TWI785229B - 單斜晶氧化鋯系奈米粒子及分散液 - Google Patents
單斜晶氧化鋯系奈米粒子及分散液 Download PDFInfo
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- TWI785229B TWI785229B TW108112722A TW108112722A TWI785229B TW I785229 B TWI785229 B TW I785229B TW 108112722 A TW108112722 A TW 108112722A TW 108112722 A TW108112722 A TW 108112722A TW I785229 B TWI785229 B TW I785229B
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- zirconia
- nanoparticles
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- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 title claims abstract description 356
- 239000002105 nanoparticle Substances 0.000 title claims abstract description 86
- 239000006185 dispersion Substances 0.000 title claims description 46
- 239000002245 particle Substances 0.000 claims abstract description 77
- 238000009826 distribution Methods 0.000 claims abstract description 34
- 239000000843 powder Substances 0.000 claims description 53
- 239000013078 crystal Substances 0.000 claims description 22
- 239000007788 liquid Substances 0.000 claims description 21
- 239000002904 solvent Substances 0.000 claims description 19
- 239000002270 dispersing agent Substances 0.000 claims description 18
- 239000011859 microparticle Substances 0.000 claims description 14
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 11
- 238000004458 analytical method Methods 0.000 claims description 9
- 238000000634 powder X-ray diffraction Methods 0.000 claims description 5
- 150000003014 phosphoric acid esters Chemical class 0.000 claims description 4
- 239000010419 fine particle Substances 0.000 claims description 2
- 238000002441 X-ray diffraction Methods 0.000 abstract description 7
- 239000011324 bead Substances 0.000 description 56
- 239000012071 phase Substances 0.000 description 48
- RKTYLMNFRDHKIL-UHFFFAOYSA-N copper;5,10,15,20-tetraphenylporphyrin-22,24-diide Chemical compound [Cu+2].C1=CC(C(=C2C=CC([N-]2)=C(C=2C=CC=CC=2)C=2C=CC(N=2)=C(C=2C=CC=CC=2)C2=CC=C3[N-]2)C=2C=CC=CC=2)=NC1=C3C1=CC=CC=C1 RKTYLMNFRDHKIL-UHFFFAOYSA-N 0.000 description 38
- 238000004519 manufacturing process Methods 0.000 description 26
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- 239000007858 starting material Substances 0.000 description 20
- 238000000034 method Methods 0.000 description 14
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 12
- 230000000052 comparative effect Effects 0.000 description 11
- 239000011248 coating agent Substances 0.000 description 10
- 239000000463 material Substances 0.000 description 10
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- 239000000523 sample Substances 0.000 description 8
- 238000001069 Raman spectroscopy Methods 0.000 description 7
- 239000007822 coupling agent Substances 0.000 description 7
- 239000002994 raw material Substances 0.000 description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
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- 238000000576 coating method Methods 0.000 description 6
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- 238000002003 electron diffraction Methods 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 4
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 4
- 125000000524 functional group Chemical group 0.000 description 4
- 229910052809 inorganic oxide Inorganic materials 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 229910052726 zirconium Inorganic materials 0.000 description 4
- 238000001237 Raman spectrum Methods 0.000 description 3
- 125000000129 anionic group Chemical group 0.000 description 3
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 3
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- 125000005641 methacryl group Chemical group 0.000 description 3
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- 229920005989 resin Polymers 0.000 description 3
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- ZAFNJMIOTHYJRJ-UHFFFAOYSA-N Diisopropyl ether Chemical compound CC(C)OC(C)C ZAFNJMIOTHYJRJ-UHFFFAOYSA-N 0.000 description 2
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 2
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 241000204667 Thermoplasma Species 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
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- 125000003277 amino group Chemical group 0.000 description 2
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- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- 229910010272 inorganic material Inorganic materials 0.000 description 2
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- 239000005453 ketone based solvent Substances 0.000 description 2
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- 230000008018 melting Effects 0.000 description 2
- 238000007500 overflow downdraw method Methods 0.000 description 2
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 2
- LLHKCFNBLRBOGN-UHFFFAOYSA-N propylene glycol methyl ether acetate Chemical compound COCC(C)OC(C)=O LLHKCFNBLRBOGN-UHFFFAOYSA-N 0.000 description 2
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- 239000000243 solution Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 125000003396 thiol group Chemical group [H]S* 0.000 description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
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- 238000004438 BET method Methods 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 229910052581 Si3N4 Inorganic materials 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- NRTOMJZYCJJWKI-UHFFFAOYSA-N Titanium nitride Chemical compound [Ti]#N NRTOMJZYCJJWKI-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 230000004931 aggregating effect Effects 0.000 description 1
