TWI808985B - 具有低混濁度之強化聚醯胺模製化合物及其模製物 - Google Patents
具有低混濁度之強化聚醯胺模製化合物及其模製物 Download PDFInfo
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- TWI808985B TWI808985B TW107128487A TW107128487A TWI808985B TW I808985 B TWI808985 B TW I808985B TW 107128487 A TW107128487 A TW 107128487A TW 107128487 A TW107128487 A TW 107128487A TW I808985 B TWI808985 B TW I808985B
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- Prior art keywords
- acid
- polyamide
- molding compound
- polyamide molding
- glass
- Prior art date
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- 239000004952 Polyamide Substances 0.000 title claims abstract description 273
- 229920002647 polyamide Polymers 0.000 title claims abstract description 273
- 238000000465 moulding Methods 0.000 title claims abstract description 187
- 150000001875 compounds Chemical class 0.000 title claims abstract description 149
- 239000000203 mixture Substances 0.000 claims abstract description 113
- 239000011521 glass Substances 0.000 claims abstract description 81
- 239000000945 filler Substances 0.000 claims abstract description 48
- 239000000654 additive Substances 0.000 claims abstract description 16
- 230000000996 additive effect Effects 0.000 claims abstract description 8
- 150000004985 diamines Chemical class 0.000 claims description 68
- 239000003365 glass fiber Substances 0.000 claims description 54
- 239000000178 monomer Substances 0.000 claims description 46
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 42
- 125000003118 aryl group Chemical group 0.000 claims description 38
- -1 alicyclic diamines Chemical class 0.000 claims description 37
- 150000001991 dicarboxylic acids Chemical class 0.000 claims description 36
- 230000009477 glass transition Effects 0.000 claims description 32
- 229920006123 polyhexamethylene isophthalamide Polymers 0.000 claims description 32
- 239000002253 acid Substances 0.000 claims description 25
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 claims description 24
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims description 20
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 20
- 229920006181 poly(hexamethylene terephthalamide)-co-poly(hexamethylene dodecanediamide) Polymers 0.000 claims description 20
- PBLZLIFKVPJDCO-UHFFFAOYSA-N 12-aminododecanoic acid Chemical compound NCCCCCCCCCCCC(O)=O PBLZLIFKVPJDCO-UHFFFAOYSA-N 0.000 claims description 18
- 239000004615 ingredient Substances 0.000 claims description 18
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 claims description 18
- 229920006110 poly(m-benzoyl4,4'-methylenebis(cyclohexylamine)) Polymers 0.000 claims description 18
- 230000003746 surface roughness Effects 0.000 claims description 15
- 150000001412 amines Chemical class 0.000 claims description 13
- 150000003951 lactams Chemical class 0.000 claims description 13
- SLXKOJJOQWFEFD-UHFFFAOYSA-N 6-aminohexanoic acid Chemical compound NCCCCCC(O)=O SLXKOJJOQWFEFD-UHFFFAOYSA-N 0.000 claims description 12
- KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical class NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 claims description 12
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims description 12
- JHWNWJKBPDFINM-UHFFFAOYSA-N Laurolactam Chemical compound O=C1CCCCCCCCCCCN1 JHWNWJKBPDFINM-UHFFFAOYSA-N 0.000 claims description 11
- 239000000835 fiber Substances 0.000 claims description 11
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 claims description 11
- KYTZHLUVELPASH-UHFFFAOYSA-N naphthalene-1,2-dicarboxylic acid Chemical compound C1=CC=CC2=C(C(O)=O)C(C(=O)O)=CC=C21 KYTZHLUVELPASH-UHFFFAOYSA-N 0.000 claims description 11
- 125000004432 carbon atom Chemical group C* 0.000 claims description 10
- 230000003287 optical effect Effects 0.000 claims description 10
- DZIHTWJGPDVSGE-UHFFFAOYSA-N 4-[(4-aminocyclohexyl)methyl]cyclohexan-1-amine Chemical compound C1CC(N)CCC1CC1CCC(N)CC1 DZIHTWJGPDVSGE-UHFFFAOYSA-N 0.000 claims description 9
- BNJOQKFENDDGSC-UHFFFAOYSA-N octadecanedioic acid Natural products OC(=O)CCCCCCCCCCCCCCCCC(O)=O BNJOQKFENDDGSC-UHFFFAOYSA-N 0.000 claims description 9
- HQHCYKULIHKCEB-UHFFFAOYSA-N tetradecanedioic acid Chemical compound OC(=O)CCCCCCCCCCCCC(O)=O HQHCYKULIHKCEB-UHFFFAOYSA-N 0.000 claims description 8
- 239000001361 adipic acid Substances 0.000 claims description 7
- RNLHGQLZWXBQNY-UHFFFAOYSA-N 3-(aminomethyl)-3,5,5-trimethylcyclohexan-1-amine Chemical compound CC1(C)CC(N)CC(C)(CN)C1 RNLHGQLZWXBQNY-UHFFFAOYSA-N 0.000 claims description 6
- HSSYVKMJJLDTKZ-UHFFFAOYSA-N 3-phenylphthalic acid Chemical compound OC(=O)C1=CC=CC(C=2C=CC=CC=2)=C1C(O)=O HSSYVKMJJLDTKZ-UHFFFAOYSA-N 0.000 claims description 6
- GKXVJHDEWHKBFH-UHFFFAOYSA-N [2-(aminomethyl)phenyl]methanamine Chemical compound NCC1=CC=CC=C1CN GKXVJHDEWHKBFH-UHFFFAOYSA-N 0.000 claims description 6
- 125000001931 aliphatic group Chemical group 0.000 claims description 6
- 238000011955 best available control technology Methods 0.000 claims description 6
- QXJJQWWVWRCVQT-UHFFFAOYSA-K calcium;sodium;phosphate Chemical compound [Na+].[Ca+2].[O-]P([O-])([O-])=O QXJJQWWVWRCVQT-UHFFFAOYSA-K 0.000 claims description 6
- QQHJDPROMQRDLA-UHFFFAOYSA-N hexadecanedioic acid Chemical compound OC(=O)CCCCCCCCCCCCCCC(O)=O QQHJDPROMQRDLA-UHFFFAOYSA-N 0.000 claims description 6
- SXQFCVDSOLSHOQ-UHFFFAOYSA-N lactamide Chemical class CC(O)C(N)=O SXQFCVDSOLSHOQ-UHFFFAOYSA-N 0.000 claims description 6
- DDLUSQPEQUJVOY-UHFFFAOYSA-N nonane-1,1-diamine Chemical compound CCCCCCCCC(N)N DDLUSQPEQUJVOY-UHFFFAOYSA-N 0.000 claims description 6
- 239000001294 propane Substances 0.000 claims description 6
- 229920006012 semi-aromatic polyamide Polymers 0.000 claims description 6
- 229920006114 semi-crystalline semi-aromatic polyamide Polymers 0.000 claims description 6
- WVDRSXGPQWNUBN-UHFFFAOYSA-N 4-(4-carboxyphenoxy)benzoic acid Chemical compound C1=CC(C(=O)O)=CC=C1OC1=CC=C(C(O)=O)C=C1 WVDRSXGPQWNUBN-UHFFFAOYSA-N 0.000 claims description 5
