TWI803510B - 用於銅互連件之晶種層 - Google Patents
用於銅互連件之晶種層 Download PDFInfo
- Publication number
- TWI803510B TWI803510B TW107129279A TW107129279A TWI803510B TW I803510 B TWI803510 B TW I803510B TW 107129279 A TW107129279 A TW 107129279A TW 107129279 A TW107129279 A TW 107129279A TW I803510 B TWI803510 B TW I803510B
- Authority
- TW
- Taiwan
- Prior art keywords
- layer
- copper
- ruthenium
- substrate
- processing chamber
- Prior art date
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Classifications
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10W—GENERIC PACKAGES, INTERCONNECTIONS, CONNECTORS OR OTHER CONSTRUCTIONAL DETAILS OF DEVICES COVERED BY CLASS H10
- H10W20/00—Interconnections in chips, wafers or substrates
- H10W20/01—Manufacture or treatment
- H10W20/031—Manufacture or treatment of conductive parts of the interconnections
- H10W20/056—Manufacture or treatment of conductive parts of the interconnections by filling conductive material into holes, grooves or trenches
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10P—GENERIC PROCESSES OR APPARATUS FOR THE MANUFACTURE OR TREATMENT OF DEVICES COVERED BY CLASS H10
- H10P14/00—Formation of materials, e.g. in the shape of layers or pillars
- H10P14/40—Formation of materials, e.g. in the shape of layers or pillars of conductive or resistive materials
- H10P14/42—Formation of materials, e.g. in the shape of layers or pillars of conductive or resistive materials using a gas or vapour
- H10P14/43—Chemical deposition, e.g. chemical vapour deposition [CVD]
- H10P14/432—Chemical deposition, e.g. chemical vapour deposition [CVD] using selective deposition
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10W—GENERIC PACKAGES, INTERCONNECTIONS, CONNECTORS OR OTHER CONSTRUCTIONAL DETAILS OF DEVICES COVERED BY CLASS H10
- H10W20/00—Interconnections in chips, wafers or substrates
- H10W20/40—Interconnections external to wafers or substrates, e.g. back-end-of-line [BEOL] metallisations or vias connecting to gate electrodes
- H10W20/41—Interconnections external to wafers or substrates, e.g. back-end-of-line [BEOL] metallisations or vias connecting to gate electrodes characterised by their conductive parts
- H10W20/425—Barrier, adhesion or liner layers
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10P—GENERIC PROCESSES OR APPARATUS FOR THE MANUFACTURE OR TREATMENT OF DEVICES COVERED BY CLASS H10
- H10P14/00—Formation of materials, e.g. in the shape of layers or pillars
- H10P14/40—Formation of materials, e.g. in the shape of layers or pillars of conductive or resistive materials
- H10P14/42—Formation of materials, e.g. in the shape of layers or pillars of conductive or resistive materials using a gas or vapour
- H10P14/44—Physical vapour deposition [PVD]
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10P—GENERIC PROCESSES OR APPARATUS FOR THE MANUFACTURE OR TREATMENT OF DEVICES COVERED BY CLASS H10
- H10P14/00—Formation of materials, e.g. in the shape of layers or pillars
- H10P14/60—Formation of materials, e.g. in the shape of layers or pillars of insulating materials
- H10P14/66—Formation of materials, e.g. in the shape of layers or pillars of insulating materials characterised by the type of materials
- H10P14/668—Formation of materials, e.g. in the shape of layers or pillars of insulating materials characterised by the type of materials the materials being characterised by the deposition precursor materials
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10W—GENERIC PACKAGES, INTERCONNECTIONS, CONNECTORS OR OTHER CONSTRUCTIONAL DETAILS OF DEVICES COVERED BY CLASS H10
- H10W20/00—Interconnections in chips, wafers or substrates
- H10W20/01—Manufacture or treatment
- H10W20/031—Manufacture or treatment of conductive parts of the interconnections
- H10W20/032—Manufacture or treatment of conductive parts of the interconnections of conductive barrier, adhesion or liner layers
