 |
| US8227369B2 (en) | 2005-05-25 | 2012-07-24 | Celanese International Corp. | Layered composition and processes for preparing and using the composition |
| DE102007025223A1 (de) * | 2007-05-31 | 2008-12-04 | Süd-Chemie AG | Zirkoniumoxid-dotierter VAM-Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung |
| DE102007025315A1 (de) * | 2007-05-31 | 2008-12-11 | Süd-Chemie AG | Katalysator zur selektiven Hydrierung acetylenischer Kohlenwasserstoffe und Verfahren zu seiner Herstellung |
| DE102007025444A1 (de) * | 2007-05-31 | 2008-12-11 | Süd-Chemie AG | VAM-Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung |
| DE102007025442B4 (de) * | 2007-05-31 | 2023-03-02 | Clariant International Ltd. | Verwendung einer Vorrichtung zur Herstellung eines Schalenkatalysators und Schalenkatalysator |
| DE102007025443A1 (de) | 2007-05-31 | 2008-12-04 | Süd-Chemie AG | Pd/Au-Schalenkatalysator enthaltend HfO2, Verfahren zu dessen Herstellung sowie dessen Verwendung |
| DE102007025324A1 (de) * | 2007-05-31 | 2008-12-11 | Süd-Chemie AG | Verfahren zur Herstellung eines Schalenkatalysators mittels eines Basen- oder Säuregemisches |
| DE102007025224A1 (de) * | 2007-05-31 | 2008-12-11 | Süd-Chemie AG | Verfahren zur Herstellung eines Schalenkatalysators |
| DE102007025362A1 (de) * | 2007-05-31 | 2008-12-11 | Süd-Chemie AG | Dotierter Pd/Au-Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung |
| DE102008059341A1 (de) | 2008-11-30 | 2010-06-10 | Süd-Chemie AG | Katalysatorträger, Verfahren zu seiner Herstellung sowie Verwendung |
| MX380959B (es) * | 2010-05-24 | 2025-03-12 | Siluria Technologies Inc | Catalizadores de nanoalambre, su preparacion y uso de los mismos. |
| EP2714265A2 (de) | 2011-05-24 | 2014-04-09 | Siluria Technologies, Inc. | Katalysatoren für petrochemische katalyse |
| DE102011081786A1 (de) | 2011-08-30 | 2013-02-28 | Wacker Chemie Ag | Verfahren zur Acetoxylierung von Olefinen in der Gasphase |
| HK1202275A1 (en) | 2011-11-29 | 2015-09-25 | Siluria Technologies, Inc. | Nanowire catalysts and methods for their use and preparation |
| US9133079B2 (en) | 2012-01-13 | 2015-09-15 | Siluria Technologies, Inc. | Process for separating hydrocarbon compounds |
| US9446397B2 (en) | 2012-02-03 | 2016-09-20 | Siluria Technologies, Inc. | Method for isolation of nanomaterials |
| CA2874043C (en) | 2012-05-24 | 2021-09-14 | Siluria Technologies, Inc. | Catalytic forms and formulations |
| AU2013266250B2 (en) | 2012-05-24 | 2017-07-06 | Lummus Technology Llc | Oxidative coupling of methane systems and methods |
| US9670113B2 (en) | 2012-07-09 | 2017-06-06 | Siluria Technologies, Inc. | Natural gas processing and systems |
| AU2013355038B2 (en) | 2012-12-07 | 2017-11-02 | Lummus Technology Llc | Integrated processes and systems for conversion of methane to multiple higher hydrocarbon products |
| US20160107143A1 (en) | 2013-03-15 | 2016-04-21 | Siluria Technologies, Inc. | Catalysts for petrochemical catalysis |
| EP3074119B1 (de) | 2013-11-27 | 2019-01-09 | Siluria Technologies, Inc. | Reaktoren und systeme zur oxidativen kupplung von methan |
| CN110655437B (zh) | 2014-01-08 | 2022-09-09 | 鲁玛斯技术有限责任公司 | 乙烯成液体的系统和方法 |
| US10377682B2 (en) | 2014-01-09 | 2019-08-13 | Siluria Technologies, Inc. | Reactors and systems for oxidative coupling of methane |
| CA3225180A1 (en) | 2014-01-09 | 2015-07-16 | Lummus Technology Llc | Oxidative coupling of methane implementations for olefin production |
| EP3137211A2 (de) | 2014-05-02 | 2017-03-08 | Siluria Technologies, Inc. | Heterogene katalysatoren |