- NEQFBGHQPUXOFH-UHFFFAOYSA-N 4-(4-carboxyphenyl)benzoic acid Chemical compound C1=CC(C(=O)O)=CC=C1C1=CC=C(C(O)=O)C=C1 NEQFBGHQPUXOFH-UHFFFAOYSA-N 0.000 claims description 5
- JHCBFGGESJQAIQ-UHFFFAOYSA-N 4-[(4-amino-3,5-dimethylcyclohexyl)methyl]-2,6-dimethylcyclohexan-1-amine Chemical compound C1C(C)C(N)C(C)CC1CC1CC(C)C(N)C(C)C1 JHCBFGGESJQAIQ-UHFFFAOYSA-N 0.000 claims description 5
- XDOLZJYETYVRKV-UHFFFAOYSA-N 7-Aminoheptanoic acid Chemical compound NCCCCCCC(O)=O XDOLZJYETYVRKV-UHFFFAOYSA-N 0.000 claims description 5
- 239000006096 absorbing agent Substances 0.000 claims description 5
- XBZSBBLNHFMTEB-UHFFFAOYSA-N cyclohexane-1,3-dicarboxylic acid Chemical compound OC(=O)C1CCCC(C(O)=O)C1 XBZSBBLNHFMTEB-UHFFFAOYSA-N 0.000 claims description 5
- SXJVFQLYZSNZBT-UHFFFAOYSA-N nonane-1,9-diamine Chemical group NCCCCCCCCCN SXJVFQLYZSNZBT-UHFFFAOYSA-N 0.000 claims description 5
- 239000002245 particle Substances 0.000 claims description 5
- 239000003381 stabilizer Substances 0.000 claims description 5
- MSVPBWBOFXVAJF-UHFFFAOYSA-N tetradecane-1,14-diamine Chemical compound NCCCCCCCCCCCCCCN MSVPBWBOFXVAJF-UHFFFAOYSA-N 0.000 claims description 5
- MRERMGPPCLQIPD-NBVRZTHBSA-N (3beta,5alpha,9alpha,22E,24R)-3,5,9-Trihydroxy-23-methylergosta-7,22-dien-6-one Chemical compound C1C(O)CCC2(C)C(CCC3(C(C(C)/C=C(\C)C(C)C(C)C)CCC33)C)(O)C3=CC(=O)C21O MRERMGPPCLQIPD-NBVRZTHBSA-N 0.000 claims description 4
- PXGZQGDTEZPERC-UHFFFAOYSA-N 1,4-cyclohexanedicarboxylic acid Chemical compound OC(=O)C1CCC(C(O)=O)CC1 PXGZQGDTEZPERC-UHFFFAOYSA-N 0.000 claims description 4
- ALYNCZNDIQEVRV-UHFFFAOYSA-N 4-aminobenzoic acid Chemical compound NC1=CC=C(C(O)=O)C=C1 ALYNCZNDIQEVRV-UHFFFAOYSA-N 0.000 claims description 4
- 125000002723 alicyclic group Chemical group 0.000 claims description 4
- WYNLDQIVFWSFIN-UHFFFAOYSA-N anthracene-1,5-dicarboxylic acid Chemical compound C1=CC=C2C=C3C(C(=O)O)=CC=CC3=CC2=C1C(O)=O WYNLDQIVFWSFIN-UHFFFAOYSA-N 0.000 claims description 4
- 239000003963 antioxidant agent Substances 0.000 claims description 4
- 150000004984 aromatic diamines Chemical class 0.000 claims description 4
- 229960002255 azelaic acid Drugs 0.000 claims description 4
- 239000003086 colorant Substances 0.000 claims description 4
- 239000012760 heat stabilizer Substances 0.000 claims description 4
- 230000004224 protection Effects 0.000 claims description 4
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 claims description 4
- GZAHZTPFIHQKJT-UHFFFAOYSA-N 4-[(4-amino-3-methylcyclohexyl)methyl]-2-methylcyclohexan-1-amine Chemical compound C1CC(N)C(C)CC1CC1CC(C)C(N)CC1.C1CC(N)C(C)CC1CC1CC(C)C(N)CC1 GZAHZTPFIHQKJT-UHFFFAOYSA-N 0.000 claims description 3
- 239000012963 UV stabilizer Substances 0.000 claims description 3
- TVCQRYPFBRXZQP-UHFFFAOYSA-N [3-(aminomethyl)cyclohexyl]methanamine Chemical compound NCC1CC(CCC1)CN.C1(CC(CCC1)CN)CN TVCQRYPFBRXZQP-UHFFFAOYSA-N 0.000 claims description 3