- H10W20/033—Manufacture or treatment of conductive parts of the interconnections of conductive barrier, adhesion or liner layers in openings in dielectrics
- H10W20/035—Manufacture or treatment of conductive parts of the interconnections of conductive barrier, adhesion or liner layers in openings in dielectrics combinations of barrier, adhesion or liner layers, e.g. multi-layered barrier layers
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10W—GENERIC PACKAGES, INTERCONNECTIONS, CONNECTORS OR OTHER CONSTRUCTIONAL DETAILS OF DEVICES COVERED BY CLASS H10
- H10W20/00—Interconnections in chips, wafers or substrates
- H10W20/01—Manufacture or treatment
- H10W20/031—Manufacture or treatment of conductive parts of the interconnections
- H10W20/032—Manufacture or treatment of conductive parts of the interconnections of conductive barrier, adhesion or liner layers
- H10W20/038—Manufacture or treatment of conductive parts of the interconnections of conductive barrier, adhesion or liner layers covering conductive structures
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10W—GENERIC PACKAGES, INTERCONNECTIONS, CONNECTORS OR OTHER CONSTRUCTIONAL DETAILS OF DEVICES COVERED BY CLASS H10
- H10W20/00—Interconnections in chips, wafers or substrates
- H10W20/01—Manufacture or treatment
- H10W20/031—Manufacture or treatment of conductive parts of the interconnections
- H10W20/032—Manufacture or treatment of conductive parts of the interconnections of conductive barrier, adhesion or liner layers
- H10W20/042—Manufacture or treatment of conductive parts of the interconnections of conductive barrier, adhesion or liner layers the barrier, adhesion or liner layers being seed or nucleation layers
- H10W20/043—Manufacture or treatment of conductive parts of the interconnections of conductive barrier, adhesion or liner layers the barrier, adhesion or liner layers being seed or nucleation layers for electroplating
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10W—GENERIC PACKAGES, INTERCONNECTIONS, CONNECTORS OR OTHER CONSTRUCTIONAL DETAILS OF DEVICES COVERED BY CLASS H10
- H10W20/00—Interconnections in chips, wafers or substrates
- H10W20/01—Manufacture or treatment
- H10W20/031—Manufacture or treatment of conductive parts of the interconnections
- H10W20/032—Manufacture or treatment of conductive parts of the interconnections of conductive barrier, adhesion or liner layers
- H10W20/042—Manufacture or treatment of conductive parts of the interconnections of conductive barrier, adhesion or liner layers the barrier, adhesion or liner layers being seed or nucleation layers
- H10W20/045—Manufacture or treatment of conductive parts of the interconnections of conductive barrier, adhesion or liner layers the barrier, adhesion or liner layers being seed or nucleation layers for deposition from the gaseous phase, e.g. for chemical vapour deposition [CVD]
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10W—GENERIC PACKAGES, INTERCONNECTIONS, CONNECTORS OR OTHER CONSTRUCTIONAL DETAILS OF DEVICES COVERED BY CLASS H10
- H10W70/00—Package substrates; Interposers; Redistribution layers [RDL]
- H10W70/60—Insulating or insulated package substrates; Interposers; Redistribution layers
- H10W70/611—Insulating or insulated package substrates; Interposers; Redistribution layers for connecting multiple chips together
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10W—GENERIC PACKAGES, INTERCONNECTIONS, CONNECTORS OR OTHER CONSTRUCTIONAL DETAILS OF DEVICES COVERED BY CLASS H10
- H10W70/00—Package substrates; Interposers; Redistribution layers [RDL]
- H10W70/60—Insulating or insulated package substrates; Interposers; Redistribution layers
- H10W70/62—Insulating or insulated package substrates; Interposers; Redistribution layers characterised by their interconnections
- H10W70/65—Shapes or dispositions of interconnections
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10W—GENERIC PACKAGES, INTERCONNECTIONS, CONNECTORS OR OTHER CONSTRUCTIONAL DETAILS OF DEVICES COVERED BY CLASS H10
