TWI848992B - 預浸體及纖維強化複合樹脂成形體 - Google Patents

預浸體及纖維強化複合樹脂成形體 Download PDF

Info

Publication number
TWI848992B
TWI848992B TW108137512A TW108137512A TWI848992B TW I848992 B TWI848992 B TW I848992B TW 108137512 A TW108137512 A TW 108137512A TW 108137512 A TW108137512 A TW 108137512A TW I848992 B TWI848992 B TW I848992B
Authority
TW
Taiwan
Prior art keywords
epoxy resin
component
resin composition
prepreg
mass
Prior art date
Application number
TW108137512A
Other languages
English (en)
Chinese (zh)
Other versions
TW202022012A (zh
Inventor
河村奈緒
寺西拓也
Original Assignee
日商三菱化學股份有限公司
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 日商三菱化學股份有限公司 filed Critical 日商三菱化學股份有限公司
Publication of TW202022012A publication Critical patent/TW202022012A/zh
Application granted granted Critical
Publication of TWI848992B publication Critical patent/TWI848992B/zh

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/003Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts characterised by the matrix material, e.g. material composition or physical properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28Shaping operations therefor
    • B29C70/40Shaping or impregnating by compression not applied
    • B29C70/42Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles
    • B29C70/44Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles using isostatic pressure, e.g. pressure difference-moulding, vacuum bag-moulding, autoclave-moulding or expanding rubber-moulding
    • B29C70/446Moulding structures having an axis of symmetry or at least one channel, e.g. tubular structures, frames
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28Shaping operations therefor
    • B29C70/40Shaping or impregnating by compression not applied
    • B29C70/42Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles
    • B29C70/46Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles using matched moulds, e.g. for deforming sheet moulding compounds [SMC] or prepregs
    • B29C70/465Shaping or impregnating by compression not applied for producing articles of definite length, i.e. discrete articles using matched moulds, e.g. for deforming sheet moulding compounds [SMC] or prepregs and impregnating by melting a solid material, e.g. sheets, powders of fibres
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/20Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
    • C08G59/22Di-epoxy compounds
    • C08G59/24Di-epoxy compounds carbocyclic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/4007Curing agents not provided for by the groups C08G59/42 - C08G59/66
    • C08G59/4014Nitrogen containing compounds
    • C08G59/4021Ureas; Thioureas; Guanidines; Dicyandiamides
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/50Amines
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/04Reinforcing macromolecular compounds with loose or coherent fibrous material
    • C08J5/0405Reinforcing macromolecular compounds with loose or coherent fibrous material with inorganic fibres
    • C08J5/042Reinforcing macromolecular compounds with loose or coherent fibrous material with inorganic fibres with carbon fibres
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/24Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
    • C08J5/241Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres
    • C08J5/243Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres using carbon fibres
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/24Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
    • C08J5/249Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs characterised by the additives used in the prepolymer mixture
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/0008Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/0025Crosslinking or vulcanising agents; including accelerators
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/16Nitrogen-containing compounds
    • C08K5/21Urea; Derivatives thereof, e.g. biuret
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00Compositions of epoxy resins; Compositions of derivatives of epoxy resins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2063/00Use of EP, i.e. epoxy resins or derivatives thereof, as moulding material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2307/00Use of elements other than metals as reinforcement
    • B29K2307/04Carbon
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2023/00Tubular articles
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2363/00Characterised by the use of epoxy resins; Derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2463/00Characterised by the use of epoxy resins; Derivatives of epoxy resins

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Inorganic Chemistry (AREA)
  • Composite Materials (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Mathematical Physics (AREA)
  • Reinforced Plastic Materials (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Epoxy Resins (AREA)
TW108137512A 2018-10-17 2019-10-17 預浸體及纖維強化複合樹脂成形體 TWI848992B (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2018-195636 2018-10-17
JP2018195636 2018-10-17

Publications (2)

Publication Number Publication Date
TW202022012A TW202022012A (zh) 2020-06-16
TWI848992B true TWI848992B (zh) 2024-07-21

Family

ID=70283858

Family Applications (1)

Application Number Title Priority Date Filing Date
TW108137512A TWI848992B (zh) 2018-10-17 2019-10-17 預浸體及纖維強化複合樹脂成形體

Country Status (6)

Country Link
US (1) US20210230385A1 (https=)
JP (1) JP7524764B2 (https=)
KR (1) KR20210077674A (https=)
CN (2) CN112839977B (https=)
TW (1) TWI848992B (https=)
WO (1) WO2020080474A1 (https=)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20250092211A1 (en) * 2022-02-16 2025-03-20 Toray Industries, Inc. Prepreg, fiber-reinforced composite material, tubular body made of fiber-reinforced composite material, golf club shaft, and fishing rod
WO2024029233A1 (ja) 2022-08-02 2024-02-08 東レ株式会社 プリプレグ、繊維強化複合材料、繊維強化複合材料製管状体、ゴルフクラブシャフトおよび釣り竿
KR20240038221A (ko) * 2022-09-15 2024-03-25 삼성전자주식회사 가전기기용 복합 파이프 및 이를 포함하는 청소기