- 239000003054 catalyst Substances 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 238000009833 condensation Methods 0.000 claims description 3
- 230000005494 condensation Effects 0.000 claims description 3
- 239000000314 lubricant Substances 0.000 claims description 3
- 229910052615 phyllosilicate Inorganic materials 0.000 claims description 3
- 239000004014 plasticizer Substances 0.000 claims description 3
- KLNPWTHGTVSSEU-UHFFFAOYSA-N undecane-1,11-diamine Chemical compound NCCCCCCCCCCCN KLNPWTHGTVSSEU-UHFFFAOYSA-N 0.000 claims description 3
- VOUJRNMURLYCFQ-UHFFFAOYSA-N 2-methylpentane-1,5-diamine Chemical compound CC(CN)CCCN.NCC(CCCN)C VOUJRNMURLYCFQ-UHFFFAOYSA-N 0.000 claims description 2
- XFDUHJPVQKIXHO-UHFFFAOYSA-N 3-aminobenzoic acid Chemical compound NC1=CC=CC(C(O)=O)=C1 XFDUHJPVQKIXHO-UHFFFAOYSA-N 0.000 claims description 2
- BDGZSRPDMRAWPJ-UHFFFAOYSA-N C(CCCCCCCCCCCCN)N.C(CCCCCCCCCCCCN)N Chemical compound C(CCCCCCCCCCCCN)N.C(CCCCCCCCCCCCN)N BDGZSRPDMRAWPJ-UHFFFAOYSA-N 0.000 claims description 2
- XIZZKYRXMSLILT-UHFFFAOYSA-N CC(CN)CCCCCCN.CC(CN)CCCCCCN Chemical compound CC(CN)CCCCCCN.CC(CN)CCCCCCN XIZZKYRXMSLILT-UHFFFAOYSA-N 0.000 claims description 2
- 101000576320 Homo sapiens Max-binding protein MNT Proteins 0.000 claims description 2
- 239000004609 Impact Modifier Substances 0.000 claims description 2
- SJIWGLIGYNLNDE-UHFFFAOYSA-N NC1C(CC(CC1)CC1CC(C(CC1)N)CC)CC.NC1C(CC(CC1)CC1CC(C(CC1)N)CC)CC Chemical compound NC1C(CC(CC1)CC1CC(C(CC1)N)CC)CC.NC1C(CC(CC1)CC1CC(C(CC1)N)CC)CC SJIWGLIGYNLNDE-UHFFFAOYSA-N 0.000 claims description 2
- FXPVLLWYUHIDLH-UHFFFAOYSA-N NCC1CCC(CC1)CN.NCC1CCC(CC1)CN Chemical compound NCC1CCC(CC1)CN.NCC1CCC(CC1)CN FXPVLLWYUHIDLH-UHFFFAOYSA-N 0.000 claims description 2
- YLBZIDMEEPTYHS-UHFFFAOYSA-N NCCCCCCCCCCN.NCCCCCCCCCCN Chemical compound NCCCCCCCCCCN.NCCCCCCCCCCN YLBZIDMEEPTYHS-UHFFFAOYSA-N 0.000 claims description 2
- YLRCRPHSAZWJNP-UHFFFAOYSA-N OC(=O)CCCCCCCCCC(O)=O.OC(=O)CCCCCCCCCC(O)=O Chemical compound OC(=O)CCCCCCCCCC(O)=O.OC(=O)CCCCCCCCCC(O)=O YLRCRPHSAZWJNP-UHFFFAOYSA-N 0.000 claims description 2
- 229920006121 Polyxylylene adipamide Polymers 0.000 claims description 2
- 150000007513 acids Chemical class 0.000 claims description 2
- 229960004050 aminobenzoic acid Drugs 0.000 claims description 2
- 239000002518 antifoaming agent Substances 0.000 claims description 2
- IVVOCRBADNIWDM-UHFFFAOYSA-N bicyclo[2.2.1]heptane-2,3-dicarboxylic acid Chemical compound C1CC2C(C(O)=O)C(C(=O)O)C1C2 IVVOCRBADNIWDM-UHFFFAOYSA-N 0.000 claims description 2
- 239000002981 blocking agent Substances 0.000 claims description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 2
- 230000001413 cellular effect Effects 0.000 claims description 2
- HGWBUDJZNFJMEJ-UHFFFAOYSA-N dodecane-1,12-diamine Chemical compound NCCCCCCCCCCCCN.NCCCCCCCCCCCCN HGWBUDJZNFJMEJ-UHFFFAOYSA-N 0.000 claims description 2
- IINXALNHMRMYDC-UHFFFAOYSA-N dodecanedioic acid Chemical compound OC(=O)CCCCCCCCCCC(O)=O.OC(=O)CCCCCCCCCCC(O)=O IINXALNHMRMYDC-UHFFFAOYSA-N 0.000 claims description 2