| EP3194070B1 (de) | 2014-09-17 | 2020-12-23 | Lummus Technology LLC | Katalysatoren zur oxidativen kupplung von methan und oxidativen dehydrierung von ethan |
| US9334204B1 (en) | 2015-03-17 | 2016-05-10 | Siluria Technologies, Inc. | Efficient oxidative coupling of methane processes and systems |
| US10793490B2 (en) | 2015-03-17 | 2020-10-06 | Lummus Technology Llc | Oxidative coupling of methane methods and systems |
| US20160289143A1 (en) | 2015-04-01 | 2016-10-06 | Siluria Technologies, Inc. | Advanced oxidative coupling of methane |
| US9328297B1 (en) | 2015-06-16 | 2016-05-03 | Siluria Technologies, Inc. | Ethylene-to-liquids systems and methods |
| EP3786138A1 (de) | 2015-10-16 | 2021-03-03 | Lummus Technology LLC | Oxidative kupplung von methan |
| WO2017180910A1 (en) | 2016-04-13 | 2017-10-19 | Siluria Technologies, Inc. | Oxidative coupling of methane for olefin production |
| US20180169561A1 (en) | 2016-12-19 | 2018-06-21 | Siluria Technologies, Inc. | Methods and systems for performing chemical separations |
| JP2020521811A (ja) | 2017-05-23 | 2020-07-27 | ラマス テクノロジー リミテッド ライアビリティ カンパニー | メタン酸化カップリングプロセスの統合 |
| TWI781186B (zh) * | 2017-06-21 | 2022-10-21 | 大陸商中國石油化工科技開發有限公司 | 用於製備異丙苯的催化劑及其用途 |
| AU2018298234B2 (en) | 2017-07-07 | 2022-11-17 | Lummus Technology Llc | Systems and methods for the oxidative coupling of methane |
| EP3917665A1 (de) | 2019-01-30 | 2021-12-08 | Lummus Technology LLC | Katalysatoren zur oxidativen kopplung von methan |
| AU2022340529A1 (en) | 2021-08-31 | 2024-02-29 | Lummus Technology Llc | Methods and systems for performing oxidative coupling of methane |
| CN119654306A (zh) | 2022-08-05 | 2025-03-18 | 国际人造丝公司 | 区催化剂装载以及使用其使烯烃乙酰氧基化的方法 |
| EP4565366A1 (de) | 2022-08-05 | 2025-06-11 | Celanese International Corporation | Katalysator für die acetoxylierung von olefinen |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA747415A (en) * | 1966-11-29 | Sennewald Kurt | Process for the manufacture of vinyl acetate | |
| DE1252662B (de) * | 1965-06-25 | |||
| ES362221A1 (es) * | 1967-12-28 | 1970-12-01 | Nat Distillers Chem Corp | Procedimiento para la preparacion de acetato de vinilo. |
| CH534005A (de) * | 1968-02-01 | 1973-02-28 | Bayer Ag | Verfahren zur Herstellung eines Palladium und Gold enthaltenden Katalysators |
| JPS514118A (en) * | 1974-06-27 | 1976-01-14 | Kuraray Co | Sakusanbiniruno seizohoho |
| JPS5136413A (en) * | 1974-09-10 | 1976-03-27 | Kuraray Co | Fuhowaesuteru no seizoho |
| US4048096A (en) * | 1976-04-12 | 1977-09-13 | E. I. Du Pont De Nemours And Company | Surface impregnated catalyst |
| DE3919524A1 (de) * | 1989-06-15 | 1990-12-20 | Hoechst Ag | Verfahren zur herstellung von vinylacetat |
-
1991
- 1991-11-18 US US07/793,131 patent/US5179056A/en not_active Expired - Fee Related
-
1992
- 1992-03-30 EP EP92302781A patent/EP0569624B1/de not_active Revoked
- 1992-03-30 DE DE69226626T patent/DE69226626T2/de not_active Revoked
- 1992-03-30 CN CN92102172A patent/CN1058480C/zh not_active Expired - Fee Related
- 1992-03-30 AT AT92302781T patent/ATE169520T1/de not_active IP Right Cessation
- 1992-03-30 ES ES92302781T patent/ES2118788T3/es not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| CN1058480C (zh) | 2000-11-15 |
| DE69226626T2 (de) | 1998-12-24 |
| EP0569624B1 (de) | 1998-08-12 |
| DE69226626D1 (de) | 1998-09-17 |
| CN1076875A (zh) | 1993-10-06 |
| ES2118788T3 (es) | 1998-10-01 |
| EP0569624A1 (de) | 1993-11-18 |
| US5179056A (en) | 1993-01-12 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| RER | Ceased as to paragraph 5 lit. 3 law introducing patent treaties |