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- 238000004220 aggregation Methods 0.000 description 1
- 150000004703 alkoxides Chemical class 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
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- QHIWVLPBUQWDMQ-UHFFFAOYSA-N butyl prop-2-enoate;methyl 2-methylprop-2-enoate;prop-2-enoic acid Chemical compound OC(=O)C=C.COC(=O)C(C)=C.CCCCOC(=O)C=C QHIWVLPBUQWDMQ-UHFFFAOYSA-N 0.000 description 1
- 125000001951 carbamoylamino group Chemical group C(N)(=O)N* 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
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- 150000001875 compounds Chemical class 0.000 description 1
- 239000000112 cooling gas Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
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- 238000002296 dynamic light scattering Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 125000000219 ethylidene group Chemical group [H]C(=[*])C([H])([H])[H] 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 230000005284 excitation Effects 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
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- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 1
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical group OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
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- 239000002609 medium Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
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- 238000006386 neutralization reaction Methods 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
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- 229910000077 silane Inorganic materials 0.000 description 1
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
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- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
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- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
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- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
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- 239000010937 tungsten Substances 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000013585 weight reducing agent Substances 0.000 description 1
- 150000003754 zirconium Chemical class 0.000 description 1
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2016257519 | 2016-12-31 | ||
| JP2016-257519 | 2016-12-31 | ||
| JP2017063994A JP6543433B2 (ja) | 2016-12-31 | 2017-03-28 | ジルコニア系ナノ粒子の製造方法 |
| JP2017-063994 | 2017-03-28 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW201932416A TW201932416A (zh) | 2019-08-16 |
| TWI785229B true TWI785229B (zh) | 2022-12-01 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW108112722A TWI785229B (zh) | 2016-12-31 | 2017-04-05 | 單斜晶氧化鋯系奈米粒子及分散液 |
| TW106111331A TWI673235B (zh) | 2016-12-31 | 2017-04-05 | 單斜晶氧化鋯系奈米粒子及其製造方法 |
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| TW106111331A TWI673235B (zh) | 2016-12-31 | 2017-04-05 | 單斜晶氧化鋯系奈米粒子及其製造方法 |
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| JP (2) | JP6543433B2 (enExample) |
| TW (2) | TWI785229B (enExample) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3921292A1 (en) * | 2019-02-05 | 2021-12-15 | Magnesium Elektron Limited | Zirconia dispersion for use in forming nano ceramics |
| WO2020179900A1 (ja) * | 2019-03-06 | 2020-09-10 | 国立大学法人東北大学 | セラミックス部材およびその製造方法 |
| EP3960721A4 (en) * | 2019-04-25 | 2023-01-25 | Tosoh Corporation | SINTERED BODIES, POWDER AND METHOD OF MAKING THEREOF |
| US12441623B2 (en) * | 2019-05-22 | 2025-10-14 | Nippon Shokubai Co., Ltd. | Zirconium oxide nanoparticles, dispersion liquid and resin composition |
| JP2025034735A (ja) * | 2023-08-31 | 2025-03-13 | 住友大阪セメント株式会社 | 組成物、多孔質膜、基材付き多孔質膜 |
| CN118725624B (zh) * | 2024-07-10 | 2026-04-14 | 山东国瓷功能材料股份有限公司 | 一种氧化锆分散液及其制备方法与应用 |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103987800A (zh) * | 2011-12-30 | 2014-08-13 | 埃西勒国际通用光学公司 | 含氧化锆颗粒胶态悬浮体用于光学物品的涂层组合物 |
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| JP4399592B2 (ja) * | 2004-03-10 | 2010-01-20 | 独立行政法人産業技術総合研究所 | 酸化ジルコニウム結晶粒子とその製造方法 |
| WO2009088043A1 (ja) * | 2008-01-09 | 2009-07-16 | Asahi Glass Company, Limited | 表面修飾ジルコニア粒子、その製造方法及び樹脂組成物 |
| JP2010111536A (ja) * | 2008-11-05 | 2010-05-20 | Osaka Univ | 金属酸化物分散液およびその製造方法 |
| JP5447916B2 (ja) * | 2009-02-17 | 2014-03-19 | Ｄｉｃ株式会社 | 無機酸化物微粒子含有樹脂組成物および該組成物から得られる硬化物 |
| EP2958858B1 (en) * | 2012-12-26 | 2020-11-25 | Essilor International | Method for producing zirconia colloids |
| JP6025701B2 (ja) * | 2013-12-18 | 2016-11-16 | レジノカラー工業株式会社 | 酸化ジルコニウム粒子の非アルコール有機溶媒分散液とその製造方法 |
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- 2017-03-28 JP JP2017063994A patent/JP6543433B2/ja active Active
- 2017-04-05 TW TW108112722A patent/TWI785229B/zh active
- 2017-04-05 TW TW106111331A patent/TWI673235B/zh active
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Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103987800A (zh) * | 2011-12-30 | 2014-08-13 | 埃西勒国际通用光学公司 | 含氧化锆颗粒胶态悬浮体用于光学物品的涂层组合物 |
Also Published As
| Publication number | Publication date |
|---|---|
| TW201825402A (zh) | 2018-07-16 |
| JP2018108914A (ja) | 2018-07-12 |
| TW201932416A (zh) | 2019-08-16 |
| JP6543433B2 (ja) | 2019-07-10 |
| JP2019147733A (ja) | 2019-09-05 |
| JP6959290B2 (ja) | 2021-11-02 |
| TWI673235B (zh) | 2019-10-01 |
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