- 239000003063 flame retardant Substances 0.000 claims description 2
- 239000005337 ground glass Substances 0.000 claims description 2
- 229910052736 halogen Inorganic materials 0.000 claims description 2
- 150000002367 halogens Chemical class 0.000 claims description 2
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 claims description 2
- VMNZBBHWHOMWAQ-UHFFFAOYSA-N pentane-1,5-diamine Chemical compound NCCCCCN.NCCCCCN VMNZBBHWHOMWAQ-UHFFFAOYSA-N 0.000 claims description 2
- DXNCZXXFRKPEPY-UHFFFAOYSA-N tridecanedioic acid Chemical compound OC(=O)CCCCCCCCCCCC(O)=O DXNCZXXFRKPEPY-UHFFFAOYSA-N 0.000 claims description 2
- SYECJBOWSGTPLU-UHFFFAOYSA-N hexane-1,1-diamine Chemical compound CCCCCC(N)N SYECJBOWSGTPLU-UHFFFAOYSA-N 0.000 claims 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims 1
- COIIQOMHNMCCAT-UHFFFAOYSA-N NCC1=CC=C(C=C1)CN.C1(=CC=C(C=C1)CN)CN Chemical compound NCC1=CC=C(C=C1)CN.C1(=CC=C(C=C1)CN)CN COIIQOMHNMCCAT-UHFFFAOYSA-N 0.000 claims 1
- JNSCXZPGFXSRGE-UHFFFAOYSA-N OC(=O)C1=CC=C(C(O)=O)N=C1.OC(=O)C1=CC=C(C(O)=O)N=C1 Chemical compound OC(=O)C1=CC=C(C(O)=O)N=C1.OC(=O)C1=CC=C(C(O)=O)N=C1 JNSCXZPGFXSRGE-UHFFFAOYSA-N 0.000 claims 1
- BXQPCGFPJPDYMZ-UHFFFAOYSA-N OC(=O)C1=CC=CC=C1C1=CC=CC=C1C(O)=O.OC(=O)C1=CC=CC=C1C1=CC=CC=C1C(O)=O Chemical compound OC(=O)C1=CC=CC=C1C1=CC=CC=C1C(O)=O.OC(=O)C1=CC=CC=C1C1=CC=CC=C1C(O)=O BXQPCGFPJPDYMZ-UHFFFAOYSA-N 0.000 claims 1
- FYRKCNKWQBRSII-UHFFFAOYSA-N [3-(aminomethyl)phenyl]methanamine Chemical group NCC1=CC=CC(CN)=C1.NCC1=CC=CC(CN)=C1 FYRKCNKWQBRSII-UHFFFAOYSA-N 0.000 claims 1
- ONYMWYWFGOYCLN-UHFFFAOYSA-N bicyclo[2.2.1]heptane-3,5-dicarboxylic acid Chemical compound C1C2C(C(=O)O)CC1CC2C(O)=O ONYMWYWFGOYCLN-UHFFFAOYSA-N 0.000 claims 1
- GSHYGIZIWMJKRV-UHFFFAOYSA-N butane-1,4-diamine Chemical group NCCCCN.NCCCCN GSHYGIZIWMJKRV-UHFFFAOYSA-N 0.000 claims 1
- SIUPRLJMTTYZLD-UHFFFAOYSA-N cyclopentane-1,3-dicarboxylic acid Chemical compound C1(CC(CC1)C(=O)O)C(=O)O.C1(CC(CC1)C(=O)O)C(=O)O SIUPRLJMTTYZLD-UHFFFAOYSA-N 0.000 claims 1
- SWFMWXHHVGHUFO-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN.NCCCCCCN SWFMWXHHVGHUFO-UHFFFAOYSA-N 0.000 claims 1
- KBWUXUSGYHVTSX-UHFFFAOYSA-N naphthalene-2,6-dicarboxylic acid Chemical compound C1=C(C(O)=O)C=CC2=CC(C(=O)O)=CC=C21.C1=C(C(O)=O)C=CC2=CC(C(=O)O)=CC=C21 KBWUXUSGYHVTSX-UHFFFAOYSA-N 0.000 claims 1
- FKUZHRFZKWKKDZ-UHFFFAOYSA-N octadecanedioic acid Chemical compound OC(=O)CCCCCCCCCCCCCCCCC(O)=O.OC(=O)CCCCCCCCCCCCCCCCC(O)=O FKUZHRFZKWKKDZ-UHFFFAOYSA-N 0.000 claims 1
- 150000004760 silicates Chemical class 0.000 claims 1
- 239000010410 layer Substances 0.000 description 32
- 238000000034 method Methods 0.000 description 14
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 13
- 229920000642 polymer Polymers 0.000 description 13
- 238000004519 manufacturing process Methods 0.000 description 10
- 238000012360 testing method Methods 0.000 description 10