- H10W20/00—Interconnections in chips, wafers or substrates
- H10W20/01—Manufacture or treatment
- H10W20/031—Manufacture or treatment of conductive parts of the interconnections
- H10W20/032—Manufacture or treatment of conductive parts of the interconnections of conductive barrier, adhesion or liner layers
- H10W20/042—Manufacture or treatment of conductive parts of the interconnections of conductive barrier, adhesion or liner layers the barrier, adhesion or liner layers being seed or nucleation layers
- H10W20/0425—Manufacture or treatment of conductive parts of the interconnections of conductive barrier, adhesion or liner layers the barrier, adhesion or liner layers being seed or nucleation layers comprising multiple stacked seed or nucleation layers
Landscapes
- Internal Circuitry In Semiconductor Integrated Circuit Devices (AREA)
- Electrodes Of Semiconductors (AREA)
- Electroplating Methods And Accessories (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201762548604P | 2017-08-22 | 2017-08-22 | |
| US62/548,604 | 2017-08-22 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW201920735A TW201920735A (zh) | 2019-06-01 |
| TWI803510B true TWI803510B (zh) | 2023-06-01 |
Family
ID=63350353
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW107129279A TWI803510B (zh) | 2017-08-22 | 2018-08-22 | 用於銅互連件之晶種層 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US10847463B2 (https=) |
| EP (1) | EP3447793B1 (https=) |
| JP (2) | JP7634930B2 (https=) |
| KR (1) | KR20190021184A (https=) |
| CN (1) | CN109461698B (https=) |
| TW (1) | TWI803510B (https=) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11177162B2 (en) * | 2019-09-17 | 2021-11-16 | International Business Machines Corporation | Trapezoidal interconnect at tight BEOL pitch |
| CN114664656A (zh) * | 2020-05-22 | 2022-06-24 | 北京屹唐半导体科技股份有限公司 | 使用臭氧气体和氢自由基的工件加工 |
| US11410881B2 (en) | 2020-06-28 | 2022-08-09 | Applied Materials, Inc. | Impurity removal in doped ALD tantalum nitride |
| US11764157B2 (en) * | 2020-07-23 | 2023-09-19 | Applied Materials, Inc. | Ruthenium liner and cap for back-end-of-line applications |
| WO2025005521A1 (ko) * | 2023-06-30 | 2025-01-02 | 주성엔지니어링(주) | 전극 형성 방법 |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20040241321A1 (en) * | 2002-06-04 | 2004-12-02 | Applied Materials, Inc. | Ruthenium layer formation for copper film deposition |
| US20060199372A1 (en) * | 2005-03-01 | 2006-09-07 | Applied Materials, Inc. | Reduction of copper dewetting by transition metal deposition |
| US20100200991A1 (en) * | 2007-03-15 | 2010-08-12 | Rohan Akolkar | Dopant Enhanced Interconnect |
| US20130292806A1 (en) * | 2012-04-13 | 2013-11-07 | Paul F. Ma | Methods For Manganese Nitride Integration |
| US20150262938A1 (en) * | 2014-03-14 | 2015-09-17 | Taiwan Semiconductor Manufacturing Company, Ltd. | Barrier Structure for Copper Interconnect |
Family Cites Families (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7101790B2 (en) | 2003-03-28 | 2006-09-05 | Taiwan Semiconductor Manufacturing Co., Ltd. | Method of forming a robust copper interconnect by dilute metal doping |
| JP2006097044A (ja) | 2004-09-28 | 2006-04-13 | L'air Liquide Sa Pour L'etude & L'exploitation Des Procede S Georges Claude | 成膜用前駆体、ルテニウム含有膜の成膜方法、ルテニウム膜の成膜方法、ルテニウム酸化物膜の成膜方法およびルテニウム酸塩膜の成膜方法 |
| US20060246699A1 (en) * | 2005-03-18 | 2006-11-02 | Weidman Timothy W | Process for electroless copper deposition on a ruthenium seed |
| JP2008098449A (ja) * | 2006-10-12 | 2008-04-24 | Ebara Corp | 基板処理装置及び基板処理方法 |
| US20080164613A1 (en) | 2007-01-10 | 2008-07-10 | International Business Machines Corporation | ULTRA-THIN Cu ALLOY SEED FOR INTERCONNECT APPLICATION |
| US20080223287A1 (en) * | 2007-03-15 | 2008-09-18 | Lavoie Adrien R | Plasma enhanced ALD process for copper alloy seed layers |
| US7659204B2 (en) * | 2007-03-26 | 2010-02-09 | Applied Materials, Inc. | Oxidized barrier layer |
| US7737028B2 (en) | 2007-09-28 | 2010-06-15 | Applied Materials, Inc. | Selective ruthenium deposition on copper materials |