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6063839A (en) * 1995-05-09 2000-05-16 Toray Industries, Inc. Prepreg of reinforcing fibers, epoxy resins, crosslinked rubber particles and curing agent
JP2016222935A (ja) * 2013-12-02 2016-12-28 三菱レイヨン株式会社 エポキシ樹脂組成物、並びにこれを用いたフィルム、プリプレグ及び繊維強化プラスチック
WO2017066056A1 (en) * 2015-10-13 2017-04-20 Dow Global Technologies Llc Fast cure epoxy composition for use in high throughput manufacturing processes
JP2017110194A (ja) * 2015-12-10 2017-06-22 三菱ケミカル株式会社 内圧成形用プリプレグ、及び繊維強化複合材料の製造方法
WO2018117214A1 (ja) * 2016-12-21 2018-06-28 三菱ケミカル株式会社 硬化性樹脂組成物、並びにこれを用いたフィルム、成形品、プリプレグ及び繊維強化プラスチック

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6168885B2 (ja) 2013-07-05 2017-07-26 ダンロップスポーツ株式会社 ゴルフクラブシャフト
JP2016216657A (ja) * 2015-05-25 2016-12-22 三菱レイヨン株式会社 エポキシ樹脂組成物、並びにこれを用いた繊維強化複合材料前駆体及び繊維強化複合材料
KR20210020937A (ko) * 2018-06-15 2021-02-24 다우 글로벌 테크놀로지스 엘엘씨 강화 에폭시 조성물

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6063839A (en) * 1995-05-09 2000-05-16 Toray Industries, Inc. Prepreg of reinforcing fibers, epoxy resins, crosslinked rubber particles and curing agent
JP2016222935A (ja) * 2013-12-02 2016-12-28 三菱レイヨン株式会社 エポキシ樹脂組成物、並びにこれを用いたフィルム、プリプレグ及び繊維強化プラスチック
WO2017066056A1 (en) * 2015-10-13 2017-04-20 Dow Global Technologies Llc Fast cure epoxy composition for use in high throughput manufacturing processes
JP2017110194A (ja) * 2015-12-10 2017-06-22 三菱ケミカル株式会社 内圧成形用プリプレグ、及び繊維強化複合材料の製造方法
WO2018117214A1 (ja) * 2016-12-21 2018-06-28 三菱ケミカル株式会社 硬化性樹脂組成物、並びにこれを用いたフィルム、成形品、プリプレグ及び繊維強化プラスチック

Also Published As

Publication number Publication date
CN112839977B (zh) 2024-02-13
CN112839977A (zh) 2021-05-25
TW202022012A (zh) 2020-06-16
CN117164914A (zh) 2023-12-05
TW202428684A (zh) 2024-07-16
WO2020080474A1 (ja) 2020-04-23
JP7524764B2 (ja) 2024-07-30
US20210230385A1 (en) 2021-07-29
JPWO2020080474A1 (ja) 2021-09-24
KR20210077674A (ko) 2021-06-25

Similar Documents

Publication Publication Date Title
JP5003827B2 (ja) 炭素繊維強化複合材料用エポキシ樹脂組成物、プリプレグおよび炭素繊維強化複合材料
CN102076735B (zh) 环氧树脂组合物以及使用该组合物的预浸料坯
RU2720681C2 (ru) Композиции эпоксидных смол и армированные волокном композитные материалы, полученные из них
JP2019526650A (ja) エポキシ樹脂組成物、プリプレグ、及び繊維強化プラスチック材料
TWI848992B (zh) 預浸體及纖維強化複合樹脂成形體
CN111770948A (zh) 热固性树脂组合物、预浸料及纤维增强复合材料
WO2017047225A1 (ja) エポキシ樹脂組成物、プリプレグおよび繊維強化複合材料
WO2012159977A1 (en) Fibre reinforced composite moulding
WO2023176935A1 (ja) Rtm用エポキシ樹脂組成物、樹脂硬化物、繊維強化複合材料およびその製造方法
JP7188136B2 (ja) プリプレグ、及び繊維強化複合樹脂成形体
JP2019189750A (ja) エポキシ樹脂組成物、エポキシ樹脂組成物を含むプリプレグおよびその硬化物
TWI917888B (zh) 預浸體、纖維強化複合樹脂成形體
JP2022501457A (ja) エポキシ樹脂組成物、プリプレグ、及び繊維強化複合材料
JP2021116349A (ja) エポキシ樹脂組成物、プリプレグおよび繊維強化プラスチック
JP7831305B2 (ja) プリプレグ、成形品、およびエポキシ樹脂組成物
JP2019059827A (ja) エポキシ樹脂組成物、プリプレグ、樹脂硬化物および繊維強化複合材料
JP2019157057A (ja) 硬化性樹脂組成物、並びにこれを用いたプリプレグ、フィルム及び繊維強化プラスチック
TWI805651B (zh) 預浸料以及纖維強化複合材料
JP2019065111A (ja) エポキシ樹脂組成物、プリプレグおよび炭素繊維強化複合材料
JP2009215481A (ja) プリプレグおよび繊維強化複合材料
TW202513700A (zh) 預浸體、纖維強化複合材料和成形體的製造方法
TW202603029A (zh) 預浸體、纖維強化複合材料以及纖維強化複合材料的製造方法、自行車用零件、高爾夫球棒用柄、網球拍、釣竿及曲棍球棒
JP2026030781A (ja) 繊維強化複合材料管状体の製造方法、繊維強化複合材料管状体、ゴルフクラブシャフトおよび釣竿
JP2025153828A (ja) エポキシ樹脂組成物、プリプレグ、及び繊維強化複合材料
JP2001278949A (ja) エポキシ樹脂組成物、プリプレグ及び繊維強化複合材料