- IGSBHTZEJMPDSZ-UHFFFAOYSA-N 4-[(4-amino-3-methylcyclohexyl)methyl]-2-methylcyclohexan-1-amine Chemical compound C1CC(N)C(C)CC1CC1CC(C)C(N)CC1 IGSBHTZEJMPDSZ-UHFFFAOYSA-N 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 9
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 8
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 8
- 238000010438 heat treatment Methods 0.000 description 8
- 238000001746 injection moulding Methods 0.000 description 8
- 239000008188 pellet Substances 0.000 description 8
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 7
- FDLQZKYLHJJBHD-UHFFFAOYSA-N [3-(aminomethyl)phenyl]methanamine Chemical compound NCC1=CC=CC(CN)=C1 FDLQZKYLHJJBHD-UHFFFAOYSA-N 0.000 description 7
- 239000000292 calcium oxide Substances 0.000 description 7
- 230000004927 fusion Effects 0.000 description 7
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 7
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 6
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 6
- 239000000395 magnesium oxide Substances 0.000 description 6
- 238000002844 melting Methods 0.000 description 6
- 230000008018 melting Effects 0.000 description 6
- 239000000377 silicon dioxide Substances 0.000 description 6
- HASUJDLTAYUWCO-UHFFFAOYSA-N 2-aminoundecanoic acid Chemical group CCCCCCCCCC(N)C(O)=O HASUJDLTAYUWCO-UHFFFAOYSA-N 0.000 description 5
- 239000012530 fluid Substances 0.000 description 5
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- WTKWFNIIIXNTDO-UHFFFAOYSA-N 3-isocyanato-5-methyl-2-(trifluoromethyl)furan Chemical compound CC1=CC(N=C=O)=C(C(F)(F)F)O1 WTKWFNIIIXNTDO-UHFFFAOYSA-N 0.000 description 4
- 229920000305 Nylon 6,10 Polymers 0.000 description 4
- 229920000572 Nylon 6/12 Polymers 0.000 description 4
- OXIKYYJDTWKERT-UHFFFAOYSA-N [4-(aminomethyl)cyclohexyl]methanamine Chemical compound NCC1CCC(CN)CC1 OXIKYYJDTWKERT-UHFFFAOYSA-N 0.000 description 4
- ISKQADXMHQSTHK-UHFFFAOYSA-N [4-(aminomethyl)phenyl]methanamine Chemical compound NCC1=CC=C(CN)C=C1 ISKQADXMHQSTHK-UHFFFAOYSA-N 0.000 description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 4
- 150000001408 amides Chemical class 0.000 description 4
- 229920006020 amorphous polyamide Polymers 0.000 description 4
- 229910052810 boron oxide Inorganic materials 0.000 description 4
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 description 4
- 239000005357 flat glass Substances 0.000 description 4
- 238000002347 injection Methods 0.000 description 4
- 239000007924 injection Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 239000000155 melt Substances 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- TVIDDXQYHWJXFK-UHFFFAOYSA-N n-Dodecanedioic acid Natural products OC(=O)CCCCCCCCCCC(O)=O TVIDDXQYHWJXFK-UHFFFAOYSA-N 0.000 description 4
- RXOHFPCZGPKIRD-UHFFFAOYSA-N naphthalene-2,6-dicarboxylic acid Chemical compound C1=C(C(O)=O)C=CC2=CC(C(=O)O)=CC=C21 RXOHFPCZGPKIRD-UHFFFAOYSA-N 0.000 description 4
- CHWRSCGUEQEHOH-UHFFFAOYSA-N potassium oxide Chemical compound [O-2].[K+].[K+] CHWRSCGUEQEHOH-UHFFFAOYSA-N 0.000 description 4