| JP2009116952A (ja) * | 2007-11-06 | 2009-05-28 | Hitachi Global Storage Technologies Netherlands Bv | 垂直磁気記録媒体およびこれを用いた磁気記憶装置 |
| TW200951241A (en) | 2008-05-30 | 2009-12-16 | Sigma Aldrich Co | Methods of forming ruthenium-containing films by atomic layer deposition |
| US7964497B2 (en) * | 2008-06-27 | 2011-06-21 | International Business Machines Corporation | Structure to facilitate plating into high aspect ratio vias |
| US20090321935A1 (en) | 2008-06-30 | 2009-12-31 | O'brien Kevin | Methods of forming improved electromigration resistant copper films and structures formed thereby |
| US8084104B2 (en) | 2008-08-29 | 2011-12-27 | Asm Japan K.K. | Atomic composition controlled ruthenium alloy film formed by plasma-enhanced atomic layer deposition |
| JP2010215982A (ja) | 2009-03-18 | 2010-09-30 | Tosoh Corp | ルテニウム錯体有機溶媒溶液を用いたルテニウム含有膜製造方法、及びルテニウム含有膜 |
| JP2012074608A (ja) * | 2010-09-29 | 2012-04-12 | Tokyo Electron Ltd | 配線形成方法 |
| CN102332426A (zh) * | 2011-09-23 | 2012-01-25 | 复旦大学 | 一种用于纳米集成电路的铜扩散阻挡层的制备方法 |
| US9142509B2 (en) * | 2012-04-13 | 2015-09-22 | Taiwan Semiconductor Manufacturing Company, Ltd. | Copper interconnect structure and method for forming the same |
| CN102903699A (zh) * | 2012-10-15 | 2013-01-30 | 复旦大学 | 一种铜互连结构及其制备方法 |
| US20140134351A1 (en) * | 2012-11-09 | 2014-05-15 | Applied Materials, Inc. | Method to deposit cvd ruthenium |
| CN103266304B (zh) | 2013-05-31 | 2015-12-23 | 江苏科技大学 | 一种高热稳定性无扩散阻挡层Cu(Ru)合金材料的制备方法 |
| JP6278827B2 (ja) | 2014-05-14 | 2018-02-14 | 株式会社Adeka | 銅化合物、薄膜形成用原料及び薄膜の製造方法 |
| US20160032455A1 (en) | 2014-07-31 | 2016-02-04 | Applied Materials, Inc. | High through-put and low temperature ald copper deposition and integration |
| US9768060B2 (en) * | 2014-10-29 | 2017-09-19 | Applied Materials, Inc. | Systems and methods for electrochemical deposition on a workpiece including removing contamination from seed layer surface prior to ECD |
| US10002834B2 (en) | 2015-03-11 | 2018-06-19 | Applied Materials, Inc. | Method and apparatus for protecting metal interconnect from halogen based precursors |
| KR20160123793A (ko) * | 2015-04-17 | 2016-10-26 | 포항공과대학교 산학협력단 | 이중층 구조를 가지는 저항변화메모리 및 이중층 구조를 가지는 저항변화메모리의 제조방법 |
| CN105355620B (zh) * | 2015-12-17 | 2018-06-22 | 上海集成电路研发中心有限公司 | 一种铜互连结构及其制造方法 |
-
2018
- 2018-08-13 US US16/102,533 patent/US10847463B2/en active Active
- 2018-08-17 EP EP18189568.1A patent/EP3447793B1/en not_active Not-in-force
- 2018-08-21 JP JP2018154364A patent/JP7634930B2/ja active Active
- 2018-08-22 TW TW107129279A patent/TWI803510B/zh active
- 2018-08-22 KR KR1020180097909A patent/KR20190021184A/ko not_active Ceased
- 2018-08-22 CN CN201810960756.9A patent/CN109461698B/zh active Active
-
2023
- 2023-09-25 JP JP2023159999A patent/JP2023182638A/ja active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20040241321A1 (en) * | 2002-06-04 | 2004-12-02 | Applied Materials, Inc. | Ruthenium layer formation for copper film deposition |
| US20060199372A1 (en) * | 2005-03-01 | 2006-09-07 | Applied Materials, Inc. | Reduction of copper dewetting by transition metal deposition |
| US20100200991A1 (en) * | 2007-03-15 | 2010-08-12 | Rohan Akolkar | Dopant Enhanced Interconnect |
| US20130292806A1 (en) * | 2012-04-13 | 2013-11-07 | Paul F. Ma | Methods For Manganese Nitride Integration |
| US20150262938A1 (en) * | 2014-03-14 | 2015-09-17 | Taiwan Semiconductor Manufacturing Company, Ltd. | Barrier Structure for Copper Interconnect |
Also Published As
| Publication number | Publication date |
|---|---|
| JP7634930B2 (ja) | 2025-02-25 |
| JP2023182638A (ja) | 2023-12-26 |
| JP2019062190A (ja) | 2019-04-18 |
| EP3447793A1 (en) | 2019-02-27 |
| TW201920735A (zh) | 2019-06-01 |
| EP3447793B1 (en) | 2021-01-06 |
| US10847463B2 (en) | 2020-11-24 |
| KR20190021184A (ko) | 2019-03-05 |
| US20190067201A1 (en) | 2019-02-28 |
| CN109461698A (zh) | 2019-03-12 |
| CN109461698B (zh) | 2024-04-12 |
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