- 229910001950 potassium oxide Inorganic materials 0.000 description 4
- 235000012239 silicon dioxide Nutrition 0.000 description 4
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 4
- 229910001948 sodium oxide Inorganic materials 0.000 description 4
- QUBNFZFTFXTLKH-UHFFFAOYSA-N 2-aminododecanoic acid Chemical class CCCCCCCCCCC(N)C(O)=O QUBNFZFTFXTLKH-UHFFFAOYSA-N 0.000 description 3
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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| EP17186920.9A EP3444113B1 (de) | 2017-08-18 | 2017-08-18 | Verstärkte polyamid-formmassen mit geringem haze und formkörper daraus |
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| EP3444112B1 (de) * | 2017-08-18 | 2020-12-23 | Ems-Chemie Ag | Verstärkte polyamid-formmassen mit geringem haze und formkörper daraus |
| US20200224028A1 (en) * | 2017-10-03 | 2020-07-16 | Mitsubishi Engineering-Plastics Corporation | Thermoplastic resin composition, resin molding, method for manufacturing plated resin molding, and method for manufacturing portable electronic device part |
| EP3502191B1 (de) | 2017-12-22 | 2021-02-17 | Ems-Chemie Ag | Polyamid-formmasse |
| EP3502164B1 (de) * | 2017-12-22 | 2022-10-05 | Ems-Chemie Ag | Polyamid-formmasse |
| EP3636406B1 (de) | 2018-10-09 | 2021-04-28 | Ems-Chemie Ag | Schlagzähmodifizierte polyamid-formmassen |
| JP7467490B2 (ja) * | 2019-02-19 | 2024-04-15 | ソルベイ スペシャルティ ポリマーズ ユーエスエー， エルエルシー | ポリアミド、組成物及び対応するモバイル電子デバイス構成部品 |
| EP3772521B1 (de) | 2019-08-09 | 2023-06-07 | Ems-Chemie Ag | Teilkristalline copolyamide, diese enthaltende formmassen und deren verwendung sowie daraus hergestellte formkörper |
| EP3772520B1 (de) | 2019-08-09 | 2023-07-12 | Ems-Chemie Ag | Polyamid-formmasse und deren verwendung sowie aus der formmasse hergestellte formkörper |
| JP2022552989A (ja) * | 2019-10-15 | 2022-12-21 | ビーエーエスエフ ソシエタス・ヨーロピア | 半芳香族ポリアミドの混合物、及び溶接ラインの強度が向上された成形品 |
| EP3842470A1 (de) | 2019-12-23 | 2021-06-30 | Ems-Chemie Ag | Polyamid-formmassen für hypochlorit-beständige anwendungen |
| EP3842496A1 (de) * | 2019-12-23 | 2021-06-30 | Ems-Chemie Ag | Polyamid-formmassen für hypochlorit-beständige anwendungen |
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| CN114835894B (zh) * | 2022-05-31 | 2023-10-20 | 广州辰东新材料有限公司 | 一种透明聚酰胺、包含其组合物及其制备方法 |
| CN115926153B (zh) * | 2023-01-12 | 2023-07-04 | 中国科学院宁波材料技术与工程研究所 | 一种生物基透明尼龙材料及其制备方法和应用 |
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| US20190055405A1 (en) | 2019-02-21 |
| KR102597340B1 (ko) | 2023-11-02 |
| US10767048B2 (en) | 2020-09-08 |
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| CN109401295B (zh) | 2023-02-03 |
| JP7327914B2 (ja) | 2023-08-16 |
| EP3444113A1 (de) | 2019-02-20 |
| TW201920477A (zh) | 2019-06-01 |
| KR20190019877A (ko) | 2019-02-27 |
| MY187516A (en) | 2021-09-24 |
| JP2019065262A (ja) | 2019-04-25 |
| EP3444113B1 (de) | 2021-01-20 |
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